All Stories

  1. Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes
  2. Transition-Metal-Like Catalysis with a Main-Group Element: Bismuth-Catalyzed C−F Coupling of Aryl Boronic Esters
  3. Übergangsmetallartige Katalyse mit einem Hauptgruppenelement: Bismutkatalysierte C‐F‐Kupplung von Arylboronsäureestern
  4. Formyltetrahydrofolate Decarbonylase Synthesizes the Active Site CO Ligand of O2-Tolerant [NiFe] Hydrogenase
  5. Stereospecific and Chemoselective Copper-Catalyzed Deaminative Silylation of Benzylic Ammonium Triflates
  6. Stereospezifische und chemoselektive kupferkatalysierte, deaminierende Silylierung von Benzylammoniumtriflaten
  7. General Synthesis and Optical Properties of N-Aryl-N′-Silyldiazenes
  8. Cationic silicon Lewis acids in catalysis
  9. Chiral Modification of the Tetrakis(pentafluorophenyl)borate Anion with Myrtanyl Groups
  10. Ionic Transfer Reactions with Cyclohexadiene-Based Surrogates
  11. Si-H Bond Activation with Bullock’s Cationic Tungsten(II) Catalyst: CO as Cooperating Ligand
  12. Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions
  13. Katalytische Difunktionalisierung von nichtaktivierten Alkenen mit reaktionsträgem Hexamethyldisilan durch Neubildung von Silyliumionen
  14. Copper‐Catalyzed Enantio‐ and Diastereoselective Addition of Silicon Nucleophiles to 3,3‐Disubstituted Cyclopropenes
  15. Lewis Säure‐katalysierte Transferhydromethallylierung für den Aufbau quartärer Kohlenstoffzentren
  16. Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers
  17. Copper-Catalyzed Regio- and Enantioselective Addition of Silicon Grignard Reagents to Alkenes Activated by Azaaryl Groups
  18. Kupferkatalysierte regio‐ und enantioselektive Addition von Silicium‐Grignard‐Reagenzien an durch Azaarylgruppen aktivierte Alkene
  19. Metal-Free Transfer Hydrobromination of C–C Triple Bonds
  20. Bioinspired Metal‐Free Formal Decarbonylation of α‐Branched Aliphatic Aldehydes at Ambient Temperature
  21. Tertiary α-Silyl Alcohols by Diastereoselective Coupling of 1,3-Dienes and Acylsilanes Initiated by Enantioselective Copper-Catalyzed Borylation
  22. Tertiäre α‐Silylalkohole mittels diastereoselektiver Kupplung von 1,3‐Dienen und Acylsilanen, eingeleitet durch enantioselektive kupferkatalysierte Borylierung
  23. Making the Silylation of Alcohols Chiral: Asymmetric Protection of Hydroxy Groups
  24. Regiodivergent and Stereospecific Aziridine Opening by Copper‐Catalyzed Addition of Silicon Grignard Reagents
  25. Mechanistic Dichotomy of Magnesium- and Zinc-Based Germanium Nucleophiles in the C(sp3 )−Ge Cross-Coupling with Alkyl Electrophiles
  26. Gegensätzliche Reaktionsweisen magnesium‐ und zinkbasierter Germaniumnukleophile in der C(sp 3 )‐Ge‐Kreuzkupplung mit Alkylelektrophilen
  27. Further Structural Modification of Sulfur-Stabilized Silicon Cations with Binaphthyl Backbones
  28. Enantioselective Construction of α-Chiral Silanes by Nickel-Catalyzed C(sp3 )−C(sp3 ) Cross-Coupling
  29. Enantioselektiver Aufbau von α‐chiralen Silanen durch nickelkatalysierte C(sp 3 )‐C(sp 3 )‐Kreuzkupplung
  30. Axially Chiral, Electrophilic Fluorophosphonium Cations: Synthesis, Lewis Acidity, and Reactivity in the Hydrosilylation of Ketones
  31. Bor-Lewis-Säure-katalysierte Transferhydrocyanierung α- und α,β-substituierter Styrole
  32. Transfer Hydrocyanation of α- and α,β-Substituted Styrenes Catalyzed by Boron Lewis Acids
  33. Kinetic Resolution of Tertiary Propargylic Alcohols by Enantioselective Cu−H-Catalyzed Si−O Coupling
  34. Kinetische Racematspaltung tertiärer Propargylalkohole durch enantioselektive Cu-H-katalysierte Si-O-Kupplung
  35. Ligand-controlled diastereodivergent, enantio- and regioselective copper-catalyzed hydroxyalkylboration of 1,3-dienes with ketones
