All Stories

  1. Intramolecular Silylarylation of α‐Olefins Enabled by Disulfide Co‐Catalysis and Maintained by Proton‐into‐Silylium Interconversion
  2. Intramolecular Silylarylation of α‐Olefins Enabled by Disulfide Co‐Catalysis and Maintained by Proton‐into‐Silylium Interconversion
  3. Proton-into-Silylium Ion Generation as a Mechanistic Switch: Divergent Ring-Opening Arylation of CF 3 -Substituted Cyclopropanes
  4. Asymmetric Transition-Metal-Catalyzed Hydrofunctionalization of Alkenylmetalloids (B, Si, and Ge)
  5. The Cation Shuffle: Interplay of silylium, carbenium, and arenium ions in superelectrophile catalysis
  6. Photoredox-Catalyzed Transfer Thiobenzoyloxylation of Styrenes Using Oxime-Based Surrogates
  7. Regio- and stereoselective tert -butylthiolation of internal alkynes with thioethers initiated and maintained by silylium-ion catalysis
  8. Epimerization-Free Synthesis of Azo-Substituted Di- and Tripeptides by Cross-Coupling of O-Triflated Derivatives and Diazenyl Anion Equivalents
  9. Kinetics and Mechanism of Enantioselective Cu-Catalyzed Alcohol Silylation
  10. Photoinduced Deoxygenative Boration of Unactivated Alcohols Involving In-Situ-Formed Alkyl Iodides
  11. Photoredox-Catalyzed Transfer Thio(poly)fluoroacyloxylation of Alkenes Using Oxime-Based Surrogates
  12. Enantioselective Miyaura Reaction by Desymmetrizing C(sp2)–B Cross‐Coupling of 1,1′‐Biaryl‐2,6‐diyl Bis(nonaflates)
  13. Enantioselective Miyaura Reaction by Desymmetrizing C(sp2)–B Cross‐Coupling of 1,1′‐Biaryl‐2,6‐diyl Bis(nonaflates)
  14. Analysis of Cyclohexa-1,4-dienes with an Asymmetrically Substituted, 3° Carbon Atom as Chiral Dihydrogen Surrogates in Reagent-Controlled Transfer Hydrogenation of Alkenes
  15. Directing Effects of Silyl and Germyl Groups in Transition‐Metal‐Catalyzed Allylic Substitution
  16. Atroposelective Synthesis of Azobenzenes by Palladium-Catalyzed Cross-Coupling of Racemic Biaryl Triflates and Diazenyl Pronucleophiles
  17. Isolation of halogen-substituted silylium ions
  18. Silylium-Ion-Promoted Formation of Methylenecyclobutenes by Formal (2 + 2) Cycloaddition of Allenylsilanes and Internal Alkynes
  19. Kinetic Resolution of BINAMs by Stereoselective Copper-Catalyzed Dehydrogenative Si–N Coupling with Prochiral Dihydrosilanes
  20. Nickel-Catalyzed Enantioconvergent C(sp3)–C(sp3) Cross-Coupling between α-Iodogermanes and Alkylzinc Reagents
  21. Dynamic Kinetic C(sp2)–Si Cross-Coupling with Si–B Reagents for the Atroposelective Construction of Unsymmetrical Heterobiaryls
  22. Kinetic Resolution of Acyclic 1,3-Diols by Copper-Catalyzed Regioselective Dehydrogenative Si–O-Coupling
  23. Photoredox-Catalyzed Transfer Aminochlorination of Unactivated Alkenes Using Oxime-Based Surrogates
  24. One-Pot Sequential Alcohol Activation and Nickel-Catalyzed Cross-Electrophile Coupling with Chlorosilanes
  25. Ionic Remote α-C–H Allenylation of Silyl Ethers Involving a [1,5]-Hydride Shift Promoted by Silylium-Ion Regeneration
  26. Silylium-Ion-Promoted (3 + 2) Annulation of Allenylsilanes with Internal Alkynes Involving a Pentadienyl-to-Allyl Cation Electrocyclization
  27. Enantio‐ and Diastereoselective Desymmetrization of 1,1’‐Biaryl‐2,6‐Dicarbaldehydes by Copper‐Catalyzed 1,2‐Addition of Silicon Nucleophiles
  28. Enantio‐ und Diastereoselektive Desymmetrisierung von 1,1’‐Biaryl‐2,6‐Dicarbaldehyden durch kupferkatalysierte 1,2‐Addition von Siliciumnukleophilen
  29. Kinetic Resolution of BINOLs and Biphenols by Atroposelective, Cu–H-Catalyzed Si–O Coupling with Hydrosilanes
  30. Enantio‐ and Regioconvergent Nickel‐Catalyzed Etherification of Phenols by Allylation to Access Chiral C(sp3)−O Allyl Aryl Ethers
  31. Enantio‐ und regiokonvergente, nickelkatalysierte Veretherung von Phenolen durch Allylierung zur Darstellung chiraler C(sp3)−O‐Allylarylether
  32. From Process Chemistry to Methodology Development in Metal-Mediated Chemistry and Catalysis
  33. Ring Contraction of Saturated Cyclic Amines and Rearrangement of Acyclic Amines Through Their Corresponding Hydroxylamines
  34. Ring Contraction of Saturated Cyclic Amines and Rearrangement of Acyclic Amines Through Their Corresponding Hydroxylamines
  35. Cationic Bis(hydrosilane)—Coinage‐Metal Complexes: Synthesis, Characterization, and Use as Catalysts for Outer‐Sphere C=O Hydrosilylation Not Involving Metal Hydrides
  36. Cationic Bis(hydrosilane)—Coinage‐Metal Complexes: Synthesis, Characterization, and Use as Catalysts for Outer‐Sphere C=O Hydrosilylation Not Involving Metal Hydrides
  37. Ni–H-Catalyzed Chemo- and Regioselective Hydroarylation of Vinylsilanes
  38. Synthesis of a Cationic Cobalt–Selenolate Complex for Cooperative Sn–H Bond Activation: Solvent-Dependent Stereoselectivity in Alkyne Hydrostannylation
  39. Silylium-Ion-Initiated Twofold Halodealkylation of Fully Alkylated Silanes
  40. Enantioselective Dearomatization of Pyridinium Salts by Copper‐Catalyzed C4‐Selective Addition of Silicon Nucleophiles
  41. Enantioselektive Dearomatisierung von Pyridiniumsalzen durch kupferkatalysierte C4‐selektive Addition von Siliciumnukleophilen
  42. Functional group transfer strategies unlock new synthetic avenues
  43. Electrophilic Activation of S−Si Reagents by Silylium Ions for Their Regio‐ and Diastereoselective Addition Across C−C Multiple Bonds
  44. Elektrophile Aktivierung von S−Si‐Reagenzien mit Silyliumionen für deren regio‐ und diastereoselektive Addition an C−C‐Mehrfachbindungen
  45. Copper-catalyzed silylation of aryl and alkenyl triflates with silylboronic esters avoiding base-mediated borylation
  46. Chiral Carborane Acids Decorated with Binol-Based Phosphonates: Synthesis, Characterization, and Application
  47. Desymmetrization of Cyclohexadienones Containing a Quaternary γ-Carbon Atom by Conjugate Addition of Boron Nucleophiles
  48. Ligand-Controlled On–Off Switch of a Silicon-Tethered Directing Group Enabling the Regiodivergent Hydroalkylation of Vinylsilanes under Ni–H Catalysis
  49. Bond-Forming Processes Enabled by Silicon-Masked Aryl- and Alkyl-Substituted Diazenes
  50. Arenium-ion-catalysed halodealkylation of fully alkylated silanes
