All Stories

  1. Acyl Group Migration in Pyranosides as Studied by Experimental and Computational Methods

    Article • Chemistry - A European Journal, May 2022, Wiley

    Professor Pedro Merino

  2. Absence of Intermediates in the BINOL-Derived Mg(II)/Phosphate-Catalyzed Desymmetrizative Ring Expansion of 1-Vinylcyclobutanols

    Article • The Journal of Organic Chemistry, December 2021, American Chemical Society (ACS)

    Professor Pedro Merino

  3. Piperidine Azasugars Bearing Lipophilic Chains: Stereoselective Synthesis and Biological Activity as Inhibitors of Glucocerebrosidase (GCase)

    Article • The Journal of Organic Chemistry, September 2021, American Chemical Society (ACS)

    Professor Pedro Merino

  4. The Pseudotransannular Ring Opening of 1‐Aminocyclohept‐4‐ene‐derived Epoxides in the Synthesis of Tropane Alkaloids: Total Synthesis of (±)‐Ferrugine

    Article • European Journal of Organic Chemistry, May 2021, Wiley

    Professor Pedro Merino

  5. Brønsted Acid Catalyzed (4 + 2) Cyclocondensation of 3-Substituted Indoles with Donor–Acceptor Cyclopropanes

    Article • Organic Letters, March 2021, American Chemical Society (ACS)

    Professor Pedro Merino

  6. Asymmetric synthesis of dibenzo[b,d]azepines by Cu-catalyzed reductive or borylative cyclization

    Article • Chemical Science, January 2021, Royal Society of Chemistry

    Professor Pedro Merino

  7. Computational evidence of glycosyl cations

    Article • Organic & Biomolecular Chemistry, January 2021, Royal Society of Chemistry

    Professor Pedro Merino

  8. α-Keto hydrazones in asymmetric aminocatalysis: reactivity through β-amino aza-dienamine intermediates

    Article • Organic Chemistry Frontiers, January 2021, Royal Society of Chemistry

    Professor Pedro Merino

  9. Enantio‐ and Diastereoselective Nucleophilic Addition of N‐tert‐Butylhydrazones to Isoquinolinium Ions through Anion‐Binding Catalysis

    Article • Angewandte Chemie, November 2020, Wiley

    Professor Pedro Merino

  10. Enantio‐ and Diastereoselective Nucleophilic Addition of N‐tert‐Butylhydrazones to Isoquinolinium Ions through Anion‐Binding Catalysis

    Article • Angewandte Chemie, November 2020, Wiley

    Professor Pedro Merino

  11. Dissecting the Essential Role of Anomeric β-Triflates in Glycosylation Reactions

    Article • Journal of the American Chemical Society, June 2020, American Chemical Society (ACS)

    Professor Pedro Merino

  12. Enantioselective Synthesis of Tropanes: Brønsted Acid Catalyzed Pseudotransannular Desymmetrization

    Article • Angewandte Chemie, March 2020, Wiley

    Professor Pedro Merino

  13. Enantioselective Synthesis of Tropanes: Brønsted Acid Catalyzed Pseudotransannular Desymmetrization

    Article • Angewandte Chemie, March 2020, Wiley

    Professor Pedro Merino

  14. Front Cover: Rearrangement Reactions in Aza-Vinylogous Povarov Products: Metal-Free Synthesis of C3 -Functionalized Quinolines and Studies on their Synthetic Application (Eur. J. Org. Chem. 38/2019)

    Article • European Journal of Organic Chemistry, September 2019, Wiley

    J. Carlos Menéndez, Professor Pedro Merino

  15. Regioselective Synthesis of 1,4,5‐Trisubstituted‐1,2,3‐Triazoles from Aryl Azides and Enaminones

    Article • European Journal of Organic Chemistry, August 2019, Wiley

    Professor Pedro Merino

  16. Rearrangement Reactions in Aza-Vinylogous Povarov Products: Metal-Free Synthesis of C3 -Functionalized Quinolines and Studies on their Synthetic Application

    Article • European Journal of Organic Chemistry, August 2019, Wiley

    J. Carlos Menéndez, Professor Pedro Merino

  17. Synthesis, Biological and In Silico Evaluation of Pure Nucleobase-Containing Spiro (Indane-Isoxazolidine) Derivatives as Potential Inhibitors of MDM2–p53 Interaction

    Article • Molecules, August 2019, MDPI AG

    Maria Luisa Di Gioia, Professor Pedro Merino

  18. Transient and intermediate carbocations in ruthenium tetroxide oxidation of saturated rings

    Article • Beilstein Journal of Organic Chemistry, July 2019, Beilstein Institut

    Professor Pedro Merino

  19. Experimental and Computational Studies on the 1,3‐Dipolar Cycloaddition between Enantiomerically Pure 2,3‐Dihydrothiazoles and Nitrones

    Article • European Journal of Organic Chemistry, June 2019, Wiley

    Professor Pedro Merino

  20. Synergistic Catalysis: Highly Enantioselective Cascade Reaction for the Synthesis of Dihydroacridines

    Article • Chemistry - A European Journal, May 2019, Wiley

    Pedro Merino, Dr Ramon Rios, Professor Pedro Merino

  21. Enantioselective Synthesis, DFT Calculations, and Preliminary Antineoplastic Activity of Dibenzo 1-Azaspiro[4.5]decanes on Drug-Resistant Leukemias

