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A new strategy to prepare soluble homogeneous catalysts is developed by introducing imidazolium into cationic calix[4]arene-based metal–organic cages (MOCs). The soluble MOCs show high activity and recyclability in the cycloaddition reaction of CO2 without the addition of any co-catalysts. This method provides new inspiration to design highly efficient catalysts by combining the advantages of homogeneous and heterogeneous catalysis.

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This page is a summary of: Soluble imidazolium-functionalized coordination cages for efficient homogeneous catalysis of CO2 cycloaddition reactions, Chemical Communications, January 2021, Royal Society of Chemistry,
DOI: 10.1039/d0cc08098e.
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