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  1. Triarylborane-Catalyzed Homogeneous Molecular Transformations Using Organic Reductants
  2. Nickel-Catalyzed Enantio- and Regioconvergent Synthesis of Allyl Aryl Thioethers from α- or γ-Silylated Allylic Chlorides
  3. Silylium-Ion-Initiated Disulfidation of Unactivated Alkenes with Disulfides: Methodology and Isolation of the Sulfenium-Ion Carriers
  4. Synthesis of Azo-Substituted Benzoxazin-4-ones by Base-Mediated Addition of Diazenyl Anions to Isatoic Anhydrides
  5. Silylium‐Ion‐Initiated Disulfidation of Internal Alkynes With Disulfides
  6. Copper-Catalyzed Enantioselective Conjugate Borylation of Silacyclohexadienones to Construct Highly Congested Stereocenters Adjacent to C−Si Bonds
  7. Intramolecular Silylarylation of α‐Olefins Enabled by Disulfide Co‐Catalysis and Maintained by Proton‐into‐Silylium Interconversion
  8. Intramolecular Silylarylation of α‐Olefins Enabled by Disulfide Co‐Catalysis and Maintained by Proton‐into‐Silylium Interconversion
  9. Proton-into-Silylium Ion Generation as a Mechanistic Switch: Divergent Ring-Opening Arylation of CF 3 -Substituted Cyclopropanes
  10. Asymmetric Transition-Metal-Catalyzed Hydrofunctionalization of Alkenylmetalloids (B, Si, and Ge)
  11. The Cation Shuffle: Interplay of silylium, carbenium, and arenium ions in superelectrophile catalysis
  12. Photoredox-Catalyzed Transfer Thiobenzoyloxylation of Styrenes Using Oxime-Based Surrogates
  13. Regio- and stereoselective tert -butylthiolation of internal alkynes with thioethers initiated and maintained by silylium-ion catalysis
  14. A general synthesis of nitriles from nitroalkanes with bis(catecholato)diboron
  15. Mechanism of the palladium-catalyzed diazenylation of aryl electrophiles: carbonate-facilitated transmetalation and ligand-dependent selectivity
  16. Enantioconvergent access to 1,1-diarylmethine silanes and germanes through nickel/photoredox-catalyzed cross-electrophile coupling
  17. Epimerization-Free Synthesis of Azo-Substituted Di- and Tripeptides by Cross-Coupling of O-Triflated Derivatives and Diazenyl Anion Equivalents
  18. Kinetics and Mechanism of Enantioselective Cu-Catalyzed Alcohol Silylation
  19. Photoinduced Deoxygenative Boration of Unactivated Alcohols Involving In-Situ-Formed Alkyl Iodides
  20. Photoredox-Catalyzed Transfer Thio(poly)fluoroacyloxylation of Alkenes Using Oxime-Based Surrogates
  21. Enantioselective Miyaura Reaction by Desymmetrizing C(sp2)–B Cross‐Coupling of 1,1′‐Biaryl‐2,6‐diyl Bis(nonaflates)
  22. Enantioselective Miyaura Reaction by Desymmetrizing C(sp2)–B Cross‐Coupling of 1,1′‐Biaryl‐2,6‐diyl Bis(nonaflates)
  23. Analysis of Cyclohexa-1,4-dienes with an Asymmetrically Substituted, 3° Carbon Atom as Chiral Dihydrogen Surrogates in Reagent-Controlled Transfer Hydrogenation of Alkenes
  24. Directing Effects of Silyl and Germyl Groups in Transition‐Metal‐Catalyzed Allylic Substitution
  25. Atroposelective Synthesis of Azobenzenes by Palladium-Catalyzed Cross-Coupling of Racemic Biaryl Triflates and Diazenyl Pronucleophiles
  26. Isolation of halogen-substituted silylium ions
  27. Silylium-Ion-Promoted Formation of Methylenecyclobutenes by Formal (2 + 2) Cycloaddition of Allenylsilanes and Internal Alkynes
  28. Kinetic Resolution of BINAMs by Stereoselective Copper-Catalyzed Dehydrogenative Si–N Coupling with Prochiral Dihydrosilanes
  29. Nickel-Catalyzed Enantioconvergent C(sp3)–C(sp3) Cross-Coupling between α-Iodogermanes and Alkylzinc Reagents
  30. Dynamic Kinetic C(sp2)–Si Cross-Coupling with Si–B Reagents for the Atroposelective Construction of Unsymmetrical Heterobiaryls
  31. Kinetic Resolution of Acyclic 1,3-Diols by Copper-Catalyzed Regioselective Dehydrogenative Si–O-Coupling
  32. Photoredox-Catalyzed Transfer Aminochlorination of Unactivated Alkenes Using Oxime-Based Surrogates
  33. One-Pot Sequential Alcohol Activation and Nickel-Catalyzed Cross-Electrophile Coupling with Chlorosilanes
  34. Ionic Remote α-C–H Allenylation of Silyl Ethers Involving a [1,5]-Hydride Shift Promoted by Silylium-Ion Regeneration
  35. Silylium-Ion-Promoted (3 + 2) Annulation of Allenylsilanes with Internal Alkynes Involving a Pentadienyl-to-Allyl Cation Electrocyclization
  36. Enantio‐ and Diastereoselective Desymmetrization of 1,1’‐Biaryl‐2,6‐Dicarbaldehydes by Copper‐Catalyzed 1,2‐Addition of Silicon Nucleophiles
  37. Enantio‐ und Diastereoselektive Desymmetrisierung von 1,1’‐Biaryl‐2,6‐Dicarbaldehyden durch kupferkatalysierte 1,2‐Addition von Siliciumnukleophilen
  38. Kinetic Resolution of BINOLs and Biphenols by Atroposelective, Cu–H-Catalyzed Si–O Coupling with Hydrosilanes
  39. Enantio‐ and Regioconvergent Nickel‐Catalyzed Etherification of Phenols by Allylation to Access Chiral C(sp3)−O Allyl Aryl Ethers
  40. Enantio‐ und regiokonvergente, nickelkatalysierte Veretherung von Phenolen durch Allylierung zur Darstellung chiraler C(sp3)−O‐Allylarylether
  41. From Process Chemistry to Methodology Development in Metal-Mediated Chemistry and Catalysis
  42. Ring Contraction of Saturated Cyclic Amines and Rearrangement of Acyclic Amines Through Their Corresponding Hydroxylamines
  43. Ring Contraction of Saturated Cyclic Amines and Rearrangement of Acyclic Amines Through Their Corresponding Hydroxylamines
  44. Cationic Bis(hydrosilane)—Coinage‐Metal Complexes: Synthesis, Characterization, and Use as Catalysts for Outer‐Sphere C=O Hydrosilylation Not Involving Metal Hydrides
  45. Cationic Bis(hydrosilane)—Coinage‐Metal Complexes: Synthesis, Characterization, and Use as Catalysts for Outer‐Sphere C=O Hydrosilylation Not Involving Metal Hydrides
  46. Ni–H-Catalyzed Chemo- and Regioselective Hydroarylation of Vinylsilanes
  47. Synthesis of a Cationic Cobalt–Selenolate Complex for Cooperative Sn–H Bond Activation: Solvent-Dependent Stereoselectivity in Alkyne Hydrostannylation
  48. Silylium-Ion-Initiated Twofold Halodealkylation of Fully Alkylated Silanes
  49. Enantioselective Dearomatization of Pyridinium Salts by Copper‐Catalyzed C4‐Selective Addition of Silicon Nucleophiles
  50. Enantioselektive Dearomatisierung von Pyridiniumsalzen durch kupferkatalysierte C4‐selektive Addition von Siliciumnukleophilen
  51. Functional group transfer strategies unlock new synthetic avenues