    Article • The Journal of Organic Chemistry, January 2019, American Chemical Society (ACS)

    Eduardo Salustiano, Professor Pedro Merino

  22. Asymmetric diastereodivergent Michael addition of 2-chloromalonate esters to conjugated imines enabled by catalyst metal change

    Article • Organic Chemistry Frontiers, January 2019, Royal Society of Chemistry

    Professor Pedro Merino

  23. Asymmetric synthesis of polycyclic 3-fluoroalkylproline derivatives by intramolecular azomethine ylide cycloaddition

    Article • Organic Chemistry Frontiers, January 2019, Royal Society of Chemistry

    Professor Pedro Merino

  24. Native Quercetin as a Chloride Receptor in an Organic Solvent

    Article • Molecules, December 2018, MDPI AG

    Professor Pedro Merino

  25. Synthesis of Enantiopure Constrained α,β-Cycloaliphatic Cystines via Diels–Alder Reaction with Homochiral Thiazolines

    Article • The Journal of Organic Chemistry, September 2018, American Chemical Society (ACS)

    Professor Pedro Merino

  26. Synthesis of 1,5-Functionalized 1,2,3-Triazoles Using Ionic Liquid/Iron(III) Chloride as an Efficient and Reusable Homogeneous Catalyst

    Article • Catalysts, August 2018, MDPI AG

    Maria Luisa Di Gioia, Professor Pedro Merino

  27. Concerted Albeit Not Pericyclic Cycloadditions: Understanding the Mechanism of the (4+3) Cycloaddition between Nitrones and 1,2‐Diaza‐1,3‐dienes

    Article • European Journal of Organic Chemistry, August 2018, Wiley

    Professor Pedro Merino

  28. Synthesis of 1,5-Functionalized 1,2,3-Triazoles Using Ionic Liquid/Iron(III) Chloride as Efficient and Reusable Homogeneous Catalyst

    Article • July 2018, MDPI AG

    Professor Pedro Merino

  29. Sequential Metal-Free Thermal 1,3-Dipolar Cycloaddition of Unactivated Azomethine Ylides

    Article • Organic Letters, June 2018, American Chemical Society (ACS)

    Professor Pedro Merino

  30. Correction to “Self-Regeneration of Chirality with l-Cysteine through 1,3-Dipolar Cycloadditions between Diazoalkanes and Enantiomerically Pure Thiazolines: Experimental and Computational Studies”

    Article • The Journal of Organic Chemistry, May 2018, American Chemical Society (ACS)

    Professor Pedro Merino

  31. Direct Hydroxymethylation of C=N Double Bonds

    Article • Letters in Organic Chemistry, April 2018, Bentham Science Publishers

    Professor Pedro Merino, Tomás Tejero

  32. Self-Regeneration of Chirality with l-Cysteine through 1,3-Dipolar Cycloadditions between Diazoalkanes and Enantiomerically Pure Thiazolines: Experimental and Computational Studies

    Article • The Journal of Organic Chemistry, March 2018, American Chemical Society (ACS)

    Professor Pedro Merino

  33. Synergistic catalysis: enantioselective cyclopropanation of alkylidene benzoxazoles by Pd(ii) and secondary amine catalysis. Scope, limitations and mechanistic insight

    Article • Organic Chemistry Frontiers, January 2018, Royal Society of Chemistry

    Dr Ramon Rios, Professor Pedro Merino

  34. (+)-Methyl (1R,2S)-2-{[4-(4-Chlorophenyl)-4-hydroxypiperidin-1-yl]methyl}-1-phenylcyclopropanecarboxylate [(+)-MR200] Derivatives as Potent and Selective Sigma Receptor Ligands: Stereochemistry and Pharmacological Properties

    Article • Journal of Medicinal Chemistry, December 2017, American Chemical Society (ACS)

    Professor Antonio Rescifina, Professor Pedro Merino

  35. Inhibitors against Fungal Cell Wall Remodeling Enzymes

    Article • ChemMedChem, December 2017, Wiley

    Professor Pedro Merino

  36. Organocatalytic Enantioselective Synthesis of Trifluoromethyl-Containing Tetralin Derivatives by Sequential (Hetero)Michael Reaction-Intramolecular Nitrone Cycloaddition

    Article • Advanced Synthesis & Catalysis, November 2017, Wiley

    Professor Pedro Merino

  37. A Case Study of Thiourea-Assisted Iminium Formation by Hydroxyl Anion Binding: Kinetic, Spectroscopic and Computational Evidences

    Article • Advanced Synthesis & Catalysis, September 2017, Wiley

    Professor Pedro Merino

  38. Pivotal Neighboring‐Group Participation in Substitution versus Elimination Reactions – Computational Evidence for Ion Pairs in the Thionation of Alcohols with Lawesson's Reagent

    Article • European Journal of Organic Chemistry, April 2017, Wiley

    Professor Pedro Merino

  39. Nitrones and nucleobase-containing spiro-isoxazolidines derived from isatin and indanone: solvent-free microwave-assisted stereoselective synthesis and theoretical calculations

