All Stories

  1. Synthesis of Azo-Substituted Benzoxazin-4-ones by Base-Mediated Addition of Diazenyl Anions to Isatoic Anhydrides
  2. Silylium‐Ion‐Initiated Disulfidation of Internal Alkynes With Disulfides
  3. Copper-Catalyzed Enantioselective Conjugate Borylation of Silacyclohexadienones to Construct Highly Congested Stereocenters Adjacent to C−Si Bonds
  4. Intramolecular Silylarylation of α‐Olefins Enabled by Disulfide Co‐Catalysis and Maintained by Proton‐into‐Silylium Interconversion
  5. Intramolecular Silylarylation of α‐Olefins Enabled by Disulfide Co‐Catalysis and Maintained by Proton‐into‐Silylium Interconversion
  6. Proton-into-Silylium Ion Generation as a Mechanistic Switch: Divergent Ring-Opening Arylation of CF 3 -Substituted Cyclopropanes
  7. Asymmetric Transition-Metal-Catalyzed Hydrofunctionalization of Alkenylmetalloids (B, Si, and Ge)
  8. The Cation Shuffle: Interplay of silylium, carbenium, and arenium ions in superelectrophile catalysis
  9. Photoredox-Catalyzed Transfer Thiobenzoyloxylation of Styrenes Using Oxime-Based Surrogates
  10. Regio- and stereoselective tert -butylthiolation of internal alkynes with thioethers initiated and maintained by silylium-ion catalysis
  11. A general synthesis of nitriles from nitroalkanes with bis(catecholato)diboron
  12. Mechanism of the palladium-catalyzed diazenylation of aryl electrophiles: carbonate-facilitated transmetalation and ligand-dependent selectivity
  13. Enantioconvergent access to 1,1-diarylmethine silanes and germanes through nickel/photoredox-catalyzed cross-electrophile coupling
  14. Epimerization-Free Synthesis of Azo-Substituted Di- and Tripeptides by Cross-Coupling of O-Triflated Derivatives and Diazenyl Anion Equivalents
  15. Kinetics and Mechanism of Enantioselective Cu-Catalyzed Alcohol Silylation
  16. Photoinduced Deoxygenative Boration of Unactivated Alcohols Involving In-Situ-Formed Alkyl Iodides
  17. Photoredox-Catalyzed Transfer Thio(poly)fluoroacyloxylation of Alkenes Using Oxime-Based Surrogates
  18. Enantioselective Miyaura Reaction by Desymmetrizing C(sp2)–B Cross‐Coupling of 1,1′‐Biaryl‐2,6‐diyl Bis(nonaflates)
  19. Enantioselective Miyaura Reaction by Desymmetrizing C(sp2)–B Cross‐Coupling of 1,1′‐Biaryl‐2,6‐diyl Bis(nonaflates)
  20. Analysis of Cyclohexa-1,4-dienes with an Asymmetrically Substituted, 3° Carbon Atom as Chiral Dihydrogen Surrogates in Reagent-Controlled Transfer Hydrogenation of Alkenes
  21. Directing Effects of Silyl and Germyl Groups in Transition‐Metal‐Catalyzed Allylic Substitution
  22. Atroposelective Synthesis of Azobenzenes by Palladium-Catalyzed Cross-Coupling of Racemic Biaryl Triflates and Diazenyl Pronucleophiles
  23. Isolation of halogen-substituted silylium ions
  24. Silylium-Ion-Promoted Formation of Methylenecyclobutenes by Formal (2 + 2) Cycloaddition of Allenylsilanes and Internal Alkynes
  25. Kinetic Resolution of BINAMs by Stereoselective Copper-Catalyzed Dehydrogenative Si–N Coupling with Prochiral Dihydrosilanes
  26. Nickel-Catalyzed Enantioconvergent C(sp3)–C(sp3) Cross-Coupling between α-Iodogermanes and Alkylzinc Reagents
  27. Dynamic Kinetic C(sp2)–Si Cross-Coupling with Si–B Reagents for the Atroposelective Construction of Unsymmetrical Heterobiaryls
  28. Kinetic Resolution of Acyclic 1,3-Diols by Copper-Catalyzed Regioselective Dehydrogenative Si–O-Coupling
  29. Photoredox-Catalyzed Transfer Aminochlorination of Unactivated Alkenes Using Oxime-Based Surrogates
  30. One-Pot Sequential Alcohol Activation and Nickel-Catalyzed Cross-Electrophile Coupling with Chlorosilanes
  31. Ionic Remote α-C–H Allenylation of Silyl Ethers Involving a [1,5]-Hydride Shift Promoted by Silylium-Ion Regeneration
  32. Silylium-Ion-Promoted (3 + 2) Annulation of Allenylsilanes with Internal Alkynes Involving a Pentadienyl-to-Allyl Cation Electrocyclization
  33. Enantio‐ and Diastereoselective Desymmetrization of 1,1’‐Biaryl‐2,6‐Dicarbaldehydes by Copper‐Catalyzed 1,2‐Addition of Silicon Nucleophiles
  34. Enantio‐ und Diastereoselektive Desymmetrisierung von 1,1’‐Biaryl‐2,6‐Dicarbaldehyden durch kupferkatalysierte 1,2‐Addition von Siliciumnukleophilen
  35. Kinetic Resolution of BINOLs and Biphenols by Atroposelective, Cu–H-Catalyzed Si–O Coupling with Hydrosilanes
  36. Enantio‐ and Regioconvergent Nickel‐Catalyzed Etherification of Phenols by Allylation to Access Chiral C(sp3)−O Allyl Aryl Ethers
  37. Enantio‐ und regiokonvergente, nickelkatalysierte Veretherung von Phenolen durch Allylierung zur Darstellung chiraler C(sp3)−O‐Allylarylether
  38. From Process Chemistry to Methodology Development in Metal-Mediated Chemistry and Catalysis
  39. Ring Contraction of Saturated Cyclic Amines and Rearrangement of Acyclic Amines Through Their Corresponding Hydroxylamines
  40. Ring Contraction of Saturated Cyclic Amines and Rearrangement of Acyclic Amines Through Their Corresponding Hydroxylamines
  41. Cationic Bis(hydrosilane)—Coinage‐Metal Complexes: Synthesis, Characterization, and Use as Catalysts for Outer‐Sphere C=O Hydrosilylation Not Involving Metal Hydrides
  42. Cationic Bis(hydrosilane)—Coinage‐Metal Complexes: Synthesis, Characterization, and Use as Catalysts for Outer‐Sphere C=O Hydrosilylation Not Involving Metal Hydrides
  43. Ni–H-Catalyzed Chemo- and Regioselective Hydroarylation of Vinylsilanes
  44. Synthesis of a Cationic Cobalt–Selenolate Complex for Cooperative Sn–H Bond Activation: Solvent-Dependent Stereoselectivity in Alkyne Hydrostannylation
  45. Silylium-Ion-Initiated Twofold Halodealkylation of Fully Alkylated Silanes
  46. Enantioselective Dearomatization of Pyridinium Salts by Copper‐Catalyzed C4‐Selective Addition of Silicon Nucleophiles
  47. Enantioselektive Dearomatisierung von Pyridiniumsalzen durch kupferkatalysierte C4‐selektive Addition von Siliciumnukleophilen
  48. Functional group transfer strategies unlock new synthetic avenues
  49. Electrophilic Activation of S−Si Reagents by Silylium Ions for Their Regio‐ and Diastereoselective Addition Across C−C Multiple Bonds
  50. Elektrophile Aktivierung von S−Si‐Reagenzien mit Silyliumionen für deren regio‐ und diastereoselektive Addition an C−C‐Mehrfachbindungen
  51. Copper-catalyzed silylation of aryl and alkenyl triflates with silylboronic esters avoiding base-mediated borylation