  52. Electrophilic Activation of S−Si Reagents by Silylium Ions for Their Regio‐ and Diastereoselective Addition Across C−C Multiple Bonds
  53. Elektrophile Aktivierung von S−Si‐Reagenzien mit Silyliumionen für deren regio‐ und diastereoselektive Addition an C−C‐Mehrfachbindungen
  54. Copper-catalyzed silylation of aryl and alkenyl triflates with silylboronic esters avoiding base-mediated borylation
  55. Chiral Carborane Acids Decorated with Binol-Based Phosphonates: Synthesis, Characterization, and Application
  56. Desymmetrization of Cyclohexadienones Containing a Quaternary γ-Carbon Atom by Conjugate Addition of Boron Nucleophiles
  57. Ligand-Controlled On–Off Switch of a Silicon-Tethered Directing Group Enabling the Regiodivergent Hydroalkylation of Vinylsilanes under Ni–H Catalysis
  58. Bond-Forming Processes Enabled by Silicon-Masked Aryl- and Alkyl-Substituted Diazenes
  59. Arenium-ion-catalysed halodealkylation of fully alkylated silanes
  60. Skeletal Rearrangements Involving Cyclopropyl- and Alkene-Stabilized Silylium Ions
  61. Fluoride-Catalyzed Arylation of α-(Trifluoromethyl)styrene Derivatives with Silicon-Masked, Functionalized Aryl Pronucleophiles
  62. Generation of Silicon-Centered Stereogenicity by Chiral Counteranion-Directed Desymmetrization of Silanediols
  63. Dehydrative Coupling of 1,1-Diarylalkenes and Cyclohexa-2,5-diene-1-carbaldehyde Derivatives Induced by a B(C6F5)3-Initiated [1,2]-Alkyl Migration
  64. Regioselective Hydroalkylation of Vinyl- and Allylsilanes as Well as Vinylgermanes under Ni–H Catalysis
  65. Discrimination of the Enantiotopic Faces of Structurally Unbiased Carbenium Ions Employing a Cyclohexadiene‐Based Chiral Hydride Source
  66. Unterscheidung der enantiotopen Seiten von strukturell unvoreingenommenen Carbeniumionen unter Verwendung einer cyclohexadienbasierten, chiralen Hydridquelle
  67. The Two Faces of Carbenium Ions: Intermolecular Trapping of Prochiral Carbocations with Stereocontrol
  68. Atroposelective Silylation of 1,1′‐Biaryl‐2,6‐diols by a Chiral Counteranion Directed Desymmetrization Enhanced by a Subsequent Kinetic Resolution
  69. Atropselektive Silylierung von 1,1′‐Biaryl‐2,6‐diolen mittels chiraler gegenaniondirigierter Desymmetrisierung und anschließender Verbesserung durch kinetische Racematspaltung
  70. Enantio- and Regioconvergent Synthesis of γ-Stereogenic Vinyl Germanes and Their Use as Masked Vinyl Halides
  71. Intramolecular 7-endo-dig-Selective Carbosilylation of Internal Alkynes Involving Silylium-Ion Regeneration
  72. Photoinduced radical–ionic dihalogen transfer to carbon–carbon multiple bonds using oxime-based surrogates
  73. Catalytically Generated Meerwein’s Salt-Type Oxonium Ions for Friedel–Crafts C(sp2)–H Methylation with Methanol
  74. B(C6F5)3‐Catalyzed Regioselective Ring Opening of Cyclic Amines with Hydrosilanes
  75. Silylium Ion Initiated Intramolecular Friedel–Crafts-Type Cyclization of 1,1-Difluoroalkenes with Subsequent Hydrodefluorination of C(sp3)–F Bonds
  76. Copper‐Catalyzed Highly Enantioselective Addition of a Silicon Nucleophile to 3‐Substituted 2H‐Azirines Using an Si−B Reagent
  77. Kupferkatalysierte, hochgradig enantioselektive Addition eines Siliciumnukleophils an 3‐substituierte 2H‐Azirine unter Verwendung eines Si‐B‐Reagenzes
  78. The [3]Dendralene Motif as an Entry into Nazarov Cyclizations by Silylium-Ion Initiation
  79. Advances in Enantioconvergent Transition-Metal-Catalyzed Cross-Coupling Reactions of Racemic α-Silyl and α-Boryl Reagents
  80. Atom-economic and stereoselective catalytic synthesis of fully substituted enol esters/carbonates of amides in acyclic systems enabled by boron Lewis acid catalysis
  81. Experimental Mechanistic Analysis of Carbonyl Hydrosilylation Catalyzed by Abu-Omar’s Rhenium(V) Oxo Complex
  82. Synthesis of Benzhydryl-Substituted Amines by Silanolate-Mediated Aldimine Arylation with Functionalized Aryl Nucleophiles Released from Diazene-Based Reagents
  83. Palladium-Catalyzed Denitrogenative Cross-Coupling of Silicon-Masked, Aryl-Substituted Diazenes and Aryl Bromides
  84. Silylium-Ion-Promoted Skeletal Reorganization of β-Silylated Cyclopropanes Bearing an Allyl Group at the Silicon Atom Coupled with Intermolecular Formation of a Quaternary Carbon Atom
  85. Boosting the Enantioselectivity of Conjugate Borylation of α,β‐Disubstituted Cyclobutenones with Monooxides of ChiralC2‐Symmetric Bis(phosphine) Ligands
  86. Synthese von unsymmetrischen Azobenzolen durch palladiumkatalysierte Kreuzkupplung von siliciummaskierten Diazenylanionen und (Hetero)arylhalogeniden
  87. Synthesis of Non‐Symmetric Azoarenes by Palladium‐Catalyzed Cross‐Coupling of Silicon‐Masked Diazenyl Anions and (Hetero)Aryl Halides
  88. Photochemical, Nickel-Catalyzed C(sp3)–C(sp3) Reductive Cross-Coupling of α-Silylated Alkyl Electrophiles and Allylic Sulfones
  89. Enantio- and Regioconvergent Nickel-Catalyzed Allylic Substitution of Racemic α- or γ-Silylated Allylic Bromides with Benzylzinc Reagents
  90. Intermolecular Carbosilylation of α‐Olefins with C(sp3)−C(sp) Bond Formation Involving Silylium‐Ion Regeneration
  91. Intermolekulare Carbosilylierung von α‐Olefinen mit C(sp3)−C(sp)‐Bindungsknüpfung unter Neubildung von Silyliumionen
  92. B(C6F5)3-Catalyzed Reductive Denitrogenation of Benzonitrile Derivatives
  93. Decarbonylative Transfer Hydrochlorination of Alkenes and Alkynes Based on a B(C6F5)3‐Initiated Grob Fragmentation
  94. Decarbonylierende Transferhydrochlorierung von Alkenen und Alkinen auf Grundlage einer B(C6F5)3‐ausgelösten Grob‐Fragmentierung
  95. Cationic Cobalt–Thiolate Complexes for the Dehydrogenative Coupling of nBu3SnH
  96. Perdeuteration of Deactivated Aryl Halides by H/D Exchange under Superelectrophile Catalysis
  97. Silylium-Ion-Promoted Hydrosilylation of Aryl-Substituted Allenes: Interception by Cyclization of the Allyl-Cation Intermediate
  98. Competition for Hydride Between Silicon and Boron: Synthesis and Characterization of a Hydroborane‐Stabilized Silylium Ion
  99. Metal-free transfer hydrochlorination of internal C–C triple bonds with a bicyclo[3.1.0]hexane-based surrogate releasing two molecules of hydrogen chloride
  100. One out of Four: Kinetic Resolution of Stereoisomeric Mixtures of Secondary Alcohols with a Quaternary Carbon Atom in the β-Position by Cu–H-Catalyzed Enantioselective Silylation