  51. Skeletal Rearrangements Involving Cyclopropyl- and Alkene-Stabilized Silylium Ions
  52. Fluoride-Catalyzed Arylation of α-(Trifluoromethyl)styrene Derivatives with Silicon-Masked, Functionalized Aryl Pronucleophiles
  53. Generation of Silicon-Centered Stereogenicity by Chiral Counteranion-Directed Desymmetrization of Silanediols
  54. Dehydrative Coupling of 1,1-Diarylalkenes and Cyclohexa-2,5-diene-1-carbaldehyde Derivatives Induced by a B(C6F5)3-Initiated [1,2]-Alkyl Migration
  55. Regioselective Hydroalkylation of Vinyl- and Allylsilanes as Well as Vinylgermanes under Ni–H Catalysis
  56. Discrimination of the Enantiotopic Faces of Structurally Unbiased Carbenium Ions Employing a Cyclohexadiene‐Based Chiral Hydride Source
  57. Unterscheidung der enantiotopen Seiten von strukturell unvoreingenommenen Carbeniumionen unter Verwendung einer cyclohexadienbasierten, chiralen Hydridquelle
  58. The Two Faces of Carbenium Ions: Intermolecular Trapping of Prochiral Carbocations with Stereocontrol
  59. Atroposelective Silylation of 1,1′‐Biaryl‐2,6‐diols by a Chiral Counteranion Directed Desymmetrization Enhanced by a Subsequent Kinetic Resolution
  60. Atropselektive Silylierung von 1,1′‐Biaryl‐2,6‐diolen mittels chiraler gegenaniondirigierter Desymmetrisierung und anschließender Verbesserung durch kinetische Racematspaltung
  61. Enantio- and Regioconvergent Synthesis of γ-Stereogenic Vinyl Germanes and Their Use as Masked Vinyl Halides
  62. Intramolecular 7-endo-dig-Selective Carbosilylation of Internal Alkynes Involving Silylium-Ion Regeneration
  63. Photoinduced radical–ionic dihalogen transfer to carbon–carbon multiple bonds using oxime-based surrogates
  64. Catalytically Generated Meerwein’s Salt-Type Oxonium Ions for Friedel–Crafts C(sp2)–H Methylation with Methanol
  65. B(C6F5)3‐Catalyzed Regioselective Ring Opening of Cyclic Amines with Hydrosilanes
  66. Silylium Ion Initiated Intramolecular Friedel–Crafts-Type Cyclization of 1,1-Difluoroalkenes with Subsequent Hydrodefluorination of C(sp3)–F Bonds
  67. Copper‐Catalyzed Highly Enantioselective Addition of a Silicon Nucleophile to 3‐Substituted 2H‐Azirines Using an Si−B Reagent
  68. Kupferkatalysierte, hochgradig enantioselektive Addition eines Siliciumnukleophils an 3‐substituierte 2H‐Azirine unter Verwendung eines Si‐B‐Reagenzes
  69. The [3]Dendralene Motif as an Entry into Nazarov Cyclizations by Silylium-Ion Initiation
  70. Advances in Enantioconvergent Transition-Metal-Catalyzed Cross-Coupling Reactions of Racemic α-Silyl and α-Boryl Reagents
  71. Atom-economic and stereoselective catalytic synthesis of fully substituted enol esters/carbonates of amides in acyclic systems enabled by boron Lewis acid catalysis
  72. Experimental Mechanistic Analysis of Carbonyl Hydrosilylation Catalyzed by Abu-Omar’s Rhenium(V) Oxo Complex
  73. Synthesis of Benzhydryl-Substituted Amines by Silanolate-Mediated Aldimine Arylation with Functionalized Aryl Nucleophiles Released from Diazene-Based Reagents
  74. Palladium-Catalyzed Denitrogenative Cross-Coupling of Silicon-Masked, Aryl-Substituted Diazenes and Aryl Bromides
  75. Silylium-Ion-Promoted Skeletal Reorganization of β-Silylated Cyclopropanes Bearing an Allyl Group at the Silicon Atom Coupled with Intermolecular Formation of a Quaternary Carbon Atom
  76. Boosting the Enantioselectivity of Conjugate Borylation of α,β‐Disubstituted Cyclobutenones with Monooxides of ChiralC2‐Symmetric Bis(phosphine) Ligands
  77. Synthese von unsymmetrischen Azobenzolen durch palladiumkatalysierte Kreuzkupplung von siliciummaskierten Diazenylanionen und (Hetero)arylhalogeniden
  78. Synthesis of Non‐Symmetric Azoarenes by Palladium‐Catalyzed Cross‐Coupling of Silicon‐Masked Diazenyl Anions and (Hetero)Aryl Halides
  79. Photochemical, Nickel-Catalyzed C(sp3)–C(sp3) Reductive Cross-Coupling of α-Silylated Alkyl Electrophiles and Allylic Sulfones
  80. Enantio- and Regioconvergent Nickel-Catalyzed Allylic Substitution of Racemic α- or γ-Silylated Allylic Bromides with Benzylzinc Reagents
  81. Intermolecular Carbosilylation of α‐Olefins with C(sp3)−C(sp) Bond Formation Involving Silylium‐Ion Regeneration
  82. Intermolekulare Carbosilylierung von α‐Olefinen mit C(sp3)−C(sp)‐Bindungsknüpfung unter Neubildung von Silyliumionen
  83. B(C6F5)3-Catalyzed Reductive Denitrogenation of Benzonitrile Derivatives
  84. Decarbonylative Transfer Hydrochlorination of Alkenes and Alkynes Based on a B(C6F5)3‐Initiated Grob Fragmentation
  85. Decarbonylierende Transferhydrochlorierung von Alkenen und Alkinen auf Grundlage einer B(C6F5)3‐ausgelösten Grob‐Fragmentierung
  86. Cationic Cobalt–Thiolate Complexes for the Dehydrogenative Coupling of nBu3SnH
  87. Perdeuteration of Deactivated Aryl Halides by H/D Exchange under Superelectrophile Catalysis
  88. Silylium-Ion-Promoted Hydrosilylation of Aryl-Substituted Allenes: Interception by Cyclization of the Allyl-Cation Intermediate
  89. Competition for Hydride Between Silicon and Boron: Synthesis and Characterization of a Hydroborane‐Stabilized Silylium Ion
  90. Metal-free transfer hydrochlorination of internal C–C triple bonds with a bicyclo[3.1.0]hexane-based surrogate releasing two molecules of hydrogen chloride
  91. One out of Four: Kinetic Resolution of Stereoisomeric Mixtures of Secondary Alcohols with a Quaternary Carbon Atom in the β-Position by Cu–H-Catalyzed Enantioselective Silylation
  92. Enantioselective, Copper-Catalyzed Addition of Nucleophilic Silicon to Alkenyl-Substituted Phosphine Oxides
  93. Synthesis of Silylated Cyclobutanone and Cyclobutene Derivatives Involving 1,4‐Addition of Zinc‐Based Silicon Nucleophiles
  94. Silylium-Ion Regeneration by Protodesilylation Enables Friedel–Crafts Alkylation with Less Isomerization and No Defunctionalization
  95. The Power of the Proton: From Superacidic Media to Superelectrophile Catalysis
  96. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  97. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  98. Nickelkatalysierte, reduktive C(sp3)‐Si‐Kreuzkupplung von α‐cyanosubstituierten Alkylelektrophilen und Chlorsilanen
  99. Nickel‐Catalyzed, Reductive C(sp3)−Si Cross‐Coupling of α‐Cyano Alkyl Electrophiles and Chlorosilanes