  52. Chiral Carborane Acids Decorated with Binol-Based Phosphonates: Synthesis, Characterization, and Application
  53. Desymmetrization of Cyclohexadienones Containing a Quaternary γ-Carbon Atom by Conjugate Addition of Boron Nucleophiles
  54. Ligand-Controlled On–Off Switch of a Silicon-Tethered Directing Group Enabling the Regiodivergent Hydroalkylation of Vinylsilanes under Ni–H Catalysis
  55. Bond-Forming Processes Enabled by Silicon-Masked Aryl- and Alkyl-Substituted Diazenes
  56. Arenium-ion-catalysed halodealkylation of fully alkylated silanes
  57. Skeletal Rearrangements Involving Cyclopropyl- and Alkene-Stabilized Silylium Ions
  58. Fluoride-Catalyzed Arylation of α-(Trifluoromethyl)styrene Derivatives with Silicon-Masked, Functionalized Aryl Pronucleophiles
  59. Generation of Silicon-Centered Stereogenicity by Chiral Counteranion-Directed Desymmetrization of Silanediols
  60. Dehydrative Coupling of 1,1-Diarylalkenes and Cyclohexa-2,5-diene-1-carbaldehyde Derivatives Induced by a B(C6F5)3-Initiated [1,2]-Alkyl Migration
  61. Regioselective Hydroalkylation of Vinyl- and Allylsilanes as Well as Vinylgermanes under Ni–H Catalysis
  62. Discrimination of the Enantiotopic Faces of Structurally Unbiased Carbenium Ions Employing a Cyclohexadiene‐Based Chiral Hydride Source
  63. Unterscheidung der enantiotopen Seiten von strukturell unvoreingenommenen Carbeniumionen unter Verwendung einer cyclohexadienbasierten, chiralen Hydridquelle
  64. The Two Faces of Carbenium Ions: Intermolecular Trapping of Prochiral Carbocations with Stereocontrol
  65. Atroposelective Silylation of 1,1′‐Biaryl‐2,6‐diols by a Chiral Counteranion Directed Desymmetrization Enhanced by a Subsequent Kinetic Resolution
  66. Atropselektive Silylierung von 1,1′‐Biaryl‐2,6‐diolen mittels chiraler gegenaniondirigierter Desymmetrisierung und anschließender Verbesserung durch kinetische Racematspaltung
  67. Enantio- and Regioconvergent Synthesis of γ-Stereogenic Vinyl Germanes and Their Use as Masked Vinyl Halides
  68. Intramolecular 7-endo-dig-Selective Carbosilylation of Internal Alkynes Involving Silylium-Ion Regeneration
  69. Photoinduced radical–ionic dihalogen transfer to carbon–carbon multiple bonds using oxime-based surrogates
  70. Catalytically Generated Meerwein’s Salt-Type Oxonium Ions for Friedel–Crafts C(sp2)–H Methylation with Methanol
  71. B(C6F5)3‐Catalyzed Regioselective Ring Opening of Cyclic Amines with Hydrosilanes
  72. Silylium Ion Initiated Intramolecular Friedel–Crafts-Type Cyclization of 1,1-Difluoroalkenes with Subsequent Hydrodefluorination of C(sp3)–F Bonds
  73. Copper‐Catalyzed Highly Enantioselective Addition of a Silicon Nucleophile to 3‐Substituted 2H‐Azirines Using an Si−B Reagent
  74. Kupferkatalysierte, hochgradig enantioselektive Addition eines Siliciumnukleophils an 3‐substituierte 2H‐Azirine unter Verwendung eines Si‐B‐Reagenzes
  75. The [3]Dendralene Motif as an Entry into Nazarov Cyclizations by Silylium-Ion Initiation
  76. Advances in Enantioconvergent Transition-Metal-Catalyzed Cross-Coupling Reactions of Racemic α-Silyl and α-Boryl Reagents
  77. Atom-economic and stereoselective catalytic synthesis of fully substituted enol esters/carbonates of amides in acyclic systems enabled by boron Lewis acid catalysis
  78. Experimental Mechanistic Analysis of Carbonyl Hydrosilylation Catalyzed by Abu-Omar’s Rhenium(V) Oxo Complex
  79. Synthesis of Benzhydryl-Substituted Amines by Silanolate-Mediated Aldimine Arylation with Functionalized Aryl Nucleophiles Released from Diazene-Based Reagents
  80. Palladium-Catalyzed Denitrogenative Cross-Coupling of Silicon-Masked, Aryl-Substituted Diazenes and Aryl Bromides
  81. Silylium-Ion-Promoted Skeletal Reorganization of β-Silylated Cyclopropanes Bearing an Allyl Group at the Silicon Atom Coupled with Intermolecular Formation of a Quaternary Carbon Atom
  82. Boosting the Enantioselectivity of Conjugate Borylation of α,β‐Disubstituted Cyclobutenones with Monooxides of ChiralC2‐Symmetric Bis(phosphine) Ligands
  83. Synthese von unsymmetrischen Azobenzolen durch palladiumkatalysierte Kreuzkupplung von siliciummaskierten Diazenylanionen und (Hetero)arylhalogeniden
  84. Synthesis of Non‐Symmetric Azoarenes by Palladium‐Catalyzed Cross‐Coupling of Silicon‐Masked Diazenyl Anions and (Hetero)Aryl Halides
  85. Photochemical, Nickel-Catalyzed C(sp3)–C(sp3) Reductive Cross-Coupling of α-Silylated Alkyl Electrophiles and Allylic Sulfones
  86. Enantio- and Regioconvergent Nickel-Catalyzed Allylic Substitution of Racemic α- or γ-Silylated Allylic Bromides with Benzylzinc Reagents
  87. Intermolecular Carbosilylation of α‐Olefins with C(sp3)−C(sp) Bond Formation Involving Silylium‐Ion Regeneration
  88. Intermolekulare Carbosilylierung von α‐Olefinen mit C(sp3)−C(sp)‐Bindungsknüpfung unter Neubildung von Silyliumionen
  89. B(C6F5)3-Catalyzed Reductive Denitrogenation of Benzonitrile Derivatives
  90. Decarbonylative Transfer Hydrochlorination of Alkenes and Alkynes Based on a B(C6F5)3‐Initiated Grob Fragmentation
  91. Decarbonylierende Transferhydrochlorierung von Alkenen und Alkinen auf Grundlage einer B(C6F5)3‐ausgelösten Grob‐Fragmentierung
  92. Cationic Cobalt–Thiolate Complexes for the Dehydrogenative Coupling of nBu3SnH
  93. Perdeuteration of Deactivated Aryl Halides by H/D Exchange under Superelectrophile Catalysis
  94. Silylium-Ion-Promoted Hydrosilylation of Aryl-Substituted Allenes: Interception by Cyclization of the Allyl-Cation Intermediate
  95. Competition for Hydride Between Silicon and Boron: Synthesis and Characterization of a Hydroborane‐Stabilized Silylium Ion
  96. Metal-free transfer hydrochlorination of internal C–C triple bonds with a bicyclo[3.1.0]hexane-based surrogate releasing two molecules of hydrogen chloride
  97. One out of Four: Kinetic Resolution of Stereoisomeric Mixtures of Secondary Alcohols with a Quaternary Carbon Atom in the β-Position by Cu–H-Catalyzed Enantioselective Silylation
  98. Enantioselective, Copper-Catalyzed Addition of Nucleophilic Silicon to Alkenyl-Substituted Phosphine Oxides
  99. Synthesis of Silylated Cyclobutanone and Cyclobutene Derivatives Involving 1,4‐Addition of Zinc‐Based Silicon Nucleophiles