    Article • RSC Advances, January 2017, Royal Society of Chemistry

    Maria Luisa Di Gioia, Professor Pedro Merino

  40. Chemical approaches to inhibitors of isoprenoid biosynthesis: targeting farnesyl and geranylgeranyl pyrophosphate synthases

    Article • RSC Advances, January 2017, Royal Society of Chemistry

    Professor Pedro Merino

  41. Introducing topology to assess the synchronicity of organic reactions. Dual reactivity of oximes with alkenes as a case study

    Article • Organic Chemistry Frontiers, January 2017, Royal Society of Chemistry

    Professor Pedro Merino

  42. New mechanistic interpretations for nitrone reactivity

    Article • Organic & Biomolecular Chemistry, January 2017, Royal Society of Chemistry

    Professor Pedro Merino

  43. Synthesis of Amino‐Acid–Nucleoside Conjugates

    Article • Asian Journal of Organic Chemistry, November 2016, Wiley

    Professor Pedro Merino

  44. Recent Advances in the Preparation of Enantiomerically Pure Hydroxylamines from Nitrones

    Article • Current Organic Synthesis, October 2016, Bentham Science Publishers

    Professor Pedro Merino

  45. Nucleoside Diphosphate Sugar Analogues that Target Glycosyltransferases

    Article • Asian Journal of Organic Chemistry, September 2016, Wiley

    Professor Pedro Merino

  46. Design and Synthesis of Dopaminergic Agonists

    Article • Current Medicinal Chemistry, September 2016, Bentham Science Publishers

    Professor Pedro Merino

  47. Cover Picture: Azomethine Ylides from Nitrones: Using Catalytic nBuLi for the Totally Stereoselective Synthesis of trans‐2‐Alkyl‐3‐oxazolines (Chem. Eur. J. 33/2016)

    Article • Chemistry - A European Journal, July 2016, Wiley

    Professor Pedro Merino

  48. Azomethine Ylides from Nitrones: Using Catalytic nBuLi for the Totally Stereoselective Synthesis of trans‐2‐Alkyl‐3‐oxazolines

    Article • Chemistry - A European Journal, June 2016, Wiley

    Professor Pedro Merino

  49. Azomethine Ylides from Nitrones: Using Catalytic nBuLi for the Totally Stereoselective Synthesis of trans‐2‐Alkyl‐3‐oxazolines

    Article • Chemistry - A European Journal, June 2016, Wiley

    Professor Pedro Merino

  50. Glycomimetics Targeting Glycosyltransferases: Synthetic, Computational and Structural Studies of Less‐Polar Conjugates

    Article • Chemistry - A European Journal, April 2016, Wiley

    Professor Pedro Merino

  51. Mechanistic Insights into the Mode of Action of Bifunctional Pyrrolidine‐Squaramide‐Derived Organocatalysts

    Article • Chemistry - A European Journal, December 2015, Wiley

    Professor Pedro Merino

  52. Rational Design of Glycomimetic Compounds Targeting theSaccharomyces cerevisiaeTransglycosylase Gas2

    Article • Chemical Biology & Drug Design, September 2015, Wiley

    Professor Pedro Merino

  53. Recent Advances on the Enantioselective Synthesis of C-Nucleosides Inhibitors of Inosine Monophosphate Dehydrogenase (IMPDH)

    Article • Current Topics in Medicinal Chemistry, May 2014, Bentham Science Publishers

    Professor Pedro Merino

  54. [2n2π + 2n2π] Cycloadditions: an alternative to forbidden [4π + 4π] processes. The case of nitrone dimerization

    Article • Organic & Biomolecular Chemistry, January 2014, Royal Society of Chemistry

    Professor Pedro Merino

  55. Highly diastereoselective 1,3-dipolar cycloadditions of chiral non-racemic nitrones to 1,2-diaza-1,3-dienes: an experimental and computational investigation

    Article • Organic & Biomolecular Chemistry, January 2014, Royal Society of Chemistry

    Professor Pedro Merino

  56. Synthesis of O- and C-glycosides derived from β-(1,3)-d-glucans

    Article • Carbohydrate Research, December 2013, Elsevier

    Professor Pedro Merino

  57. Stereoselective 1,3-dipolar cycloadditions of nitrones derived from amino acids. Asymmetric synthesis of N-(alkoxycarbonylmethyl)-3-hydroxypyrrolidin-2-ones

    Article • Tetrahedron, November 2013, Elsevier

    Professor Pedro Merino, Venerando Pistarà

  58. Evasive Neutral 2-Aza-Cope Rearrangements. Kinetic and Computational Studies with Cyclic Nitrones

    Article • European Journal of Organic Chemistry, July 2013, Wiley

    Professor Pedro Merino

  59. Chemical Synthesis of Nucleoside Analogues

    Article • February 2013, Wiley

    Professor Pedro Merino

  60. Recent Advances in the Chemical Synthesis of Aza-Nucleosides

    Article • February 2013, Wiley

    Professor Pedro Merino

  61. Chemical Synthesis of Conformationally Constrained PNA Monomers

    Article • February 2013, Wiley

    Professor Pedro Merino

  62. The High Selectivity of the Cp2ZrHCl Reducing Agent for Imides: A Combined Experimental and Theoretical Study on γ-Lactam and Isoxazolidinone Derivatives

