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  1. Correspondence on “Water‐Derived Radical Species Initiate Six‐Electron Oxidation of Cyclic Ketones in Microdroplets” Angew. Chem. Int. Ed . 2026, e1888676
  2. Correspondence on “Water‐Derived Radical Species Initiate Six‐Electron Oxidation of Cyclic Ketones in Microdroplets” Angew. Chem. Int. Ed . 2026, e1888676
  3. Comment on “Radical-mediated proton transfer enables hydroxyl radical formation in charge-delocalized water” by R. Zhao, Q. Zhang, N. Yang, L. Li, Z. Li and C. Cui, Chem. Sci. , 2025, <...
  4. Water droplets, H2O2, electric fields, solvation, e−aq, and H2O•+
  5. Syntheses of peroxynitrite, product of the reaction of superoxide with nitrogen monoxide
  6. Was H2O2 generated before oxygenic photosynthesis?
  7. Possible formation of trioxidocarbonate(•1−) (CO3•−) instead of hydroxyl radical (HO•) from superoxide anions (O2•−) during paraquat poisoning under physiological conditions
  8. Was hydrogen peroxide present before the arrival of oxygenic photosynthesis? The important role of iron(II) in the Archean ocean
  9. A century of the Warburg effect
  10. The Warburg effect – Discovered 100 years ago
  11. Superoxide does not react with hydrogen peroxide in water.
  12. The reaction of hydrogen peroxide with iron(II)
  13. Fe(I) is not involved in the Fenton reaction
  14. The yield of radicals from the reaction of ONOO- with CO2 decreases at higher CO2 concentrations
  15. Superoxide does not react with hydrogen peroxide.
  16. A guide to reactions of iron
  17. The iron bolt is an award given during the Gordon Oxyradical Conference.
  18. Peroxynitrite forms very rapidly an adduct with CO2, which decays by reacting with a 2nd CO2
  19. Discovery and importance of hydrogen peroxide
  20. Rapid reduction of the oxyform of cytochrome P450 by a hydrated electron
  21. Autoxidation of NO
  22. Introduction for the special issue on the chemistry of redox signaling
  23. Limits on the reactions of sulfur-containing biomolecules
  24. Element names
  25. Electrode Potentials ofl-Tryptophan,l-Tyrosine, 3-Nitro-l-tyrosine, 2,3-Difluoro-l-tyrosine, and 2,3,5-Trifluoro-l-tyrosine
  26. The title says it all.
  27. History of hydrogen peroxide
  28. Primary photochemistry of peroxynitrite in aqueous solution
  29. Superoxide-mediated post-translational modification of tyrosine residues
  30. Corrigendum to “Rapid reaction of superoxide with insulin-tyrosyl radicals to generate a hydroperoxide with subsequent glutathione addition” [Free Radic. Biol. Med. 70 (2014) 86–95]
  31. Redox Properties and Activity of Iron–Citrate Complexes: Evidence for Redox Cycling
  32. Protein thiyl radical reactions and product formation: a kinetic simulation
  33. Concurrent Cooperativity and Substrate Inhibition in the Epoxidation of Carbamazepine by Cytochrome P450 3A4 Active Site Mutants Inspired by Molecular Dynamics Simulations
  34. Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)
  35. CHAPTER 1. Peroxynitrite: The Basics
  36. Iron(II) binding by cereal beta-glucan
  37. ONOOH does not react with H2: Potential beneficial effects of H2 as an antioxidant by selective reaction with hydroxyl radicals and peroxynitrite
  38. Why Selenocysteine Replaces Cysteine in Thioredoxin Reductase: A Radical Hypothesis
  39. Rapid reaction of superoxide with insulin-tyrosyl radicals to generate a hydroperoxide with subsequent glutathione addition
  40. The kinetics of the reaction of nitrogen dioxide with iron(II)- and iron(III) cytochrome c
  41. Intramolecular 1,2‐ and 1,3‐Hydrogen Transfer Reactions of Thiyl Radicals
  42. Repair of Protein Radicals by Antioxidants
  43. Standard electrode potentials involving radicals in aqueous solution: inorganic radicals
  44. The complex interplay of iron metabolism, reactive oxygen species, and reactive nitrogen species: Insights into the potential of various iron therapies to induce oxidative and nitrosative stress
