What is it about?

The substitution reactions of the benzonitrile (PhCN) complex cis-[Pd(PhCN)2C12] with the sodium salts of some amino acids, namely L-tyrosine (tyrH), L-phenylalanine (pheH), L-glutamic acid (gluH), L-glutamine (glnH), L-cysteine (cysH) and glycine (glyH) have been investigated. The isolated complexes [Pd(tyr)2].H2O, [Pd(phe)2].2H2O, [Pd(glu)2], [Pd(gln)2].H2O, Na2[Pd(cys)2].0.5Me2CO and [Pd(gly)2].0.5H2O have been characterized by elemental analysis, conductivity measurements, IR, electronic absorption and 1H- and 13C-NMR spectra.

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Why is it important?

The synthesis of new Pd(II) amino acid complexes and using NMR as good characterization method

Perspectives

This work provides the synthetic methods of new amino acid Pd(II) complexes with characterization

Professor Basem F Ali
King Faisal University

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This page is a summary of: Bis-Chelated Pd(II)-Amino Acid Complexes: Substitution Reactions ofcis-Dichlorobis(benzonitrile)Palladium(II) with Amino Acids, Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, February 2014, Taylor & Francis, DOI: 10.1080/15533174.2013.819895.
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