  100. Silylium-Ion Regeneration by Protodesilylation Enables Friedel–Crafts Alkylation with Less Isomerization and No Defunctionalization
  101. The Power of the Proton: From Superacidic Media to Superelectrophile Catalysis
  102. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  103. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  104. Nickelkatalysierte, reduktive C(sp3)‐Si‐Kreuzkupplung von α‐cyanosubstituierten Alkylelektrophilen und Chlorsilanen
  105. Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes
  106. Transition‐Metal‐Free Coupling of Polyfluorinated Arenes and Functionalized, Masked Aryl Nucleophiles
  107. B(C6F5)3-Catalyzed Diastereoselective Formal (4 + 1)-Cycloaddition of Vinylcyclopropanes and Et2SiH2
  108. Radical entry into Ni-catalyzed transfer hydrocyanation using cheap AIBN
  109. Metal‐Free Hydrosilylation of Ketenes with Silicon Electrophiles: Access to Fully Substituted Aldehyde‐Derived Silyl Enol Ethers
  110. Enantio‐ and Regioconvergent Nickel‐Catalyzed C(sp3)−C(sp3) Cross‐Coupling of Allylic Electrophiles Steered by a Silyl Group
  111. Enantio‐ und regiokonvergente, nickelkatalysierte C(sp3)‐C(sp3)‐Kreuzkupplung von allylischen Elektrophilen gelenkt durch eine Silylgruppe
  112. Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts
  113. Chemoselective Deoxygenation of 2° Benzylic Alcohols through a Sequence of Formylation and B(C6F5)3‐Catalyzed Reduction
  114. Enantioconvergent and Regioselective Synthesis of Allenylsilanes by Nickel-Catalyzed C(sp2)–C(sp3) Cross-Coupling Starting from Racemic α-Silylated Propargylic Bromides
  115. Development of a Radical Silylzincation of (Het)Aryl‐Substituted Alkynes and Computational Insights into the Origin of the trans‐Stereoselectivity
  116. Diastereotopic Group-Selective Intramolecular Aldol Reactions Initiated by Enantioselective Conjugate Silylation: Diastereodivergence Controlled by the Silicon Nucleophile
  117. The Trityl Cation Embedded into a [7]Helicene-Like Backbone: Preparation and Application as a Lewis Acid Catalyst
  118. Aufeinanderfolgende β,β′‐selektive C(sp3)‐H‐Silylierung von tertiären Aminen mit Dihydrosilanen katalysiert durch B(C6F5)3
  119. Consecutive β,β′‐Selective C(sp3)−H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C6F5)3
  120. At Long Last: The Me3Si Group as a Masked Alcohol
  121. Zu guter Letzt: Die Me3Si‐Gruppe als ein getarnter Alkohol
  122. Activation of the Si–B interelement bond related to catalysis
  123. Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes
  124. Mild reductive rearrangement of oximes and oxime ethers to secondary amines with hydrosilanes catalyzed by B(C6F5)3
  125. Kinetic Resolution of Neopentylic Secondary Alcohols by Cu–H-Catalyzed Enantioselective Silylation with Hydrosilanes
  126. Cationic Ru–Se Complexes for Cooperative Si–H Bond Activation
  127. Dynamic Kinetic Resolution of Alcohols by Enantioselective Silylation Enabled by Two Orthogonal Transition‐Metal Catalysts
  128. Dynamische kinetische Racematspaltung von Alkoholen mittels enantioselektiver Silylierung ermöglicht durch zwei orthogonale Übergangsmetallkatalysatoren
  129. The Cyclohexa‐2,5‐dienyl Group as a Placeholder for Hydrogen: Organocatalytic Michael Addition of an Acetaldehyde Surrogate
  130. Enantioselective Synthesis of α-Chiral Propargylic Silanes by Copper-Catalyzed 1,4-Selective Addition of Silicon Nucleophiles to Enyne-Type α,β,γ,δ-Unsaturated Acceptors
  131. B(C6F5)3-Catalyzed Hydrosilylation of Vinylcyclopropanes
  132. Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates
  133. Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration
  134. Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration
  135. Reductive Deamination with Hydrosilanes Catalyzed by B(C6F5)3
  136. Reduktive Desaminierung mit Hydrosilanen katalysiert durch B(C6F5)3
  137. Copper-Catalyzed Enantioselective and Exo-Selective Addition of Silicon Nucleophiles to 7-Oxa- and 7-Azabenzonorbornadiene Derivatives
  138. Synthese eines gegenanionstabilisierten Bis(silylium)ions
  139. Synthesis of a Counteranion‐Stabilized Bis(silylium) Ion
  140. Kilian Muñiz (1970–2020)
  141. Seeds for the Future: Growing Chemistry Trends
  142. Autocatalytic Carbonyl Arylation through In Situ Release of Aryl Nucleophiles from N‐Aryl‐N′‐Silyldiazenes
  143. Autokatalytische Carbonylarylierung mittels lokaler Freisetzung von Arylnukleophilen ausgehend von N‐Aryl‐N′‐silyldiazenen
  144. Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes
  145. Transition-Metal-Like Catalysis with a Main-Group Element: Bismuth-Catalyzed C−F Coupling of Aryl Boronic Esters
  146. Übergangsmetallartige Katalyse mit einem Hauptgruppenelement: Bismutkatalysierte C‐F‐Kupplung von Arylboronsäureestern
  147. Formyltetrahydrofolate Decarbonylase Synthesizes the Active Site CO Ligand of O2-Tolerant [NiFe] Hydrogenase
  148. Defunctionalisation catalysed by boron Lewis acids
  149. Emerging Strategies for C–H Silylation
  150. Outstanding Reviewers for Chemical Science in 2019
  151. Stereospecific and Chemoselective Copper-Catalyzed Deaminative Silylation of Benzylic Ammonium Triflates
  152. Stereospezifische und chemoselektive kupferkatalysierte, deaminierende Silylierung von Benzylammoniumtriflaten
  153. General Synthesis and Optical Properties of N-Aryl-N′-Silyldiazenes
  154. Cationic silicon Lewis acids in catalysis
  155. Chiral Modification of the Tetrakis(pentafluorophenyl)borate Anion with Myrtanyl Groups
  156. Ionic Transfer Reactions with Cyclohexadiene-Based Surrogates
  157. Si-H Bond Activation with Bullock’s Cationic Tungsten(II) Catalyst: CO as Cooperating Ligand
  158. Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions
  159. Katalytische Difunktionalisierung von nichtaktivierten Alkenen mit reaktionsträgem Hexamethyldisilan durch Neubildung von Silyliumionen
  160. Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes
  161. Lewis Säure‐katalysierte Transferhydromethallylierung für den Aufbau quartärer Kohlenstoffzentren
  162. Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers
  163. Characterization of hydrogen-substituted silylium ions in the condensed phase
  164. Copper-Catalyzed Regio- and Enantioselective Addition of Silicon Grignard Reagents to Alkenes Activated by Azaaryl Groups