    Article • European Journal of Organic Chemistry, November 2012, Wiley

    Professor Pedro Merino

  63. Recent Progress on Fucosyltransferase Inhibitors

    Article • Mini-Reviews in Medicinal Chemistry, November 2012, Bentham Science Publishers

    Professor Pedro Merino

  64. Dual reactivity of O-α-allenyl esters under palladium(0) catalysis: From carbopalladation/allylic alkylation domino sequence to decarboxylative allenylation

    Article • Journal of Organometallic Chemistry, September 2012, Elsevier

    Professor Pedro Merino

  65. Highly stereoselective synthesis of imino-C-di- and trisaccharides as hydrolytically stable glycomimetics

    Article • Tetrahedron, August 2012, Elsevier

    Professor Pedro Merino

  66. Truncated Reverse Isoxazolidinyl Nucleosides: A New Class of Allosteric HIV-1 Reverse Transcriptase Inhibitors

    Article • ChemMedChem, February 2012, Wiley

    Professor Pedro Merino

  67. Stereoselective Hydride Transfer by Aryl-Alcohol Oxidase, a Member of the GMC Superfamily

    Article • ChemBioChem, January 2012, Wiley

    Professor Pedro Merino

  68. CROSS-COUPLING REACTIONS FOR THE SYNTHESIS OF C-GLYCOSIDES AND RELATED COMPOUNDS

    Article • Heterocycles, January 2012, Japan Institute of Heterocyclic Chemistry

    Professor Pedro Merino

  69. Water-compatible one-pot organocatalytic asymmetric synthesis of cyclic nitrones. Application in intramolecular 1,3-dipolar cycloadditions

    Article • Tetrahedron Letters, November 2011, Elsevier

    Professor Pedro Merino

  70. High-yield synthesis of pyrrolidinyl PNA monomers

    Article • Tetrahedron Letters, November 2011, Elsevier

    Professor Pedro Merino, Venerando Pistarà

  71. Structural Insights into the Mechanism of Protein O-Fucosylation

    Article • PLOS One, September 2011, PLOS

    Professor Pedro Merino, Dr. Santosh Panjikar

  72. Nitrone Ylides: Two Possible 1,3-Dipolar Cycloadditions but Only One Stepwise Formation of all-cis-5-Aryl-2,3,5-trisubstituted N-Hydroxypyrrolidines

    Article • European Journal of Organic Chemistry, September 2011, Wiley

    Professor Pedro Merino

  73. Mannich-Type Reactions of Nitrones, Oximes, and Hydrazones

    Article • Synlett, August 2011, Thieme Publishing Group

    Professor Pedro Merino

  74. Organocatalytic Activation of Imines and Related Compounds Through Hydrogen-Bond Interactions

    Article • Current Organic Chemistry, July 2011, Bentham Science Publishers

    Professor Pedro Merino

  75. Sequential Nucleophilic Addition/Intramolecular Cycloaddition to Chiral Nonracemic Cyclic Nitrones: A Highly Stereoselective Approach to Polyhydroxynortropane Alkaloids

    Article • The Journal of Organic Chemistry, May 2011, American Chemical Society (ACS)

    Professor Pedro Merino

  76. Thiourea catalyzed organocatalytic enantioselective Michael addition of diphenyl phosphite to nitroalkenes

    Article • Organic & Biomolecular Chemistry, January 2011, Royal Society of Chemistry

    Professor Pedro Merino

  77. Organocatalyzed Michael Addition Reaction by Novel (2R,3aS,7aS)-Octa-hydroindole-2-carboxylic Acid, a New Fused Proline

    Article • Synlett, January 2011, Thieme Publishing Group

    Professor Pedro Merino

  78. Experimental and theoretical studies on Mannich-type reactions of chiral non-racemic N-(benzyloxyethyl) nitrones

    Article • Tetrahedron Asymmetry, December 2010, Elsevier

    Professor Pedro Merino

  79. Asymmetric organocatalytic synthesis of γ-nitrocarbonyl compounds through Michael and Domino reactions

    Article • Tetrahedron Asymmetry, November 2010, Elsevier

    Professor Pedro Merino

  80. Tunable Diastereoselection of Biased Rigid Systems by Lewis Acid Induced Conformational Effects: A Rationalization of the Vinylation of Cyclic Nitrones En Route to Polyhydroxylated Pyrrolidines

    Article • Chemistry - A European Journal, August 2010, Wiley

    Professor Pedro Merino

  81. Expanding the Limits of Organoboron Chemistry: Synthesis of Functionalized Arylboronates

    Article • Angewandte Chemie, July 2010, Wiley

    Professor Pedro Merino

  82. Chemical Synthesis of Heterocyclic−Sugar Nucleoside Analogues

    Article • Chemical Reviews, June 2010, American Chemical Society (ACS)

    Professor Pedro Merino

  83. Synthesis of d-arabinose-derived polyhydroxylated pyrrolidine, indolizidine and pyrrolizidine alkaloids. Total synthesis of hyacinthacine A2

