Professor Martin Oestreich
Technische Universitat Berlin
Professor, Chemistry
Germany
My co-authors include
Rolf Breinbauer
Christophe DARCEL
Professor Thomas J J Müller
Find me at
My Publications
Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cycl...
Organic Letters
January 2020
Transition-Metal-Like Catalysis with a Main-Group Element: Bismuth-Catalyzed C−F Coupli...
Angewandte Chemie International Edition
January 2020
Übergangsmetallartige Katalyse mit einem Hauptgruppenelement: Bismutkatalysierte C‐F‐Ku...
Angewandte Chemie
January 2020
Formyltetrahydrofolate Decarbonylase Synthesizes the Active Site CO Ligand of O2-Tolera...
Journal of the American Chemical Society
January 2020
Stereospecific and Chemoselective Copper-Catalyzed Deaminative Silylation of Benzylic A...
Angewandte Chemie International Edition
December 2019
Stereospezifische und chemoselektive kupferkatalysierte, deaminierende Silylierung von ...
Angewandte Chemie
December 2019
General Synthesis and Optical Properties of N-Aryl-N′-Silyldiazenes
Organometallics
December 2019
Cationic silicon Lewis acids in catalysis
Nature Reviews Chemistry
November 2019
Chiral Modification of the Tetrakis(pentafluorophenyl)borate Anion with Myrtanyl Groups
European Journal of Organic Chemistry
November 2019
Ionic Transfer Reactions with Cyclohexadiene-Based Surrogates
Synlett
November 2019
Si-H Bond Activation with Bullock’s Cationic Tungsten(II) Catalyst: CO as Cooperating L...
Journal of the American Chemical Society
November 2019
Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane...
Angewandte Chemie International Edition
October 2019
Katalytische Difunktionalisierung von nichtaktivierten Alkenen mit reaktionsträgem Hexa...
Angewandte Chemie
October 2019
Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,...
Chemistry - A European Journal
October 2019
Lewis Säure‐katalysierte Transferhydromethallylierung für den Aufbau quartärer Kohlenst...
Angewandte Chemie
September 2019
Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Ca...
Angewandte Chemie International Edition
September 2019
Copper-Catalyzed Regio- and Enantioselective Addition of Silicon Grignard Reagents to A...
Angewandte Chemie International Edition
June 2019
Kupferkatalysierte regio‐ und enantioselektive Addition von Silicium‐Grignard‐Reagenzie...
Angewandte Chemie
June 2019
Metal-Free Transfer Hydrobromination of C–C Triple Bonds
Organic Letters
May 2019
Bioinspired Metal‐Free Formal Decarbonylation of α‐Branched Aliphatic Aldehydes at Ambi...
Chemistry - A European Journal
May 2019
Tertiary α-Silyl Alcohols by Diastereoselective Coupling of 1,3-Dienes and Acylsilanes ...
Angewandte Chemie International Edition
May 2019
Tertiäre α‐Silylalkohole mittels diastereoselektiver Kupplung von 1,3‐Dienen und Acylsi...
Angewandte Chemie
May 2019
Making the Silylation of Alcohols Chiral: Asymmetric Protection of Hydroxy Groups
Chemistry - A European Journal
May 2019
Regiodivergent and Stereospecific Aziridine Opening by Copper‐Catalyzed Addition of Sil...
Chemistry - A European Journal
April 2019
Mechanistic Dichotomy of Magnesium- and Zinc-Based Germanium Nucleophiles in the C(sp3 ...
Angewandte Chemie International Edition
April 2019
Gegensätzliche Reaktionsweisen magnesium‐ und zinkbasierter Germaniumnukleophile in der...
Angewandte Chemie
April 2019
Further Structural Modification of Sulfur-Stabilized Silicon Cations with Binaphthyl Ba...
Synthesis
March 2019
Enantioselective Construction of α-Chiral Silanes by Nickel-Catalyzed C(sp3 )−C(sp3 ) C...
Angewandte Chemie International Edition
February 2019
Enantioselektiver Aufbau von α‐chiralen Silanen durch nickelkatalysierte C(sp ...
Angewandte Chemie
February 2019
Axially Chiral, Electrophilic Fluorophosphonium Cations: Synthesis, Lewis Acidity, and ...
Organometallics
January 2019
Bor-Lewis-Säure-katalysierte Transferhydrocyanierung α- und α,β-substituierter Styrole
Angewandte Chemie
January 2019
Transfer Hydrocyanation of α- and α,β-Substituted Styrenes Catalyzed by Boron Lewis Acids
Angewandte Chemie International Edition
January 2019
Kinetic Resolution of Tertiary Propargylic Alcohols by Enantioselective Cu−H-Catalyzed ...
Angewandte Chemie International Edition
January 2019
Kinetische Racematspaltung tertiärer Propargylalkohole durch enantioselektive Cu-H-kata...
Angewandte Chemie
January 2019
Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydr...
Chemical Science
January 2019
Using alcohols as simple H2-equivalents for copper-catalysed transfer semihydrogenation...