  45. Cytochrome c and superoxide
  46. Reactions of the tetraoxidosulfate(˙−) and hydroxyl radicals with poly(sodium α-methylstyrene sulfonate)
  47. Decomposition kinetics of peroxynitrite: influence of pH and buffer
  48. Efficient depletion of ascorbate by amino acid and protein radicals under oxidative stress
  49. Chemical Characterization of the Smallest S -Nitrosothiol, HSNO; Cellular Cross-talk of H 2 S and S -Nitros...
  50. Hydrogen Exchange Equilibria in Thiols
  51. Nitrosation, Thiols, and Hemoglobin: Energetics and Kinetics
  52. Fast repair of protein radicals by urate
  53. Reversible Hydrogen Transfer Reactions in Thiyl Radicals From Cysteine and Related Molecules: Absolute Kinetics and Equilibrium Constants Determined by Pulse Radiolysis
  54. Peroxynitrous acid: controversy and consensus surrounding an enigmatic oxidant
  55. Kinetic Simulation of the Chemical Stabilization Mechanism in Fuel Cell Membranes Using Cerium and Manganese Redox Couples
  56. Erratum: Otto Warburg's contributions to current concepts of cancer metabolism
  57. Otto Warburg's contributions to current concepts of cancer metabolism
  58. Why do fuel cell membranes break down?
  59. Water increases rates of epoxidation by Mn(iii)porphyrins/imidazole/IO4− in CH2Cl2. Analogy with peroxidase and chlorite dismutase
  60. Radicals in Fuel Cell Membranes: Mechanisms of Formation and Ionomer Attack
  61. Radical (HO●, H● and HOO●) Formation and Ionomer Degradation in Polymer Electrolyte Fuel Cells
  62. Distance-Dependent Diffusion-Controlled Reaction of •NO and O2•− at Chemical Equilibrium with ONOO−
  63. Hydrogen Exchange Equilibria in Glutathione Radicals: Rate Constants
  64. Selenium and Sulfur in Exchange Reactions: A Comparative Study
  65. Electrode potentials of partially reduced oxygen species, from dioxygen to water
  66. Reduction of protein radicals by GSH and ascorbate: potential biological significance
  67. Why do proteins use selenocysteine instead of cysteine?
  68. Damage to fuel cell membranes. Reaction of HO˙ with an oligomer of poly(sodium styrene sulfonate) and subsequent reaction with O2
  69. Photon-Initiated Homolysis of Peroxynitrous Acid
  70. Intermediates in the Autoxidation of Nitrogen Monoxide
  71. Efficient repair of protein radicals by ascorbate
  72. Peroxynitrate is formed rapidly during decomposition of peroxynitrite at neutral pH
  73. Preparation and Properties of Lithium and Sodium Peroxynitrite
  74. Reversible Intramolecular Hydrogen Transfer between Cysteine Thiyl Radicals and Glycine and Alanine in Model Peptides: Absolute Rate Constants Derived from Pulse Radiolysis and Laser Flash Photolysis
  75. Kinetics of Tyrosyl Radical Reduction by Selenocysteine
  76. Antioxidant Nanoreactor Based on Superoxide Dismutase Encapsulated in Superoxide-Permeable Vesicles
  77. Homolysis of the Peroxynitrite Anion Detected with Permanganate
  78. Two Pathways of Carbon Dioxide Catalyzed Oxidative Coupling of Phenol by Peroxynitrite
  79. The glutathione thiyl radical does not react with nitrogen monoxide
  80. Oxygen Activation by Cytochrome P450:  A Thermodynamic Analysis
  81. Oxidation-state-dependent reactions of cytochrome c with the trioxidocarbonate(•1−) radical: a pulse radiolysis study
  82. Fenton Chemistry and Iron Chelation under Physiologically Relevant Conditions:  Electrochemistry and Kinetics
  83. Catalysis of Electron Transfer by Selenocysteine
  84. Two Pathways of Carbon Dioxide Catalyzed Oxidative Coupling of Phenol by Peroxynitrite
  85. Dissociation of CP20 from Iron(II)(cp20)3: A Pulse Radiolysis Study
  86. The kinetics of oxidation of GSH by protein radicals
  87. Corrigendum to “Kinetics properties of Cu,Zn-superoxide dismutase as a function of metal content” [Arch. Biochem. Biophys. 439 (2005) 234–240]