    Article • Tetrahedron, February 2010, Elsevier

    Professor Pedro Merino

  84. Intramolecular 1,3-dipolar cycloaddition of N-alkenyl nitrones en route to glycosyl piperidines

    Article • Tetrahedron Letters, December 2009, Elsevier

    Professor Pedro Merino

  85. Synthesis of N-(Benzyloxyethyl)- and N-(Alkoxycarbonylmethyl)nitrones

    Article • Synthesis, November 2009, Thieme Publishing Group

    Professor Pedro Merino

  86. Enantioselective Organocatalytic Diels-Alder Reactions

    Article • Synthesis, November 2009, Thieme Publishing Group

    Professor Pedro Merino

  87. The Role of the Indole in Important Organocatalytic Enantioselective Friedel-Crafts Alkylation Reactions

    Article • Current Organic Chemistry, November 2009, Bentham Science Publishers

    Professor Pedro Merino

  88. Chemistry and Biology of Iminosugar Di- and Oligosaccharides

    Article • Current Chemical Biology, September 2009, Bentham Science Publishers

    Professor Pedro Merino

  89. Stereoselective Synthesis and Biological Evaluations of Novel 3′-Deoxy-4′-azaribonucleosides as Inhibitors of Hepatitis C Virus RNA Replication

    Article • Journal of Medicinal Chemistry, July 2009, American Chemical Society (ACS)

    Professor Antonio Rescifina, Professor Pedro Merino

  90. Catalytic Enantioselective Aza‐Henry Reactions

    Article • European Journal of Organic Chemistry, May 2009, Wiley

    Professor Pedro Merino

  91. Recent Developments on Rotaxane-Based Shuttles

    Article • Current Organic Chemistry, March 2009, Bentham Science Publishers

    Professor Antonio Rescifina, Professor Pedro Merino

  92. Organocatalyzed Strecker reactions

    Article • Tetrahedron, February 2009, Elsevier

    Professor Pedro Merino

  93. Exploring Nitrone Chemistry: Towards the Enantiodivergent Synthesis of 6-Substituted 4-Hydroxypipecolic Acid Derivatives

    Article • European Journal of Organic Chemistry, August 2008, Wiley

    Professor Pedro Merino

  94. Catalytic Enantioselective Hydrophosphonylation of Aldehydes and Imines

    Article • Advanced Synthesis & Catalysis, June 2008, Wiley

    Professor Pedro Merino

  95. Nucleophilic Additions to Cyclic Nitrones en Route to Iminocyclitols – Total Syntheses of DMDP, 6-deoxy-DMDP, DAB-1, CYB-3, Nectrisine, and Radicamine B

    Article • European Journal of Organic Chemistry, June 2008, Wiley

    Professor Pedro Merino

  96. Current Developments in the Synthesis and Biological Activity of Aza-C-Nucleosides:Immucillins and Related Compounds

    Article • Current Medicinal Chemistry, April 2008, Bentham Science Publishers

    Professor Pedro Merino

  97. Nucleophilic Additions and Redox Reactions of Polyhydroxypyrroline N -Oxides on the Way to Pyrrolidine Alkaloids: Total Synthesis of Radicamine B

    Article • Synlett, October 2007, Thieme Publishing Group

    Professor Pedro Merino

  98. Furan Oxidations in Organic Synthesis: Recent Advances and Applications

    Article • Current Organic Chemistry, August 2007, Bentham Science Publishers

    Professor Pedro Merino

  99. 3-(Aminomethyl)-2-(carboxymethyl)isoxazolidinyl nucleosides: building blocks for peptide nucleic acid analogues

    Article • Tetrahedron Asymmetry, July 2007, Elsevier

    Professor Pedro Merino

  100. Experimental and theoretical evidences of 2-aza-Cope rearrangement of nitrones

    Article • Tetrahedron Letters, May 2007, Elsevier

    Professor Pedro Merino

  101. Hydroxylamine Oxygen as Nucleophile in Palladium(0)- and Palladium(II)-Catalyzed Allylic Alkylation: A Novel Access to Isoxazolidines

    Article • Synlett, April 2007, Thieme Publishing Group

    Professor Pedro Merino

  102. A DFT study on the 1,3-dipolar cycloaddition reactions of C-(hetaryl) nitrones with methyl acrylate and vinyl acetate

    Article • Tetrahedron, February 2007, Elsevier

    Professor Antonio Rescifina, Professor Pedro Merino

  103. A DFT Study of the Molecular Mechanisms of the Nucleophilic Addition of Ester-Derived Lithium Enolates and Silyl Ketene Acetals to Nitrones: Effects of the Lewis Acid Catalyst

    Article • European Journal of Organic Chemistry, August 2006, Wiley

    Professor Pedro Merino

  104. Stereoselective synthesis of pyrrolidinyl glycines from nitrones: complementarity of nucleophilic addition and 1,3-dipolar cycloaddition

    Article • Tetrahedron Letters, July 2006, Elsevier

    Professor Pedro Merino

  105. Enantiodivergent Synthesis of d - and l - e rythro -Sphingosines through Mannich-Type Reactions of N -Benzyl-2,3- O -isopropylidene- d -glyceraldehyde Nitrone

