All Stories

  1. How metal ions link in metal–organic frameworks: dots, rods, sheets, and 3D secondary building units exemplified by a Y(iii) 4,4′-oxydibenzoate
  2. Site Selective Boron Directed Ortho Benzylation of N-Aryl Amides: Access to Structurally Diversified Dibenzoazepines
  3. Effects of Alkyl Spacer Length in Carbazole‐Based Self‐Assembled Monolayer Materials on Molecular Conformation and Organic Solar Cell Performance
  4. The Open and Closed Forms of a Perfluoro Diarylethene Photoswitch─Halogen Bonding, Network Topology, and CSD Analysis
  5. Polymorphism of Bis(benzimidazole)bis(thiocyanato-N)cobalt(II) and Its Relevance to Studies of the Chief Color Test for Cocaine
  6. A single site catalyst supported in mesoporous UiO-66 for catalytic conversion of carbon dioxide to formate
  7. Synthesis of Metal–Organic Frameworks through Enzymatically Recycled Polyethylene Terephthalate
  8. Photochemical Access to Substituted β-Lactams and β-Lactones via the Zimmerman–O’Connell–Griffin Rearrangement
  9. Hydrogenation of Carbon Dioxide to Formate by Noble Metal Catalysts Supported on a Chemically Stable Lanthanum Rod-Metal–Organic Framework
  10. Boron-Powered Halogenation for Precise C-Halogen Bonding in Amides and Ureas
  11. A hexagon based Mn(ii) rod metal–organic framework – structure, SF6gas sorption, magnetism and electrochemistry
  12. Synthesis, structure and magnetic properties of two bis(oxalato)cuprate(ii) salts with pyridinium type counter ions
  13. Synthesis, structure diversity, and antimicrobial studies of Ag(i) complexes with quinoline-type ligands
  14. Tuning the topology of a 2D metal–organic framework from 2D to 3D using modulator assisted synthesis
  15. Pore size effect of 1,3,6,8-tetrakis(4-carboxyphenyl)pyrene-based metal-organic frameworks for enhanced SF6 adsorption with high selectivity
  16. Heterometallic {Fe18M6} (M = Y, Gd, Dy) Pivalate Wheels Display Solvent-Induced Polymorphism
  17. Chiral Lanthanum Metal–Organic Framework with Gated CO2 Sorption and Concerted Framework Flexibility
  18. Octanuclear heterometallic FeIII-CeIV pivalate clusters: From a close {Fe4Ce4(μ4-O)4} cage to an open {Fe4Ce4(μ4-O)2(μ3-O)2} core
  19. A Robust and Biocompatible Bismuth Ellagate MOF Synthesized Under Green Ambient Conditions
  20. Metal-Organic Frameworks
  21. Metal–Organic Frameworks with Hexakis(4-carboxyphenyl)benzene: Extensions to Reticular Chemistry and Introducing Foldable Nets
  22. Cyclometalation of lanthanum(iii) based MOF for catalytic hydrogenation of carbon dioxide to formate
  23. Elements of X
  24. Natural and synthetic metal oxalates – a topology approach
  25. Mark Your Calendar
  26. Lignin Based Molecular Materials – a Zinc Vanillate with a Hydrogen Bonded 4‐ and 8‐connected Net with a New Topology
  27. Mark Your Calendar
  28. Conformational chiral polymorphism in cis-bis-triphenylphosphine complexes of transition metals
  29. Elucidation of the elusive structure and formula of the active pharmaceutical ingredient bismuth subgallate by continuous rotation electron diffraction
  30. Brief encounters with dubnium
  31. Mechanochemical Immobilisation of Metathesis Catalysts in a Metal–Organic Framework
  32. Now you see me too
  33. Designing, Describing and Disseminating New Materials by using the Network Topology Approach
  34. The Three-letter Element Symbols:
  35. Topology analysis reveals supramolecular organisation of 96 large complex ions into one geometrical object
  36. Rhodium roles
  37. Potent potassium
  38. Enhanced Synthesis of Metal-Organic Frameworks on the Surface of Electrospun Cellulose Nanofibers
