All Stories

  1. A redox active rod coordination polymer from tetrakis(4-carboxylic acid biphenyl)tetrathiafulvalene
  2. An Octacarboxylate-Linked Sodium Metal–Organic Framework with High Porosity
  3. Unlocking New Topologies in Zr-Based Metal–Organic Frameworks by Combining Linker Flexibility and Building Block Disorder
  4. Three-periodic nets, tilings and surfaces. A short review and new results
  5. Net-clipping as a top-down approach for the prediction of topologies of MOFs built from reduced-symmetry linkers
  6. Chiral Motifs in Highly Interpenetrated Metal–Organic Frameworks Formed from Achiral Tetrahedral Ligands**
  7. The Microscopic Diamond Anvil Cell: Stabilization of Superhard, Superconducting Carbon Allotropes at Ambient Pressure
  8. The Microscopic Diamond Anvil Cell: Stabilization of Superhard, Superconducting Carbon Allotropes at Ambient Pressure
  9. Customized Synthesis: Solvent- and Acid-Assisted Topology Evolution in Zirconium-Tetracarboxylate Frameworks
  10. Vibrational properties of graphdiynes as 2D carbon materials beyond graphene
  11. Visualization and Quantification of Geometric Diversity in Metal–Organic Frameworks
  12. Design of MOFs with Absolute Structures: A Case Study
  13. Designing All Graphdiyne Materials as Graphene Derivatives: Topologically Driven Modulation of Electronic Properties
  14. The Different Story of π Bonds
  15. High‐Throughput Electron Diffraction Reveals a Hidden Novel Metal–Organic Framework for Electrocatalysis
  16. High‐Throughput Electron Diffraction Reveals a Hidden Novel Metal–Organic Framework for Electrocatalysis
  17. CrystalGrower: a generic computer program for Monte Carlo modelling of crystal growth
  18. Size-Selective Urea-Containing Metal–Organic Frameworks as Receptors for Anions
  19. A New Group of Edge-transitive 3-Periodic Nets and Their Derived Nets for Reticular Chemistry
  20. Record Complexity in the Polycatenation of Three Porous Hydrogen-Bonded Organic Frameworks with Stepwise Adsorption Behaviors
  21. Isotopy classes for 3-periodic net embeddings
  22. New Quasicrystal Approximant in the Sc–Pd System: From Topological Data Mining to the Bench
  23. A Porous Covalent Organic Framework with Voided Square Grid Topology for Atmospheric Water Harvesting
  24. Combined DFT and geometrical–topological analysis of Li-ion conductivity in complex hydrides
  25. Breathing Metal–Organic Framework Based on Flexible Inorganic Building Units
  26. Diversifying molecular and topological space via a supramolecular solid-state synthesis: a purely organic mok net sustained by hydrogen bonds
  27. Predicting superhard materials via a machine learning informed evolutionary structure search
  28. Topochemical Synthesis of Single-Crystalline Hydrogen-Bonded Cross-Linked Organic Frameworks and Their Guest-Induced Elastic Expansion
  29. Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks
  30. Three Cationic, Nonporous CuI-Coordination Polymers: Structural Investigation and Vapor Iodine Capture
  31. Autoluminescent Metal–Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF
  32. Toward Engineering Chiral Rodlike Metal–Organic Frameworks with Rare Topologies
  33. Generating carbon schwarzites via zeolite-templating
  34. Deconstruction of Crystalline Networks into Underlying Nets: Relevance for Terminology Guidelines and Crystallographic Databases
  35. Lu5Pd4Ge8 and Lu3Pd4Ge4: Two More Germanides among Polar Intermetallics
  36. Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
  37. Distinguishing Metal–Organic Frameworks
  38. Data-driven learning and prediction of inorganic crystal structures
  39. Water-stable fluorinated metal–organic frameworks (F-MOFs) with hydrophobic properties as efficient and highly active heterogeneous catalysts in aqueous solution
  40. Topology of Intermetallic Structures: From Statistics to Rational Design
  41. Packing topology in crystals of proteins and small molecules: a comparison