  165. Kupferkatalysierte regio‐ und enantioselektive Addition von Silicium‐Grignard‐Reagenzien an durch Azaarylgruppen aktivierte Alkene
  166. Metal-Free Transfer Hydrobromination of C–C Triple Bonds
  167. Bioinspired Metal‐Free Formal Decarbonylation of α‐Branched Aliphatic Aldehydes at Ambient Temperature
  168. Tertiary α-Silyl Alcohols by Diastereoselective Coupling of 1,3-Dienes and Acylsilanes Initiated by Enantioselective Copper-Catalyzed Borylation
  169. Tertiäre α‐Silylalkohole mittels diastereoselektiver Kupplung von 1,3‐Dienen und Acylsilanen, eingeleitet durch enantioselektive kupferkatalysierte Borylierung
  170. Making the Silylation of Alcohols Chiral: Asymmetric Protection of Hydroxy Groups
  171. Regiodivergent and Stereospecific Aziridine Opening by Copper‐Catalyzed Addition of Silicon Grignard Reagents
  172. Mechanistic Dichotomy of Magnesium- and Zinc-Based Germanium Nucleophiles in the C(sp3 )−Ge Cross-Coupling with Alkyl Electrophiles
  173. Gegensätzliche Reaktionsweisen magnesium‐ und zinkbasierter Germaniumnukleophile in der C(sp 3 )‐Ge‐Kreuzkupplung mit Alkylelektrophilen
  174. Further Structural Modification of Sulfur-Stabilized Silicon Cations with Binaphthyl Backbones
  175. Enantioselective Construction of α-Chiral Silanes by Nickel-Catalyzed C(sp3 )−C(sp3 ) Cross-Coupling
  176. Enantioselektiver Aufbau von α‐chiralen Silanen durch nickelkatalysierte C(sp 3 )‐C(sp 3 )‐Kreuzkupplung
  177. Axially Chiral, Electrophilic Fluorophosphonium Cations: Synthesis, Lewis Acidity, and Reactivity in the Hydrosilylation of Ketones
  178. Bor-Lewis-Säure-katalysierte Transferhydrocyanierung α- und α,β-substituierter Styrole
  179. Transfer Hydrocyanation of α- and α,β-Substituted Styrenes Catalyzed by Boron Lewis Acids
  180. Kinetic Resolution of Tertiary Propargylic Alcohols by Enantioselective Cu−H-Catalyzed Si−O Coupling
  181. Kinetische Racematspaltung tertiärer Propargylalkohole durch enantioselektive Cu-H-katalysierte Si-O-Kupplung
  182. Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydroxyalkylboration of 1,3-dienes with ketones
  183. Using alcohols as simple H2-equivalents for copper-catalysed transfer semihydrogenations of alkynes
  184. Metal-Free Transfer Hydroiodination of C–C Multiple Bonds
  185. Copper-Catalyzed Cross-Coupling of Vinyliodonium Salts and Zinc-Based Silicon Nucleophiles
  186. Palladium-Catalyzed Three-Component Reaction of Dihydrosilanes and Vinyl Iodides in the Presence of Alcohols: Rapid Assembly of Silyl Ethers of Tertiary Silanes
  187. C(sp3)–Si Cross-Coupling
  188. Achieving Enantioselectivity in Difficult Cyclohexa-1,3-diene Diels–Alder Reactions with Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts
  189. Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution
  190. Einelektronenübertragungsreaktionen in frustrierten und klassischen Silyliumion/Phosphan-Lewis-Paaren
  191. Single-Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphane Lewis Pairs
  192. Regioselective Transfer Hydrodeuteration of Alkenes with a Hydrogen Deuteride Surrogate Using B(C6F5)3 Catalysis
  193. Electrophilic Phosphonium Cations as Lewis Acid Catalysts in Diels–Alder Reactions and Nazarov Cyclizations
  194. Bioinspired Catalytic Generation of Main-group Electrophiles by Cooperative Bond Activation
  195. Bench-Stable Stock Solutions of Silicon Grignard Reagents: Application to Iron- and Cobalt-Catalyzed Radical C(sp3 )-Si Cross-Coupling Reactions
  196. Stabile Stammlösungen von Silicium-Grignard-Reagenzien: Anwendung in eisen- und cobaltkatalysierten radikalischen C(sp3 )-Si-Kreuzkupplungsreaktionen
  197. Copper-Catalyzed Double C(sp3)–Si Coupling of Geminal Dibromides: Ionic-to-Radical Switch in the Reaction Mechanism
  198. Enantioselective Nazarov Cyclizations Catalyzed by an Axial Chiral C6 F5 -Substituted Boron Lewis Acid
  199. Enantioselektive Nazarov-Cyclisierungen, die von einer axial-chiralen, C6 F5 -substituierten Bor-Lewis-Säure katalysiert werden
  200. Z-Selective Hydrostannylation of Terminal and Internal C–C Triple Bonds Initiated by the Trityl Cation
  201. Copper-Catalyzed Silylation of C(sp3)–H Bonds Adjacent to Amide Nitrogen Atoms
  202. Innenrücktitelbild: Kinetische Racematspaltung α-hydroxysubstituierter Oximether durch enantioselektive Cu-H-katalysierte Si-O-Kupplung (Angew. Chem. 33/2018)
  203. Inside Back Cover: Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu−H-Catalyzed Si−O Coupling (Angew. Chem. Int. Ed. 33/2018)
  204. Cleavage of Unactivated Si−C(sp3 ) Bonds with Reed's Carborane Acids: Formation of Known and Unknown Silylium Ions
  205. Spaltung nicht aktivierter Si-C(sp3 )-Bindungen mit Reedschen Carboransäuren: Bildung bekannter und unbekannter Silyliumionen
  206. Custom Hydrosilane Synthesis Based on Monosilane
  207. Electrophilic Formylation of Arenes by Silylium Ion Mediated Activation of Carbon Monoxide
  208. Elektrophile Formylierung von Aromaten durch silyliumionvermittelte Aktivierung von Kohlenmonoxid
  209. Direct Acetophenone-Acetophenone Crossed Aldol Reaction and Aldol Self-Reaction Promoted by a Tethered Ru-S Complex
  210. Refinement of the Catalyst Backbone of Chiral Intramolecular Silicon-Sulfur Lewis Pairs: Improved Enantioselectivity in the Diels-Alder Reaction of Cyclohexa-1,3-diene and Chalcone Derivatives
  211. Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu−H-Catalyzed Si−O Coupling
  212. Kinetische Racematspaltung α-hydroxysubstituierter Oximether durch enantioselektive Cu-H-katalysierte Si-O-Kupplung
  213. A Neutral RuII Hydride Complex for the Regio- and Chemoselective Reduction of N -Silylpyridinium Ions
  214. The electrophilic aromatic substitution approach to C–H silylation and C–H borylation
  215. Catalytic Dehydrogenative Stannylation of C(sp)–H Bonds Involving Cooperative Sn–H Bond Activation of Hydrostannanes
  216. Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion
  217. Copper-Catalyzed Substitution of α-Triflyloxy Nitriles and Esters with Silicon Nucleophiles under Inversion of the Configuration
  218. Two-Silicon Cycle for Carbonyl Hydrosilylation with Nikonov’s Cationic Ruthenium(II) Catalyst
  219. Cooperative Al–H Bond Activation in DIBAL-H: Catalytic Generation of an Alumenium-Ion-Like Lewis Acid for Hydrodefluorinative Friedel–Crafts Alkylation