  39. Let’s Talk about MOFs—Topology and Terminology of Metal-Organic Frameworks and Why We Need Them
  40. The synthesis, structure, topology and catalytic application of a novel cubane-based copper(ii) metal–organic framework derived from a flexible amido tripodal acid
  41. Towards the chemical control of molecular packing: syntheses and crystal structures of threetrans-[NiL4(NCS)2] complexes
  42. Crystal structures and hydrogen bond analysis of five amino acid conjugates of terephthalic and benzene-1,2,3-tricarboxylic acids
  43. Network topology approach to new allotropes of the group 14 elements
  44. Special Issue on Metal-Organic Frameworks, Porous Coordination Polymers and Zeolites
  45. Metal-ligand bond lengths and strengths: are they correlated? A detailed CSD analysis
  46. Single-Crystal-to-Single-Crystal Transformation of a Novel 2-Fold Interpenetrated Cadmium-Organic Framework with Trimesate and 1,2-Bis(4-pyridyl)ethane into the Thermally Desolvated Form Which Exhibits Liquid and Gas Sorption Properties
  47. Effects of Different Substituents on the Crystal Structures and Antimicrobial Activities of Six Ag(I) Quinoline Compounds
  48. Concomitant Metal Organic Frameworks of Cobalt(II) and 3-(4-Pyridyl)benzoate: Optimized Synthetic Conditions of Solvatochromic and Thermochromic Systems
  49. A new methanol solvate and Hirshfeld analysis of π-stacking in 2,3,6,7,10,11-hexahydroxytriphenylene solvates
  50. Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013)
  51. Preparation of potentially porous, chiral organometallic materials through spontaneous resolution of pincer palladium conformers
  52. Terminology for Coordination Polymers and MOFs
  53. Topological studies of three related metal-organic frameworks of GdIII and 5-nitroisophthalate
  54. 2,3,6,7,10,11-Hexamethoxytriphenylene (HMTP): A new organic cathode material for lithium batteries
  55. Network and Graph Set Analysis
  56. Coordination polymers, metal–organic frameworks and the need for terminology guidelines
  57. Synthetic and crystallographic studies of bicyclo[3.3.1]nonane derivatives: from strong to weak hydrogen bonds and the stereochemistry of network formation
  58. Neutral Organometallic Halogen Bond Acceptors: Halogen Bonding in Complexes of PCPPdX (X = Cl, Br, I) with Iodine (I2), 1,4-Diiodotetrafluorobenzene (F4DIBz), and 1,4-Diiodooctafluorobutane (F8DIBu)
  59. Vinylimidazole copolymers: coordination chemistry, solubility, and cross-linking as function of Cu2+ and Zn2+ complexation
  60. 2D Bipyrimidine silver(I) nitrate: Synthesis, X-ray structure, solution chemistry and anti-microbial activity
  61. 2,3,6,7,10,11-Hexahydroxytriphenylene tetrahydrate: a new form of an important starting material for supramolecular chemistry and covalent organic frameworks
  62. Bis 4,5-diazafluoren-9-one silver(i) nitrate: synthesis, X-ray structures, solution chemistry, hydrogel loading, DNA coupling and anti-bacterial screening
  63. Multi-component self-assembly of molecule based materials by coordination networks and weak intermolecular synthons
  64. The coordination polymer poly[(μ3-3-aminocarbonylpyrazine-2-carboxylato-κ3N1:O2:O2′)silver(I)]
  65. Synthesis, Crystal Structure, Quantum Chemical Calculations, DNA Interactions, and Antimicrobial Activity of [Ag(2-amino-3-methylpyridine)2]NO3 and [Ag(pyridine-2-carboxaldoxime)NO3]
  66. Family of Isoreticular Chiral Metal−Organic Frameworks Based on Coordination and Hydrogen Bonds in [M[Co(ethylenediamine)(oxalato) 2 ] 2 ]