Chemical Communications
January 2019
Metal-Free Transfer Hydroiodination of C–C Multiple Bonds
Journal of the American Chemical Society
December 2018
Copper-Catalyzed Cross-Coupling of Vinyliodonium Salts and Zinc-Based Silicon Nucleophiles
Organic Letters
December 2018
Palladium-Catalyzed Three-Component Reaction of Dihydrosilanes and Vinyl Iodides in the...
Chemistry - A European Journal
December 2018
C(sp3)–Si Cross-Coupling
ACS Catalysis
November 2018
Achieving Enantioselectivity in Difficult Cyclohexa-1,3-diene Diels–Alder Reactions wit...
Organic Letters
October 2018
Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substit...
Synthesis
October 2018
Einelektronenübertragungsreaktionen in frustrierten und klassischen Silyliumion/Phospha...
Angewandte Chemie
October 2018
Single-Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphan...
Angewandte Chemie International Edition
October 2018
Regioselective Transfer Hydrodeuteration of Alkenes with a Hydrogen Deuteride Surrogate...
Organic Letters
October 2018
Electrophilic Phosphonium Cations as Lewis Acid Catalysts in Diels–Alder Reactions and ...
Organometallics
September 2018
Bioinspired Catalytic Generation of Main-group Electrophiles by Cooperative Bond Activa...
CHIMIA International Journal for Chemistry
September 2018
Bench-Stable Stock Solutions of Silicon Grignard Reagents: Application to Iron- and Cob...
Angewandte Chemie International Edition
August 2018
Stabile Stammlösungen von Silicium-Grignard-Reagenzien: Anwendung in eisen- und cobaltk...
Angewandte Chemie
August 2018
Copper-Catalyzed Double C(sp3)–Si Coupling of Geminal Dibromides: Ionic-to-Radical Swit...
Organic Letters
August 2018
Enantioselective Nazarov Cyclizations Catalyzed by an Axial Chiral C6 F5 -Substituted B...
Angewandte Chemie International Edition
July 2018
Enantioselektive Nazarov-Cyclisierungen, die von einer axial-chiralen, C6 F5 -substitui...
Angewandte Chemie
July 2018
Z-Selective Hydrostannylation of Terminal and Internal C–C Triple Bonds Initiated by th...
Organometallics
July 2018
Copper-Catalyzed Silylation of C(sp3)–H Bonds Adjacent to Amide Nitrogen Atoms
Organic Letters
June 2018
Innenrücktitelbild: Kinetische Racematspaltung α-hydroxysubstituierter Oximether durch ...
Angewandte Chemie
June 2018
Inside Back Cover: Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantios...
Angewandte Chemie International Edition
June 2018
Cleavage of Unactivated Si−C(sp3 ) Bonds with Reed's Carborane Acids: Formation of Know...
Angewandte Chemie International Edition
June 2018
Spaltung nicht aktivierter Si-C(sp3 )-Bindungen mit Reedschen Carboransäuren: Bildung b...
Angewandte Chemie
June 2018
Custom Hydrosilane Synthesis Based on Monosilane
Chem
June 2018
Electrophilic Formylation of Arenes by Silylium Ion Mediated Activation of Carbon Monoxide
Angewandte Chemie International Edition
May 2018
Elektrophile Formylierung von Aromaten durch silyliumionvermittelte Aktivierung von Koh...
Angewandte Chemie
May 2018
Direct Acetophenone-Acetophenone Crossed Aldol Reaction and Aldol Self-Reaction Promote...
European Journal of Organic Chemistry
May 2018
Refinement of the Catalyst Backbone of Chiral Intramolecular Silicon-Sulfur Lewis Pairs...
European Journal of Organic Chemistry
May 2018
Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu−H-Catal...
Angewandte Chemie International Edition
April 2018
Kinetische Racematspaltung α-hydroxysubstituierter Oximether durch enantioselektive Cu-...
Angewandte Chemie
April 2018
A Neutral RuII Hydride Complex for the Regio- and Chemoselective Reduction of N -Silyl...
Chemistry - A European Journal
March 2018
The electrophilic aromatic substitution approach to C–H silylation and C–H borylation
Pure and Applied Chemistry
February 2018
Catalytic Dehydrogenative Stannylation of C(sp)–H Bonds Involving Cooperative Sn–H Bond...
Journal of the American Chemical Society
January 2018
Thermodynamic versus kinetic control in substituent redistribution reactions of silyliu...
Chemical Science
January 2018
Copper-Catalyzed Substitution of α-Triflyloxy Nitriles and Esters with Silicon Nucleoph...
Organic Letters
December 2017
Two-Silicon Cycle for Carbonyl Hydrosilylation with Nikonov’s Cationic Ruthenium(II) Ca...
ACS Catalysis
November 2017
Cooperative Al–H Bond Activation in DIBAL-H: Catalytic Generation of an Alumenium-Ion-L...
Journal of the American Chemical Society
November 2017
Cluster Preface: Silicon in Synthesis and Catalysis
Synlett
October 2017
An Expedient Procedure for the Synthesis of Benzo[4,5]silolo[2,3-b]thiophenes and Relat...
Organometallics
October 2017
Copper-Catalyzed Decarboxylative Radical Silylation of Redox-Active Aliphatic Carboxyli...
Angewandte Chemie International Edition
August 2017
Kupferkatalysierte decarboxylierende radikalische Silylierung von redoxaktiven aliphati...
