What is it about?
The substitution reactions of the benzonitrile (PhCN) complex cis-[Pd(PhCN)2C12] with the sodium salts of some amino acids, namely L-tyrosine (tyrH), L-phenylalanine (pheH), L-glutamic acid (gluH), L-glutamine (glnH), L-cysteine (cysH) and glycine (glyH) have been investigated. The isolated complexes [Pd(tyr)2].H2O, [Pd(phe)2].2H2O, [Pd(glu)2], [Pd(gln)2].H2O, Na2[Pd(cys)2].0.5Me2CO and [Pd(gly)2].0.5H2O have been characterized by elemental analysis, conductivity measurements, IR, electronic absorption and 1H- and 13C-NMR spectra.
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Why is it important?
The synthesis of new Pd(II) amino acid complexes and using NMR as good characterization method
Perspectives
This work provides the synthetic methods of new amino acid Pd(II) complexes with characterization
Professor Basem F Ali
King Faisal University
Read the Original
This page is a summary of: Bis-Chelated Pd(II)-Amino Acid Complexes: Substitution Reactions of cis-Dichlorobis(benzonitrile)Palladium(II) with Amino Acids, Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, October 2014, Taylor & Francis,
DOI: 10.1080/15533174.2013.819895.
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