All Stories

  1. Inter- versus Intramolecular Structural Manipulation of a Dichromium(II) Pacman Complex through Pressure Variation
  2. Thorium Mono- and Bis(imido) Complexes Made by Reprotonation of cyclo -Metalated Amides
  3. Selective Oligomerization and [2 + 2 + 2] Cycloaddition of Terminal Alkynes from Simple Actinide Precatalysts
  4. Uranium(III) Coordination Chemistry and Oxidation in a Flexible Small-Cavity Macrocycle
  5. Macrocyclic Platforms for the Construction of Tetranuclear Oxo and Hydroxo Zinc Clusters
  6. Characterizing Pressure-Induced Uranium CH Agostic Bonds
  7. Characterizing Pressure-Induced Uranium CH Agostic Bonds
  8. Control of Oxo-Group Functionalization and Reduction of the Uranyl Ion
  9. ChemInform Abstract: C-H Bond Activation by f-Block Complexes
  10. Catalytic one-electron reduction of uranyl(vi) to Group 1 uranyl(v) complexes via Al(iii) coordination
  11. CH Bond Activation by f-Block Complexes
  12. C-H-Aktivierung mit Komplexen der f-Block-Elemente
  13. New Chemistry from an Old Reagent: Mono- and Dinuclear Macrocyclic Uranium(III) Complexes from [U(BH 4 ) 3 (THF) 2 ]
  14. Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex
  15. Switchable π-coordination and C–H metallation in small-cavity macrocyclic uranium and thorium complexes
  16. Homo- and heteroleptic alkoxycarbene f-element complexes and their reactivity towards acidic N–H and C–H bonds
  17. Protonolysis and thermolysis reactions of functionalised NHC–carbene boranes and borates
  18. Arene-ligated heteroleptic terphenolate complexes of thorium
  19. ChemInform Abstract: Inorganic Chemistry: A Reducing Role for Boron
  20. Isocyanide and Phosphine Oxide Coordination in Binuclear Chromium Pacman Complexes
  21. A reducing role for boron
  22. Thermally Stable Uranium Dinitrogen Complex with Siloxide Supporting Ligands
  23. Oxo-Group-14-Element Bond Formation in Binuclear Uranium(V) Pacman Complexes
  24. Numerical and experimental investigation of near-infrared-visible luminescence in erbium doped sol-gel SiO2
  25. Oxo-Functionalization and Reduction of the Uranyl Ion through Lanthanide-Element Bond Homolysis: Synthetic, Structural, and Bonding Analysis of a Series of Singly Reduced Uranyl–Rare Earth 5f 1 -4f n Complexes
  26. Tuning the catalytic properties of rare earth borohydrides for the polymerisation of isoprene
  27. Carbon monoxide and carbon dioxide insertion chemistry of f-block N-heterocyclic carbene complexes
  28. Uranium(iv) amido-borohydrides as highly active diene polymerisation catalysts
  29. Numerical and experimental investigation of NIR-to-visible energy up-conversion in Er3+-doped sol–gel SiO2 powders
  30. Single-molecule magnets: Uranyl steps in the ring
  31. Controlled Deprotection and Reorganization of Uranyl Oxo Groups in a Binuclear Macrocyclic Environment
  32. Controlled Deprotection and Reorganization of Uranyl Oxo Groups in a Binuclear Macrocyclic Environment
  33. Spontaneous reduction and C–H borylation of arenes mediated by uranium(III) disproportionation
  34. Strongly coupled binuclear uranium–oxo complexes from uranyl oxo rearrangement and reductive silylation
  35. Co-linear, double-uranyl coordination by an expanded Schiff-base polypyrrole macrocycle
  36. Theoretical exploration of uranyl complexes of a designed polypyrrolic macrocycle: structure/property effects of hinge size on Pacman-shaped complexes
  37. ChemInform Abstract: Uranium-Mediated Activation of Small Molecules
  38. Numerical and experimental investigation of upconversion in Er doped sol-gel SiO2
  39. Oxo Group Protonation and Silylation of Pentavalent Uranyl Pacman Complexes
  40. Oxo Group Protonation and Silylation of Pentavalent Uranyl Pacman Complexes
  41. Carbon–Silicon and Carbon–Carbon Bond Formation by Elimination Reactions at Metal N-Heterocyclic Carbene Complexes
  42. Small Molecule Activation by Uranium Tris(aryloxides): Experimental and Computational Studies of Binding of N 2 , Coupling of CO, and Deoxygenation Insertion of CO 2 under Ambient Conditions
  43. Uranium-mediated activation of small molecules
  44. Theoretical predictions of cofacial bis(actinyl) complexes of a stretched Schiff-base calixpyrrole ligand
  45. Carbon monoxide coupling and functionalisation at a simple uranium coordination complex
  46. Women in Chemistry — Interview with Polly Arnold
  47. Single-Electron Uranyl Reduction by a Rare-Earth Cation
  48. Single-Electron Uranyl Reduction by a Rare-Earth Cation
  49. New UIII and UIV silylamides and an improved synthesis of NaN(SiMe2R)2 (R = Me, Ph)
  50. Uranyl oxo activation and functionalization by metal cation coordination
  51. Cation o' nine tails
  52. Covalency in CeIV and UIV Halide and N-Heterocyclic Carbene Bonds
  53. Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis
  54. Addition-Elimination Reactions across the M−C Bond of Metal N-Heterocyclic Carbenes
  55. The Effect of the Equatorial Environment on Oxo-Group Silylation of the Uranyl Dication: A Computational Study
  56. Uranium−Nitrogen Multiple Bonding: Isostructural Anionic, Neutral, and Cationic Uranium Nitride Complexes Featuring a Linear U═N═U Core
  57. Chiral Indium Alkoxide Complexes as Initiators for the Stereoselective Ring-Opening Polymerization of rac -Lactide
  58. Lanthanide/actinide differentiation with sterically encumbered N-heterocyclic carbene ligands
  59. Equatorial ligand substitution by hydroxide in uranyl Pacman complexes of a Schiff-base pyrrole macrocycle
  60. Constructing cerium supramolecular wheels and encapsulating uranium with a Schiff-base calixpyrrole ligand
  61. ChemInform Abstract: F-Block N-Heterocyclic Carbene Complexes
  62. Chelating N-Heterocyclic Carbene Alkoxide as a Supporting Ligand for Pd II/IV C−H Bond Functionalization Catalysis
  63. Ligand Recognition Processes in the Formation of HomochiralC3-Symmetric LnL3Complexes of a Chiral Alkoxide
  64. Pentavalent uranyl complexes
  65. F-Block N-Heterocyclic Carbene Complexes
  66. Now U=C it
  67. Magnesium and zinc complexes of functionalised, saturated N-heterocyclic carbene ligands: carbene lability and functionalisation, and lactide polymerisation catalysis
  68. A DFT study of the single electron reduction and silylation of the U–O bond of the uranyl dication in a macrocyclic environment
  69. An unsupported transition metal–lanthanide bond; synthesis and crystal structure of an Nd–Fe amido N-heterocyclic carbene complex
  70. Computational Density Functional Study of Polypyrrolic Macrocycles: Analysis of Actinyl-Oxo to 3d Transition Metal Bonding
  71. Functionalised Saturated-Backbone Carbene Ligands: Yttrium and Uranyl Alkoxy-Carbene Complexes and Bicyclic Carbene-Alcohol Adducts
  72. Low-Valent Uranium Iodides: Straightforward Solution Syntheses of UI 3 and UI 4 Etherates
  73. Comparisons between Yttrium and Titanium N-Heterocyclic Carbene Complexes in the Search for Early Transition Metal NHC Backbonding Interactions
  74. C3-Symmetric Lanthanide Tris(alkoxide) Complexes Formed by Preferential Complexation and Their Stereoselective Polymerization ofrac-Lactide
  75. C3-Symmetric Lanthanide Tris(alkoxide) Complexes Formed by Preferential Complexation and Their Stereoselective Polymerization ofrac-Lactide
  76. Synthesis and reactivity of neodymium(III) amido-tethered N-heterocyclic carbene complexes
  77. ChemInform Abstract: Anionic Tethered N-Heterocyclic Carbene Chemistry
  78. Reduction and selective oxo group silylation of the uranyl dication
  79. Magnesium amido N-heterocyclic carbene complexes
  80. Synthesis and structural characterisation of an yttrium–alkyl–alkylidene
  81. Synthesis and NHC Lability of d0 Lithium, Yttrium, Titanium, and Zirconium Amido Bis(N-heterocyclic carbene) Complexes
  82. A Lanthanide−Gallium Complex Stabilized by the N-Heterocyclic Carbene Group
  83. Abnormal N-heterocyclic carbenes
  84. F-Block N-Heterocyclic Carbene Complexes
  85. Anionic tethered N-heterocyclic carbene chemistry
  86. Tetravalent cerium carbene complexes
  87. Synthesis and characterisation of yttrium complexes supported by the β-diketiminate ligand {ArNC(CH3)CHC(CH3)NAr}– (Ar = 2,6-Pri2C6H3)
  88. Titanium(III) Alkoxy-N-heterocyclic Carbenes and a Safe, Low-Cost Route to TiCl 3 (THF) 3
  89. Sterically demanding bi- and tridentate alkoxy-N-heterocyclic carbenes
  90. Selective Oxo Functionalization of the Uranyl Ion with 3d Metal Cations
  91. Titanium(IV) Alkoxy-N-heterocyclic Carbenes:  Structural Preferences of Alkoxide and Bromide Adducts
  92. Deprotonation of N-Heterocyclic Carbenes to Afford Heterobimetallic Organolanthanide Complexes
  93. F-block N-heterocyclic carbene complexes
  94. Bifunctional yttrium(iii) and titanium(iv) NHC catalysts for lactide polymerisation
  95. Group I cation templated formation of luminescent mono- and bis-substituted thionaphthol heterobimetallic complexes of Pr, Nd, Eu and Tb
  96. Silver alkoxide and amino N-heterocyclic carbenes; syntheses and crystal structures
  97. Synthesis and Small Molecule Reactivity of Uranium(IV) Alkoxide Complexes with both Bound and Pendant N-heterocyclic Carbene Ligands
  98. Synthesis of Heteroleptic Cerium(III) Anionic Amido-Tethered N-Heterocyclic Carbene Complexes
  99. Regioselective C–H activation of lanthanide-bound N-heterocyclic carbenes
  100. Thermally stable potassium N-heterocyclic carbene complexes with alkoxide ligands, and a polymeric crystal structure with distorted, bridging carbenes
  101. Asymmetric Lithium(I) and Copper(II) Alkoxy-N-heterocyclic Carbene Complexes; Crystallographic Characterization and Lewis Acid Catalysis.