Angewandte Chemie
August 2017
B(C6F5)3-Catalyzed Reduction of Sulfoxides and Sulfones to Sulfides with Hydrosilanes
Synthesis
July 2017
BArF3-Catalyzed Imine Hydroboration with Pinacolborane Not Requiring the Assistance of ...
Organometallics
June 2017
Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative...
Nature Communications
June 2017
Exhaustive Chemoselective Reduction of Nitriles by Catalytic Hydrosilylation Involving ...
Synlett
May 2017
Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A ...
Journal of the American Chemical Society
May 2017
Photocatalysis Enabling Acceptorless Dehydrogenation of Benzofused Saturated Rings at R...
Angewandte Chemie International Edition
May 2017
Photokatalyse ermöglicht die akzeptorfreie Dehydrierung von benzanellierten gesättigten...
Angewandte Chemie
May 2017
Synthesis of a Chiral Borate Counteranion, Its Trityl Salt, and Application Thereof in ...
European Journal of Organic Chemistry
April 2017
Cooperative Catalysis at Metal–Sulfur Bonds
Accounts of Chemical Research
April 2017
Access to Fully Alkylated Germanes by B(C6F5)3-Catalyzed Transfer Hydrogermylation of A...
Organic Letters
March 2017
A Tethered Ru-S Complex with an Axial Chiral Thiolate Ligand for Cooperative Si-H Bond ...
Chemistry - A European Journal
March 2017
Katalytische Friedel-Crafts-C-H-Borylierung elektronenreicher Arene: starke Reaktionsbe...
Angewandte Chemie International Edition
February 2017
Catalytic Friedel-Crafts C−H Borylation of Electron-Rich Arenes: Dramatic Rate Accelera...
Angewandte Chemie International Edition
February 2017
Hidden Enantioselective Hydrogenation of N-Silyl Enamines and Silyl Enol Ethers in Net ...
Organometallics
February 2017
B(C6F5)3-Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl...
Angewandte Chemie International Edition
February 2017
B(C6F5)3-katalysierte chemoselektive Defunktionalisierung von etherhaltigen primären Al...
Angewandte Chemie
February 2017
Bis(silylenyl)-substituted ferrocene-stabilized η<sup>6</sup>-arene iron(0) complexes: ...
Dalton Transactions
January 2017
Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed t...
Chemical Communications
January 2017
Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes
Chemical Science
January 2017
Catalytic Access to Indole-Fused Benzosiloles by 2-Fold Electrophilic C–H Silylation wi...
Organometallics
December 2016
Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel-Craft...
Angewandte Chemie International Edition
November 2016
Elektrophile aromatische Substitution mit Siliciumelektrophilen: die katalytische Fried...
Angewandte Chemie
November 2016
Teaching nature the unnatural
Science
November 2016
Stereodivergent Synthesis of β-Heteroatom-Substituted Vinylsilanes by Sequential Silyl...
Synthesis
November 2016
3-tert -Butyl-Substituted Cyclohexa-1,4-dienes as Isobutane Equivalents in the B(C6 F5 ...
Chemistry - A European Journal
October 2016
Copper-Catalyzed Cross-Coupling of Silicon Pronucleophiles with Unactivated Alkyl Elect...
Journal of the American Chemical Society
October 2016
Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF ...
Chemistry - A European Journal
August 2016
Enantioselective Diels–Alder Reactions of Cyclohexa-1,3-diene and Chalcones Catalyzed b...
Organometallics
August 2016
Ausbalancieren von C=C-Funktionalisierung und C=O-Reduktion in der Cu-H-Katalyse
Angewandte Chemie
August 2016
Balancing C=C Functionalization and C=O Reduction in Cu−H Catalysis
Angewandte Chemie International Edition
August 2016
Merging Platinum-Catalyzed Alkene Hydrosilylation with SiH4 Surrogates: Salt-Free Prepa...
Organometallics
July 2016
Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel–Craf...
Journal of the American Chemical Society
June 2016
B(C6F5)3-Catalyzed Reduction of Aromatic and Aliphatic Nitro Groups with Hydrosilanes
European Journal of Organic Chemistry
June 2016
Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru−S Complexes: From Coop...
Chemistry - A European Journal
June 2016
The Asymmetric Piers Hydrosilylation
Journal of the American Chemical Society
May 2016
Brønsted Acid-Catalyzed Transfer Hydrogenation of Imines and Alkenes Using Cyclohexa-1,...
Organic Letters
May 2016
Stereodivergent Silylzincation of α-Heteroatom-Substituted Alkynes
Organic Letters
April 2016
Metal-Free Phosphine Oxide Reductions Catalyzed by B(C6F5)3 and Electrophilic Fluoropho...
Organometallics
March 2016
An Air-Stable Dimeric Ru–S Complex with an NHC as Ancillary Ligand for Cooperative Si–H...
Organometallics
March 2016
Copper-Catalyzed Si–B Bond Activation in the Nucleophilic Substitution of Primary Aliph...
Synlett
March 2016
Planar Chiral, Ferrocene-Stabilized Silicon Cations
Chemistry - A European Journal
March 2016
Durch Nichtedelmetallsalze ausgelöste Friedel-Crafts-artige intermolekulare C-H-Silylie...