  101. Enantioselective, Copper-Catalyzed Addition of Nucleophilic Silicon to Alkenyl-Substituted Phosphine Oxides
  102. Synthesis of Silylated Cyclobutanone and Cyclobutene Derivatives Involving 1,4‐Addition of Zinc‐Based Silicon Nucleophiles
  103. Silylium-Ion Regeneration by Protodesilylation Enables Friedel–Crafts Alkylation with Less Isomerization and No Defunctionalization
  104. The Power of the Proton: From Superacidic Media to Superelectrophile Catalysis
  105. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  106. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  107. Nickelkatalysierte, reduktive C(sp3)‐Si‐Kreuzkupplung von α‐cyanosubstituierten Alkylelektrophilen und Chlorsilanen
  108. Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes
  109. Transition‐Metal‐Free Coupling of Polyfluorinated Arenes and Functionalized, Masked Aryl Nucleophiles
  110. B(C6F5)3-Catalyzed Diastereoselective Formal (4 + 1)-Cycloaddition of Vinylcyclopropanes and Et2SiH2
  111. Radical entry into Ni-catalyzed transfer hydrocyanation using cheap AIBN
  112. Metal‐Free Hydrosilylation of Ketenes with Silicon Electrophiles: Access to Fully Substituted Aldehyde‐Derived Silyl Enol Ethers
  113. Enantio‐ and Regioconvergent Nickel‐Catalyzed C(sp3)−C(sp3) Cross‐Coupling of Allylic Electrophiles Steered by a Silyl Group
  114. Enantio‐ und regiokonvergente, nickelkatalysierte C(sp3)‐C(sp3)‐Kreuzkupplung von allylischen Elektrophilen gelenkt durch eine Silylgruppe
  115. Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts
  116. Chemoselective Deoxygenation of 2° Benzylic Alcohols through a Sequence of Formylation and B(C6F5)3‐Catalyzed Reduction
  117. Enantioconvergent and Regioselective Synthesis of Allenylsilanes by Nickel-Catalyzed C(sp2)–C(sp3) Cross-Coupling Starting from Racemic α-Silylated Propargylic Bromides
  118. Development of a Radical Silylzincation of (Het)Aryl‐Substituted Alkynes and Computational Insights into the Origin of the trans‐Stereoselectivity
  119. Diastereotopic Group-Selective Intramolecular Aldol Reactions Initiated by Enantioselective Conjugate Silylation: Diastereodivergence Controlled by the Silicon Nucleophile
  120. The Trityl Cation Embedded into a [7]Helicene-Like Backbone: Preparation and Application as a Lewis Acid Catalyst
  121. Aufeinanderfolgende β,β′‐selektive C(sp3)‐H‐Silylierung von tertiären Aminen mit Dihydrosilanen katalysiert durch B(C6F5)3
  122. Consecutive β,β′‐Selective C(sp3)−H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C6F5)3
  123. At Long Last: The Me3Si Group as a Masked Alcohol
  124. Zu guter Letzt: Die Me3Si‐Gruppe als ein getarnter Alkohol
  125. Activation of the Si–B interelement bond related to catalysis
  126. Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes
  127. Mild reductive rearrangement of oximes and oxime ethers to secondary amines with hydrosilanes catalyzed by B(C6F5)3
  128. Kinetic Resolution of Neopentylic Secondary Alcohols by Cu–H-Catalyzed Enantioselective Silylation with Hydrosilanes
  129. Cationic Ru–Se Complexes for Cooperative Si–H Bond Activation
  130. Dynamic Kinetic Resolution of Alcohols by Enantioselective Silylation Enabled by Two Orthogonal Transition‐Metal Catalysts
  131. Dynamische kinetische Racematspaltung von Alkoholen mittels enantioselektiver Silylierung ermöglicht durch zwei orthogonale Übergangsmetallkatalysatoren
  132. The Cyclohexa‐2,5‐dienyl Group as a Placeholder for Hydrogen: Organocatalytic Michael Addition of an Acetaldehyde Surrogate
  133. Enantioselective Synthesis of α-Chiral Propargylic Silanes by Copper-Catalyzed 1,4-Selective Addition of Silicon Nucleophiles to Enyne-Type α,β,γ,δ-Unsaturated Acceptors
  134. B(C6F5)3-Catalyzed Hydrosilylation of Vinylcyclopropanes
  135. Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates
  136. Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration
  137. Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration
  138. Reductive Deamination with Hydrosilanes Catalyzed by B(C6F5)3
  139. Reduktive Desaminierung mit Hydrosilanen katalysiert durch B(C6F5)3
  140. Copper-Catalyzed Enantioselective and Exo-Selective Addition of Silicon Nucleophiles to 7-Oxa- and 7-Azabenzonorbornadiene Derivatives
  141. Synthese eines gegenanionstabilisierten Bis(silylium)ions
  142. Synthesis of a Counteranion‐Stabilized Bis(silylium) Ion
  143. Kilian Muñiz (1970–2020)
  144. Seeds for the Future: Growing Chemistry Trends
  145. Autocatalytic Carbonyl Arylation through In Situ Release of Aryl Nucleophiles from N‐Aryl‐N′‐Silyldiazenes
  146. Autokatalytische Carbonylarylierung mittels lokaler Freisetzung von Arylnukleophilen ausgehend von N‐Aryl‐N′‐silyldiazenen
  147. Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes
  148. Transition-Metal-Like Catalysis with a Main-Group Element: Bismuth-Catalyzed C−F Coupling of Aryl Boronic Esters
  149. Übergangsmetallartige Katalyse mit einem Hauptgruppenelement: Bismutkatalysierte C‐F‐Kupplung von Arylboronsäureestern
  150. Formyltetrahydrofolate Decarbonylase Synthesizes the Active Site CO Ligand of O2-Tolerant [NiFe] Hydrogenase
  151. Defunctionalisation catalysed by boron Lewis acids
  152. Emerging Strategies for C–H Silylation
  153. Outstanding Reviewers for Chemical Science in 2019
  154. Stereospecific and Chemoselective Copper-Catalyzed Deaminative Silylation of Benzylic Ammonium Triflates
  155. Stereospezifische und chemoselektive kupferkatalysierte, deaminierende Silylierung von Benzylammoniumtriflaten
  156. General Synthesis and Optical Properties of N-Aryl-N′-Silyldiazenes
  157. Cationic silicon Lewis acids in catalysis
  158. Chiral Modification of the Tetrakis(pentafluorophenyl)borate Anion with Myrtanyl Groups
  159. Ionic Transfer Reactions with Cyclohexadiene-Based Surrogates
  160. Si-H Bond Activation with Bullock’s Cationic Tungsten(II) Catalyst: CO as Cooperating Ligand
  161. Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions
  162. Katalytische Difunktionalisierung von nichtaktivierten Alkenen mit reaktionsträgem Hexamethyldisilan durch Neubildung von Silyliumionen
  163. Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes
  164. Lewis Säure‐katalysierte Transferhydromethallylierung für den Aufbau quartärer Kohlenstoffzentren
  165. Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers
  166. Characterization of hydrogen-substituted silylium ions in the condensed phase
  167. Copper-Catalyzed Regio- and Enantioselective Addition of Silicon Grignard Reagents to Alkenes Activated by Azaaryl Groups
  168. Kupferkatalysierte regio‐ und enantioselektive Addition von Silicium‐Grignard‐Reagenzien an durch Azaarylgruppen aktivierte Alkene
  169. Metal-Free Transfer Hydrobromination of C–C Triple Bonds
  170. Bioinspired Metal‐Free Formal Decarbonylation of α‐Branched Aliphatic Aldehydes at Ambient Temperature
  171. Tertiary α-Silyl Alcohols by Diastereoselective Coupling of 1,3-Dienes and Acylsilanes Initiated by Enantioselective Copper-Catalyzed Borylation
  172. Tertiäre α‐Silylalkohole mittels diastereoselektiver Kupplung von 1,3‐Dienen und Acylsilanen, eingeleitet durch enantioselektive kupferkatalysierte Borylierung
  173. Making the Silylation of Alcohols Chiral: Asymmetric Protection of Hydroxy Groups
  174. Regiodivergent and Stereospecific Aziridine Opening by Copper‐Catalyzed Addition of Silicon Grignard Reagents
  175. Mechanistic Dichotomy of Magnesium- and Zinc-Based Germanium Nucleophiles in the C(sp3 )−Ge Cross-Coupling with Alkyl Electrophiles
  176. Gegensätzliche Reaktionsweisen magnesium‐ und zinkbasierter Germaniumnukleophile in der C(sp 3 )‐Ge‐Kreuzkupplung mit Alkylelektrophilen
  177. Further Structural Modification of Sulfur-Stabilized Silicon Cations with Binaphthyl Backbones
  178. Enantioselective Construction of α-Chiral Silanes by Nickel-Catalyzed C(sp3 )−C(sp3 ) Cross-Coupling
  179. Enantioselektiver Aufbau von α‐chiralen Silanen durch nickelkatalysierte C(sp 3 )‐C(sp 3 )‐Kreuzkupplung
  180. Axially Chiral, Electrophilic Fluorophosphonium Cations: Synthesis, Lewis Acidity, and Reactivity in the Hydrosilylation of Ketones
  181. Bor-Lewis-Säure-katalysierte Transferhydrocyanierung α- und α,β-substituierter Styrole
  182. Transfer Hydrocyanation of α- and α,β-Substituted Styrenes Catalyzed by Boron Lewis Acids
  183. Kinetic Resolution of Tertiary Propargylic Alcohols by Enantioselective Cu−H-Catalyzed Si−O Coupling
  184. Kinetische Racematspaltung tertiärer Propargylalkohole durch enantioselektive Cu-H-katalysierte Si-O-Kupplung
  185. Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydroxyalkylboration of 1,3-dienes with ketones
  186. Using alcohols as simple H2-equivalents for copper-catalysed transfer semihydrogenations of alkynes
  187. Metal-Free Transfer Hydroiodination of C–C Multiple Bonds
  188. Copper-Catalyzed Cross-Coupling of Vinyliodonium Salts and Zinc-Based Silicon Nucleophiles
  189. Palladium-Catalyzed Three-Component Reaction of Dihydrosilanes and Vinyl Iodides in the Presence of Alcohols: Rapid Assembly of Silyl Ethers of Tertiary Silanes
  190. C(sp3)–Si Cross-Coupling
  191. Achieving Enantioselectivity in Difficult Cyclohexa-1,3-diene Diels–Alder Reactions with Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts
  192. Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution
  193. Einelektronenübertragungsreaktionen in frustrierten und klassischen Silyliumion/Phosphan-Lewis-Paaren
  194. Single-Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphane Lewis Pairs
  195. Regioselective Transfer Hydrodeuteration of Alkenes with a Hydrogen Deuteride Surrogate Using B(C6F5)3 Catalysis
  196. Electrophilic Phosphonium Cations as Lewis Acid Catalysts in Diels–Alder Reactions and Nazarov Cyclizations
  197. Bioinspired Catalytic Generation of Main-group Electrophiles by Cooperative Bond Activation
  198. Bench-Stable Stock Solutions of Silicon Grignard Reagents: Application to Iron- and Cobalt-Catalyzed Radical C(sp3 )-Si Cross-Coupling Reactions
  199. Stabile Stammlösungen von Silicium-Grignard-Reagenzien: Anwendung in eisen- und cobaltkatalysierten radikalischen C(sp3 )-Si-Kreuzkupplungsreaktionen
  200. Copper-Catalyzed Double C(sp3)–Si Coupling of Geminal Dibromides: Ionic-to-Radical Switch in the Reaction Mechanism
  201. Enantioselective Nazarov Cyclizations Catalyzed by an Axial Chiral C6 F5 -Substituted Boron Lewis Acid
  202. Enantioselektive Nazarov-Cyclisierungen, die von einer axial-chiralen, C6 F5 -substituierten Bor-Lewis-Säure katalysiert werden
  203. Z-Selective Hydrostannylation of Terminal and Internal C–C Triple Bonds Initiated by the Trityl Cation
  204. Copper-Catalyzed Silylation of C(sp3)–H Bonds Adjacent to Amide Nitrogen Atoms
  205. Innenrücktitelbild: Kinetische Racematspaltung α-hydroxysubstituierter Oximether durch enantioselektive Cu-H-katalysierte Si-O-Kupplung (Angew. Chem. 33/2018)
  206. Inside Back Cover: Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu−H-Catalyzed Si−O Coupling (Angew. Chem. Int. Ed. 33/2018)
  207. Cleavage of Unactivated Si−C(sp3 ) Bonds with Reed's Carborane Acids: Formation of Known and Unknown Silylium Ions
  208. Spaltung nicht aktivierter Si-C(sp3 )-Bindungen mit Reedschen Carboransäuren: Bildung bekannter und unbekannter Silyliumionen
  209. Custom Hydrosilane Synthesis Based on Monosilane
  210. Electrophilic Formylation of Arenes by Silylium Ion Mediated Activation of Carbon Monoxide
  211. Elektrophile Formylierung von Aromaten durch silyliumionvermittelte Aktivierung von Kohlenmonoxid
  212. Direct Acetophenone-Acetophenone Crossed Aldol Reaction and Aldol Self-Reaction Promoted by a Tethered Ru-S Complex
  213. Refinement of the Catalyst Backbone of Chiral Intramolecular Silicon-Sulfur Lewis Pairs: Improved Enantioselectivity in the Diels-Alder Reaction of Cyclohexa-1,3-diene and Chalcone Derivatives
  214. Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu−H-Catalyzed Si−O Coupling
  215. Kinetische Racematspaltung α-hydroxysubstituierter Oximether durch enantioselektive Cu-H-katalysierte Si-O-Kupplung
  216. A Neutral RuII Hydride Complex for the Regio- and Chemoselective Reduction of N -Silylpyridinium Ions
  217. The electrophilic aromatic substitution approach to C–H silylation and C–H borylation
  218. Catalytic Dehydrogenative Stannylation of C(sp)–H Bonds Involving Cooperative Sn–H Bond Activation of Hydrostannanes
  219. Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion
  220. Copper-Catalyzed Substitution of α-Triflyloxy Nitriles and Esters with Silicon Nucleophiles under Inversion of the Configuration
  221. Two-Silicon Cycle for Carbonyl Hydrosilylation with Nikonov’s Cationic Ruthenium(II) Catalyst