  220. Cluster Preface: Silicon in Synthesis and Catalysis
  221. An Expedient Procedure for the Synthesis of Benzo[4,5]silolo[2,3-b]thiophenes and Related Systems
  222. Copper-Catalyzed Decarboxylative Radical Silylation of Redox-Active Aliphatic Carboxylic Acid Derivatives
  223. Kupferkatalysierte decarboxylierende radikalische Silylierung von redoxaktiven aliphatischen Carbonsäurederivaten
  224. B(C6F5)3-Catalyzed Reduction of Sulfoxides and Sulfones to Sulfides with Hydrosilanes
  225. BArF3-Catalyzed Imine Hydroboration with Pinacolborane Not Requiring the Assistance of an Additional Lewis Base
  226. Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes
  227. Exhaustive Chemoselective Reduction of Nitriles by Catalytic Hydrosilylation Involving Cooperative Si–H Bond Activation
  228. Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study
  229. Photocatalysis Enabling Acceptorless Dehydrogenation of Benzofused Saturated Rings at Room Temperature
  230. Photokatalyse ermöglicht die akzeptorfreie Dehydrierung von benzanellierten gesättigten Ringen bei Raumtemperatur
  231. Synthesis of a Chiral Borate Counteranion, Its Trityl Salt, and Application Thereof in Lewis-Acid Catalysis
  232. Cooperative Catalysis at Metal–Sulfur Bonds
  233. Access to Fully Alkylated Germanes by B(C6F5)3-Catalyzed Transfer Hydrogermylation of Alkenes
  234. A Tethered Ru-S Complex with an Axial Chiral Thiolate Ligand for Cooperative Si-H Bond Activation: Application to Enantioselective Imine Reduction
  235. Katalytische Friedel-Crafts-C-H-Borylierung elektronenreicher Arene: starke Reaktionsbeschleunigung durch Versetzen mit Alkenen
  236. Catalytic Friedel-Crafts C−H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes
  237. Hidden Enantioselective Hydrogenation of N-Silyl Enamines and Silyl Enol Ethers in Net C═N and C═O Hydrosilylations Catalyzed by Ru–S Complexes with One Monodentate Chiral Phosphine Ligand
  238. B(C6F5)3-Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl Tosylates with Hydrosilanes
  239. B(C6F5)3-katalysierte chemoselektive Defunktionalisierung von etherhaltigen primären Alkyltosylaten mit Hydrosilanen
  240. Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application
  241. Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes
  242. Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes
  243. C H Bond Functionalization at the Benzene Core of Indoles and Indolines (Excluding C-2 and C-3)
  244. 4.4.7 Product Subclass 7: Silylboron Reagents
  245. Catalytic Access to Indole-Fused Benzosiloles by 2-Fold Electrophilic C–H Silylation with Dihydrosilanes
  246. Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel-Crafts C−H Silylation
  247. Elektrophile aromatische Substitution mit Siliciumelektrophilen: die katalytische Friedel-Crafts-C-H-Silylierung
  248. Teaching nature the unnatural
  249. Stereodivergent Synthesis of β-Heteroatom-Substituted Vinyl­silanes by Sequential Silylzincation–Copper(I)-Mediated Electrophilic­ Substitution
  250. 3-tert -Butyl-Substituted Cyclohexa-1,4-dienes as Isobutane Equivalents in the B(C6 F5 )3 -Catalyzed Transfer Hydro-tert -Butylation of Alkenes
  251. Copper-Catalyzed Cross-Coupling of Silicon Pronucleophiles with Unactivated Alkyl Electrophiles Coupled with Radical Cyclization
  252. Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF 3 Does What B(C6 F5 )3 Cannot Do!
  253. Enantioselective Diels–Alder Reactions of Cyclohexa-1,3-diene and Chalcones Catalyzed by Intramolecular Silicon–Sulfur Lewis Pairs as Chiral Lewis Acids
  254. Ausbalancieren von C=C-Funktionalisierung und C=O-Reduktion in der Cu-H-Katalyse
  255. Balancing C=C Functionalization and C=O Reduction in Cu−H Catalysis
  256. Merging Platinum-Catalyzed Alkene Hydrosilylation with SiH4 Surrogates: Salt-Free Preparation of Trihydrosilanes
  257. Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel–Crafts C–H Silylation
  258. B(C6F5)3-Catalyzed Reduction of Aromatic and Aliphatic Nitro Groups with Hydrosilanes
  259. Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru−S Complexes: From Cooperative Dihydrogen Activation to Hydride Abstraction/Proton Release from Dihydrogen Surrogates
  260. The Asymmetric Piers Hydrosilylation
  261. Brønsted Acid-Catalyzed Transfer Hydrogenation of Imines and Alkenes Using Cyclohexa-1,4-dienes as Dihydrogen Surrogates
  262. Stereodivergent Silylzincation of α-Heteroatom-Substituted Alkynes
  263. Metal-Free Phosphine Oxide Reductions Catalyzed by B(C6F5)3 and Electrophilic Fluorophosphonium Cations
  264. An Air-Stable Dimeric Ru–S Complex with an NHC as Ancillary Ligand for Cooperative Si–H Bond Activation
  265. Copper-Catalyzed Si–B Bond Activation in the Nucleophilic Substitution of Primary Aliphatic Triflates
  266. Planar Chiral, Ferrocene-Stabilized Silicon Cations
  267. Durch Nichtedelmetallsalze ausgelöste Friedel-Crafts-artige intermolekulare C-H-Silylierung von elektronenreichen Arenen
  268. Friedel-Crafts-Type Intermolecular C−H Silylation of Electron-Rich Arenes Initiated by Base-Metal Salts
  269. Transfer Hydrosilylation
  270. Catalytic Electrophilic CH Silylation of Pyridines Enabled by Temporary Dearomatization
  271. Extending the Scope of the B(C6F5)3-Catalyzed CN Bond Reduction: Hydrogenation of Oxime Ethers and Hydrazones
  272. Phosphinic Amide as Directing Group Enabling Palladium(II)-CatalyzedorthoC−H Alkenylation of Anilines without and with Alkylation at the Nitrogen Atom
  273. B(C6F5)3-Catalyzed Transfer of Dihydrogen from One Unsaturated Hydrocarbon to Another
  274. Formal SiH4 chemistry using stable and easy-to-handle surrogates
  275. The Cyclohexadienyl-Leaving-Group Approach toward Donor-Stabilized Silylium Ions
  276. A Catalytic SEAr Approach to Dibenzosiloles Functionalized at Both Benzene Cores
  277. Intramolecularly Sulfur-Stabilized Silicon Cations with Chiral Binaphthyl Backbones: Synthesis of Three Different Motifs and Their Application in Enantioselective Diels–Alder Reactions
  278. Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors
  279. Platinum(0)-Catalyzed Indolyne Insertion into Bis(pinacolato)diboron Followed by Site-Selective Suzuki–Miyaura Cross-Coupling
  280. Synthesis of 2,6-Dihalogenated Purine Nucleosides by Thermostable Nucleoside Phosphorylases