  88. Redox cycling of iron complexes of N-(dithiocarboxy)sarcosine and N-methyl-d-glucamine dithiocarbamate
  89. Peroxynitrite efficiently mediates the interconversion of redox intermediates of myeloperoxidase
  90. Inhibition of the Fenton reaction by nitrogen monoxide
  91. Kinetics properties of Cu,Zn-superoxide dismutase as a function of metal content
  92. Chemiluminescence of Pholasin caused by peroxynitrite
  93. Peroxynitritometal complexes
  94. On the Chemical and Electrochemical One-Electron Reduction of Peroxynitrous Acid
  95. The history of naming elements.
  96. Qualitative and Quantitative Determination of Nitrite and Nitrate with Ion Chromatography
  97. Intramolecular addition of cysteine thiyl radicals to phenylalanine in peptides: formation of cyclohexadienyl type radicals
  98. Calmodulin methionine residues are targets for one-electron oxidation by hydroxyl radicals: formation of S∴N three-electron bonded radical complexes
  99. Redox Properties of the Iron Complexes of Orally Active Iron Chelators CP20, CP502, CP509, and ICL670
  100. Preventing Nitrite Contamination in Tetramethylammonium Peroxynitrite Solutions
  101. UV Photolysis of 3-Nitrotyrosine Generates Highly Oxidizing Species:  A Potential Source of Photooxidative Stress
  102. Human peroxiredoxin 5 is a peroxynitrite reductase
  103. Kinetics Evidence for a Complex between Peroxynitrous Acid and Titanium(IV)
  104. The mechanisms of S-nitrosothiol decomposition catalyzed by iron
  105. Mechanistic insight into the peroxidase catalyzed nitration of tyrosine derivatives by nitrite and hydrogen peroxide
  106. Rapid scavenging of peroxynitrous acid by monohydroascorbate
  107. Evaluation of Activation Volumes for the Conversion of Peroxynitrous to Nitric Acid
  108. Peroxynitrite-mediated oxidation of dichlorodihydrofluorescein and dihydrorhodamine
  109. Oxidation of Nitrite by Peroxynitrous Acid
  110. Peroxynitrous Acid ‐ Where is the Hydroxyl Radical?
  111. Erratum to “NO Nomenclature?” [Nitric Oxide 6 (2002), 96–98]
  112. The Rate Constant of the Reaction of Superoxide with Nitrogen Monoxide:  Approaching the Diffusion Limit
  113. The Haber-Weiss cycle—71 years later
  114. NO Nomenclature?
  115. Studies of metal-binding properties of Cu,Zn superoxide dismutase by isothermal titration calorimetry
  116. Naming of new elements(IUPAC Recommendations 2002)
  117. Product Distribution of Peroxynitrite Decay as a Function of pH, Temperature, and Concentration
  118. 100 Years of peroxynitrite chemistry and 11 years of peroxynitrite biochemistry
  119. Hydrolysis and Photolysis of Tris(tetraethylammonium) Pentacyanoperoxynitritocobaltate(III): Evidence for a Novel Complex, Pentacyanonitratocobaltate(III)