  222. Cooperative Al–H Bond Activation in DIBAL-H: Catalytic Generation of an Alumenium-Ion-Like Lewis Acid for Hydrodefluorinative Friedel–Crafts Alkylation
  223. Cluster Preface: Silicon in Synthesis and Catalysis
  224. An Expedient Procedure for the Synthesis of Benzo[4,5]silolo[2,3-b]thiophenes and Related Systems
  225. Copper-Catalyzed Decarboxylative Radical Silylation of Redox-Active Aliphatic Carboxylic Acid Derivatives
  226. Kupferkatalysierte decarboxylierende radikalische Silylierung von redoxaktiven aliphatischen Carbonsäurederivaten
  227. B(C6F5)3-Catalyzed Reduction of Sulfoxides and Sulfones to Sulfides with Hydrosilanes
  228. BArF3-Catalyzed Imine Hydroboration with Pinacolborane Not Requiring the Assistance of an Additional Lewis Base
  229. Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes
  230. Exhaustive Chemoselective Reduction of Nitriles by Catalytic Hydrosilylation Involving Cooperative Si–H Bond Activation
  231. Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study
  232. Photocatalysis Enabling Acceptorless Dehydrogenation of Benzofused Saturated Rings at Room Temperature
  233. Photokatalyse ermöglicht die akzeptorfreie Dehydrierung von benzanellierten gesättigten Ringen bei Raumtemperatur
  234. Synthesis of a Chiral Borate Counteranion, Its Trityl Salt, and Application Thereof in Lewis-Acid Catalysis
  235. Cooperative Catalysis at Metal–Sulfur Bonds
  236. Access to Fully Alkylated Germanes by B(C6F5)3-Catalyzed Transfer Hydrogermylation of Alkenes
  237. A Tethered Ru-S Complex with an Axial Chiral Thiolate Ligand for Cooperative Si-H Bond Activation: Application to Enantioselective Imine Reduction
  238. Katalytische Friedel-Crafts-C-H-Borylierung elektronenreicher Arene: starke Reaktionsbeschleunigung durch Versetzen mit Alkenen
  239. Catalytic Friedel-Crafts C−H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes
  240. Hidden Enantioselective Hydrogenation of N-Silyl Enamines and Silyl Enol Ethers in Net C═N and C═O Hydrosilylations Catalyzed by Ru–S Complexes with One Monodentate Chiral Phosphine Ligand
  241. B(C6F5)3-Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl Tosylates with Hydrosilanes
  242. B(C6F5)3-katalysierte chemoselektive Defunktionalisierung von etherhaltigen primären Alkyltosylaten mit Hydrosilanen
  243. Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application
  244. Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes
  245. Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes
  246. C H Bond Functionalization at the Benzene Core of Indoles and Indolines (Excluding C-2 and C-3)
  247. 4.4.7 Product Subclass 7: Silylboron Reagents
  248. Catalytic Access to Indole-Fused Benzosiloles by 2-Fold Electrophilic C–H Silylation with Dihydrosilanes
  249. Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel-Crafts C−H Silylation
  250. Elektrophile aromatische Substitution mit Siliciumelektrophilen: die katalytische Friedel-Crafts-C-H-Silylierung
  251. Teaching nature the unnatural
  252. Stereodivergent Synthesis of β-Heteroatom-Substituted Vinyl­silanes by Sequential Silylzincation–Copper(I)-Mediated Electrophilic­ Substitution
  253. 3-tert -Butyl-Substituted Cyclohexa-1,4-dienes as Isobutane Equivalents in the B(C6 F5 )3 -Catalyzed Transfer Hydro-tert -Butylation of Alkenes
  254. Copper-Catalyzed Cross-Coupling of Silicon Pronucleophiles with Unactivated Alkyl Electrophiles Coupled with Radical Cyclization
  255. Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF 3 Does What B(C6 F5 )3 Cannot Do!
  256. Enantioselective Diels–Alder Reactions of Cyclohexa-1,3-diene and Chalcones Catalyzed by Intramolecular Silicon–Sulfur Lewis Pairs as Chiral Lewis Acids
  257. Ausbalancieren von C=C-Funktionalisierung und C=O-Reduktion in der Cu-H-Katalyse
  258. Balancing C=C Functionalization and C=O Reduction in Cu−H Catalysis
  259. Merging Platinum-Catalyzed Alkene Hydrosilylation with SiH4 Surrogates: Salt-Free Preparation of Trihydrosilanes
  260. Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel–Crafts C–H Silylation
  261. B(C6F5)3-Catalyzed Reduction of Aromatic and Aliphatic Nitro Groups with Hydrosilanes
  262. Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru−S Complexes: From Cooperative Dihydrogen Activation to Hydride Abstraction/Proton Release from Dihydrogen Surrogates
  263. The Asymmetric Piers Hydrosilylation
  264. Brønsted Acid-Catalyzed Transfer Hydrogenation of Imines and Alkenes Using Cyclohexa-1,4-dienes as Dihydrogen Surrogates
  265. Stereodivergent Silylzincation of α-Heteroatom-Substituted Alkynes
  266. Metal-Free Phosphine Oxide Reductions Catalyzed by B(C6F5)3 and Electrophilic Fluorophosphonium Cations
  267. An Air-Stable Dimeric Ru–S Complex with an NHC as Ancillary Ligand for Cooperative Si–H Bond Activation
  268. Copper-Catalyzed Si–B Bond Activation in the Nucleophilic Substitution of Primary Aliphatic Triflates
  269. Planar Chiral, Ferrocene-Stabilized Silicon Cations
  270. Durch Nichtedelmetallsalze ausgelöste Friedel-Crafts-artige intermolekulare C-H-Silylierung von elektronenreichen Arenen
  271. Friedel-Crafts-Type Intermolecular C−H Silylation of Electron-Rich Arenes Initiated by Base-Metal Salts
  272. Transfer Hydrosilylation
  273. Catalytic Electrophilic CH Silylation of Pyridines Enabled by Temporary Dearomatization
  274. Extending the Scope of the B(C6F5)3-Catalyzed CN Bond Reduction: Hydrogenation of Oxime Ethers and Hydrazones
  275. Phosphinic Amide as Directing Group Enabling Palladium(II)-CatalyzedorthoC−H Alkenylation of Anilines without and with Alkylation at the Nitrogen Atom
  276. B(C6F5)3-Catalyzed Transfer of Dihydrogen from One Unsaturated Hydrocarbon to Another
  277. Formal SiH4 chemistry using stable and easy-to-handle surrogates
  278. The Cyclohexadienyl-Leaving-Group Approach toward Donor-Stabilized Silylium Ions
  279. A Catalytic SEAr Approach to Dibenzosiloles Functionalized at Both Benzene Cores
  280. Intramolecularly Sulfur-Stabilized Silicon Cations with Chiral Binaphthyl Backbones: Synthesis of Three Different Motifs and Their Application in Enantioselective Diels–Alder Reactions
  281. Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors
  282. Platinum(0)-Catalyzed Indolyne Insertion into Bis(pinacolato)diboron Followed by Site-Selective Suzuki–Miyaura Cross-Coupling