    Article • The Journal of Organic Chemistry, June 2006, American Chemical Society (ACS)

    Professor Pedro Merino

  106. High stereocontrol in the allylation of chiral non-racemic α-alkoxy and α-amino nitrones

    Article • Tetrahedron Letters, May 2006, Elsevier

    Professor Pedro Merino

  107. Heterocyclic Nucleosides: Chemical Synthesis and Biological Properties

    Article • Current Medicinal Chemistry, March 2006, Bentham Science Publishers

    Professor Pedro Merino

  108. Corrigendum to “Enantioselective synthesis of N,O-psiconucleosides”

    Article • Tetrahedron Asymmetry, November 2005, Elsevier

    Professor Antonio Rescifina, Professor Pedro Merino

  109. An efficient approach to enantiomeric isoxazolidinyl analogues of tiazofurin based on nitrone cycloadditions

    Article • Tetrahedron Asymmetry, November 2005, Elsevier

    Professor Pedro Merino

  110. Zinc(II) Triflate-Controlled 1,3-Dipolar Cycloadditions of C -(2-Thiazolyl)nitrones:  Application to the Synthesis of a Novel Isoxazolidinyl Analogue of Tiazofurin

    Article • The Journal of Organic Chemistry, October 2005, American Chemical Society (ACS)

    Professor Antonio Rescifina, Professor Pedro Merino

  111. Stereoselective Allylation Reactions of Imines and Related Compounds

    Article • Current Organic Synthesis, October 2005, Bentham Science Publishers

    Professor Pedro Merino

  112. Enantioselective 1,3-Dipolar Cycloaddition of Nitrones to Methacrolein Catalyzed by (η 5 -C 5 Me 5 )M{( R )-Prophos} Containing Complexes (M = Rh, Ir; ( R )-Prophos = 1,2-bis(Diphenylphosphino)propane):  On the Origin of the Enantioselectivity

    Article • Journal of the American Chemical Society, September 2005, American Chemical Society (ACS)

    Professor Pedro Merino

  113. New Concise Total Synthesis of (+)-Lentiginosine and Some Structural Analogues

    Article • The Journal of Organic Chemistry, August 2005, American Chemical Society (ACS)

    Professor Pedro Merino

  114. New developments in nucleophilic additions to nitrones

    Article • Comptes Rendus Chimie, May 2005, Elsevier

    Professor Pedro Merino

  115. Nucleophilic additions of lithiated allylphenylsulfone to nitrones: experimental and theoretical investigations

    Article • Tetrahedron, March 2005, Elsevier

    Professor Pedro Merino

  116. Straightforward synthesis of enantiopure 2-aminomethyl and 2-hydroxymethyl pyrrolidines with complete stereocontrol

    Article • Tetrahedron Letters, February 2005, Elsevier

    Professor Pedro Merino

  117. Organocatalyzed Asymmetricα-Aminoxylation of Aldehydes and Ketones—An Efficient Access to Enantiomerically Pureα-Hydroxycarbonyl Compounds, Diols, and Even Amino Alcohols

    Article • Angewandte Chemie, June 2004, Wiley

    Professor Pedro Merino

  118. Organometallic gold(III) and gold(I) complexes as catalysts for the 1,3-dipolar cycloaddition to nitrones: synthesis of novel gold–nitrone derivatives

    Article • Journal of Organometallic Chemistry, May 2004, Elsevier

    Professor Pedro Merino

  119. The Complete Characterization of a Rhodium Lewis Acid−Dipolarophile Complex as an Intermediate for the Enantioselective Catalytic 1,3-Dipolar Cycloaddition of C , N -Diphenylnitrone to Methacrolein

    Article • Journal of the American Chemical Society, March 2004, American Chemical Society (ACS)

    Professor Pedro Merino

  120. Fully Stereoselective Nucleophilic Addition to a Novel Chiral PyrrolineN-Oxide: Total Syntheses of (2S,3R)-3-Hydroxy-3-methylproline and Its (2R)-Epimer

    Article • European Journal of Organic Chemistry, February 2004, Wiley

    Professor Pedro Merino

  121. Diastereoselective synthesis of homo-N,O-nucleosides

    Article • Tetrahedron, January 2004, Elsevier

    Professor Antonio Rescifina, Professor Pedro Merino

  122. 1,3-Dipolar cycloaddition between N-benzyl-C-glycosyl nitrones and methyl acrylate en route to glycosyl pyrrolidines

    Article • Tetrahedron Asymmetry, November 2003, Elsevier

    Professor Pedro Merino, Dr Santiago Franco

  123. Diastereo- and Enantioselective Synthesis of 1′-C-BranchedN,O-Nucleosides

    Article • Nucleosides Nucleotides & Nucleic Acids, October 2003, Taylor & Francis

    Professor Antonio Rescifina, Professor Pedro Merino

  124. Iterative Organometallic Addition to Chiral Hydroxylated Cyclic Nitrones: Highly Stereoselective Syntheses of α,α‘- and α,α-Substituted Hydroxypyrrolidines