  281. A Constellation of Deuterium-Labeled Silanes as a Simple Mechanistic Probe not Requiring Absolute Configuration Determination
  282. Temperature-Dependent Direct Enantioconvergent Silylation of a Racemic Cyclic Allylic Phosphate by Copper(I)-Catalyzed Allylic Substitution
  283. Faszinierende Chemie des Wasserstoffatomtransfers auf Alkene inspiriert durch Probleme in Totalsynthesen
  284. Fascinating Hydrogen Atom Transfer Chemistry of Alkenes Inspired by Problems in Total Synthesis
  285. Temperature-Dependent Chemoselective Hydrosilylation of Carbon Dioxide to Formaldehyde or Methanol Oxidation State
  286. Direct and Transfer Hydrosilylation Reactions Catalyzed by Fully or Partially Fluorinated Triarylboranes: A Systematic Study
  287. A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes
  288. Mechanism of the cooperative Si–H bond activation at Ru–S bonds
  289. Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex
  290. Asymmetric Addition of Boron and Silicon Nucleophiles
  291. B(C6F5)3-Catalyzed Transfer Hydrogenation of Imines and Related Heteroarenes Using Cyclohexa-1,4-dienes as a Dihydrogen Source
  292. B(C6F5)3-katalysierte Transferhydrierung von Iminen und verwandten Heteroaromaten mit Cyclohexa-1,4-dienen als Wasserstoffquelle
  293. Exceptionally Mild Palladium(II)-Catalyzed Dehydrogenative C–H/C–H Arylation of Indolines at the C-7 Position under Air
  294. Chemoselective Tin–Boron Exchange Aided by the Use of Dummy Ligands at the Tin Atom
  295. B(C6F5)3-Catalyzed Hydrogenation of Oxime Ethers without Cleavage of the NO Bond
  296. B(C6F5)3-katalysierte Hydrierung von Oximethern ohne Spaltung der N-O-Bindung
  297. Trans-Selective Radical Silylzincation of Ynamides
  298. Trans-Selective Radical Silylzincation of Ynamides
  299. McQuade’s Six-Membered NHC–Copper(I) Complexes for Catalytic Asymmetric­ Silyl Transfer
  300. Copper(I)-Catalyzed Regioselective Addition of Nucleophilic Silicon Across Terminal and Internal Carbon-Carbon Triple Bonds
  301. New Frontiers and Challenges in Silicon Chemistry:ISOS XVII in Berlin
  302. Intramolecularly Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts
  303. En Route to Stable All-Carbon-Substituted Silylenes: Synthesis and Reactivity of a Bis(α-spirocyclopropyl)silylene
  304. Martin Oestreich
  305. Martin Oestreich
  306. Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative SiN Coupling
  307. Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex
  308. Enantioselektive Addition von Siliciumnukleophilen an Aldimine mit einem präformierten NHC-Kupfer(I)-Komplex als Katalysator
  309. Enantioselective Addition of Silicon Nucleophiles to Aldimines Using a Preformed NHC-Copper(I) Complex as the Catalyst
  310. Diastereotopic Group Selection in Hydroxy‐Directed Intramolecular CH Alkenylation of Indole under Oxidative Palladium(II) Catalysis
  311. Tris(5,6,7,8-tetrafluoronaphthalen-2-yl)borane, a Partially Fluorinated Boron Lewis Acid with Fluorination Distal to the Boron Atom
  312. Brandaktuelles von der enantioselektiven intermolekularen Heck-Reaktion
  313. Breaking News on the Enantioselective Intermolecular Heck Reaction
  314. Salt-Free Preparation of Trimethylsilyl Ethers by B(C6F5)3-Catalyzed Transfer Silylation by Using a Me3SiH Surrogate
  315. Metal-Catalyzed Cross-Coupling Reactions and More
  316. 7.21 Addition Reactions with Formation of CarbonHalogen Bonds
  317. Ferrocene-Stabilized Silicon Cations as Catalysts for Diels–Alder Reactions: Attempted Experimental Quantification of Lewis Acidity and ReactIR Kinetic Analysis
  318. Silylium Ion Promoted Reduction of Imines with Hydrosilanes
  319. Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism
  320. The Family of Ferrocene‐Stabilized Silylium Ions: Synthesis,29Si NMR Characterization, Lewis Acidity, Substituent Scrambling, and Quantum‐Chemical Analyses
  321. Oxidative Palladium(II)-Catalyzed C-7 Alkenylation of Indolines
  322. 3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes
  323. 3-Silylierte Cyclohexa-1,4-diene als Vorstufen für gasförmige Hydrosilane: die B(C6F5)3-katalysierte Transferhydrosilylierung von Alkenen
  324. Katalytische 1,4-selektive Hydrosilylierung von Pyridinverbindungen und benzanellierten Verwandten
  325. Catalytic 1,4-Selective Hydrosilylation of Pyridines and Benzannulated Congeners
  326. Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane
  327. Main-Group Lewis Acids for C–F Bond Activation
  328. Oxidative Palladium(II)-Catalyzed Dehydrogenative CH/CH Cross-Coupling of 2,3-Substituted Indolines with Arenes at the C7 Position
  329. Regio- and Diastereoselective Copper(I)-Catalyzed Allylic Substitution of δ-Hydroxy Allylic Chlorides by a Silicon Nucleophile
  330. SiH Bond Activation: Bridging Lewis Acid Catalysis with Brookhart’s Iridium(III) Pincer Complex and B(C6F5)3
  331. Si-H-Bindungsaktivierung: Parallelen der Lewis-Säure-Katalyse mit Brookharts Iridium(III)-Pincerkomplex und B(C6F5)3
  332. Asymmetrische Synthese α-chiraler Allylsilane durch enantiokonvergente γ-selektive Kupfer(I)-katalysierte allylische Silylierung
  333. Asymmetric Synthesis of α-Chiral Allylic Silanes by Enantioconvergent γ-Selective Copper(I)-Catalyzed Allylic Silylation
  334. C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle
  335. The Renaissance of Silicon-Stereogenic Silanes: A Personal Account
  336. Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis
  337. Catalytic dehydrogenative Si–N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base
  338. Aerobic Palladium(II)-Catalyzed Dehydrogenation of Cyclohexene-1-carbonyl Indole Amides: An Indole-Directed Aromatization
  339. Reversible Heterolytic Si–H Bond Activation by an Intramolecular Frustrated Lewis Pair
  340. Illuminating the Mechanism of the Borane-Catalyzed Hydrosilylation of Imines with Both an Axially Chiral Borane and Silane
  341. 1,2,3,4-Tetrahydro-1-(1,1-dimethylethyl)-1-silanaphthalene
  342. 1,2,3,4-Tetrahydro-1-(1-methylethyl)-1-silanaphthalene
  343. Hemilabile BINAP(O) as a Chiral Ligand in Desymmetrizing Mizoroki-Heck Cyclizations
  344. Copper(I)-Catalyzed Regio- and Chemoselective Single and Double Addition of Nucleophilic Silicon to Propargylic Chlorides and Phosphates