  283. Synthesis of 2,6-Dihalogenated Purine Nucleosides by Thermostable Nucleoside Phosphorylases
  284. A Constellation of Deuterium-Labeled Silanes as a Simple Mechanistic Probe not Requiring Absolute Configuration Determination
  285. Temperature-Dependent Direct Enantioconvergent Silylation of a Racemic Cyclic Allylic Phosphate by Copper(I)-Catalyzed Allylic Substitution
  286. Faszinierende Chemie des Wasserstoffatomtransfers auf Alkene inspiriert durch Probleme in Totalsynthesen
  287. Fascinating Hydrogen Atom Transfer Chemistry of Alkenes Inspired by Problems in Total Synthesis
  288. Temperature-Dependent Chemoselective Hydrosilylation of Carbon Dioxide to Formaldehyde or Methanol Oxidation State
  289. Direct and Transfer Hydrosilylation Reactions Catalyzed by Fully or Partially Fluorinated Triarylboranes: A Systematic Study
  290. A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes
  291. Mechanism of the cooperative Si–H bond activation at Ru–S bonds
  292. Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex
  293. Asymmetric Addition of Boron and Silicon Nucleophiles
  294. B(C6F5)3-Catalyzed Transfer Hydrogenation of Imines and Related Heteroarenes Using Cyclohexa-1,4-dienes as a Dihydrogen Source
  295. B(C6F5)3-katalysierte Transferhydrierung von Iminen und verwandten Heteroaromaten mit Cyclohexa-1,4-dienen als Wasserstoffquelle
  296. Exceptionally Mild Palladium(II)-Catalyzed Dehydrogenative C–H/C–H Arylation of Indolines at the C-7 Position under Air
  297. Chemoselective Tin–Boron Exchange Aided by the Use of Dummy Ligands at the Tin Atom
  298. B(C6F5)3-Catalyzed Hydrogenation of Oxime Ethers without Cleavage of the NO Bond
  299. B(C6F5)3-katalysierte Hydrierung von Oximethern ohne Spaltung der N-O-Bindung
  300. Trans-Selective Radical Silylzincation of Ynamides
  301. Trans-Selective Radical Silylzincation of Ynamides
  302. McQuade’s Six-Membered NHC–Copper(I) Complexes for Catalytic Asymmetric­ Silyl Transfer
  303. Copper(I)-Catalyzed Regioselective Addition of Nucleophilic Silicon Across Terminal and Internal Carbon-Carbon Triple Bonds
  304. New Frontiers and Challenges in Silicon Chemistry:ISOS XVII in Berlin
  305. Intramolecularly Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts
  306. En Route to Stable All-Carbon-Substituted Silylenes: Synthesis and Reactivity of a Bis(α-spirocyclopropyl)silylene
  307. Martin Oestreich
  308. Martin Oestreich
  309. Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative SiN Coupling
  310. Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex
  311. Enantioselektive Addition von Siliciumnukleophilen an Aldimine mit einem präformierten NHC-Kupfer(I)-Komplex als Katalysator
  312. Enantioselective Addition of Silicon Nucleophiles to Aldimines Using a Preformed NHC-Copper(I) Complex as the Catalyst
  313. Diastereotopic Group Selection in Hydroxy‐Directed Intramolecular CH Alkenylation of Indole under Oxidative Palladium(II) Catalysis
  314. Tris(5,6,7,8-tetrafluoronaphthalen-2-yl)borane, a Partially Fluorinated Boron Lewis Acid with Fluorination Distal to the Boron Atom
  315. Brandaktuelles von der enantioselektiven intermolekularen Heck-Reaktion
  316. Breaking News on the Enantioselective Intermolecular Heck Reaction
  317. Salt-Free Preparation of Trimethylsilyl Ethers by B(C6F5)3-Catalyzed Transfer Silylation by Using a Me3SiH Surrogate
  318. Metal-Catalyzed Cross-Coupling Reactions and More
  319. 7.21 Addition Reactions with Formation of CarbonHalogen Bonds
  320. Ferrocene-Stabilized Silicon Cations as Catalysts for Diels–Alder Reactions: Attempted Experimental Quantification of Lewis Acidity and ReactIR Kinetic Analysis
  321. Silylium Ion Promoted Reduction of Imines with Hydrosilanes
  322. Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism
  323. The Family of Ferrocene‐Stabilized Silylium Ions: Synthesis,29Si NMR Characterization, Lewis Acidity, Substituent Scrambling, and Quantum‐Chemical Analyses
  324. Oxidative Palladium(II)-Catalyzed C-7 Alkenylation of Indolines
  325. 3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes
  326. 3-Silylierte Cyclohexa-1,4-diene als Vorstufen für gasförmige Hydrosilane: die B(C6F5)3-katalysierte Transferhydrosilylierung von Alkenen
  327. Katalytische 1,4-selektive Hydrosilylierung von Pyridinverbindungen und benzanellierten Verwandten
  328. Catalytic 1,4-Selective Hydrosilylation of Pyridines and Benzannulated Congeners
  329. Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane
  330. Main-Group Lewis Acids for C–F Bond Activation
  331. Oxidative Palladium(II)-Catalyzed Dehydrogenative CH/CH Cross-Coupling of 2,3-Substituted Indolines with Arenes at the C7 Position
  332. Regio- and Diastereoselective Copper(I)-Catalyzed Allylic Substitution of δ-Hydroxy Allylic Chlorides by a Silicon Nucleophile
  333. SiH Bond Activation: Bridging Lewis Acid Catalysis with Brookhart’s Iridium(III) Pincer Complex and B(C6F5)3
  334. Si-H-Bindungsaktivierung: Parallelen der Lewis-Säure-Katalyse mit Brookharts Iridium(III)-Pincerkomplex und B(C6F5)3
  335. Asymmetrische Synthese α-chiraler Allylsilane durch enantiokonvergente γ-selektive Kupfer(I)-katalysierte allylische Silylierung
  336. Asymmetric Synthesis of α-Chiral Allylic Silanes by Enantioconvergent γ-Selective Copper(I)-Catalyzed Allylic Silylation
  337. C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle
  338. The Renaissance of Silicon-Stereogenic Silanes: A Personal Account
  339. Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis
  340. Catalytic dehydrogenative Si–N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base
  341. Aerobic Palladium(II)-Catalyzed Dehydrogenation of Cyclohexene-1-carbonyl Indole Amides: An Indole-Directed Aromatization
  342. Reversible Heterolytic Si–H Bond Activation by an Intramolecular Frustrated Lewis Pair
  343. Illuminating the Mechanism of the Borane-Catalyzed Hydrosilylation of Imines with Both an Axially Chiral Borane and Silane
  344. 1,2,3,4-Tetrahydro-1-(1,1-dimethylethyl)-1-silanaphthalene
  345. 1,2,3,4-Tetrahydro-1-(1-methylethyl)-1-silanaphthalene
  346. Hemilabile BINAP(O) as a Chiral Ligand in Desymmetrizing Mizoroki-Heck Cyclizations
  347. Copper(I)-Catalyzed Regio- and Chemoselective Single and Double Addition of Nucleophilic Silicon to Propargylic Chlorides and Phosphates