Angewandte Chemie
January 2016
Friedel-Crafts-Type Intermolecular C−H Silylation of Electron-Rich Arenes Initiated by ...
Angewandte Chemie International Edition
January 2016
Transfer Hydrosilylation
Angewandte Chemie International Edition
November 2015
Catalytic Electrophilic CH Silylation of Pyridines Enabled by Temporary Dearomatization
Angewandte Chemie International Edition
November 2015
Extending the Scope of the B(C6F5)3-Catalyzed CN Bond Reduction: Hydrogenation of Oxim...
Chemistry - A European Journal
October 2015
Phosphinic Amide as Directing Group Enabling Palladium(II)-CatalyzedorthoC−H Alkenylati...
Chemistry - An Asian Journal
September 2015
B(C6F5)3-Catalyzed Transfer of Dihydrogen from One Unsaturated Hydrocarbon to Another
Angewandte Chemie International Edition
August 2015
Formal SiH4 chemistry using stable and easy-to-handle surrogates
Nature Chemistry
August 2015
The Cyclohexadienyl-Leaving-Group Approach toward Donor-Stabilized Silylium Ions
Organometallics
August 2015
A Catalytic SEAr Approach to Dibenzosiloles Functionalized at Both Benzene Cores
Angewandte Chemie International Edition
July 2015
Intramolecularly Sulfur-Stabilized Silicon Cations with Chiral Binaphthyl Backbones: Sy...
Organometallics
June 2015
Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic S...
Chemistry - A European Journal
May 2015
Platinum(0)-Catalyzed Indolyne Insertion into Bis(pinacolato)diboron Followed by Site-S...
Organic Letters
April 2015
Synthesis of 2,6-Dihalogenated Purine Nucleosides by Thermostable Nucleoside Phosphoryl...
Advanced Synthesis & Catalysis
March 2015
A Constellation of Deuterium-Labeled Silanes as a Simple Mechanistic Probe not Requirin...
Angewandte Chemie International Edition
March 2015
Temperature-Dependent Direct Enantioconvergent Silylation of a Racemic Cyclic Allylic P...
Synthesis
February 2015
Faszinierende Chemie des Wasserstoffatomtransfers auf Alkene inspiriert durch Probleme ...
Angewandte Chemie International Edition
February 2015
Fascinating Hydrogen Atom Transfer Chemistry of Alkenes Inspired by Problems in Total S...
Angewandte Chemie International Edition
February 2015
Temperature-Dependent Chemoselective Hydrosilylation of Carbon Dioxide to Formaldehyde ...
Organometallics
February 2015
Direct and Transfer Hydrosilylation Reactions Catalyzed by Fully or Partially Fluorinat...
Organometallics
January 2015
A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes
Chemical Society Reviews
January 2015
Mechanism of the cooperative Si–H bond activation at Ru–S bonds
Chemical Science
January 2015
Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer co...
Chemical Science
January 2015
Asymmetric Addition of Boron and Silicon Nucleophiles
January 2015
B(C6F5)3-Catalyzed Transfer Hydrogenation of Imines and Related Heteroarenes Using Cycl...
Angewandte Chemie International Edition
December 2014
B(C6F5)3-katalysierte Transferhydrierung von Iminen und verwandten Heteroaromaten mit C...
Angewandte Chemie International Edition
December 2014
Exceptionally Mild Palladium(II)-Catalyzed Dehydrogenative C–H/C–H Arylation of Indolin...
Organic Letters
November 2014
Chemoselective Tin–Boron Exchange Aided by the Use of Dummy Ligands at the Tin Atom
Organometallics
October 2014
B(C6F5)3-Catalyzed Hydrogenation of Oxime Ethers without Cleavage of the NO Bond
Angewandte Chemie International Edition
October 2014
B(C6F5)3-katalysierte Hydrierung von Oximethern ohne Spaltung der N-O-Bindung
Angewandte Chemie
October 2014
Trans-Selective Radical Silylzincation of Ynamides
Angewandte Chemie International Edition
August 2014
Trans-Selective Radical Silylzincation of Ynamides
Angewandte Chemie
August 2014
McQuade’s Six-Membered NHC–Copper(I) Complexes for Catalytic Asymmetric Silyl Transfer
Synthesis
July 2014
Copper(I)-Catalyzed Regioselective Addition of Nucleophilic Silicon Across Terminal and...
Chemistry - An Asian Journal
July 2014
New Frontiers and Challenges in Silicon Chemistry:ISOS XVII in Berlin
Chemistry - A European Journal
July 2014
Intramolecularly Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts
Organometallics
July 2014
En Route to Stable All-Carbon-Substituted Silylenes: Synthesis and Reactivity of a Bis(...
Organometallics
July 2014
Martin Oestreich
Angewandte Chemie
June 2014
Martin Oestreich
Angewandte Chemie International Edition
June 2014
Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes...
Chemistry - A European Journal
May 2014
Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationi...
Journal of the American Chemical Society
May 2014
Enantioselektive Addition von Siliciumnukleophilen an Aldimine mit einem präformierten ...