  36. Using alcohols as simple H2-equivalents for copper-catalysed transfer semihydrogenations of alkynes
  37. Metal-Free Transfer Hydroiodination of C–C Multiple Bonds
  38. Copper-Catalyzed Cross-Coupling of Vinyliodonium Salts and Zinc-Based Silicon Nucleophiles
  39. Palladium-Catalyzed Three-Component Reaction of Dihydrosilanes and Vinyl Iodides in the Presence of Alcohols: Rapid Assembly of Silyl Ethers of Tertiary Silanes
  40. C(sp3)–Si Cross-Coupling
  41. Achieving Enantioselectivity in Difficult Cyclohexa-1,3-diene Diels–Alder Reactions with Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts
  42. Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution
  43. Einelektronenübertragungsreaktionen in frustrierten und klassischen Silyliumion/Phosphan-Lewis-Paaren
  44. Single-Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphane Lewis Pairs
  45. Regioselective Transfer Hydrodeuteration of Alkenes with a Hydrogen Deuteride Surrogate Using B(C6F5)3 Catalysis
  46. Electrophilic Phosphonium Cations as Lewis Acid Catalysts in Diels–Alder Reactions and Nazarov Cyclizations
  47. Bioinspired Catalytic Generation of Main-group Electrophiles by Cooperative Bond Activation
  48. Bench-Stable Stock Solutions of Silicon Grignard Reagents: Application to Iron- and Cobalt-Catalyzed Radical C(sp3 )-Si Cross-Coupling Reactions
  49. Stabile Stammlösungen von Silicium-Grignard-Reagenzien: Anwendung in eisen- und cobaltkatalysierten radikalischen C(sp3 )-Si-Kreuzkupplungsreaktionen
  50. Copper-Catalyzed Double C(sp3)–Si Coupling of Geminal Dibromides: Ionic-to-Radical Switch in the Reaction Mechanism
  51. Enantioselective Nazarov Cyclizations Catalyzed by an Axial Chiral C6 F5 -Substituted Boron Lewis Acid
  52. Enantioselektive Nazarov-Cyclisierungen, die von einer axial-chiralen, C6 F5 -substituierten Bor-Lewis-Säure katalysiert werden
  53. Z-Selective Hydrostannylation of Terminal and Internal C–C Triple Bonds Initiated by the Trityl Cation
  54. Copper-Catalyzed Silylation of C(sp3)–H Bonds Adjacent to Amide Nitrogen Atoms
  55. Innenrücktitelbild: Kinetische Racematspaltung α-hydroxysubstituierter Oximether durch enantioselektive Cu-H-katalysierte Si-O-Kupplung (Angew. Chem. 33/2018)
  56. Inside Back Cover: Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu−H-Catalyzed Si−O Coupling (Angew. Chem. Int. Ed. 33/2018)
  57. Cleavage of Unactivated Si−C(sp3 ) Bonds with Reed's Carborane Acids: Formation of Known and Unknown Silylium Ions
  58. Spaltung nicht aktivierter Si-C(sp3 )-Bindungen mit Reedschen Carboransäuren: Bildung bekannter und unbekannter Silyliumionen
  59. Custom Hydrosilane Synthesis Based on Monosilane
  60. Electrophilic Formylation of Arenes by Silylium Ion Mediated Activation of Carbon Monoxide
  61. Elektrophile Formylierung von Aromaten durch silyliumionvermittelte Aktivierung von Kohlenmonoxid
  62. Direct Acetophenone-Acetophenone Crossed Aldol Reaction and Aldol Self-Reaction Promoted by a Tethered Ru-S Complex
  63. Refinement of the Catalyst Backbone of Chiral Intramolecular Silicon-Sulfur Lewis Pairs: Improved Enantioselectivity in the Diels-Alder Reaction of Cyclohexa-1,3-diene and Chalcone Derivatives
  64. Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu−H-Catalyzed Si−O Coupling
  65. Kinetische Racematspaltung α-hydroxysubstituierter Oximether durch enantioselektive Cu-H-katalysierte Si-O-Kupplung
  66. A Neutral RuII Hydride Complex for the Regio- and Chemoselective Reduction of N -Silylpyridinium Ions
  67. The electrophilic aromatic substitution approach to C–H silylation and C–H borylation
  68. Catalytic Dehydrogenative Stannylation of C(sp)–H Bonds Involving Cooperative Sn–H Bond Activation of Hydrostannanes