    Article • Organic Letters, October 2003, American Chemical Society (ACS)

    Professor Pedro Merino

  125. Enantioselective synthesis of N,O-psiconucleosides

    Article • Tetrahedron Asymmetry, August 2003, Elsevier

    Professor Antonio Rescifina, Professor Pedro Merino

  126. Isoxazolidine analogues of pseudouridine: a new class of modified nucleosides

    Article • Tetrahedron, June 2003, Elsevier

    Professor Antonio Rescifina, Professor Pedro Merino

  127. A DFT study on the 1,3-dipolar cycloaddition reactions of C-(methoxycarbonyl)-N-methyl nitrone with methyl acrylate and vinyl acetate

    Article • Tetrahedron, May 2003, Elsevier

    Professor Antonio Rescifina, Professor Pedro Merino

  128. A comparative study of the stereoselective addition of trimethylsilyl cyanide and diethylaluminum cyanide to chiral cyclic nitrones

    Article • Tetrahedron Asymmetry, February 2003, Elsevier

    Professor Pedro Merino

  129. An investigation of the Lewis acid mediated 1,3-dipolar cycloaddition between N-benzyl-C-(2-pyridyl)nitrone and allylic alcohol. Direct entry to isoxazolidinyl C-nucleosidesElectronic supplementary information (ESI) available: optimized geometries (PDB...

    Article • Organic & Biomolecular Chemistry, January 2003, Royal Society of Chemistry

    Professor Pedro Merino

  130. Enantioselective synthesis of 4-hydroxy-d-pyroglutamic acid derivatives by an asymmetric 1,3-dipolar cycloaddition

    Article • Tetrahedron Asymmetry, February 2002, Elsevier

    Professor Antonio Rescifina, Professor Pedro Merino

  131. Experimental and theoretical study of the 1,3-dipolar cycloaddition between d-glyceraldehyde nitrones and acrylates. Diastereoselective approach to 4-hydroxy pyroglutamic acid derivatives

    Article • Tetrahedron Asymmetry, February 2002, Elsevier

    Professor Pedro Merino

  132. Understanding the high diastereofacial discrimination in nucleophilic additions to nitrones: the first ab initio study on the nucleophilic addition reactions of chiral nitrones with Grignard reagents

    Article • Tetrahedron, September 2001, Elsevier

    Professor Pedro Merino

  133. Stereodivergent Approaches to the Synthesis of Isoxazolidine Analogues of α-Amino Acid Nucleosides. Total Synthesis of Isoxazolidinyl Deoxypolyoxin C and Uracil Polyoxin C †

    Article • The Journal of Organic Chemistry, September 2000, American Chemical Society (ACS)

    Professor Pedro Merino

  134. Stereoselective synthesis of l-isoxazolidinyl thymidine from N-benzyl-1,2-di-O-isopropylidene-d-glyceraldehyde nitrone (BIGN)

    Article • Tetrahedron Asymmetry, April 2000, Elsevier

    Professor Pedro Merino

  135. 1,3-Dipolar Cycloaddition of Furfuryl Nitrones with Acrylates. A Convenient Approach to Protected 4-Hydroxypyroglutamic Acids

    Article • The Journal of Organic Chemistry, March 2000, American Chemical Society (ACS)

    Professor Pedro Merino

  136. Highly diastereoselective nucleophilic addition of organometallic reagents to 2-pyrrolidinyl nitrones: a semiempirical approach

    Article • Tetrahedron Asymmetry, May 1999, Elsevier

    Dr Santiago Franco, Professor Pedro Merino

  137. Stereochemistry of α-(tert-butoxycarbonylamino) hydroxylamines: 1H NMR analysis of hydroxylamines derived from 2-pyrrolidinyl nitrones

    Article • Tetrahedron Asymmetry, May 1999, Elsevier

    Dr Santiago Franco, Professor Pedro Merino

  138. Chapter 2 Recent advances in the reaction of metalated aromatic heterocycles with carbonyl compounds and their imino derivatives

    Article • January 1999, Elsevier

    Professor Pedro Merino

  139. Asymmetric synthesis of an isoxazolidine nucleoside analog of thymine polyoxin C

    Article • Tetrahedron Letters, August 1998, Elsevier

    Dr Santiago Franco, Professor Pedro Merino

  140. Asymmetric Addition Reactions of Lithium (Trimethylsilyl)acetylide with Chiral α-Amino Nitrones. Synthesis of Diastereomerically Pure N-Hydroxy-α-amino Acids

    Article • The Journal of Organic Chemistry, July 1998, American Chemical Society (ACS)

    Professor Pedro Merino

  141. Erratum

    Article • Tetrahedron Asymmetry, June 1998, Elsevier

    Professor Pedro Merino

  142. Ready access to enantiopure 5-substituted-3-pyrrolin-2-ones from N-benzyl-2,3-O-isopropylidene-d-glyceraldehyde nitrone (BIGN)

    Article • Tetrahedron Asymmetry, May 1998, Elsevier

    Professor Pedro Merino

  143. Totally stereocontrolled synthesis of α,β-diamino acids by addition of Grignard reagents to nitrones derived from l -serine