  100. Transition‐Metal‐Free Coupling of Polyfluorinated Arenes and Functionalized, Masked Aryl Nucleophiles
  101. B(C6F5)3-Catalyzed Diastereoselective Formal (4 + 1)-Cycloaddition of Vinylcyclopropanes and Et2SiH2
  102. Radical entry into Ni-catalyzed transfer hydrocyanation using cheap AIBN
  103. Metal‐Free Hydrosilylation of Ketenes with Silicon Electrophiles: Access to Fully Substituted Aldehyde‐Derived Silyl Enol Ethers
  104. Enantio‐ and Regioconvergent Nickel‐Catalyzed C(sp3)−C(sp3) Cross‐Coupling of Allylic Electrophiles Steered by a Silyl Group
  105. Enantio‐ und regiokonvergente, nickelkatalysierte C(sp3)‐C(sp3)‐Kreuzkupplung von allylischen Elektrophilen gelenkt durch eine Silylgruppe
  106. Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts
  107. Chemoselective Deoxygenation of 2° Benzylic Alcohols through a Sequence of Formylation and B(C6F5)3‐Catalyzed Reduction
  108. Enantioconvergent and Regioselective Synthesis of Allenylsilanes by Nickel-Catalyzed C(sp2)–C(sp3) Cross-Coupling Starting from Racemic α-Silylated Propargylic Bromides
  109. Development of a Radical Silylzincation of (Het)Aryl‐Substituted Alkynes and Computational Insights into the Origin of the trans‐Stereoselectivity
  110. Diastereotopic Group-Selective Intramolecular Aldol Reactions Initiated by Enantioselective Conjugate Silylation: Diastereodivergence Controlled by the Silicon Nucleophile
  111. The Trityl Cation Embedded into a [7]Helicene-Like Backbone: Preparation and Application as a Lewis Acid Catalyst
  112. Aufeinanderfolgende β,β′‐selektive C(sp3)‐H‐Silylierung von tertiären Aminen mit Dihydrosilanen katalysiert durch B(C6F5)3
  113. Consecutive β,β′‐Selective C(sp3)−H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C6F5)3
  114. At Long Last: The Me3Si Group as a Masked Alcohol
  115. Zu guter Letzt: Die Me3Si‐Gruppe als ein getarnter Alkohol
  116. Activation of the Si–B interelement bond related to catalysis
  117. Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes
  118. Mild reductive rearrangement of oximes and oxime ethers to secondary amines with hydrosilanes catalyzed by B(C6F5)3
  119. Kinetic Resolution of Neopentylic Secondary Alcohols by Cu–H-Catalyzed Enantioselective Silylation with Hydrosilanes
  120. Cationic Ru–Se Complexes for Cooperative Si–H Bond Activation
  121. Dynamic Kinetic Resolution of Alcohols by Enantioselective Silylation Enabled by Two Orthogonal Transition‐Metal Catalysts
  122. Dynamische kinetische Racematspaltung von Alkoholen mittels enantioselektiver Silylierung ermöglicht durch zwei orthogonale Übergangsmetallkatalysatoren
  123. The Cyclohexa‐2,5‐dienyl Group as a Placeholder for Hydrogen: Organocatalytic Michael Addition of an Acetaldehyde Surrogate
  124. Enantioselective Synthesis of α-Chiral Propargylic Silanes by Copper-Catalyzed 1,4-Selective Addition of Silicon Nucleophiles to Enyne-Type α,β,γ,δ-Unsaturated Acceptors
  125. B(C6F5)3-Catalyzed Hydrosilylation of Vinylcyclopropanes
  126. Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates
  127. Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration
  128. Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration
  129. Reductive Deamination with Hydrosilanes Catalyzed by B(C6F5)3
  130. Reduktive Desaminierung mit Hydrosilanen katalysiert durch B(C6F5)3
  131. Copper-Catalyzed Enantioselective and Exo-Selective Addition of Silicon Nucleophiles to 7-Oxa- and 7-Azabenzonorbornadiene Derivatives
  132. Synthese eines gegenanionstabilisierten Bis(silylium)ions
  133. Synthesis of a Counteranion‐Stabilized Bis(silylium) Ion
  134. Kilian Muñiz (1970–2020)
  135. Seeds for the Future: Growing Chemistry Trends
  136. Autocatalytic Carbonyl Arylation through In Situ Release of Aryl Nucleophiles from N‐Aryl‐N′‐Silyldiazenes
  137. Autokatalytische Carbonylarylierung mittels lokaler Freisetzung von Arylnukleophilen ausgehend von N‐Aryl‐N′‐silyldiazenen
  138. Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes
  139. Transition-Metal-Like Catalysis with a Main-Group Element: Bismuth-Catalyzed C−F Coupling of Aryl Boronic Esters
  140. Übergangsmetallartige Katalyse mit einem Hauptgruppenelement: Bismutkatalysierte C‐F‐Kupplung von Arylboronsäureestern
  141. Formyltetrahydrofolate Decarbonylase Synthesizes the Active Site CO Ligand of O2-Tolerant [NiFe] Hydrogenase
  142. Defunctionalisation catalysed by boron Lewis acids
  143. Emerging Strategies for C–H Silylation
  144. Outstanding Reviewers for Chemical Science in 2019
  145. Stereospecific and Chemoselective Copper-Catalyzed Deaminative Silylation of Benzylic Ammonium Triflates
  146. Stereospezifische und chemoselektive kupferkatalysierte, deaminierende Silylierung von Benzylammoniumtriflaten
  147. General Synthesis and Optical Properties of N-Aryl-N′-Silyldiazenes
  148. Cationic silicon Lewis acids in catalysis
  149. Chiral Modification of the Tetrakis(pentafluorophenyl)borate Anion with Myrtanyl Groups
  150. Ionic Transfer Reactions with Cyclohexadiene-Based Surrogates
  151. Si-H Bond Activation with Bullock’s Cationic Tungsten(II) Catalyst: CO as Cooperating Ligand
  152. Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions
  153. Katalytische Difunktionalisierung von nichtaktivierten Alkenen mit reaktionsträgem Hexamethyldisilan durch Neubildung von Silyliumionen
  154. Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes
  155. Lewis Säure‐katalysierte Transferhydromethallylierung für den Aufbau quartärer Kohlenstoffzentren
  156. Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers
  157. Characterization of hydrogen-substituted silylium ions in the condensed phase
  158. Copper-Catalyzed Regio- and Enantioselective Addition of Silicon Grignard Reagents to Alkenes Activated by Azaaryl Groups
  159. Kupferkatalysierte regio‐ und enantioselektive Addition von Silicium‐Grignard‐Reagenzien an durch Azaarylgruppen aktivierte Alkene
  160. Metal-Free Transfer Hydrobromination of C–C Triple Bonds
  161. Bioinspired Metal‐Free Formal Decarbonylation of α‐Branched Aliphatic Aldehydes at Ambient Temperature