Angewandte Chemie International Edition
April 2014
Enantioselective Addition of Silicon Nucleophiles to Aldimines Using a Preformed NHC-Co...
Angewandte Chemie International Edition
April 2014
Diastereotopic Group Selection in Hydroxy‐Directed Intramolecular CH Alkenylation of I...
Advanced Synthesis & Catalysis
March 2014
Tris(5,6,7,8-tetrafluoronaphthalen-2-yl)borane, a Partially Fluorinated Boron Lewis Aci...
Organometallics
March 2014
Brandaktuelles von der enantioselektiven intermolekularen Heck-Reaktion
Angewandte Chemie
January 2014
Breaking News on the Enantioselective Intermolecular Heck Reaction
Angewandte Chemie International Edition
January 2014
Salt-Free Preparation of Trimethylsilyl Ethers by B(C6F5)3-Catalyzed Transfer Silylatio...
European Journal of Organic Chemistry
January 2014
Metal-Catalyzed Cross-Coupling Reactions and More
January 2014
7.21 Addition Reactions with Formation of CarbonHalogen Bonds
January 2014
Ferrocene-Stabilized Silicon Cations as Catalysts for Diels–Alder Reactions: Attempted ...
Organometallics
December 2013
Silylium Ion Promoted Reduction of Imines with Hydrosilanes
Organometallics
November 2013
Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction wit...
Journal of the American Chemical Society
November 2013
The Family of Ferrocene‐Stabilized Silylium Ions: Synthesis,29Si NMR Characterization, ...
Chemistry - A European Journal
October 2013
Oxidative Palladium(II)-Catalyzed C-7 Alkenylation of Indolines
Organic Letters
October 2013
3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-C...
Angewandte Chemie International Edition
September 2013
3-Silylierte Cyclohexa-1,4-diene als Vorstufen für gasförmige Hydrosilane: die B(C6F5)3...
Angewandte Chemie
September 2013
Katalytische 1,4-selektive Hydrosilylierung von Pyridinverbindungen und benzanellierten...
Angewandte Chemie
August 2013
Catalytic 1,4-Selective Hydrosilylation of Pyridines and Benzannulated Congeners
Angewandte Chemie International Edition
August 2013
Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive D...
Journal of the American Chemical Society
July 2013
Main-Group Lewis Acids for C–F Bond Activation
ACS Catalysis
July 2013
Oxidative Palladium(II)-Catalyzed Dehydrogenative CH/CH Cross-Coupling of 2,3-Substit...
Chemistry - A European Journal
July 2013
Regio- and Diastereoselective Copper(I)-Catalyzed Allylic Substitution of δ-Hydroxy All...
European Journal of Organic Chemistry
June 2013
SiH Bond Activation: Bridging Lewis Acid Catalysis with Brookhart’s Iridium(III) Pince...
Angewandte Chemie International Edition
April 2013
Si-H-Bindungsaktivierung: Parallelen der Lewis-Säure-Katalyse mit Brookharts Iridium(II...
Angewandte Chemie
April 2013
Asymmetrische Synthese α-chiraler Allylsilane durch enantiokonvergente γ-selektive Kupf...
Angewandte Chemie
March 2013
Asymmetric Synthesis of α-Chiral Allylic Silanes by Enantioconvergent γ-Selective Coppe...
Angewandte Chemie International Edition
March 2013
C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silic...
Journal of the American Chemical Society
January 2013
The Renaissance of Silicon-Stereogenic Silanes: A Personal Account
January 2013
Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis
Chemical Reviews
January 2013
Catalytic dehydrogenative Si–N coupling of pyrroles, indoles, carbazoles as well as ani...
Chemical Communications
January 2013
Aerobic Palladium(II)-Catalyzed Dehydrogenation of Cyclohexene-1-carbonyl Indole Amides...
The Journal of Organic Chemistry
October 2012
Reversible Heterolytic Si–H Bond Activation by an Intramolecular Frustrated Lewis Pair
Zeitschrift für Naturforschung B
October 2012
Illuminating the Mechanism of the Borane-Catalyzed Hydrosilylation of Imines with Both ...
Chemistry - A European Journal
September 2012
1,2,3,4-Tetrahydro-1-(1,1-dimethylethyl)-1-silanaphthalene
September 2012
1,2,3,4-Tetrahydro-1-(1-methylethyl)-1-silanaphthalene
September 2012
Hemilabile BINAP(O) as a Chiral Ligand in Desymmetrizing Mizoroki-Heck Cyclizations
ChemCatChem
August 2012
Copper(I)-Catalyzed Regio- and Chemoselective Single and Double Addition of Nucleophili...
Organic Letters
August 2012
Base-Free Dehydrogenative Coupling of Enolizable Carbonyl Compounds with Silanes
Organic Letters
June 2012
Two-Directional Desymmetrization by Double 1,4-Addition of Silicon and Boron Nucleophiles
Organic Letters
May 2012
Organic Reactions. Volume 75 (Diamond Volume). Herausgegeben von Scott E. Denmark.
Angewandte Chemie
April 2012
Organic Reactions. Volume 75 (Diamond Volume). Edited by Scott E. Denmark.