  42. Two Exceptional Patterns of Helical Secondary Building Units Found in Metal–Organic Framework Structures
  43. Self-Catenated Coordination Polymers Involving Bis-pyridyl-bis-amide
  44. Extracting Crystal Chemistry from Amorphous Carbon Structures
  45. Urea Metal–Organic Frameworks for Nitro-Substituted Compounds Sensing
  46. How 2-periodic coordination networks are interweaved: entanglement isomerism and polymorphism
  47. Capture of volatile iodine by newly prepared and characterized non-porous [CuI]n-based coordination polymers
  48. A new glance on R2MGe6(R = rare earth metal, M = another metal) compounds. An experimental and theoretical study of R2PdGe6germanides
  49. The R2Pd3Ge5 (R = La–Nd, Sm) germanides: synthesis, crystal structure and symmetry reduction
  50. Homo Citans and Carbon Allotropes: For an Ethics of Citation
  51. Homo Citansund Kohlenstoffallotrope: Für eine Ethik des Zitierens
  52. Searching New Crystalline Substrates for OMBE: Topological and Energetic Aspects of Cleavable Organic Crystals
  53. Crystal structures of the new ternary stannides La3Mg4−xSn2+x and LaMg3−xSn2
  54. Metal–organic frameworks assembled from flexible alicyclic carboxylate and bipyridyl ligands for sensing of nitroaromatic explosives
  55. Spinel type twins of the new cubic Er6Zn23Ge compound
  56. Li-Filled, B-Substituted Carbon Clathrates
  57. Diorganotin(IV) complexes with 2-furancarboxylic acid hydrazone derivative of benzoylacetone: Synthesis, X-ray structure, antibacterial activity, DNA cleavage and molecular docking
  58. A Collection of Topological Types of Nanoclusters and Its Application to Icosahedron-Based Intermetallics
  59. Vacancy Ordering as a Driving Factor for Structural Changes in Ternary Germanides: The New R2Zn1–xGe6Series of Polar Intermetallics (R = Rare-Earth Metal)
  60. From zeolite nets to sp3carbon allotropes: a topology-based multiscale theoretical study
  61. Structural directing roles of isomeric phenylenediacetate ligands in the formation of coordination networks based on flexible N,N′-di(3-pyridyl)suberoamide
  62. Interpenetration of three-periodic networks in crystal structures: Description and classification methods, geometrical-topological conditions of implementation
  63. Phase equilibria in the La–Mg–Ge system at 500°C and crystal structure of the new ternary compounds La11Mg2Ge7 and LaMg3−xGe2
  64. Entangled Two-Dimensional Coordination Networks: A General Survey
  65. Applied Topological Analysis of Crystal Structures with the Program Package ToposPro
  66. Influence of the counter anion and steric hindrance of pyrazolyl and imidazolyl flexible ligands on the structure of zinc-based coordination polymers
  67. Textural properties of a large collection of computationally constructed MOFs and zeolites
  68. Stepwise formation of heteronuclear coordination networks based on quadruple-bonded dimolybdenum units containing formamidinate ligands
  69. γ-Brass Polyhedral Core in Intermetallics: The Nanocluster Model
  70. Nets with collisions (unstable nets) and crystal chemistry
  71. Influence of the counter ion on the structure of two new copper(I) coordination polymers: Synthesis, structural characterization and thermal analysis
  72. The Zeolite Conundrum: Why Are There so Many Hypothetical Zeolites and so Few Observed? A Possible Answer from the Zeolite-Type Frameworks Perceived As Packings of Tiles
  73. The asc Trinodal Platform: Two‐Step Assembly of Triangular, Tetrahedral, and Trigonal‐Prismatic Molecular Building Blocks
  74. Construction of N,N′-di(3-pyridyl)adipoamide-based Zn(ii) and Cd(ii) coordination networks by tuning the isomeric effect of polycarboxylate ligands
  75. Two C28 Clathrates
  76. A Database of Topological Representations of Polynuclear Nickel Compounds
  77. A topological method for the classification of entanglements in crystal networksA preliminary account of this work was presented at the workshop `Topological dynamics in physics and biology' held in Pisa, 12–13 July 2011.