  120. Oxidation of NADH by Chloramines and Chloramides and Its Activation by Iodide and by Tertiary Amines
  121. The Haber-Weiss cycle – 70 years later
  122. Reaction of peroxynitrite with carbon dioxide: intermediates and determination of the yield of CO3 •– and NO2 •
  123. On the Oxidation of Cytochrome c by Hypohalous Acids
  124. Gibbs Energy of Formation of Peroxynitrite
  125. Names for muonium and hydrogen atoms and their ions(IUPAC Recommendations 2001)
  126. Reactions of Peroxynitrite with Phenolic and Carbonyl Compounds: Flavonoids are not Scavengers of Peroxynitrite
  127. Peroxynitrite does not decompose to singlet oxygen ( 1 Δ g O 2 ) and nitroxyl (NO − )
  128. On the Irreversible Destruction of Reduced Nicotinamide Nucleotides by Hypohalous Acids
  129. The Preparation of Apo-Cu,Zn Superoxide Dismutase by Ion-Exchange Chromatography on Iminodiacetic Acid–Sepharose
  130. The Quantitative Oxidation of Methionine to Methionine Sulfoxide by Peroxynitrite
  131. Mechanism of Reaction of Myeloperoxidase with Nitrite
  132. Synthesis and Characterization of Tris(tetraethylammonium) Pentacyanoperoxynitritocobaltate(III)
  133. Names for inorganic radicals (IUPAC Recommendations 2000)
  134. Conformation of Peroxynitrite:  Determination by Crystallographic Analysis
  135. Correspondence
  136. [36] Peroxynitrite studied by stopped-flow spectroscopy
  137. Kinetic Study of the Reaction of Glutathione Peroxidase with Peroxynitrite
  138. Peroxynitrite Uncloaked? Volume 11, Number 7, July 1998, pp 716−717
  139. The basic chemistry of nitrogen monoxide and peroxynitrite
  140. Peroxynitrite Uncloaked?
  141. The chemistry of peroxynitrite, a biological toxin
  142. Formation and Properties of Peroxynitrite as Studied by Laser Flash Photolysis, High-Pressure Stopped-Flow Technique, and Pulse Radiolysis Volume 10, Number 11, November 1997, pp 1285−1292
  143. The Reaction of Peroxynitrite with Zeaxanthin
  144. Can ONOOH Undergo Homolysis?
  145. Hydrogen Isotope Effect on the Isomerization of Peroxynitrous Acid
  146. Formation and Properties of Peroxynitrite as Studied by Laser Flash Photolysis, High-Pressure Stopped-Flow Technique, and Pulse Radiolysis
  147. Kinetic study of the reaction of ebselen with peroxynitrite
  148. Nitric oxide, superoxide, and peroxynitrite: the good, the bad, and ugly
  149. Reaction of peroxynitrite with L-tryptophan
  150. The enthalpy of isomerization of peroxynitrite to nitrate
  151. [27] Syntheses of peroxynitrite: To go with the flow or on solid grounds?
  152. Nitration and Hydroxylation of Phenolic Compounds by Peroxynitrite
  153. Ab Initio and NMR Study of Peroxynitrite and Peroxynitrous Acid:  Important Biological Oxidants
  154. Thermodynamics of reactions involving nitrogen-oxygen compounds
  155. Say NO to nitric oxide: Nomenclature for nitrogen- and oxygen-containing compounds
  156. [18] Nitration and hydroxylation of phenolic compounds by peroxynitrite
  157. A Novel Hexanuclear FeIII‐cis‐Inositolato Complex as a Model for FeIII–Polyol Interactions in Aqueous Solution
  158. Ein neuartiger sechskerniger FeIII‐cis‐Inositolato‐Komplex als Modell für FeIII‐Polyol‐Wechselwirkungen in wäßriger Lösung
  159. A practical method for preparing peroxynitrite solutions of low ionic strength and free of hydrogen peroxide
  160. The kinetics of the oxidation of l-ascorbic acid by peroxynitrite
  161. Thermodynamic considerations on the formation of reactive species from hypochlorite, superoxide and nitrogen monoxide Could nitrosyl chloride be produced by neutrophils and macrophages?
  162. On the pH-dependent yield of hydroxyl radical products from peroxynitrite
  163. The hazard of hydroxyl radicals, a reply
  164. NO comments
  165. Chemistry of iron and copper in radical reactions
  166. The centennial of the Fenton reaction
  167. The nitration and hydroxylation of phenol and salicylic acid by peroxynitrite
  168. ALS, SOD and peroxynitrite
  169. Ferredoxin binding site on ferredoxin: NADP+ reductase
  170. Binding of ferredoxin to ferredoxin: NADP+ oxidoreductase: The role of carboxyl groups, electrostatic surface potential, and molecular dipole moment