  67. Anionic zinc-trimesic acid MOFs with unusual topologies: Reversible hydration studies
  68. Synthesis, X-ray structure and anti-corrosion activity of two silver(I) pyrazino complexes
  69. New Topology in Azide-Bridged Cobalt(II) Complexes: the Weak Ferromagnet [Co2(N3)4(Hexamethylenetetramine)(H2O)]n
  70. Oxalate- and Squarate-Biimidazole Supramolecular Synthons: Hydrogen-Bonded Networks Based on [Co(H2biimidazole)3]3+
  71. Two 2-D copper(II) azido compounds: catena -poly[ di -μ1,1- azido, di -μN,O-(quinolinecarboxylato)(aqua)copper(II)] and 1-D catena -poly[ di -μN,N′-(quinoxaline)copper(II)nitrate]
  72. Network analysis of barium oxalates Ba(C2O4)m(HC2O4)n(H2C2O4)p(H2O)q, including the new, uniform, five-connected loh net
  73. Methyl groups control coordination number, stoichiometry, network and magnetism in a Cu(ii)-azide-pyrazine (6,3) 2D net
  74. Network analysis of bicyclo[3.3.1]nonanes: the diol, the dione and the acetal
  75. Syntheses, structure, and magnetic properties of extended structured Cr(II) pentacyanopropenide compounds
  76. Synthesis, EPR and DFT calculations of rare Ag(II)porphyrins and the crystal structure of [Zn(II)tetrakis(4-bromo-2-thiophene)porphyrin]
  77. The role of intermolecular interactions in the assemblies of FeII and CoII tetrakis-isothiocyanatometalates with tris(1,10-phenanthroline)-RuII: Crystal structures of two dual-metal assemblies featuring octahedral cationic and tetrahedral anionic modules
  78. An interpenetrating primitive cubic net formed by hydrogen bonds and coordination bonds incatena-poly[[bis(methanol-κO)bis(thiocyanato-κN)iron(II)]-μ-1,2-bis(4-pyridylmethylene)hydrazine-κ2N:N′]
  79. A three-dimensional net of Δ-tris(1,10-phenanthroline)ruthenium(II) in the dual-metal self-assembly of bis[tris(1,10-phenanthroline)ruthenium(II)] tetraisothiocyanatoiron(II) bis(perchlorate)
  80. An unusual 3D-topology and dominant ferromagnetic couplings in two Cu(ii)–azide coordination polymers
  81. 1D and 2D FeII Azide Coordination Polymers with Ferromagnetic Canting
  82. Hydrogen Bond Control of Dimensionality in Organometallic {2,6-Bis[(di-t-butylphosphino)methyl]phenyl}palladium(II) Compounds:  Dimers, Chains, and a 3D-Net with an Apparent Channel Structure
  83. 1D and 3D coordination polymers with the M(μ1,μ1-X)2M motif (M=Na, Zn, Cd): Observation of a linear
  84. Synthesis and Structure of Silver Complexes with Nicotinate-Type Ligands Having Antibacterial Activities against Clinically Isolated Antibiotic Resistant Pathogens
  85. Synthesis, structure, network and thermal analysis of four 5-(pyrazinyl)tetrazolato copper(II) and cobalt(II) complexes
  86. 4,4′-(Azinodimethylene)dipyridinium bis(tetrafluoroborate) and 4-[(4-pyridylmethylene)hydrazonomethyl]pyridinium perchlorate: two different hydrogen-bonding motifs
  87. Transformations of the chameleon ligand 1,10-phenanthroline-5,6-dione/diol:cis-dichlorido(1,10-phenanthroline-5,6-dione-κ2N,N′)-trans-dipyridinecobalt(II) pyridine disolvate prepared from the diol
  88. Syntheses, crystal structures, optical limiting properties, and DFT calculations of three thiophene-2-aldazine Schiff base derivatives
  89. An Approach to Helical Tubular Self-Aggregation Using C 2 -Symmetric Self-Complementary Hydrogen-Bonding Cavity Molecules
  90. Synthesis, a case of isostructural packing, and antimicrobial activity of silver(i)quinoxaline nitrate, silver(i)(2,5-dimethylpyrazine) nitrate and two related silver aminopyridine compounds
  91. Coordination bonds and strong hydrogen bonds giving a framework material based on a 4- and 8-connected net in [Ca[Co(en)(oxalato)2]2]n