  162. Tertiary α-Silyl Alcohols by Diastereoselective Coupling of 1,3-Dienes and Acylsilanes Initiated by Enantioselective Copper-Catalyzed Borylation
  163. Tertiäre α‐Silylalkohole mittels diastereoselektiver Kupplung von 1,3‐Dienen und Acylsilanen, eingeleitet durch enantioselektive kupferkatalysierte Borylierung
  164. Making the Silylation of Alcohols Chiral: Asymmetric Protection of Hydroxy Groups
  165. Regiodivergent and Stereospecific Aziridine Opening by Copper‐Catalyzed Addition of Silicon Grignard Reagents
  166. Mechanistic Dichotomy of Magnesium- and Zinc-Based Germanium Nucleophiles in the C(sp3 )−Ge Cross-Coupling with Alkyl Electrophiles
  167. Gegensätzliche Reaktionsweisen magnesium‐ und zinkbasierter Germaniumnukleophile in der C(sp 3 )‐Ge‐Kreuzkupplung mit Alkylelektrophilen
  168. Further Structural Modification of Sulfur-Stabilized Silicon Cations with Binaphthyl Backbones
  169. Enantioselective Construction of α-Chiral Silanes by Nickel-Catalyzed C(sp3 )−C(sp3 ) Cross-Coupling
  170. Enantioselektiver Aufbau von α‐chiralen Silanen durch nickelkatalysierte C(sp 3 )‐C(sp 3 )‐Kreuzkupplung
  171. Axially Chiral, Electrophilic Fluorophosphonium Cations: Synthesis, Lewis Acidity, and Reactivity in the Hydrosilylation of Ketones
  172. Bor-Lewis-Säure-katalysierte Transferhydrocyanierung α- und α,β-substituierter Styrole
  173. Transfer Hydrocyanation of α- and α,β-Substituted Styrenes Catalyzed by Boron Lewis Acids
  174. Kinetic Resolution of Tertiary Propargylic Alcohols by Enantioselective Cu−H-Catalyzed Si−O Coupling
  175. Kinetische Racematspaltung tertiärer Propargylalkohole durch enantioselektive Cu-H-katalysierte Si-O-Kupplung
  176. Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydroxyalkylboration of 1,3-dienes with ketones
  177. Using alcohols as simple H2-equivalents for copper-catalysed transfer semihydrogenations of alkynes
  178. Metal-Free Transfer Hydroiodination of C–C Multiple Bonds
  179. Copper-Catalyzed Cross-Coupling of Vinyliodonium Salts and Zinc-Based Silicon Nucleophiles
  180. Palladium-Catalyzed Three-Component Reaction of Dihydrosilanes and Vinyl Iodides in the Presence of Alcohols: Rapid Assembly of Silyl Ethers of Tertiary Silanes
  181. C(sp3)–Si Cross-Coupling
  182. Achieving Enantioselectivity in Difficult Cyclohexa-1,3-diene Diels–Alder Reactions with Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts
  183. Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution
  184. Einelektronenübertragungsreaktionen in frustrierten und klassischen Silyliumion/Phosphan-Lewis-Paaren
  185. Single-Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphane Lewis Pairs
  186. Regioselective Transfer Hydrodeuteration of Alkenes with a Hydrogen Deuteride Surrogate Using B(C6F5)3 Catalysis
  187. Electrophilic Phosphonium Cations as Lewis Acid Catalysts in Diels–Alder Reactions and Nazarov Cyclizations
  188. Bioinspired Catalytic Generation of Main-group Electrophiles by Cooperative Bond Activation
  189. Bench-Stable Stock Solutions of Silicon Grignard Reagents: Application to Iron- and Cobalt-Catalyzed Radical C(sp3 )-Si Cross-Coupling Reactions
  190. Stabile Stammlösungen von Silicium-Grignard-Reagenzien: Anwendung in eisen- und cobaltkatalysierten radikalischen C(sp3 )-Si-Kreuzkupplungsreaktionen
  191. Copper-Catalyzed Double C(sp3)–Si Coupling of Geminal Dibromides: Ionic-to-Radical Switch in the Reaction Mechanism
  192. Enantioselective Nazarov Cyclizations Catalyzed by an Axial Chiral C6 F5 -Substituted Boron Lewis Acid
  193. Enantioselektive Nazarov-Cyclisierungen, die von einer axial-chiralen, C6 F5 -substituierten Bor-Lewis-Säure katalysiert werden
  194. Z-Selective Hydrostannylation of Terminal and Internal C–C Triple Bonds Initiated by the Trityl Cation
  195. Copper-Catalyzed Silylation of C(sp3)–H Bonds Adjacent to Amide Nitrogen Atoms
  196. Innenrücktitelbild: Kinetische Racematspaltung α-hydroxysubstituierter Oximether durch enantioselektive Cu-H-katalysierte Si-O-Kupplung (Angew. Chem. 33/2018)
  197. Inside Back Cover: Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu−H-Catalyzed Si−O Coupling (Angew. Chem. Int. Ed. 33/2018)
  198. Cleavage of Unactivated Si−C(sp3 ) Bonds with Reed's Carborane Acids: Formation of Known and Unknown Silylium Ions
  199. Spaltung nicht aktivierter Si-C(sp3 )-Bindungen mit Reedschen Carboransäuren: Bildung bekannter und unbekannter Silyliumionen
  200. Custom Hydrosilane Synthesis Based on Monosilane
  201. Electrophilic Formylation of Arenes by Silylium Ion Mediated Activation of Carbon Monoxide
  202. Elektrophile Formylierung von Aromaten durch silyliumionvermittelte Aktivierung von Kohlenmonoxid
  203. Direct Acetophenone-Acetophenone Crossed Aldol Reaction and Aldol Self-Reaction Promoted by a Tethered Ru-S Complex
  204. Refinement of the Catalyst Backbone of Chiral Intramolecular Silicon-Sulfur Lewis Pairs: Improved Enantioselectivity in the Diels-Alder Reaction of Cyclohexa-1,3-diene and Chalcone Derivatives
  205. Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu−H-Catalyzed Si−O Coupling
  206. Kinetische Racematspaltung α-hydroxysubstituierter Oximether durch enantioselektive Cu-H-katalysierte Si-O-Kupplung
  207. A Neutral RuII Hydride Complex for the Regio- and Chemoselective Reduction of N -Silylpyridinium Ions
  208. The electrophilic aromatic substitution approach to C–H silylation and C–H borylation
  209. Catalytic Dehydrogenative Stannylation of C(sp)–H Bonds Involving Cooperative Sn–H Bond Activation of Hydrostannanes
  210. Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion
  211. Copper-Catalyzed Substitution of α-Triflyloxy Nitriles and Esters with Silicon Nucleophiles under Inversion of the Configuration
  212. Two-Silicon Cycle for Carbonyl Hydrosilylation with Nikonov’s Cationic Ruthenium(II) Catalyst
  213. Cooperative Al–H Bond Activation in DIBAL-H: Catalytic Generation of an Alumenium-Ion-Like Lewis Acid for Hydrodefluorinative Friedel–Crafts Alkylation
  214. Cluster Preface: Silicon in Synthesis and Catalysis
  215. An Expedient Procedure for the Synthesis of Benzo[4,5]silolo[2,3-b]thiophenes and Related Systems