  171. Ab initio calculations on ONOOH and ONOO?
  172. A thermodynamic appraisal of the radical sink hypothesis
  173. Peroxynitrite, a cloaked oxidant formed by nitric oxide and superoxide
  174. The quality of nutrition letters in free radical biology & medicine: A reply
  175. A small point
  176. The hydroxylation of tryptophan
  177. The hydroxylation of phenylalanine and tyrosine: A comparison with salicylate and tryptophan
  178. Spirohydantoin inhibitors of aldose reductase inhibit iron- and copper-catalysed ascorbate oxidation in vitro
  179. The superoxide dismutase activities of two higher-valent manganese complexes, MnIV desferrioxamine and MnIII cyclam
  180. Reactions of Fe(II)‐ATP and Fe(II)‐citrate complexes with t‐butyl hydroperoxide and cumyl hydroperoxide
  181. TRANSITION METALS IN OXIDATIVE STRESS: AN OVERVIEW
  182. CATALYSIS OF OXYRADICAL REACTIONS BY IRON COMPLEXES
  183. Oxyradicals and multivitamin tablets
  184. Thermodynamic considerations on the generation of hydroxyl radicals from nitrous oxide—No laughing matter
  185. Reactions of Fe(II)‐ATP and Fe(II)‐citrate complexes with t‐butyl hydroperoxide and cumyl hydroperoxide
  186. Oxyradical reactions: from bond‐dissociation energies to reduction potentials
  187. Reactions of iron(II) nucleotide complexes with hydrogen peroxide
  188. What is in a name? Rules for radicals
  189. Catalysis of oxyradical reactions by iron
  190. [12] Distinction between hydroxyl radical and ferryl species
  191. The hydroxylation of the salicylate anion by a fenton reaction and Γ-radiolysis: A consideration of the respective mechanisms
  192. Electron affinity of chlorine dioxide
  193. Hormesis
  194. Electrostatic interactions of 4-carboxy-2,6-dinitrophenyllysine-modified cytochromes c with physiological and non-physiological redox partners
  195. The electron-transfer site of spinach plastocyanin
  196. Reactions of iron(II) nitrilotriacetate and iron(II) ethylenediamine-N,N'-diacetate complexes with hydrogen peroxide
  197. Thermodynamics of reactions involving oxyradicals and hydrogen peroxide
  198. Reduction potential of the carbon dioxide/carbon dioxide radical anion: a comparison with other C1 radicals
  199. Effect of a dipole moment on the ionic strength dependence of electron-transfer reactions of cytochrome c
  200. The reaction between ferrous polyaminocarboxylate complexes and hydrogen peroxide: An investigation of the reaction intermediates by stopped flow spectrophotometry
  201. Effects of γ-irradiation on Isolated Rat Liver Mitochondria
  202. In vitro damage to rat lens by xanthine-xanthine oxidase: Protection by ascorbate
  203. Catalysis of superoxide dismutation by manganese aminopolycarboxylate complexes
  204. Energetics of interconversion reactions of oxyradicals
  205. The reaction of ferrous EDTA with hydrogen peroxide: Evidence against hydroxyl radical formation
  206. The Radiation Chemistry of Cytochrome c
  207. The oxidizing nature of the hydroxyl radical. A comparison with the ferryl ion (FeO2+)
  208. Is cytochrome c reactivity determined by dipole moment or by local charges?
  209. CHEMIOSMOTIC ATPase MECHANISMS
  210. The reduction potential of the couple O3/O·−3
  211. The Relation between the Dipole Moment of Cytochrome c and the Activity with Cytochrome c Reductase and Cytochrome c Oxidase
  212. Basic issues in binding
  213. Use of singly modified cytochrome c derivatives to determine the site for electron transfer in reactions with inorganic complexes
  214. Effect of a molecular dipole on the ionic strength dependence of a biomolecular rate constant. Identification of the site of reaction
  215. THE HABER‐WEISS CYCLE
  216. The electric potential field around cytochrome c and the effect of ionic strength on reaction rates of horse cytochrome c
  217. A tunnelling model to explain the reduction of ferricytochrome c by H and OH radicals
  218. EFFECTS OF ANIONS ON THE REACTION BETWEEN CYTOCHROME c AND CYTOCHROME c OXIDASE
  219. Mechanism of reactions involving singlet oxygen and the superoxide anion
  220. Mechanism of the reaction of hydrated electrons with ferrocytochrome c
  221. Erratum
  222. The kinetics of the reduction of cytochrome c by the superoxide anion radical
  223. Reactions involving singlet oxygen and the superoxide anion