What is it about?
The substitution reactions of the benzonitrile (PhCN) complex cis-[Pd(PhCN)2C12] with the sodium salts of some amino acids, namely L-tyrosine (tyrH), L-phenylalanine (pheH), L-glutamic acid (gluH), L-glutamine (glnH), L-cysteine (cysH) and glycine (glyH) have been investigated. The isolated complexes [Pd(tyr)2].H2O, [Pd(phe)2].2H2O, [Pd(glu)2], [Pd(gln)2].H2O, Na2[Pd(cys)2].0.5Me2CO and [Pd(gly)2].0.5H2O have been characterized by elemental analysis, conductivity measurements, IR, electronic absorption and 1H- and 13C-NMR spectra.
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Why is it important?
The synthesis of new Pd(II) amino acid complexes and using NMR as good characterization method
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This page is a summary of: Bis-Chelated Pd(II)-Amino Acid Complexes: Substitution Reactions ofcis-Dichlorobis(benzonitrile)Palladium(II) with Amino Acids, Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, February 2014, Taylor & Francis, DOI: 10.1080/15533174.2013.819895.
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