  216. Copper-Catalyzed Decarboxylative Radical Silylation of Redox-Active Aliphatic Carboxylic Acid Derivatives
  217. Kupferkatalysierte decarboxylierende radikalische Silylierung von redoxaktiven aliphatischen Carbonsäurederivaten
  218. B(C6F5)3-Catalyzed Reduction of Sulfoxides and Sulfones to Sulfides with Hydrosilanes
  219. BArF3-Catalyzed Imine Hydroboration with Pinacolborane Not Requiring the Assistance of an Additional Lewis Base
  220. Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes
  221. Exhaustive Chemoselective Reduction of Nitriles by Catalytic Hydrosilylation Involving Cooperative Si–H Bond Activation
  222. Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study
  223. Photocatalysis Enabling Acceptorless Dehydrogenation of Benzofused Saturated Rings at Room Temperature
  224. Photokatalyse ermöglicht die akzeptorfreie Dehydrierung von benzanellierten gesättigten Ringen bei Raumtemperatur
  225. Synthesis of a Chiral Borate Counteranion, Its Trityl Salt, and Application Thereof in Lewis-Acid Catalysis
  226. Cooperative Catalysis at Metal–Sulfur Bonds
  227. Access to Fully Alkylated Germanes by B(C6F5)3-Catalyzed Transfer Hydrogermylation of Alkenes
  228. A Tethered Ru-S Complex with an Axial Chiral Thiolate Ligand for Cooperative Si-H Bond Activation: Application to Enantioselective Imine Reduction
  229. Katalytische Friedel-Crafts-C-H-Borylierung elektronenreicher Arene: starke Reaktionsbeschleunigung durch Versetzen mit Alkenen
  230. Catalytic Friedel-Crafts C−H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes
  231. Hidden Enantioselective Hydrogenation of N-Silyl Enamines and Silyl Enol Ethers in Net C═N and C═O Hydrosilylations Catalyzed by Ru–S Complexes with One Monodentate Chiral Phosphine Ligand
  232. B(C6F5)3-Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl Tosylates with Hydrosilanes
  233. B(C6F5)3-katalysierte chemoselektive Defunktionalisierung von etherhaltigen primären Alkyltosylaten mit Hydrosilanen
  234. Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application
  235. Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes
  236. Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes
  237. C H Bond Functionalization at the Benzene Core of Indoles and Indolines (Excluding C-2 and C-3)
  238. 4.4.7 Product Subclass 7: Silylboron Reagents
  239. Catalytic Access to Indole-Fused Benzosiloles by 2-Fold Electrophilic C–H Silylation with Dihydrosilanes
  240. Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel-Crafts C−H Silylation
  241. Elektrophile aromatische Substitution mit Siliciumelektrophilen: die katalytische Friedel-Crafts-C-H-Silylierung
  242. Teaching nature the unnatural
  243. Stereodivergent Synthesis of β-Heteroatom-Substituted Vinyl­silanes by Sequential Silylzincation–Copper(I)-Mediated Electrophilic­ Substitution
  244. 3-tert -Butyl-Substituted Cyclohexa-1,4-dienes as Isobutane Equivalents in the B(C6 F5 )3 -Catalyzed Transfer Hydro-tert -Butylation of Alkenes
  245. Copper-Catalyzed Cross-Coupling of Silicon Pronucleophiles with Unactivated Alkyl Electrophiles Coupled with Radical Cyclization
  246. Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF 3 Does What B(C6 F5 )3 Cannot Do!
  247. Enantioselective Diels–Alder Reactions of Cyclohexa-1,3-diene and Chalcones Catalyzed by Intramolecular Silicon–Sulfur Lewis Pairs as Chiral Lewis Acids
  248. Ausbalancieren von C=C-Funktionalisierung und C=O-Reduktion in der Cu-H-Katalyse
  249. Balancing C=C Functionalization and C=O Reduction in Cu−H Catalysis
  250. Merging Platinum-Catalyzed Alkene Hydrosilylation with SiH4 Surrogates: Salt-Free Preparation of Trihydrosilanes
  251. Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel–Crafts C–H Silylation
  252. B(C6F5)3-Catalyzed Reduction of Aromatic and Aliphatic Nitro Groups with Hydrosilanes
  253. Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru−S Complexes: From Cooperative Dihydrogen Activation to Hydride Abstraction/Proton Release from Dihydrogen Surrogates
  254. The Asymmetric Piers Hydrosilylation
  255. Brønsted Acid-Catalyzed Transfer Hydrogenation of Imines and Alkenes Using Cyclohexa-1,4-dienes as Dihydrogen Surrogates
  256. Stereodivergent Silylzincation of α-Heteroatom-Substituted Alkynes
  257. Metal-Free Phosphine Oxide Reductions Catalyzed by B(C6F5)3 and Electrophilic Fluorophosphonium Cations
  258. An Air-Stable Dimeric Ru–S Complex with an NHC as Ancillary Ligand for Cooperative Si–H Bond Activation
  259. Copper-Catalyzed Si–B Bond Activation in the Nucleophilic Substitution of Primary Aliphatic Triflates
  260. Planar Chiral, Ferrocene-Stabilized Silicon Cations
  261. Durch Nichtedelmetallsalze ausgelöste Friedel-Crafts-artige intermolekulare C-H-Silylierung von elektronenreichen Arenen
  262. Friedel-Crafts-Type Intermolecular C−H Silylation of Electron-Rich Arenes Initiated by Base-Metal Salts
  263. Transfer Hydrosilylation
  264. Catalytic Electrophilic CH Silylation of Pyridines Enabled by Temporary Dearomatization
  265. Extending the Scope of the B(C6F5)3-Catalyzed CN Bond Reduction: Hydrogenation of Oxime Ethers and Hydrazones
  266. Phosphinic Amide as Directing Group Enabling Palladium(II)-CatalyzedorthoC−H Alkenylation of Anilines without and with Alkylation at the Nitrogen Atom
  267. B(C6F5)3-Catalyzed Transfer of Dihydrogen from One Unsaturated Hydrocarbon to Another
  268. Formal SiH4 chemistry using stable and easy-to-handle surrogates
  269. The Cyclohexadienyl-Leaving-Group Approach toward Donor-Stabilized Silylium Ions
  270. A Catalytic SEAr Approach to Dibenzosiloles Functionalized at Both Benzene Cores
  271. Intramolecularly Sulfur-Stabilized Silicon Cations with Chiral Binaphthyl Backbones: Synthesis of Three Different Motifs and Their Application in Enantioselective Diels–Alder Reactions
  272. Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors
  273. Platinum(0)-Catalyzed Indolyne Insertion into Bis(pinacolato)diboron Followed by Site-Selective Suzuki–Miyaura Cross-Coupling
  274. Synthesis of 2,6-Dihalogenated Purine Nucleosides by Thermostable Nucleoside Phosphorylases
  275. A Constellation of Deuterium-Labeled Silanes as a Simple Mechanistic Probe not Requiring Absolute Configuration Determination