  69. Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion
  70. Copper-Catalyzed Substitution of α-Triflyloxy Nitriles and Esters with Silicon Nucleophiles under Inversion of the Configuration
  71. Two-Silicon Cycle for Carbonyl Hydrosilylation with Nikonov’s Cationic Ruthenium(II) Catalyst
  72. Cooperative Al–H Bond Activation in DIBAL-H: Catalytic Generation of an Alumenium-Ion-Like Lewis Acid for Hydrodefluorinative Friedel–Crafts Alkylation
  73. Cluster Preface: Silicon in Synthesis and Catalysis
  74. An Expedient Procedure for the Synthesis of Benzo[4,5]silolo[2,3-b]thiophenes and Related Systems
  75. Copper-Catalyzed Decarboxylative Radical Silylation of Redox-Active Aliphatic Carboxylic Acid Derivatives
  76. Kupferkatalysierte decarboxylierende radikalische Silylierung von redoxaktiven aliphatischen Carbonsäurederivaten
  77. B(C6F5)3-Catalyzed Reduction of Sulfoxides and Sulfones to Sulfides with Hydrosilanes
  78. BArF3-Catalyzed Imine Hydroboration with Pinacolborane Not Requiring the Assistance of an Additional Lewis Base
  79. Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes
  80. Exhaustive Chemoselective Reduction of Nitriles by Catalytic Hydrosilylation Involving Cooperative Si–H Bond Activation
  81. Potassium tert-Butoxide-Catalyzed Dehydrogenative C–H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study
  82. Photocatalysis Enabling Acceptorless Dehydrogenation of Benzofused Saturated Rings at Room Temperature
  83. Photokatalyse ermöglicht die akzeptorfreie Dehydrierung von benzanellierten gesättigten Ringen bei Raumtemperatur
  84. Synthesis of a Chiral Borate Counteranion, Its Trityl Salt, and Application Thereof in Lewis-Acid Catalysis
  85. Cooperative Catalysis at Metal–Sulfur Bonds
  86. Access to Fully Alkylated Germanes by B(C6F5)3-Catalyzed Transfer Hydrogermylation of Alkenes
  87. A Tethered Ru-S Complex with an Axial Chiral Thiolate Ligand for Cooperative Si-H Bond Activation: Application to Enantioselective Imine Reduction
  88. Katalytische Friedel-Crafts-C-H-Borylierung elektronenreicher Arene: starke Reaktionsbeschleunigung durch Versetzen mit Alkenen
  89. Catalytic Friedel-Crafts C−H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes
  90. Hidden Enantioselective Hydrogenation of N-Silyl Enamines and Silyl Enol Ethers in Net C═N and C═O Hydrosilylations Catalyzed by Ru–S Complexes with One Monodentate Chiral Phosphine Ligand
  91. B(C6F5)3-Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl Tosylates with Hydrosilanes
  92. B(C6F5)3-katalysierte chemoselektive Defunktionalisierung von etherhaltigen primären Alkyltosylaten mit Hydrosilanen
  93. Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application
  94. Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes
  95. Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes
  96. Catalytic Access to Indole-Fused Benzosiloles by 2-Fold Electrophilic C–H Silylation with Dihydrosilanes
  97. Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel-Crafts C−H Silylation
  98. Elektrophile aromatische Substitution mit Siliciumelektrophilen: die katalytische Friedel-Crafts-C-H-Silylierung
  99. Teaching nature the unnatural
  100. Stereodivergent Synthesis of β-Heteroatom-Substituted Vinyl­silanes by Sequential Silylzincation–Copper(I)-Mediated Electrophilic­ Substitution
  101. 3-tert -Butyl-Substituted Cyclohexa-1,4-dienes as Isobutane Equivalents in the B(C6 F5 )3 -Catalyzed Transfer Hydro-tert -Butylation of Alkenes
  102. Copper-Catalyzed Cross-Coupling of Silicon Pronucleophiles with Unactivated Alkyl Electrophiles Coupled with Radical Cyclization
  103. Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF 3 Does What B(C6 F5 )3 Cannot Do!