  102. Uranyl Complexation by a Schiff-Base, Polypyrrolic Macrocycle
  103. Perspectives in organometallic chemistry
  104. Di- and Trivalent Ruthenium Complexes of Chelating, Anionic N-Heterocyclic Carbenes
  105. Asymmetric lithium(i) and copper(ii) alkoxy-N-heterocyclic carbene complexes; crystallographic characterisation and Lewis acid catalysisElectronic supplementary information (ESI) available: full synthetic and structural details. See
  106. Synthesis and luminescence studies of mono- and C3-symmetric, tris(ligand) complexes of Sm(iii), Y(iii) and Eu(iii) with sulfur-bridged binaphtholate ligands
  107. Bent metal carbene geometries in amido N-heterocyclic carbene complexes
  108. Group 4 Complexes of Chelating Dianionic [OSO] Binaphtholate Ligands; Synthesis and Alkene Polymerisation Catalysis
  109. Anionic Amido N-Heterocyclic Carbenes: Synthesis of Covalently Tethered Lanthanide–Carbene Complexes
  110. Anionic Amido N-Heterocyclic Carbenes: Synthesis of Covalently Tethered Lanthanide–Carbene Complexes
  111. Arene complexation of Sm, Eu, Tm and Yb atoms: a variable temperature spectroscopic investigation
  112. Organometallic Chemistry of Monometallic Species
  113. Synthesis of mono- and di-potassium salts and methoxy adducts of sulfur-bridged biphenols by selective deprotonationElectronic supplementary information (ESI) available: full characterisation for all complexes described and packing diagrams for 3 and 5...
  114. Mechanistic insight into the lanthanide (iii) salt catalysed monoacylation of symmetrical diols from structural modelsElectronic supplementary information (ESI) available: experimental details. See
  115. Symmetric and asymmetric samarium alkoxide derivatives of bridging sulfur biphenolate and binaphtholate ligands; synthetic, structural, and catalytic studies
  116. Organometallic chemistry of silver and copperN-heterocyclic carbene complexes
  117. 20  Organometallic chemistry of monometallic species
  118. Selective reduction in ring size of silsesquioxane oligomers mediated by potassium metal
  119. A functional model for lanthanide doped silicate materials: synthesis of an apically substituted samarium silsesquioxane complex
  120. Direct Synthesis of Coordination and Organometallic Compounds
  121. Arene-Bridged Diuranium Complexes:  Inverted Sandwiches Supported by δ Backbonding
  122. Metal Vapor Synthesis as a Straightforward Route to Group 10 Homoleptic Carbene Complexes
  123. Heterodinuclear Uranium/Molybdenum Dinitrogen Complexes
  124. The first stable scandocene: synthesis and characterisation of bis(η-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II)
  125. The first structurally authenticated zerovalent heteroarene complex of a lanthanide; synthesis and X-ray structure of bis(2,4,6-tri-tert-butyl- phosphorin)holmium(O)
  126. An experimental and theoretical investigation of the electronic structure of Pd and Pt bis(carbene) complexes
  127. The First Example of a Formal Scandium(I) Complex:  Synthesis and Molecular Structure of a 22-Electron Scandium Triple Decker Incorporating the Novel 1,3,5-Triphosphabenzene Ring
  128. Synthesis of Permethylindenyl Complexes of the Early Transition Metals. Crystal Structures of Ti(.eta.5-C9Me7)Cl3 and Zr(.eta.5-C9Me7)2Cl2