  276. Temperature-Dependent Direct Enantioconvergent Silylation of a Racemic Cyclic Allylic Phosphate by Copper(I)-Catalyzed Allylic Substitution
  277. Faszinierende Chemie des Wasserstoffatomtransfers auf Alkene inspiriert durch Probleme in Totalsynthesen
  278. Fascinating Hydrogen Atom Transfer Chemistry of Alkenes Inspired by Problems in Total Synthesis
  279. Temperature-Dependent Chemoselective Hydrosilylation of Carbon Dioxide to Formaldehyde or Methanol Oxidation State
  280. Direct and Transfer Hydrosilylation Reactions Catalyzed by Fully or Partially Fluorinated Triarylboranes: A Systematic Study
  281. A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes
  282. Mechanism of the cooperative Si–H bond activation at Ru–S bonds
  283. Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex
  284. Asymmetric Addition of Boron and Silicon Nucleophiles
  285. B(C6F5)3-Catalyzed Transfer Hydrogenation of Imines and Related Heteroarenes Using Cyclohexa-1,4-dienes as a Dihydrogen Source
  286. B(C6F5)3-katalysierte Transferhydrierung von Iminen und verwandten Heteroaromaten mit Cyclohexa-1,4-dienen als Wasserstoffquelle
  287. Exceptionally Mild Palladium(II)-Catalyzed Dehydrogenative C–H/C–H Arylation of Indolines at the C-7 Position under Air
  288. Chemoselective Tin–Boron Exchange Aided by the Use of Dummy Ligands at the Tin Atom
  289. B(C6F5)3-Catalyzed Hydrogenation of Oxime Ethers without Cleavage of the NO Bond
  290. B(C6F5)3-katalysierte Hydrierung von Oximethern ohne Spaltung der N-O-Bindung
  291. Trans-Selective Radical Silylzincation of Ynamides
  292. Trans-Selective Radical Silylzincation of Ynamides
  293. McQuade’s Six-Membered NHC–Copper(I) Complexes for Catalytic Asymmetric­ Silyl Transfer
  294. Copper(I)-Catalyzed Regioselective Addition of Nucleophilic Silicon Across Terminal and Internal Carbon-Carbon Triple Bonds
  295. New Frontiers and Challenges in Silicon Chemistry:ISOS XVII in Berlin
  296. Intramolecularly Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts
  297. En Route to Stable All-Carbon-Substituted Silylenes: Synthesis and Reactivity of a Bis(α-spirocyclopropyl)silylene
  298. Martin Oestreich
  299. Martin Oestreich
  300. Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative SiN Coupling
  301. Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex
  302. Enantioselektive Addition von Siliciumnukleophilen an Aldimine mit einem präformierten NHC-Kupfer(I)-Komplex als Katalysator
  303. Enantioselective Addition of Silicon Nucleophiles to Aldimines Using a Preformed NHC-Copper(I) Complex as the Catalyst
  304. Diastereotopic Group Selection in Hydroxy‐Directed Intramolecular CH Alkenylation of Indole under Oxidative Palladium(II) Catalysis
  305. Tris(5,6,7,8-tetrafluoronaphthalen-2-yl)borane, a Partially Fluorinated Boron Lewis Acid with Fluorination Distal to the Boron Atom
  306. Brandaktuelles von der enantioselektiven intermolekularen Heck-Reaktion
  307. Breaking News on the Enantioselective Intermolecular Heck Reaction
  308. Salt-Free Preparation of Trimethylsilyl Ethers by B(C6F5)3-Catalyzed Transfer Silylation by Using a Me3SiH Surrogate
  309. Metal-Catalyzed Cross-Coupling Reactions and More
  310. 7.21 Addition Reactions with Formation of CarbonHalogen Bonds
  311. Ferrocene-Stabilized Silicon Cations as Catalysts for Diels–Alder Reactions: Attempted Experimental Quantification of Lewis Acidity and ReactIR Kinetic Analysis
  312. Silylium Ion Promoted Reduction of Imines with Hydrosilanes
  313. Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism
  314. The Family of Ferrocene‐Stabilized Silylium Ions: Synthesis,29Si NMR Characterization, Lewis Acidity, Substituent Scrambling, and Quantum‐Chemical Analyses
  315. Oxidative Palladium(II)-Catalyzed C-7 Alkenylation of Indolines
  316. 3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes
  317. 3-Silylierte Cyclohexa-1,4-diene als Vorstufen für gasförmige Hydrosilane: die B(C6F5)3-katalysierte Transferhydrosilylierung von Alkenen
  318. Katalytische 1,4-selektive Hydrosilylierung von Pyridinverbindungen und benzanellierten Verwandten
  319. Catalytic 1,4-Selective Hydrosilylation of Pyridines and Benzannulated Congeners
  320. Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane
  321. Main-Group Lewis Acids for C–F Bond Activation
  322. Oxidative Palladium(II)-Catalyzed Dehydrogenative CH/CH Cross-Coupling of 2,3-Substituted Indolines with Arenes at the C7 Position
  323. Regio- and Diastereoselective Copper(I)-Catalyzed Allylic Substitution of δ-Hydroxy Allylic Chlorides by a Silicon Nucleophile
  324. SiH Bond Activation: Bridging Lewis Acid Catalysis with Brookhart’s Iridium(III) Pincer Complex and B(C6F5)3
  325. Si-H-Bindungsaktivierung: Parallelen der Lewis-Säure-Katalyse mit Brookharts Iridium(III)-Pincerkomplex und B(C6F5)3
  326. Asymmetrische Synthese α-chiraler Allylsilane durch enantiokonvergente γ-selektive Kupfer(I)-katalysierte allylische Silylierung
  327. Asymmetric Synthesis of α-Chiral Allylic Silanes by Enantioconvergent γ-Selective Copper(I)-Catalyzed Allylic Silylation
  328. C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle
  329. The Renaissance of Silicon-Stereogenic Silanes: A Personal Account
  330. Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis
  331. Catalytic dehydrogenative Si–N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base
  332. Aerobic Palladium(II)-Catalyzed Dehydrogenation of Cyclohexene-1-carbonyl Indole Amides: An Indole-Directed Aromatization
  333. Reversible Heterolytic Si–H Bond Activation by an Intramolecular Frustrated Lewis Pair
  334. Illuminating the Mechanism of the Borane-Catalyzed Hydrosilylation of Imines with Both an Axially Chiral Borane and Silane
  335. 1,2,3,4-Tetrahydro-1-(1,1-dimethylethyl)-1-silanaphthalene
  336. 1,2,3,4-Tetrahydro-1-(1-methylethyl)-1-silanaphthalene
  337. Hemilabile BINAP(O) as a Chiral Ligand in Desymmetrizing Mizoroki-Heck Cyclizations
  338. Copper(I)-Catalyzed Regio- and Chemoselective Single and Double Addition of Nucleophilic Silicon to Propargylic Chlorides and Phosphates