Angewandte Chemie International Edition
April 2012
Catalytic enantioselective dehydrogenative Si–O coupling of oxime ether-functionalized ...
Tetrahedron
April 2012
Silylium Ion-Catalyzed Challenging Diels–Alder Reactions: The Danger of Hidden Proton C...
Journal of the American Chemical Society
February 2012
Ein neuer Weg der C-H-Alkenylierung: Silanol als helfende Hand
Angewandte Chemie
January 2012
A New Direction in CH Alkenylation: Silanol as a Helping Hand
Angewandte Chemie International Edition
January 2012
Aerobic Palladium(II)-Catalyzed 5-endo-trig Cyclization: An Entry into the Diastereosel...
Angewandte Chemie International Edition
December 2011
Aerobe Palladium(II)-katalysierte 5-endo-trig-Cyclisierung als ein Einstieg in die dias...
Angewandte Chemie
December 2011
Copper-Catalyzed 1,2-Addition of Nucleophilic Silicon to Aldehydes: Mechanistic Insight...
Chemistry - A European Journal
October 2011
BINAP versus BINAP(O) in Asymmetric Intermolecular Mizoroki-Heck Reactions: Substantial...
Chemistry - A European Journal
September 2011
Copper(I)-Catalyzed Regioselective Propargylic Substitution Involving Si–B Bond Activation
Organic Letters
August 2011
A New Motif for Lewis Base Catalysis: Asymmetric Reduction of β-Enamino Esters
ChemCatChem
August 2011
A Unique Transition Metal-Stabilized Silicon Cation
Journal of the American Chemical Society
August 2011
An Axially Chiral, Electron-Deficient Borane: Synthesis, Coordination Chemistry, Lewis ...
Chemistry - A European Journal
July 2011
Activation of the Si−B Linkage: Copper-Catalyzed Addition of Nucleophilic Silicon to Im...
Organic Letters
April 2011
Shortened Synthesis of a Silicon-Stereogenic Cyclic Silane
Synthesis
April 2011
Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low...
Journal of the American Chemical Society
March 2011
Organische Chemie 2010
Nachrichten aus der Chemie
March 2011
All-Carbon-Substituted Quaternary Carbon Atoms in Oxindoles by an Aerobic Palladium(II)...
European Journal of Organic Chemistry
January 2011
Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate ad...
Chemical Communications
January 2011
Self-regeneration of a silylium ion catalyst in carbonyl reduction
Chemical Communications
January 2011
Stereochemical Surprises in the Lewis Acid-Mediated Allylation of Isatins
The Journal of Organic Chemistry
October 2010
Kupferkatalysierte Si-B-Bindungsaktivierung in der verzweigtselektiven allylischen Subs...
Angewandte Chemie
September 2010
Copper-Catalyzed SiB Bond Activation in Branched-Selective Allylic Substitution of Lin...
Angewandte Chemie International Edition
September 2010
Base-Catalyzed Dehydrogenative Si-O Coupling of Dihydrosilanes: Silylene Protection of ...
Synlett
August 2010
Transition-Metal-Catalyzed C-P Cross-Coupling Reactions
Synthesis
August 2010
Der asymmetrische konjugierte Silyltransfer in iterativen katalytischen Sequenzen: Synt...
Angewandte Chemie
July 2010
Asymmetric Conjugate Silyl Transfer in Iterative Catalytic Sequences: Synthesis of the ...
Angewandte Chemie International Edition
July 2010
Expeditious synthesis of TADDOL-derived phosphoramidite and phosphonite ligands
Tetrahedron Asymmetry
May 2010
Katalytische asymmetrische Si-O-Kupplung einfacher achiraler Silane und chiraler donorf...
Angewandte Chemie
March 2010
Catalytic Asymmetric SiO Coupling of Simple Achiral Silanes and Chiral Donor-Functiona...
Angewandte Chemie International Edition
March 2010
Organische Chemie 2009
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March 2010
Enantioselektive konjugierte Borylierung
Angewandte Chemie
February 2010
Enantioselective Conjugate Borylation
Angewandte Chemie International Edition
January 2010
Silicon- and Tin-Based Cuprates: Now Catalytic in Copper!
Chemistry - A European Journal
January 2010
Expedient access to branched allylic silanes by copper-catalysed allylic substitution o...
Chemical Communications
January 2010
Asymmetric Si–O coupling of alcohols
Organic & Biomolecular Chemistry
January 2010
Silylium ions in catalysis
Dalton Transactions
January 2010
Enantioselective Fujiwara-Moritani Indole and Pyrrole Annulations Catalyzed by Chiral P...
European Journal of Organic Chemistry
November 2009
Ein gezähmtes Silyliumion für Diels-Alder-Reaktionen bei niedrigen Temperaturen
Angewandte Chemie International Edition
October 2009
Taming the Silylium Ion for Low-Temperature Diels-Alder Reactions
Angewandte Chemie International Edition
October 2009
B(C 6 F 5 ) 3 -Catalyzed Reduction of Ketones and Imines Using Silicon-Stereogenic Sil...
European Journal of Organic Chemistry
October 2009
Conjugate phosphination of cyclic and acyclic acceptors using Rh(I)–phosphine or Rh(I)–...