    Article • Tetrahedron Asymmetry, February 1998, Elsevier

    Professor Pedro Merino

  144. Chiral Hydroxylamines. IV. 1-(N-Benzyl-N-hydroxyamino)-2:3;4:5-di-O-isopropylidene-α-D-mannofuranose

    Article • Acta Crystallographica Section C Crystal Structure Communications, November 1997, International Union of Crystallography

    Professor Pedro Merino

  145. Diastereoselective nucleophilic addition of acetylide to N-benzyl-2, nitrone (BIGN). Stereodivergent synthesis of β-hydroxy-α-(hydroxyamino)- and β-hydroxy-α-amino acids

    Article • Tetrahedron Asymmetry, October 1997, Elsevier

    Professor Pedro Merino

  146. Stereoselective grignard reactions to α-amino nitrones. Synthesis of optically active α-aminohydroxylamines and 1,2-diamines

    Article • Tetrahedron Asymmetry, July 1997, Elsevier

    Professor Pedro Merino

  147. A new entry to glycosylamines

    Article • Glycoconjugate Journal, June 1997, Springer Science + Business Media

    Professor Pedro Merino

  148. Stereocontrolled addition of Grignard reagents to α-alkoxy nitrones. Synthesis of syn and anti 3-amino-1,2-diols

    Article • Tetrahedron Asymmetry, June 1997, Elsevier

    Professor Pedro Merino

  149. 1,3-Dipolar cycloaddition of C-(2-thiazolyl)nitrones to chiral acrylates. Synthesis of enantiopure α-amino-2-alkylthiazoles and 5-formylpyrrolidin-2-ones

    Article • Tetrahedron, March 1997, Elsevier

    Professor Pedro Merino

  150. Stereocontrolled synthesis of 2,3-diaminobutanoic acids

    Article • Tetrahedron Letters, March 1997, Elsevier

    Professor Pedro Merino

  151. Direct vinylation and ethynylation of nitrones. Stereodivergent synthesis of allyl and propargyl amines

    Article • Tetrahedron Asymmetry, July 1996, Elsevier

    Professor Pedro Merino

  152. Absolute configuration determination in furfuryl amines and hydroxylamines by circular dichroism

    Article • Tetrahedron Asymmetry, May 1996, Elsevier

    Dr Santiago Franco, Professor Pedro Merino

  153. A straightforward synthesis of L-isoserinal

    Article • Tetrahedron, May 1996, Elsevier

    Professor Pedro Merino

  154. Enantioselective addition of Grignard reagents to a 2-thiazolyl nitrone

    Article • Tetrahedron Asymmetry, March 1996, Elsevier

    Professor Pedro Merino

  155. Chelation- and Non-chelation-Controlled Addition of 2-(Trimethylsilyl)thiazole to .alpha.-Amino Aldehydes: Stereoselective Synthesis of the .beta.-Amino-.alpha.-hydroxy Aldehyde Intermediate for the Preparation of the Human Immunodeficiency Virus Prote...

    Article • The Journal of Organic Chemistry, December 1995, American Chemical Society (ACS)

    Professor Pedro Merino

  156. Stereoselective Addition of Cyanide Reagents to Nitrones.

    Article • Tetrahedron Letters, September 1995, Elsevier

    Professor Pedro Merino

  157. Determination of the absolute configuration of α-amino-2-alkylthiazoles by circular dichroism

    Article • Tetrahedron Asymmetry, September 1995, Elsevier

    Professor Pedro Merino

  158. Total synthesis of thymine polyoxin C

    Article • Tetrahedron Letters, December 1994, Elsevier

    Professor Pedro Merino

  159. Tunable stereoselectivity in the addition of 2-lithiothiazole to L-serinal derived N-benzyl nitroe. Synthesis of C-2 epimer 2,3-diamino-4-hydroxybutanals

    Article • Journal of the Chemical Society Chemical Communications, January 1994, Royal Society of Chemistry

    Professor Pedro Merino

  160. Totally chemical synthesis of azasugars via thiazole intermediates. Stereodivergent routes to (-)-nojirimycin, (-)-mannojirimycin and their 3-deoxy derivatives from serine

    Article • Tetrahedron, April 1993, Elsevier

    Professor Pedro Merino

  161. Stereoselective aminohomologation of chiral α-alkoxy aldehydes via thiazole addition to nitrones. Application to the synthesis of N-acetyl-d-mannosamine

    Article • Tetrahedron Letters, July 1992, Elsevier

    Professor Pedro Merino

  162. On the reaction of anthranilic acid with thionyl chloride: The actual structure of “kametani's sulfinamide anhydride”

    Article • Tetrahedron Letters, July 1991, Elsevier

    Professor Pedro Merino

  163. A concise new route to 3-deoxy-d-manno-2-octulosonic acid (KDO) from D-arabinose and 2-acetylthiazole

    Article • Tetrahedron Letters, January 1990, Elsevier

    Professor Pedro Merino

  164. Regio- and stereoselective conjugate addition of nitrogen nucleophiles to 2-alkenyl n-methylthiazolium iodides. synthesis of d-3-epi-daunosamine and some lincosamine analogues

    Article • Tetrahedron, January 1990, Elsevier

    Professor Pedro Merino