  348. Base-Free Dehydrogenative Coupling of Enolizable Carbonyl Compounds with Silanes
  349. Two-Directional Desymmetrization by Double 1,4-Addition of Silicon and Boron Nucleophiles
  350. Organic Reactions. Volume 75 (Diamond Volume). Herausgegeben von Scott E. Denmark.
  351. Organic Reactions. Volume 75 (Diamond Volume). Edited by Scott E. Denmark.
  352. Catalytic enantioselective dehydrogenative Si–O coupling of oxime ether-functionalized alcohols
  353. Silylium Ion-Catalyzed Challenging Diels–Alder Reactions: The Danger of Hidden Proton Catalysis with Strong Lewis Acids
  354. Ein neuer Weg der C-H-Alkenylierung: Silanol als helfende Hand
  355. A New Direction in CH Alkenylation: Silanol as a Helping Hand
  356. Aerobic Palladium(II)-Catalyzed 5-endo-trig Cyclization: An Entry into the Diastereoselective C-2 Alkenylation of Indoles with Tri- and Tetrasubstituted Double Bonds
  357. Aerobe Palladium(II)-katalysierte 5-endo-trig-Cyclisierung als ein Einstieg in die diastereoselektive C-2-Alkenylierung von Indolen mit tri- und tetrasubstituierten Doppelbindungen
  358. Copper-Catalyzed 1,2-Addition of Nucleophilic Silicon to Aldehydes: Mechanistic Insight and Catalytic Systems
  359. BINAP versus BINAP(O) in Asymmetric Intermolecular Mizoroki-Heck Reactions: Substantial Effects on Selectivities
  360. Copper(I)-Catalyzed Regioselective Propargylic Substitution Involving Si–B Bond Activation
  361. A New Motif for Lewis Base Catalysis: Asymmetric Reduction of β-Enamino Esters
  362. A Unique Transition Metal-Stabilized Silicon Cation
  363. An Axially Chiral, Electron-Deficient Borane: Synthesis, Coordination Chemistry, Lewis Acidity, and Reactivity
  364. Activation of the Si−B Linkage: Copper-Catalyzed Addition of Nucleophilic Silicon to Imines
  365. Shortened Synthesis of a Silicon-Stereogenic Cyclic Silane
  366. Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism
  367. Organische Chemie 2010
  368. All-Carbon-Substituted Quaternary Carbon Atoms in Oxindoles by an Aerobic Palladium(II)-Catalyzed Ring Closure onto Tri- and Tetrasubstituted Double Bonds
  369. Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles
  370. Self-regeneration of a silylium ion catalyst in carbonyl reduction
  371. Stereochemical Surprises in the Lewis Acid-Mediated Allylation of Isatins
  372. Kupferkatalysierte Si-B-Bindungsaktivierung in der verzweigtselektiven allylischen Substitution linearer Allylchloride
  373. Copper-Catalyzed SiB Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides
  374. Base-Catalyzed Dehydrogenative Si-O Coupling of Dihydrosilanes: Silylene Protection of Diols
  375. Transition-Metal-Catalyzed C-P Cross-Coupling Reactions
  376. Der asymmetrische konjugierte Silyltransfer in iterativen katalytischen Sequenzen: Synthese des C7-C16-Fragments von (+)-Neopeltolid
  377. Asymmetric Conjugate Silyl Transfer in Iterative Catalytic Sequences: Synthesis of the C7-C16 Fragment of (+)-Neopeltolide
  378. Expeditious synthesis of TADDOL-derived phosphoramidite and phosphonite ligands
  379. Katalytische asymmetrische Si-O-Kupplung einfacher achiraler Silane und chiraler donorfunktionalisierter Alkohole
  380. Catalytic Asymmetric SiO Coupling of Simple Achiral Silanes and Chiral Donor-Functionalized Alcohols
  381. Organische Chemie 2009
  382. Enantioselektive konjugierte Borylierung
  383. Enantioselective Conjugate Borylation
  384. Silicon- and Tin-Based Cuprates: Now Catalytic in Copper!
  385. Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides
  386. Asymmetric Si–O coupling of alcohols
  387. Silylium ions in catalysis
  388. Enantioselective Fujiwara-Moritani Indole and Pyrrole Annulations Catalyzed by Chiral Palladium(II)-NicOx Complexes
  389. Ein gezähmtes Silyliumion für Diels-Alder-Reaktionen bei niedrigen Temperaturen
  390. Taming the Silylium Ion for Low-Temperature Diels-Alder Reactions
  391. B(C 6 F 5 ) 3 -Catalyzed Reduction of Ketones and Imines Using Silicon-Stereogenic Silanes: Stereoinduction by Single-Point Binding
  392. Conjugate phosphination of cyclic and acyclic acceptors using Rh(I)–phosphine or Rh(I)–carbene complexes. Probing the mechanism with chirality at the silicon atom or the phosphorus atom of the Si–P reagent
  393. Rhodium(I)-catalyzed enantioselective 1,4-addition of nucleophilic silicon
  394. Enantiospezifische Synthese und Allylierung ausschließlich Kohlenstoff-substituierter, α-chiraler Allylstannane
  395. Enantiospecific Synthesis and Allylation of All-Carbon-Substituted α-Chiral Allylic Stannanes
  396. Asymmetrische Ringschlussmetathese mit Pfiff
  397. Asymmetric Ring-Closing Metathesis with a Twist
  398. Palladium(II)-Catalyzed Conjugate Phosphination of Electron-Deficient Acceptors
  399. Potassiumtert-Butoxide-Catalyzed Dehydrogenative SiO Coupling: Reactivity Pattern and Mechanism of an Underappreciated Alcohol Protection
  400. Organische Chemie 2008
  401. The Mizoroki–Heck Reaction
  402. Facile preparation of CF3-substituted carbinols with an azine donor and subsequent kinetic resolution through stereoselective Si–O coupling
  403. Stereoselective Alcohol Silylation by Dehydrogenative Si-O Coupling: Scope, Limitations, and Mechanism of the Cu-H-Catalyzed Non-Enzymatic Kinetic Resolution with Silicon-Stereogenic Silanes
  404. A Catalytic Asymmetric Fujiwara-Moritani Cyclization
  405. Schlüssiger Nachweis eines SN2-Si-Mechanismus in der B(C6F5)3- katalysierten Hydrosilylierung von Carbonylverbindungen: Einsichten in die verwandte Hydrierung
  406. Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation
  407. Transition-Metal-Free Conjugate Stannyl Transfer to α,β-Unsaturated Carbonyl and Carboxyl Compounds in Basic Aqueous Media
  408. Katalytische asymmetrische C-Si-Bindungsknüpfung an acyclischen α,β-ungesättigten Akzeptoren durch RhI-katalysierten konjugierten Silyltransfer mithilfe einer Si-B-Bindung
  409. Catalytic Asymmetric CSi Bond Formation to Acyclic α,β-Unsaturated Acceptors by RhI-Catalyzed Conjugate Silyl Transfer Using a SiB Linkage
  410. Enantio- and Diastereotopos Differentiation in the Palladium(II)-Catalyzed Hydrosilylation of Bicyclo[2.2.1]alkene Scaffolds with Silicon-Stereogenic Silanes
  411. Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane
  412. Kinetic Resolution and Desymmetrization by Stereoselective Silylation of Alcohols
  413. Kinetische Racematspaltung und Desymmetrisierung durch stereoselektive Silylierung von Alkoholen
  414. Chirale Erkennung mit siliciumstereogenen Silanen: außergewöhnliche Selektivitätsfaktoren bei der kinetischen Racematspaltung von donorfunktionalisierten Alkoholen
  415. Chiral Recognition with Silicon-Stereogenic Silanes: Remarkable Selectivity Factors in the Kinetic Resolution of Donor-Functionalized Alcohols
  416. Oxygen Donor-Mediated Equilibration of Diastereomeric Alkene−Palladium(II) Intermediates in Enantioselective Desymmetrizing Heck Cyclizations
  417. Silicon-Stereogenic Silanes in Asymmetric Catalysis
  418. Polishing a Diamond in the Rough: “Cu—H” Catalysis with Silanes
  419. Asymmetric Synthesis - The Essentials
  420. Conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis: A comparative study
  421. Vom Schleifen eines “Rohdiamanten”: die “Cu-H”-Katalyse mit Silanen
  422. Polishing a Diamond in the Rough: “CuH” Catalysis with Silanes
  423. Rhodium(i)-catalysed conjugate phosphination of cyclic α,β-unsaturated ketones with silylphosphines as masked phosphinides
  424. Directed Mizoroki–Heck Reactions
  425. Synthesis by Hydration of Alkynes
  426. Synthesis by Direct Hydration
  427. Intermolecular Chirality Transfer from Silicon to Carbon:  Interrogation of the Two-Silicon Cycle for Pd-Catalyzed Hydrosilylation by Stereoisotopochemical Crossover