  92. A unique example of a high symmetry three- and four-connected hydrogen bonded 3D-network
  93. Can DFT calculations help the molecular designer to construct molecule based magnetic materials?
  94. New homogeneous and alternating Mn(II)-azido 1D systems
  95. Four-connected nets
  96. Nets with higher connectivity than four
  97. Why bother with nets ?
  98. Some mathematics related to 3D-nets
  99. Interpenetration - strategies and nomenclature
  100. Computational tools
  101. What is a net?
  102. Naming the nets and finding them
  103. The most common 3D-nets
  104. Three-connected nets
  105. Introduction and a short dictionary of network terminology
  106. Nets with both three- and four-connected nodes
  107. 3D-nets as specific synthetic targets - Crystal Engineering
  108. Design and Synthesis of a C 2 -Symmetric Self-Complementary Hydrogen-Bonding Cleft Molecule Based on the Bicyclo[3.3.1]nonane and 4-Oxo-5-azaindole Framework. Formation of Channels and Inclusion Complexes in the Solid State
  109. X-ray and NMR study of the fate of the Co(1,10-phenanthroline-5,6-diketone)33+ ion in aqueous solution: supramolecular motifs in the packing of 1,10-phenanthroline-5,6-diketone and 1,10-phenanthroline-5,6-diol complexes
  110. Cobalt 2,2′-biimidazole complexes co-crystallised with di-acids — synthesis, structure and quantum chemical calculations
  111. A (10,3)-b net by sulfate hydrogen-bonded biimidazolate complexes
  112. The Cyano Nitronyl Nitroxide Radical: Experimental and Theoretical Evidence for the Fourth Case of the McConnell-I Mechanism
  113. EPR Studies on a Stable Sulfinyl Radical Observed in the Iron−Oxygen-Reconstituted Y177F/I263C Protein R2 Double Mutant of Ribonucleotide Reductase from Mouse†
  114. Crucial Influence of Solvent and Chirality—The Formation of Helices and Three-Dimensional Nets by Hydrogen-Bonded Biimidazolate Complexes
  115. Cover Picture
  116. Crucial Influence of Solvent and Chirality—The Formation of Helices and Three-Dimensional Nets by Hydrogen-Bonded Biimidazolate Complexes
  117. Strong Supramolecular-Based Magnetic Exchange in π-Stacked Radicals. Structure and Magnetism of a Hydrogen-Bonded Verdazyl Radical:Hydroquinone Molecular Solid
  118. Spin Distributions, Ring Conformations, and Spiroconjugation in “Phosphaverdazyl” Radicals
  119. X-ray Structures and DFT Calculations on Rhodium−Olefin Complexes:  Comments on the103Rh NMR Shift−Stability Correlation
  120. On the structures and properties of Cr(DMSO)63+ and the coordination polymer [cis-Cr(III)(oxalate)2(DMSO)2K(DMSO)2]n
  121. On tuning the copper(I) coordination number in halocuprate(I) anions: new insights into cation control
  122. Fe−Catecholate and Fe−Oxalate Vibrations and Isotopic Substitution Shifts from DFT Quantum Chemistry
  123. Spin Density Maps in the Triplet Ground State of [Cu 2 ( t -Bupy) 4 (N 3 ) 2 ](ClO 4 ) 2 ( t -Bupy = p - tert -butylpyridine):  A Polarized Neutron Diffraction Study
  124. Protonation of π-alkene–rhodium(I) complexes leads to σ-alkyl–rhodium(III)—an NMR study
  125. Spin Density Maps for the Ferrimagnetic Chain Compound MnCu(pba)(H 2 O) 3 ·2H 2 O (pba = 1,2-Propylenebis(oxamato)):  Polarized Neutron Diffraction and Theoretical Studies
  126. The Importance of Magnetic Coupling Through Atoms with Large Spin Densities—Structure and Magnetic Properties ofmeso-Tetrakis-(4′-tert-Butylphenyl)Porphinatomanganese(III) Hexacyanobutadienide, [MnIIITtBuPP]+[C4(CN)6].-
  127. The Correlation Between Transition Metal NMR Chemical Shifts and the Stability of Coordination Compounds
  128. Quantum Chemical Approach to the Assignment of Iron−Catecholate Vibrations and Isotopic Substitution Shifts
  129. Structural and Magnetization Studies of a New (μ-Oxo)bis(μ-carboxylato)dimanganese(III) Complex with a Terminal Hydroxo Ligand
  130. Spin Density Calculations on the Tetraphenylverdazyl Radical and Two Nitroxide Radicals: First and Second Order Spin Polarization.
  131. Spin-Density Maps for an Oxamido-Bridged Mn(II)Cu(II) Binuclear Compound. Polarized Neutron Diffraction and Theoretical Studies
  132. Spin-Transition and Ferromagnetic Interactions in Copper(II) Complexes of a 3-Pyridyl-Substituted Imino Nitroxide. Dependence of the Magnetic Properties upon Crystal Packing
  133. 103Rh chemical shifts and trans influence of ligands in rhodoximes and organorhodoximes
  134. Fe-catecholate vibrations from molecular orbital calculations — isotopic labelling experiments and assignments
  135. The oxidation of [Co(edta)]2− by [Co(phen)3]3+
  136. Solution structures of [IrH2(1,5-cyclooctadiene) (bisphosphine)](CF3SO3) complexes. Homo- and heteronuclear long-range couplings from hydride and phosphorus spins to cyclooctadiene protons
  137. The Dynamic Behaviour and NMR Solution structures of complexes of the type (Bisphosphine)(cycloocta‐1,5‐diene)iridium(I) and the X‐ray crystal structure of (cycloocta‐1,5‐diene)((−)‐norphos)iridium(I) hexafluorophosphate