  339. Base-Free Dehydrogenative Coupling of Enolizable Carbonyl Compounds with Silanes
  340. Two-Directional Desymmetrization by Double 1,4-Addition of Silicon and Boron Nucleophiles
  341. Organic Reactions. Volume 75 (Diamond Volume). Herausgegeben von Scott E. Denmark.
  342. Organic Reactions. Volume 75 (Diamond Volume). Edited by Scott E. Denmark.
  343. Catalytic enantioselective dehydrogenative Si–O coupling of oxime ether-functionalized alcohols
  344. Silylium Ion-Catalyzed Challenging Diels–Alder Reactions: The Danger of Hidden Proton Catalysis with Strong Lewis Acids
  345. Ein neuer Weg der C-H-Alkenylierung: Silanol als helfende Hand
  346. A New Direction in CH Alkenylation: Silanol as a Helping Hand
  347. Aerobic Palladium(II)-Catalyzed 5-endo-trig Cyclization: An Entry into the Diastereoselective C-2 Alkenylation of Indoles with Tri- and Tetrasubstituted Double Bonds
  348. Aerobe Palladium(II)-katalysierte 5-endo-trig-Cyclisierung als ein Einstieg in die diastereoselektive C-2-Alkenylierung von Indolen mit tri- und tetrasubstituierten Doppelbindungen
  349. Copper-Catalyzed 1,2-Addition of Nucleophilic Silicon to Aldehydes: Mechanistic Insight and Catalytic Systems
  350. BINAP versus BINAP(O) in Asymmetric Intermolecular Mizoroki-Heck Reactions: Substantial Effects on Selectivities
  351. Copper(I)-Catalyzed Regioselective Propargylic Substitution Involving Si–B Bond Activation
  352. A New Motif for Lewis Base Catalysis: Asymmetric Reduction of β-Enamino Esters
  353. A Unique Transition Metal-Stabilized Silicon Cation
  354. An Axially Chiral, Electron-Deficient Borane: Synthesis, Coordination Chemistry, Lewis Acidity, and Reactivity
  355. Activation of the Si−B Linkage: Copper-Catalyzed Addition of Nucleophilic Silicon to Imines
  356. Shortened Synthesis of a Silicon-Stereogenic Cyclic Silane
  357. Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism
  358. Organische Chemie 2010
  359. All-Carbon-Substituted Quaternary Carbon Atoms in Oxindoles by an Aerobic Palladium(II)-Catalyzed Ring Closure onto Tri- and Tetrasubstituted Double Bonds
  360. Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles
  361. Self-regeneration of a silylium ion catalyst in carbonyl reduction
  362. Stereochemical Surprises in the Lewis Acid-Mediated Allylation of Isatins
  363. Kupferkatalysierte Si-B-Bindungsaktivierung in der verzweigtselektiven allylischen Substitution linearer Allylchloride
  364. Copper-Catalyzed SiB Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides
  365. Base-Catalyzed Dehydrogenative Si-O Coupling of Dihydrosilanes: Silylene Protection of Diols
  366. Transition-Metal-Catalyzed C-P Cross-Coupling Reactions
  367. Der asymmetrische konjugierte Silyltransfer in iterativen katalytischen Sequenzen: Synthese des C7-C16-Fragments von (+)-Neopeltolid
  368. Asymmetric Conjugate Silyl Transfer in Iterative Catalytic Sequences: Synthesis of the C7-C16 Fragment of (+)-Neopeltolide
  369. Expeditious synthesis of TADDOL-derived phosphoramidite and phosphonite ligands
  370. Katalytische asymmetrische Si-O-Kupplung einfacher achiraler Silane und chiraler donorfunktionalisierter Alkohole
  371. Catalytic Asymmetric SiO Coupling of Simple Achiral Silanes and Chiral Donor-Functionalized Alcohols
  372. Organische Chemie 2009
  373. Enantioselektive konjugierte Borylierung
  374. Enantioselective Conjugate Borylation
  375. Silicon- and Tin-Based Cuprates: Now Catalytic in Copper!
  376. Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides
  377. Asymmetric Si–O coupling of alcohols
  378. Silylium ions in catalysis
  379. Enantioselective Fujiwara-Moritani Indole and Pyrrole Annulations Catalyzed by Chiral Palladium(II)-NicOx Complexes
  380. Ein gezähmtes Silyliumion für Diels-Alder-Reaktionen bei niedrigen Temperaturen
  381. Taming the Silylium Ion for Low-Temperature Diels-Alder Reactions
  382. B(C 6 F 5 ) 3 -Catalyzed Reduction of Ketones and Imines Using Silicon-Stereogenic Silanes: Stereoinduction by Single-Point Binding
  383. Conjugate phosphination of cyclic and acyclic acceptors using Rh(I)–phosphine or Rh(I)–carbene complexes. Probing the mechanism with chirality at the silicon atom or the phosphorus atom of the Si–P reagent
  384. Rhodium(I)-catalyzed enantioselective 1,4-addition of nucleophilic silicon
  385. Enantiospezifische Synthese und Allylierung ausschließlich Kohlenstoff-substituierter, α-chiraler Allylstannane
  386. Enantiospecific Synthesis and Allylation of All-Carbon-Substituted α-Chiral Allylic Stannanes
  387. Asymmetrische Ringschlussmetathese mit Pfiff
  388. Asymmetric Ring-Closing Metathesis with a Twist
  389. Palladium(II)-Catalyzed Conjugate Phosphination of Electron-Deficient Acceptors
  390. Potassiumtert-Butoxide-Catalyzed Dehydrogenative SiO Coupling: Reactivity Pattern and Mechanism of an Underappreciated Alcohol Protection
  391. Organische Chemie 2008
  392. The Mizoroki–Heck Reaction
  393. Facile preparation of CF3-substituted carbinols with an azine donor and subsequent kinetic resolution through stereoselective Si–O coupling
  394. Stereoselective Alcohol Silylation by Dehydrogenative Si-O Coupling: Scope, Limitations, and Mechanism of the Cu-H-Catalyzed Non-Enzymatic Kinetic Resolution with Silicon-Stereogenic Silanes
  395. A Catalytic Asymmetric Fujiwara-Moritani Cyclization
  396. Schlüssiger Nachweis eines SN2-Si-Mechanismus in der B(C6F5)3- katalysierten Hydrosilylierung von Carbonylverbindungen: Einsichten in die verwandte Hydrierung
  397. Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation
  398. Transition-Metal-Free Conjugate Stannyl Transfer to α,β-Unsaturated Carbonyl and Carboxyl Compounds in Basic Aqueous Media
  399. Katalytische asymmetrische C-Si-Bindungsknüpfung an acyclischen α,β-ungesättigten Akzeptoren durch RhI-katalysierten konjugierten Silyltransfer mithilfe einer Si-B-Bindung
  400. Catalytic Asymmetric CSi Bond Formation to Acyclic α,β-Unsaturated Acceptors by RhI-Catalyzed Conjugate Silyl Transfer Using a SiB Linkage
  401. Enantio- and Diastereotopos Differentiation in the Palladium(II)-Catalyzed Hydrosilylation of Bicyclo[2.2.1]alkene Scaffolds with Silicon-Stereogenic Silanes
  402. Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane
  403. Kinetic Resolution and Desymmetrization by Stereoselective Silylation of Alcohols
  404. Kinetische Racematspaltung und Desymmetrisierung durch stereoselektive Silylierung von Alkoholen
  405. Chirale Erkennung mit siliciumstereogenen Silanen: außergewöhnliche Selektivitätsfaktoren bei der kinetischen Racematspaltung von donorfunktionalisierten Alkoholen
  406. Chiral Recognition with Silicon-Stereogenic Silanes: Remarkable Selectivity Factors in the Kinetic Resolution of Donor-Functionalized Alcohols
  407. Oxygen Donor-Mediated Equilibration of Diastereomeric Alkene−Palladium(II) Intermediates in Enantioselective Desymmetrizing Heck Cyclizations
  408. Silicon-Stereogenic Silanes in Asymmetric Catalysis
  409. Polishing a Diamond in the Rough: “Cu—H” Catalysis with Silanes
  410. Asymmetric Synthesis - The Essentials
  411. Conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis: A comparative study
  412. Vom Schleifen eines “Rohdiamanten”: die “Cu-H”-Katalyse mit Silanen
  413. Polishing a Diamond in the Rough: “CuH” Catalysis with Silanes
  414. Rhodium(i)-catalysed conjugate phosphination of cyclic α,β-unsaturated ketones with silylphosphines as masked phosphinides
  415. Directed Mizoroki–Heck Reactions
  416. Synthesis by Hydration of Alkynes
  417. Synthesis by Direct Hydration
  418. Intermolecular Chirality Transfer from Silicon to Carbon:  Interrogation of the Two-Silicon Cycle for Pd-Catalyzed Hydrosilylation by Stereoisotopochemical Crossover