  345. Base-Free Dehydrogenative Coupling of Enolizable Carbonyl Compounds with Silanes
  346. Two-Directional Desymmetrization by Double 1,4-Addition of Silicon and Boron Nucleophiles
  347. Organic Reactions. Volume 75 (Diamond Volume). Herausgegeben von Scott E. Denmark.
  348. Organic Reactions. Volume 75 (Diamond Volume). Edited by Scott E. Denmark.
  349. Catalytic enantioselective dehydrogenative Si–O coupling of oxime ether-functionalized alcohols
  350. Silylium Ion-Catalyzed Challenging Diels–Alder Reactions: The Danger of Hidden Proton Catalysis with Strong Lewis Acids
  351. Ein neuer Weg der C-H-Alkenylierung: Silanol als helfende Hand
  352. A New Direction in CH Alkenylation: Silanol as a Helping Hand
  353. Aerobic Palladium(II)-Catalyzed 5-endo-trig Cyclization: An Entry into the Diastereoselective C-2 Alkenylation of Indoles with Tri- and Tetrasubstituted Double Bonds
  354. Aerobe Palladium(II)-katalysierte 5-endo-trig-Cyclisierung als ein Einstieg in die diastereoselektive C-2-Alkenylierung von Indolen mit tri- und tetrasubstituierten Doppelbindungen
  355. Copper-Catalyzed 1,2-Addition of Nucleophilic Silicon to Aldehydes: Mechanistic Insight and Catalytic Systems
  356. BINAP versus BINAP(O) in Asymmetric Intermolecular Mizoroki-Heck Reactions: Substantial Effects on Selectivities
  357. Copper(I)-Catalyzed Regioselective Propargylic Substitution Involving Si–B Bond Activation
  358. A New Motif for Lewis Base Catalysis: Asymmetric Reduction of β-Enamino Esters
  359. A Unique Transition Metal-Stabilized Silicon Cation
  360. An Axially Chiral, Electron-Deficient Borane: Synthesis, Coordination Chemistry, Lewis Acidity, and Reactivity
  361. Activation of the Si−B Linkage: Copper-Catalyzed Addition of Nucleophilic Silicon to Imines
  362. Shortened Synthesis of a Silicon-Stereogenic Cyclic Silane
  363. Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism
  364. Organische Chemie 2010
  365. All-Carbon-Substituted Quaternary Carbon Atoms in Oxindoles by an Aerobic Palladium(II)-Catalyzed Ring Closure onto Tri- and Tetrasubstituted Double Bonds
  366. Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles
  367. Self-regeneration of a silylium ion catalyst in carbonyl reduction
  368. Stereochemical Surprises in the Lewis Acid-Mediated Allylation of Isatins
  369. Kupferkatalysierte Si-B-Bindungsaktivierung in der verzweigtselektiven allylischen Substitution linearer Allylchloride
  370. Copper-Catalyzed SiB Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides
  371. Base-Catalyzed Dehydrogenative Si-O Coupling of Dihydrosilanes: Silylene Protection of Diols
  372. Transition-Metal-Catalyzed C-P Cross-Coupling Reactions
  373. Der asymmetrische konjugierte Silyltransfer in iterativen katalytischen Sequenzen: Synthese des C7-C16-Fragments von (+)-Neopeltolid
  374. Asymmetric Conjugate Silyl Transfer in Iterative Catalytic Sequences: Synthesis of the C7-C16 Fragment of (+)-Neopeltolide
  375. Expeditious synthesis of TADDOL-derived phosphoramidite and phosphonite ligands
  376. Katalytische asymmetrische Si-O-Kupplung einfacher achiraler Silane und chiraler donorfunktionalisierter Alkohole
  377. Catalytic Asymmetric SiO Coupling of Simple Achiral Silanes and Chiral Donor-Functionalized Alcohols
  378. Organische Chemie 2009
  379. Enantioselektive konjugierte Borylierung
  380. Enantioselective Conjugate Borylation
  381. Silicon- and Tin-Based Cuprates: Now Catalytic in Copper!
  382. Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides
  383. Asymmetric Si–O coupling of alcohols
  384. Silylium ions in catalysis
  385. Enantioselective Fujiwara-Moritani Indole and Pyrrole Annulations Catalyzed by Chiral Palladium(II)-NicOx Complexes
  386. Ein gezähmtes Silyliumion für Diels-Alder-Reaktionen bei niedrigen Temperaturen
  387. Taming the Silylium Ion for Low-Temperature Diels-Alder Reactions
  388. B(C 6 F 5 ) 3 -Catalyzed Reduction of Ketones and Imines Using Silicon-Stereogenic Silanes: Stereoinduction by Single-Point Binding
  389. Conjugate phosphination of cyclic and acyclic acceptors using Rh(I)–phosphine or Rh(I)–carbene complexes. Probing the mechanism with chirality at the silicon atom or the phosphorus atom of the Si–P reagent
  390. Rhodium(I)-catalyzed enantioselective 1,4-addition of nucleophilic silicon
  391. Enantiospezifische Synthese und Allylierung ausschließlich Kohlenstoff-substituierter, α-chiraler Allylstannane
  392. Enantiospecific Synthesis and Allylation of All-Carbon-Substituted α-Chiral Allylic Stannanes
  393. Asymmetrische Ringschlussmetathese mit Pfiff
  394. Asymmetric Ring-Closing Metathesis with a Twist
  395. Palladium(II)-Catalyzed Conjugate Phosphination of Electron-Deficient Acceptors
  396. Potassiumtert-Butoxide-Catalyzed Dehydrogenative SiO Coupling: Reactivity Pattern and Mechanism of an Underappreciated Alcohol Protection
  397. Organische Chemie 2008
  398. The Mizoroki–Heck Reaction
  399. Facile preparation of CF3-substituted carbinols with an azine donor and subsequent kinetic resolution through stereoselective Si–O coupling
  400. Stereoselective Alcohol Silylation by Dehydrogenative Si-O Coupling: Scope, Limitations, and Mechanism of the Cu-H-Catalyzed Non-Enzymatic Kinetic Resolution with Silicon-Stereogenic Silanes
  401. A Catalytic Asymmetric Fujiwara-Moritani Cyclization
  402. Schlüssiger Nachweis eines SN2-Si-Mechanismus in der B(C6F5)3- katalysierten Hydrosilylierung von Carbonylverbindungen: Einsichten in die verwandte Hydrierung
  403. Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation
  404. Transition-Metal-Free Conjugate Stannyl Transfer to α,β-Unsaturated Carbonyl and Carboxyl Compounds in Basic Aqueous Media
  405. Katalytische asymmetrische C-Si-Bindungsknüpfung an acyclischen α,β-ungesättigten Akzeptoren durch RhI-katalysierten konjugierten Silyltransfer mithilfe einer Si-B-Bindung
  406. Catalytic Asymmetric CSi Bond Formation to Acyclic α,β-Unsaturated Acceptors by RhI-Catalyzed Conjugate Silyl Transfer Using a SiB Linkage
  407. Enantio- and Diastereotopos Differentiation in the Palladium(II)-Catalyzed Hydrosilylation of Bicyclo[2.2.1]alkene Scaffolds with Silicon-Stereogenic Silanes
  408. Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane
  409. Kinetic Resolution and Desymmetrization by Stereoselective Silylation of Alcohols
  410. Kinetische Racematspaltung und Desymmetrisierung durch stereoselektive Silylierung von Alkoholen
  411. Chirale Erkennung mit siliciumstereogenen Silanen: außergewöhnliche Selektivitätsfaktoren bei der kinetischen Racematspaltung von donorfunktionalisierten Alkoholen
  412. Chiral Recognition with Silicon-Stereogenic Silanes: Remarkable Selectivity Factors in the Kinetic Resolution of Donor-Functionalized Alcohols
  413. Oxygen Donor-Mediated Equilibration of Diastereomeric Alkene−Palladium(II) Intermediates in Enantioselective Desymmetrizing Heck Cyclizations
  414. Silicon-Stereogenic Silanes in Asymmetric Catalysis
  415. Polishing a Diamond in the Rough: “Cu—H” Catalysis with Silanes
  416. Asymmetric Synthesis - The Essentials
  417. Conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis: A comparative study
  418. Vom Schleifen eines “Rohdiamanten”: die “Cu-H”-Katalyse mit Silanen
  419. Polishing a Diamond in the Rough: “CuH” Catalysis with Silanes
  420. Rhodium(i)-catalysed conjugate phosphination of cyclic α,β-unsaturated ketones with silylphosphines as masked phosphinides
  421. Directed Mizoroki–Heck Reactions
  422. Synthesis by Hydration of Alkynes
  423. Synthesis by Direct Hydration
  424. Intermolecular Chirality Transfer from Silicon to Carbon:  Interrogation of the Two-Silicon Cycle for Pd-Catalyzed Hydrosilylation by Stereoisotopochemical Crossover