  78. High-nuclearity cobalt coordination clusters: Synthetic, topological and magnetic aspects
  79. Insight into the SBU Condensation in Mg Coordination and Supramolecular Frameworks: A Combined Experimental and Theoretical Study
  80. Totally unimodular nets
  81. A method for topological analysis of high nuclearity coordination clusters and its application to Mn coordination compounds
  82. Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands
  83. New Ternary Germanides La4Mg5Ge6 and La4Mg7Ge6: Crystal Structure and Chemical Bonding
  84. Synthesis and characterization of new oligomeric and polymeric complexes based on the [CuII(bpca)]+ unit [Hbpca=bis(2-pyridylcarbonyl)amine]
  85. Super Flexibility of a 2D Cu-Based Porous Coordination Framework on Gas Adsorption in Comparison with a 3D Framework of Identical Composition: Framework Dimensionality-Dependent Gas Adsorptivities
  86. New Types of Multishell Nanoclusters with a Frank–Kasper Polyhedral Core in Intermetallics
  87. Interpenetrated metal–organic frameworks of self-catenated four-connected mok nets
  88. Underlying nets in three-periodic coordination polymers: topology, taxonomy and prediction from a computer-aided analysis of the Cambridge Structural Database
  89. The novel metalloligand [Fe(bppd)3] (bppd = 1,3-bis(4-pyridyl)-1,3-propanedionate) for the crystal engineering of heterometallic coordination networks with different silver salts. Anionic control of the structures
  90. Periodic-Graph Approaches in Crystal Structure Prediction
  91. Halogen-bonded and interpenetrated networks through the self-assembly of diiodoperfluoroarene and tetrapyridyl tectons
  92. Heterometallic Modular Metal–Organic 3D Frameworks Assembled via New Tris‐β‐Diketonate Metalloligands: Nanoporous Materials for Anion Exchange and Scaffolding of Selected Anionic Guests
  93. Synthesis and characterization of new tetra-substituted porphyrins with exo-donor carboxylic groups as building blocks for supramolecular architectures: Catalytic and structural studies of their metalated derivatives
  94. Natural Tilings for Zeolite-Type Frameworks
  95. Polycatenation weaves a 3D web
  96. New Metal−Organic Framework with Uninodal 4-Connected Topology Displaying Interpenetration, Self-Catenation, and Second-Order Nonlinear Optical Response
  97. Nanocluster Model of Intermetallic Compounds with Giant Unit Cells: β, β′-Mg 2 Al 3 Polymorphs
  98. Vertex-, face-, point-, Schläfli-, and Delaney-symbols in nets, polyhedra and tilings: recommended terminology
  99. Ligand dependent topology changes in six zinc coordination polymers
  100. Crystallization Behavior of Coordination Polymers. 1. Kinetic and Thermodynamic Features of 1,3-Bis(4-pyridyl)propane/MCl 2 Systems
  101. Three Lanthanum MOF Polymorphs: Insights into Kinetically and Thermodynamically Controlled Phases
  102. Topological relations between three-periodic nets. II. Binodal nets
  103. Controlling the Structure of Arenedisulfonates toward Catalytically Active Materials
  104. Ligand isomerism-controlled structural diversity of cadmium(II) perchlorate coordination polymers containing dipyridyladipoamide ligands
  105. A Short History of an Elusive Yet Ubiquitous Structure in Chemistry, Materials, and Mathematics
  106. Interpenetrated Three-Dimensional Networks of Hydrogen-Bonded Organic Species: A Systematic Analysis of the Cambridge Structural Database
  107. Dendrimeric Tectons in Halogen Bonding-Based Crystal Engineering
  108. A Rare-Earth MOF Series: Fascinating Structure, Efficient Light Emitters, and Promising Catalysts
  109. Generation of a 4-crossing [2]-catenane motif by the 2D→2D parallel interpenetration of pairs of (4,4) sheets