  419. Organische Chemie online… und gratis?
  420. Organic Chemistry Online … and for Free?
  421. An Enantioselective Access to an Anthracycline AB Synthon by a ­Desymmetrizing Heck Cyclization
  422. Rhodiumkatalysierter enantioselektiver konjugierter Silyltransfer: 1,4-Addition von Silylboronsäureestern an cyclische Enone und Lactone
  423. Rhodium-Catalyzed Enantioselective Conjugate Silyl Transfer: 1,4-Addition of Silyl Boronic Esters to Cyclic Enones and Lactones
  424. Preparation of a Privileged Silicon-Stereogenic Silane: Classicalversus Kinetic Resolution
  425. Copper-Free and Copper-Promoted Conjugate Addition Reactions of Bis(triorganosilyl) Zincs and Tris(triorganosilyl) Zincates
  426. Organische Chemie 2005
  427. Quaternary Stereocenters. Challenges and Solutions for Organic Synthesis. Herausgegeben von Jens Christoffers und Angelika Baro.
  428. Quaternary Stereocenters. Challenges and Solutions for Organic Synthesis. Edited by Jens Christoffers and Angelika Baro.
  429. Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl) zincs. Enantiospecific preparation of α-chiral silanes
  430. Silylzincation of carbon–carbon multiple bonds revisited
  431. Chirality Transfer from Silicon to Carbon
  432. Kinetische Racematspaltung von chiralen sekundären Alkoholen durch dehydrierende Kupplung mit zurückgewinnbaren, siliciumstereogenen Silanen
  433. Kinetic Resolution of Chiral Secondary Alcohols by Dehydrogenative Coupling with Recyclable Silicon-Stereogenic Silanes
  434. OMCOS 13
  435. Kaleidoskop der Katalyse: Heidelberger Forum für Molekulare Katalyse 2005
  436. Kaleidoscope of Catalysis: Heidelberg Forum of Molecular Catalysis 2005
  437. Schweizer Leckerli: Bürgenstock 2005
  438. Swiss Delight: Bürgenstock 2005
  439. Chemie-Nachwuchsgruppenleiter in Freiburg
  440. Strategien zur katalytischen asymmetrischen elektrophilen ?-Halogenierung von Carbonylverbindungen
  441. Strategies for Catalytic Asymmetric Electrophilic ? Halogenation of Carbonyl Compounds
  442. Practical Synthesis of Allylic Silanes from Allylic Esters and Carbamates by Stereoselective Copper-Catalyzed Allylic Substitution Reactions
  443. ?Echter? Chiralit�tstransfer von Silicium auf Kohlenstoff: asymmetrische Verst�rkung in einer reagenskontrollierten palladiumkatalysierten Hydrosilylierung
  444. ?True? Chirality Transfer from Silicon to Carbon: Asymmetric Amplification in a Reagent-Controlled Palladium-Catalyzed Hydrosilylation
  445. Neighbouring‐Group Effects in Heck Reactions
  446. Hypervalent Silicon as a Reactive Site in Selective Bond-Forming Processes
  447. Catalytic Desymmetrizing Intramolecular Heck Reaction: Evidence for an Unusual Hydroxy-Directed Migratory Insertion
  448. On the Mechanism of the Reductive Metallation of Asymmetrically Substituted Silyl Chlorides
  449. Katalytische desymmetrisierende intramolekulare Heck-Reaktion: Nachweis einer ungewöhnlichen hydroxydirigierten Alkeninsertion
  450. Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters
  451. 23. Regio-Symposium in Falkau/Schwarzwald
  452. Copper-Catalyzed Conjugate Addition of a Bis(triorganosilyl) Zinc and a Methyl(triorganosilyl) Magnesium
  453. Catalytic Asymmetric Synthesis of Quaternary Carbons Bearing Two Aryl Substituents. Enantioselective Synthesis of 3-Alkyl-3-Aryl Oxindoles by Catalytic Asymmetric Intramolecular Heck Reactions
  454. A Convergent Method for the Synthesis of Highly Enantiomerically Enriched Cyclic Silanes with Silicon-Centered Chirality
  455. Vereitelteβ-Hydrideliminierung: Abfangen der Alkylpalladiumzwischenstufe einer asymmetrischen intramolekularen Heck-Reaktion
  456. Thwartingβ-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction
  457. Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds
  458. Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds
  459. (−)-Sparteine-Mediated Asymmetric Intramolecular Carbolithiation of Alkenes: Synthesis of Enantiopure Cyclopentanes with Three Consecutive Stereogenic Centers
  460. (−)-Sparteine-Mediated Stereoselective Intramolecular Carbolithiation of 4-Substituted 5-Hexynyl Carbamates. Synthesis of Enantiopure 1,3-Difunctionalized Alkylidene Cyclopentanes
  461. Corrigendum
  462. (−)-Sparteine-mediated stereoselective intramolecular conjugate addition reactions of dienes and enynes
  463. (−)-Sparteine-mediated stereoselective intramolecular carbolithiation of alkynes
  464. Stereoselective Preparation and Reactions of Cycloalkylzinc Compounds
  465. Stereoselektive Herstellung und Reaktionen von Cycloalkylzinkverbindungen
  466. Formation of Carbocycles
  467. Palladium-Catalyzed Arylation Reactions of Alkenes (Mizoroki–Heck Reaction and Related Processes)
  468. Taming Super Lewis Acids for Catalysis: The Family of Ferrocene-Stabilized Silicon Cations
  469. Diverse Modes of Silane Activation for the Hydrosilylation of Carbonyl Compounds