  428. Organische Chemie online… und gratis?
  429. Organic Chemistry Online … and for Free?
  430. An Enantioselective Access to an Anthracycline AB Synthon by a ­Desymmetrizing Heck Cyclization
  431. Rhodiumkatalysierter enantioselektiver konjugierter Silyltransfer: 1,4-Addition von Silylboronsäureestern an cyclische Enone und Lactone
  432. Rhodium-Catalyzed Enantioselective Conjugate Silyl Transfer: 1,4-Addition of Silyl Boronic Esters to Cyclic Enones and Lactones
  433. Preparation of a Privileged Silicon-Stereogenic Silane: Classicalversus Kinetic Resolution
  434. Copper-Free and Copper-Promoted Conjugate Addition Reactions of Bis(triorganosilyl) Zincs and Tris(triorganosilyl) Zincates
  435. Organische Chemie 2005
  436. Quaternary Stereocenters. Challenges and Solutions for Organic Synthesis. Herausgegeben von Jens Christoffers und Angelika Baro.
  437. Quaternary Stereocenters. Challenges and Solutions for Organic Synthesis. Edited by Jens Christoffers and Angelika Baro.
  438. Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl) zincs. Enantiospecific preparation of α-chiral silanes
  439. Silylzincation of carbon–carbon multiple bonds revisited
  440. Chirality Transfer from Silicon to Carbon
  441. Kinetische Racematspaltung von chiralen sekundären Alkoholen durch dehydrierende Kupplung mit zurückgewinnbaren, siliciumstereogenen Silanen
  442. Kinetic Resolution of Chiral Secondary Alcohols by Dehydrogenative Coupling with Recyclable Silicon-Stereogenic Silanes
  443. OMCOS 13
  444. Kaleidoskop der Katalyse: Heidelberger Forum für Molekulare Katalyse 2005
  445. Kaleidoscope of Catalysis: Heidelberg Forum of Molecular Catalysis 2005
  446. Schweizer Leckerli: Bürgenstock 2005
  447. Swiss Delight: Bürgenstock 2005
  448. Chemie-Nachwuchsgruppenleiter in Freiburg
  449. Strategien zur katalytischen asymmetrischen elektrophilen ?-Halogenierung von Carbonylverbindungen
  450. Strategies for Catalytic Asymmetric Electrophilic ? Halogenation of Carbonyl Compounds
  451. Practical Synthesis of Allylic Silanes from Allylic Esters and Carbamates by Stereoselective Copper-Catalyzed Allylic Substitution Reactions
  452. ?Echter? Chiralit�tstransfer von Silicium auf Kohlenstoff: asymmetrische Verst�rkung in einer reagenskontrollierten palladiumkatalysierten Hydrosilylierung
  453. ?True? Chirality Transfer from Silicon to Carbon: Asymmetric Amplification in a Reagent-Controlled Palladium-Catalyzed Hydrosilylation
  454. Neighbouring‐Group Effects in Heck Reactions
  455. Hypervalent Silicon as a Reactive Site in Selective Bond-Forming Processes
  456. Catalytic Desymmetrizing Intramolecular Heck Reaction: Evidence for an Unusual Hydroxy-Directed Migratory Insertion
  457. On the Mechanism of the Reductive Metallation of Asymmetrically Substituted Silyl Chlorides
  458. Katalytische desymmetrisierende intramolekulare Heck-Reaktion: Nachweis einer ungewöhnlichen hydroxydirigierten Alkeninsertion
  459. Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters
  460. 23. Regio-Symposium in Falkau/Schwarzwald
  461. Copper-Catalyzed Conjugate Addition of a Bis(triorganosilyl) Zinc and a Methyl(triorganosilyl) Magnesium
  462. Catalytic Asymmetric Synthesis of Quaternary Carbons Bearing Two Aryl Substituents. Enantioselective Synthesis of 3-Alkyl-3-Aryl Oxindoles by Catalytic Asymmetric Intramolecular Heck Reactions
  463. A Convergent Method for the Synthesis of Highly Enantiomerically Enriched Cyclic Silanes with Silicon-Centered Chirality
  464. Vereitelteβ-Hydrideliminierung: Abfangen der Alkylpalladiumzwischenstufe einer asymmetrischen intramolekularen Heck-Reaktion
  465. Thwartingβ-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction
  466. Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds
  467. Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds
  468. (−)-Sparteine-Mediated Asymmetric Intramolecular Carbolithiation of Alkenes: Synthesis of Enantiopure Cyclopentanes with Three Consecutive Stereogenic Centers
  469. (−)-Sparteine-Mediated Stereoselective Intramolecular Carbolithiation of 4-Substituted 5-Hexynyl Carbamates. Synthesis of Enantiopure 1,3-Difunctionalized Alkylidene Cyclopentanes
  470. Corrigendum
  471. (−)-Sparteine-mediated stereoselective intramolecular conjugate addition reactions of dienes and enynes
  472. (−)-Sparteine-mediated stereoselective intramolecular carbolithiation of alkynes
  473. Stereoselective Preparation and Reactions of Cycloalkylzinc Compounds
  474. Stereoselektive Herstellung und Reaktionen von Cycloalkylzinkverbindungen
  475. Formation of Carbocycles
  476. Palladium-Catalyzed Arylation Reactions of Alkenes (Mizoroki–Heck Reaction and Related Processes)
  477. Taming Super Lewis Acids for Catalysis: The Family of Ferrocene-Stabilized Silicon Cations
  478. Diverse Modes of Silane Activation for the Hydrosilylation of Carbonyl Compounds