Tetrahedron
August 2009
Rhodium(I)-catalyzed enantioselective 1,4-addition of nucleophilic silicon
Tetrahedron
July 2009
Enantiospezifische Synthese und Allylierung ausschließlich Kohlenstoff-substituierter, ...
Angewandte Chemie International Edition
June 2009
Enantiospecific Synthesis and Allylation of All-Carbon-Substituted α-Chiral Allylic Sta...
Angewandte Chemie International Edition
June 2009
Asymmetrische Ringschlussmetathese mit Pfiff
Angewandte Chemie International Edition
March 2009
Asymmetric Ring-Closing Metathesis with a Twist
Angewandte Chemie International Edition
March 2009
Palladium(II)-Catalyzed Conjugate Phosphination of Electron-Deficient Acceptors
Organic Letters
March 2009
Potassiumtert-Butoxide-Catalyzed Dehydrogenative SiO Coupling: Reactivity Pattern and ...
Chemistry - An Asian Journal
March 2009
Organische Chemie 2008
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March 2009
The Mizoroki–Heck Reaction
February 2009
Facile preparation of CF3-substituted carbinols with an azine donor and subsequent kine...
Organic & Biomolecular Chemistry
January 2009
Stereoselective Alcohol Silylation by Dehydrogenative Si-O Coupling: Scope, Limitations...
Chemistry - A European Journal
November 2008
A Catalytic Asymmetric Fujiwara-Moritani Cyclization
Synlett
August 2008
Schlüssiger Nachweis eines SN2-Si-Mechanismus in der B(C6F5)3- katalysierten Hydrosilyl...
Angewandte Chemie
July 2008
Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation o...
Angewandte Chemie International Edition
July 2008
Transition-Metal-Free Conjugate Stannyl Transfer to α,β-Unsaturated Carbonyl and Carbox...
Synlett
July 2008
Katalytische asymmetrische C-Si-Bindungsknüpfung an acyclischen α,β-ungesättigten Akzep...
Angewandte Chemie
May 2008
Catalytic Asymmetric CSi Bond Formation to Acyclic α,β-Unsaturated Acceptors by RhI-Ca...
Angewandte Chemie International Edition
May 2008
Enantio- and Diastereotopos Differentiation in the Palladium(II)-Catalyzed Hydrosilylat...
European Journal of Organic Chemistry
May 2008
Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereose...
Organic & Biomolecular Chemistry
January 2008
Kinetic Resolution and Desymmetrization by Stereoselective Silylation of Alcohols
Angewandte Chemie International Edition
January 2008
Kinetische Racematspaltung und Desymmetrisierung durch stereoselektive Silylierung von ...
Angewandte Chemie
January 2008
Chirale Erkennung mit siliciumstereogenen Silanen: außergewöhnliche Selektivitätsfaktor...
Angewandte Chemie International Edition
December 2007
Chiral Recognition with Silicon-Stereogenic Silanes: Remarkable Selectivity Factors in ...
Angewandte Chemie International Edition
December 2007
Oxygen Donor-Mediated Equilibration of Diastereomeric Alkene−Palladium(II) Intermediate...
Journal of the American Chemical Society
November 2007
Silicon-Stereogenic Silanes in Asymmetric Catalysis
Synlett
July 2007
Polishing a Diamond in the Rough: “Cu—H” Catalysis with Silanes
ChemInform
April 2007
Asymmetric Synthesis - The Essentials
Synthesis
March 2007
Conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis: A compa...
Beilstein Journal of Organic Chemistry
February 2007
Vom Schleifen eines “Rohdiamanten”: die “Cu-H”-Katalyse mit Silanen
Angewandte Chemie
January 2007
Polishing a Diamond in the Rough: “CuH” Catalysis with Silanes
Angewandte Chemie International Edition
January 2007
Rhodium(i)-catalysed conjugate phosphination of cyclic α,β-unsaturated ketones with sil...
Chemical Communications
January 2007
Directed Mizoroki–Heck Reactions
January 2007
Synthesis by Hydration of Alkynes
January 2007
Synthesis by Direct Hydration
January 2007
Intermolecular Chirality Transfer from Silicon to Carbon: Interrogation of the Two-Sil...
Journal of the American Chemical Society
January 2007
Organische Chemie online… und gratis?
Angewandte Chemie
November 2006
Organic Chemistry Online … and for Free?
Angewandte Chemie International Edition
November 2006
An Enantioselective Access to an Anthracycline AB Synthon by a Desymmetrizing Heck Cyc...
Synlett
November 2006
Rhodiumkatalysierter enantioselektiver konjugierter Silyltransfer: 1,4-Addition von Sil...
Angewandte Chemie
August 2006
Rhodium-Catalyzed Enantioselective Conjugate Silyl Transfer: 1,4-Addition of Silyl Boro...
Angewandte Chemie International Edition
August 2006
Preparation of a Privileged Silicon-Stereogenic Silane: Classicalversus Kinetic Resolution
Advanced Synthesis & Catalysis
July 2006
Copper-Free and Copper-Promoted Conjugate Addition Reactions of Bis(triorganosilyl) Zin...