  110. Interpenetrated three-dimensional hydrogen-bonded networks from metal–organic molecular and one- or two-dimensional polymeric motifs
  111. Metal–organic coordination frameworks assembled with the long flexible ligand 4,4′-bis(imidazol-1-ylmethyl)biphenyl
  112. A New Polycatenated 3D Array of Interlaced 2D Brickwall Layers and 1D Molecular Ladders in [Mn 2 (bix) 3 (NO 3 ) 4 ]·2CHCl 3 [bix = 1,4-bis(imidazol-1-ylmethyl)benzene] That Undergoes Supramolecular Isomerization upon Guest Removal
  113. An Indium Layered MOF as Recyclable Lewis Acid Catalyst
  114. Double−Step Gas Sorption of a Two−Dimensional Metal−Organic Framework
  115. Three-periodic nets and tilings: natural tilings for nets
  116. Highly Interpenetrated Supramolecular Networks Supported by N⋅⋅⋅I Halogen Bonding
  117. Preparation and electrochemical behaviour of {[Ru(bipy)4Cl2Ag]NO3(CHCl3)·6H2O}n obtained from the self-assembly of trans-Ru(bipy)4Cl2 and AgNO3
  118. New metal–organic frameworks and supramolecular arrays assembled with the bent ditopic ligand 4,4-diaminodiphenylmethane
  119. What do we know about three-periodic nets?
  120. Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part II [1]. Analysis of the Inorganic Crystal Structure Database (ICSD)
  121. Four new 2D porous polymeric frames from the self-assembly of silver triflate and silver tosylate with free-base and Zn-metallated 5,10,15,20-tetra(4-pyridyl)porphyrin
  122. Parallel and Inclined (1D → 2D) Interlacing Modes in New Polyrotaxane Frameworks [M2(bix)3(SO4)2] [M = Zn(II), Cd(II); Bix = 1,4-Bis(imidazol-1-ylmethyl)benzene]
  123. The Cation as a Tool to Get Spin-Canted Three-Dimensional Iron(III) Networks
  124. Main Group Element Nets to a T
  125. Non‐Natural Eight‐Connected Solid‐State Materials: A New Coordination Chemistry
  126. A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)2(H2O)2](SO4)·7H2O [bix = 1,4-bis(imidazol-1-yl...
  127. Interpenetrating metal–organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database
  128. Supramolecular isomers in the same crystal: a new case involving two different types of layers polycatenated in the 3D architecture of [Cu(bix)2(SO4)]·7.5H2O [bix = 1,4-bis(imidazol-1-ylmethyl)benzene]
  129. An Unusual Three-Dimensional Coordination Network Formed by Parallel Polycatenation of Two-Fold Interpenetrated (6,3) Layers Based on a Novel Three-Connecting Ligand
  130. Polycatenation, polythreading and polyknotting in coordination network chemistry
  131. Design, Synthesis, and Structural Characterization of Molecular and Supramolecular Heterobimetallic Metallamacrocycles Based on the 1,1‘-Bis(4-pyridyl)ferrocene (Fe(η 5 -C 5 H 4 -1-C 5 H 4 N) 2 ) Ligand
  132. Silver(i) polymeric coordination frameworks assembled with the new multimodal ligand 2,2′-azobispyrazine
  133. Open Network Architectures from the Self-Assembly of AgNO3 and 5,10,15,20-Tetra(4-pyridyl)porphyrin (H2tpyp) Building Blocks: The Exceptional Self-Penetrating Topology of the 3D Network of [Ag8(ZnIItpyp)7(H2O)2](NO3)8
  134. Borromean links and other non-conventional links in ‘polycatenated’ coordination polymers: re-examination of some puzzling networks
  135. New architectures from the self-assembly of MIISO4 salts with bis(4-pyridyl) ligands. The first case of polycatenation involving three distinct sets of 2D polymeric (4,4)-layers parallel to a common axis
  136. Crystal Engineering of Mixed-Metal Ru–Ag Coordination Networks by Using the trans-[RuCl2(pyz)4] (pyz=pyrazine) Building Block This work was supported by MURST within the project “Solid Supermolecules” 2000–2001 and by CSMTBO-CNR Center.