  425. Organische Chemie online… und gratis?
  426. Organic Chemistry Online … and for Free?
  427. An Enantioselective Access to an Anthracycline AB Synthon by a ­Desymmetrizing Heck Cyclization
  428. Rhodiumkatalysierter enantioselektiver konjugierter Silyltransfer: 1,4-Addition von Silylboronsäureestern an cyclische Enone und Lactone
  429. Rhodium-Catalyzed Enantioselective Conjugate Silyl Transfer: 1,4-Addition of Silyl Boronic Esters to Cyclic Enones and Lactones
  430. Preparation of a Privileged Silicon-Stereogenic Silane: Classicalversus Kinetic Resolution
  431. Copper-Free and Copper-Promoted Conjugate Addition Reactions of Bis(triorganosilyl) Zincs and Tris(triorganosilyl) Zincates
  432. Organische Chemie 2005
  433. Quaternary Stereocenters. Challenges and Solutions for Organic Synthesis. Herausgegeben von Jens Christoffers und Angelika Baro.
  434. Quaternary Stereocenters. Challenges and Solutions for Organic Synthesis. Edited by Jens Christoffers and Angelika Baro.
  435. Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl) zincs. Enantiospecific preparation of α-chiral silanes
  436. Silylzincation of carbon–carbon multiple bonds revisited
  437. Chirality Transfer from Silicon to Carbon
  438. Kinetische Racematspaltung von chiralen sekundären Alkoholen durch dehydrierende Kupplung mit zurückgewinnbaren, siliciumstereogenen Silanen
  439. Kinetic Resolution of Chiral Secondary Alcohols by Dehydrogenative Coupling with Recyclable Silicon-Stereogenic Silanes
  440. OMCOS 13
  441. Kaleidoskop der Katalyse: Heidelberger Forum für Molekulare Katalyse 2005
  442. Kaleidoscope of Catalysis: Heidelberg Forum of Molecular Catalysis 2005
  443. Schweizer Leckerli: Bürgenstock 2005
  444. Swiss Delight: Bürgenstock 2005
  445. Chemie-Nachwuchsgruppenleiter in Freiburg
  446. Strategien zur katalytischen asymmetrischen elektrophilen ?-Halogenierung von Carbonylverbindungen
  447. Strategies for Catalytic Asymmetric Electrophilic ? Halogenation of Carbonyl Compounds
  448. Practical Synthesis of Allylic Silanes from Allylic Esters and Carbamates by Stereoselective Copper-Catalyzed Allylic Substitution Reactions
  449. ?Echter? Chiralit�tstransfer von Silicium auf Kohlenstoff: asymmetrische Verst�rkung in einer reagenskontrollierten palladiumkatalysierten Hydrosilylierung
  450. ?True? Chirality Transfer from Silicon to Carbon: Asymmetric Amplification in a Reagent-Controlled Palladium-Catalyzed Hydrosilylation
  451. Neighbouring‐Group Effects in Heck Reactions
  452. Hypervalent Silicon as a Reactive Site in Selective Bond-Forming Processes
  453. Catalytic Desymmetrizing Intramolecular Heck Reaction: Evidence for an Unusual Hydroxy-Directed Migratory Insertion
  454. On the Mechanism of the Reductive Metallation of Asymmetrically Substituted Silyl Chlorides
  455. Katalytische desymmetrisierende intramolekulare Heck-Reaktion: Nachweis einer ungewöhnlichen hydroxydirigierten Alkeninsertion
  456. Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters
  457. 23. Regio-Symposium in Falkau/Schwarzwald
  458. Copper-Catalyzed Conjugate Addition of a Bis(triorganosilyl) Zinc and a Methyl(triorganosilyl) Magnesium
  459. Catalytic Asymmetric Synthesis of Quaternary Carbons Bearing Two Aryl Substituents. Enantioselective Synthesis of 3-Alkyl-3-Aryl Oxindoles by Catalytic Asymmetric Intramolecular Heck Reactions
  460. A Convergent Method for the Synthesis of Highly Enantiomerically Enriched Cyclic Silanes with Silicon-Centered Chirality
  461. Vereitelteβ-Hydrideliminierung: Abfangen der Alkylpalladiumzwischenstufe einer asymmetrischen intramolekularen Heck-Reaktion
  462. Thwartingβ-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction
  463. Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds
  464. Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds
  465. (−)-Sparteine-Mediated Asymmetric Intramolecular Carbolithiation of Alkenes: Synthesis of Enantiopure Cyclopentanes with Three Consecutive Stereogenic Centers
  466. (−)-Sparteine-Mediated Stereoselective Intramolecular Carbolithiation of 4-Substituted 5-Hexynyl Carbamates. Synthesis of Enantiopure 1,3-Difunctionalized Alkylidene Cyclopentanes
  467. Corrigendum
  468. (−)-Sparteine-mediated stereoselective intramolecular conjugate addition reactions of dienes and enynes
  469. (−)-Sparteine-mediated stereoselective intramolecular carbolithiation of alkynes
  470. Stereoselective Preparation and Reactions of Cycloalkylzinc Compounds
  471. Stereoselektive Herstellung und Reaktionen von Cycloalkylzinkverbindungen
  472. Formation of Carbocycles
  473. Palladium-Catalyzed Arylation Reactions of Alkenes (Mizoroki–Heck Reaction and Related Processes)
  474. Taming Super Lewis Acids for Catalysis: The Family of Ferrocene-Stabilized Silicon Cations
  475. Diverse Modes of Silane Activation for the Hydrosilylation of Carbonyl Compounds