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The search for low-cost and high-performance electrocatalysts for oxygen evolution reaction (OER) has aroused enormous research interest in the last few years. Reported herein is the topotactic construction of a binuclear Co-based metal–organic framework (Co2-tzpa) using a solvothermal reaction. Prominently, as a porous catalyst, Co2-tzpa holds its activity for at least 25 hours and exhibits low OER overpotentials of 336 and 396 mV to achieve the current density of 10 mA cm−2 in 1 M KOH and 0.1 M KOH, respectively. The excellent OER performance should be attributed to each cobalt site coordinated with two tetrazolate N atoms.

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This page is a summary of: A binuclear Co-based metal–organic framework towards efficient oxygen evolution reaction, Chemical Communications, January 2021, Royal Society of Chemistry,
DOI: 10.1039/d1cc01492g.
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