  137. Using long bis(4-pyridyl) ligands designed for the self-assembly of coordination frameworks and architectures
  138. A three-dimensional nanoporous flexible network of ‘square-planar’ copper(ii) centres with an unusual topologyElectronic supplementary information (ESI) available: XRPD spectra. See http://www.rsc.org/suppdata/cc/b2/b202588d/
  139. Novel hetero-bimetallic metalla-macrocycles based on the bis-1-pyridyl ferrocene [Fe(η5-C5H4-1-C5H4N)2] ligand. Design, synthesis and structural characterization of the complexes [Fe(η5-C5H4-1-C5H4N)2](Agi)22+/(Cuii)24+/(Znii)24+
  140. Three Novel Interpenetrating Diamondoid Networks from Self-Assembly of 1,12-Dodecanedinitrile with Silver(I) Salts
  141. Coordination networks from the self-assembly of silver salts and the linear chain dinitriles NC(CH2)nCN (n = 2 to 7): a systematic investigation of the role of counterions and of the increasing length of the spacers
  142. Monitoring the Crystal Growth and Interconversion of New Coordination Networks in the Self-assembly of MCl 2 Salts (M = Co, Ni, Cu, Cd) and 1,3-Bis(4-pyridyl)propane
  143. Synthesis, Structural Analysis, and Superconductivity of Ba x V 6 S 8
  144. Discrete molecular and extended polymeric copper(I) halide complexes of tetradentate thioether macrocycles
  145. Interlinked molecular squares with [Cu(2,2′-bipy)]2+ corners generating a three-dimensional network of unprecedented topological type
  146. Structural Properties and Topological Diversity of Polymeric Ag(I)-hexamethylenetetramine Complexes: Self-Assembly of Three Novel Two-Dimensional Coordination Networks and Their Supramolecular Interactions
  147. Polymeric Layers Catenated by Ribbons of Rings in a Three-Dimensional Self-Assembled Architecture: A Nanoporous Network with Spongelike Behavior
  148. Hydrothermal Synthesis and Structural Characterization of a Novel Hydroxo Stannate: Sr2Sn(OH)8
  149. New examples of self-catenation in two three-dimensional polymeric co-ordination networks †
  150. Chiral packing of chiral quintuple layers polycatenated to give a three-dimensional network in the coordination polymer [Co5(bpe)9(H2O)8(SO4)4](SO4)·14H2O [bpe = 1,2-bis(4-pyridyl)ethane]
  151. Crystal engineering of coordination polymers and architectures using the [Cu(2,2′-bipy)]2+ molecular corner as building block (bipy = 2,2′-bipyridyl)
  152. 1,2- eq,eq -[Re 2 (CO) 8 (THF) 2 ]:  A Reactive Re 2 (CO) 8 Fragment That Easily Activates H−H and C−H Bonds
  153. Complex Interwoven Polymeric Frames from the Self-Assembly of Silver(I) Cations and Sebaconitrile
  154. A new type of supramolecular entanglement in the silver(I) coordination polymer [Ag2(bpethy)5](BF4)2 [bpethy = 1,2-bis(4-pyridyl)ethyne]
  155. Exploring Tellurides: Synthesis and Characterization of New Binary, Ternary, and Quaternary Compounds
  156. Stepwise electron-induced demolition of the Ni-I ?-bond in complexes with tetradentate tripodal ligands: A theoretical rationalization of structural and electrochemical results
  157. MO theory made visible
  158. Aromaticity and Agostic Interactions as Stabilizing Factors in Trinuclear Rhenium Clusters with Low Electron Count
  159. Stabilisation of trivalent nickel through 1 : 2 co-ordination by cyclic terdentate ligands CH2CH2NH(CH2)2NH(CH2)2X (X = NH, O, or S)
  160. Networks, Topologies, and Entanglements