Synthesis
July 2006
Organische Chemie 2005
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March 2006
Quaternary Stereocenters. Challenges and Solutions for Organic Synthesis. Herausgegeben...
Angewandte Chemie
January 2006
Quaternary Stereocenters. Challenges and Solutions for Organic Synthesis. Edited by Jen...
Angewandte Chemie International Edition
January 2006
Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl...
Chemical Communications
January 2006
Silylzincation of carbon–carbon multiple bonds revisited
Chemical Communications
January 2006
Chirality Transfer from Silicon to Carbon
Chemistry - A European Journal
January 2006
Kinetische Racematspaltung von chiralen sekundären Alkoholen durch dehydrierende Kupplu...
Angewandte Chemie
November 2005
Kinetic Resolution of Chiral Secondary Alcohols by Dehydrogenative Coupling with Recycl...
Angewandte Chemie International Edition
November 2005
OMCOS 13
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October 2005
Kaleidoskop der Katalyse: Heidelberger Forum für Molekulare Katalyse 2005
Angewandte Chemie International Edition
August 2005
Kaleidoscope of Catalysis: Heidelberg Forum of Molecular Catalysis 2005
Angewandte Chemie International Edition
August 2005
Schweizer Leckerli: Bürgenstock 2005
Angewandte Chemie
June 2005
Swiss Delight: Bürgenstock 2005
Angewandte Chemie International Edition
June 2005
Chemie-Nachwuchsgruppenleiter in Freiburg
Nachrichten aus der Chemie
May 2005
Strategien zur katalytischen asymmetrischen elektrophilen ?-Halogenierung von Carbonylv...
Angewandte Chemie International Edition
April 2005
Strategies for Catalytic Asymmetric Electrophilic ? Halogenation of Carbonyl Compounds
Angewandte Chemie International Edition
April 2005
Practical Synthesis of Allylic Silanes from Allylic Esters and Carbamates by Stereosele...
Advanced Synthesis & Catalysis
April 2005
?Echter? Chiralit�tstransfer von Silicium auf Kohlenstoff: asymmetrische Verst�rkung in...
Angewandte Chemie
March 2005
?True? Chirality Transfer from Silicon to Carbon: Asymmetric Amplification in a Reagent...
Angewandte Chemie International Edition
March 2005
Neighbouring‐Group Effects in Heck Reactions
European Journal of Organic Chemistry
March 2005
Hypervalent Silicon as a Reactive Site in Selective Bond-Forming Processes
Synthesis
January 2005
Catalytic Desymmetrizing Intramolecular Heck Reaction: Evidence for an Unusual Hydroxy-...
Angewandte Chemie International Edition
January 2005
On the Mechanism of the Reductive Metallation of Asymmetrically Substituted Silyl Chlor...
European Journal of Organic Chemistry
January 2005
Katalytische desymmetrisierende intramolekulare Heck-Reaktion: Nachweis einer ungewöhnl...
Angewandte Chemie International Edition
December 2004
Facile protocol for the highly regioselective and stereodivergent synthesis of substitu...
Chemical Communications
January 2004
23. Regio-Symposium in Falkau/Schwarzwald
Nachrichten aus der Chemie
January 2004
Copper-Catalyzed Conjugate Addition of a Bis(triorganosilyl) Zinc and a Methyl(triorgan...
Synlett
January 2004
Catalytic Asymmetric Synthesis of Quaternary Carbons Bearing Two Aryl Substituents. Ena...
Journal of the American Chemical Society
May 2003
A Convergent Method for the Synthesis of Highly Enantiomerically Enriched Cyclic Silane...
Synthesis
January 2003
Vereitelteβ-Hydrideliminierung: Abfangen der Alkylpalladiumzwischenstufe einer asymmetr...
Angewandte Chemie
April 2001
Thwartingβ-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymme...
Angewandte Chemie International Edition
April 2001
Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Comp...
Chemistry - A European Journal
August 2000
Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Comp...
Chemistry - A European Journal
August 2000
(−)-Sparteine-Mediated Asymmetric Intramolecular Carbolithiation of Alkenes: Synthesis ...
Helvetica Chimica Acta
November 1999
Helvetica Chimica Acta
November 1999
(−)-Sparteine-Mediated Stereoselective Intramolecular Carbolithiation of 4-Substituted ...
The Journal of Organic Chemistry
November 1999
Corrigendum
Tetrahedron Letters
April 1999
(−)-Sparteine-mediated stereoselective intramolecular conjugate addition reactions of d...
Tetrahedron Letters
March 1999
(−)-Sparteine-mediated stereoselective intramolecular carbolithiation of alkynes
Tetrahedron Letters
March 1998
Stereoselective Preparation and Reactions of Cycloalkylzinc Compounds
Angewandte Chemie International Edition in English
February 1997
Stereoselektive Herstellung und Reaktionen von Cycloalkylzinkverbindungen
Angewandte Chemie
February 1997
Formation of Carbocycles
Palladium-Catalyzed Arylation Reactions of Alkenes (Mizoroki–Heck Reaction and Related ...
Taming Super Lewis Acids for Catalysis: The Family of Ferrocene-Stabilized Silicon Cations
Diverse Modes of Silane Activation for the Hydrosilylation of Carbonyl Compounds