  104. Enantioselective Diels–Alder Reactions of Cyclohexa-1,3-diene and Chalcones Catalyzed by Intramolecular Silicon–Sulfur Lewis Pairs as Chiral Lewis Acids
  105. Ausbalancieren von C=C-Funktionalisierung und C=O-Reduktion in der Cu-H-Katalyse
  106. Balancing C=C Functionalization and C=O Reduction in Cu−H Catalysis
  107. Merging Platinum-Catalyzed Alkene Hydrosilylation with SiH4 Surrogates: Salt-Free Preparation of Trihydrosilanes
  108. Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel–Crafts C–H Silylation
  109. B(C6F5)3-Catalyzed Reduction of Aromatic and Aliphatic Nitro Groups with Hydrosilanes
  110. Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru−S Complexes: From Cooperative Dihydrogen Activation to Hydride Abstraction/Proton Release from Dihydrogen Surrogates
  111. The Asymmetric Piers Hydrosilylation
  112. Brønsted Acid-Catalyzed Transfer Hydrogenation of Imines and Alkenes Using Cyclohexa-1,4-dienes as Dihydrogen Surrogates
  113. Stereodivergent Silylzincation of α-Heteroatom-Substituted Alkynes
  114. Metal-Free Phosphine Oxide Reductions Catalyzed by B(C6F5)3 and Electrophilic Fluorophosphonium Cations
  115. An Air-Stable Dimeric Ru–S Complex with an NHC as Ancillary Ligand for Cooperative Si–H Bond Activation
  116. Copper-Catalyzed Si–B Bond Activation in the Nucleophilic Substitution of Primary Aliphatic Triflates
  117. Planar Chiral, Ferrocene-Stabilized Silicon Cations
  118. Durch Nichtedelmetallsalze ausgelöste Friedel-Crafts-artige intermolekulare C-H-Silylierung von elektronenreichen Arenen
  119. Friedel-Crafts-Type Intermolecular C−H Silylation of Electron-Rich Arenes Initiated by Base-Metal Salts
  120. Transfer Hydrosilylation
  121. Catalytic Electrophilic CH Silylation of Pyridines Enabled by Temporary Dearomatization
  122. Extending the Scope of the B(C6F5)3-Catalyzed CN Bond Reduction: Hydrogenation of Oxime Ethers and Hydrazones
  123. Phosphinic Amide as Directing Group Enabling Palladium(II)-CatalyzedorthoC−H Alkenylation of Anilines without and with Alkylation at the Nitrogen Atom
  124. B(C6F5)3-Catalyzed Transfer of Dihydrogen from One Unsaturated Hydrocarbon to Another
  125. Formal SiH4 chemistry using stable and easy-to-handle surrogates
  126. The Cyclohexadienyl-Leaving-Group Approach toward Donor-Stabilized Silylium Ions
  127. A Catalytic SEAr Approach to Dibenzosiloles Functionalized at Both Benzene Cores
  128. Intramolecularly Sulfur-Stabilized Silicon Cations with Chiral Binaphthyl Backbones: Synthesis of Three Different Motifs and Their Application in Enantioselective Diels–Alder Reactions
  129. Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors
  130. Platinum(0)-Catalyzed Indolyne Insertion into Bis(pinacolato)diboron Followed by Site-Selective Suzuki–Miyaura Cross-Coupling
  131. Synthesis of 2,6-Dihalogenated Purine Nucleosides by Thermostable Nucleoside Phosphorylases
  132. A Constellation of Deuterium-Labeled Silanes as a Simple Mechanistic Probe not Requiring Absolute Configuration Determination
  133. Temperature-Dependent Direct Enantioconvergent Silylation of a Racemic Cyclic Allylic Phosphate by Copper(I)-Catalyzed Allylic Substitution
  134. Faszinierende Chemie des Wasserstoffatomtransfers auf Alkene inspiriert durch Probleme in Totalsynthesen
  135. Fascinating Hydrogen Atom Transfer Chemistry of Alkenes Inspired by Problems in Total Synthesis
  136. Temperature-Dependent Chemoselective Hydrosilylation of Carbon Dioxide to Formaldehyde or Methanol Oxidation State
  137. Direct and Transfer Hydrosilylation Reactions Catalyzed by Fully or Partially Fluorinated Triarylboranes: A Systematic Study
  138. A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes
  139. Mechanism of the cooperative Si–H bond activation at Ru–S bonds
  140. Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex
  141. Asymmetric Addition of Boron and Silicon Nucleophiles
  142. B(C6F5)3-Catalyzed Transfer Hydrogenation of Imines and Related Heteroarenes Using Cyclohexa-1,4-dienes as a Dihydrogen Source
  143. B(C6F5)3-katalysierte Transferhydrierung von Iminen und verwandten Heteroaromaten mit Cyclohexa-1,4-dienen als Wasserstoffquelle
  144. Exceptionally Mild Palladium(II)-Catalyzed Dehydrogenative C–H/C–H Arylation of Indolines at the C-7 Position under Air
  145. Chemoselective Tin–Boron Exchange Aided by the Use of Dummy Ligands at the Tin Atom
  146. B(C6F5)3-Catalyzed Hydrogenation of Oxime Ethers without Cleavage of the NO Bond
  147. B(C6F5)3-katalysierte Hydrierung von Oximethern ohne Spaltung der N-O-Bindung
  148. Trans-Selective Radical Silylzincation of Ynamides
  149. Trans-Selective Radical Silylzincation of Ynamides
  150. McQuade’s Six-Membered NHC–Copper(I) Complexes for Catalytic Asymmetric­ Silyl Transfer
  151. Copper(I)-Catalyzed Regioselective Addition of Nucleophilic Silicon Across Terminal and Internal Carbon-Carbon Triple Bonds
  152. New Frontiers and Challenges in Silicon Chemistry:ISOS XVII in Berlin
  153. Intramolecularly Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts
  154. En Route to Stable All-Carbon-Substituted Silylenes: Synthesis and Reactivity of a Bis(α-spirocyclopropyl)silylene
  155. Martin Oestreich
  156. Martin Oestreich
  157. Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative SiN Coupling
  158. Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex
  159. Enantioselektive Addition von Siliciumnukleophilen an Aldimine mit einem präformierten NHC-Kupfer(I)-Komplex als Katalysator
  160. Enantioselective Addition of Silicon Nucleophiles to Aldimines Using a Preformed NHC-Copper(I) Complex as the Catalyst
  161. Diastereotopic Group Selection in Hydroxy‐Directed Intramolecular CH Alkenylation of Indole under Oxidative Palladium(II) Catalysis
  162. Tris(5,6,7,8-tetrafluoronaphthalen-2-yl)borane, a Partially Fluorinated Boron Lewis Acid with Fluorination Distal to the Boron Atom
  163. Brandaktuelles von der enantioselektiven intermolekularen Heck-Reaktion
  164. Breaking News on the Enantioselective Intermolecular Heck Reaction
  165. Salt-Free Preparation of Trimethylsilyl Ethers by B(C6F5)3-Catalyzed Transfer Silylation by Using a Me3SiH Surrogate
  166. Metal-Catalyzed Cross-Coupling Reactions and More
  167. 7.21 Addition Reactions with Formation of CarbonHalogen Bonds
  168. Ferrocene-Stabilized Silicon Cations as Catalysts for Diels–Alder Reactions: Attempted Experimental Quantification of Lewis Acidity and ReactIR Kinetic Analysis
  169. Silylium Ion Promoted Reduction of Imines with Hydrosilanes
  170. Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism
  171. The Family of Ferrocene‐Stabilized Silylium Ions: Synthesis,29Si NMR Characterization, Lewis Acidity, Substituent Scrambling, and Quantum‐Chemical Analyses
  172. Oxidative Palladium(II)-Catalyzed C-7 Alkenylation of Indolines
  173. 3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes
  174. 3-Silylierte Cyclohexa-1,4-diene als Vorstufen für gasförmige Hydrosilane: die B(C6F5)3-katalysierte Transferhydrosilylierung von Alkenen
  175. Katalytische 1,4-selektive Hydrosilylierung von Pyridinverbindungen und benzanellierten Verwandten
  176. Catalytic 1,4-Selective Hydrosilylation of Pyridines and Benzannulated Congeners
  177. Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane
  178. Main-Group Lewis Acids for C–F Bond Activation
  179. Oxidative Palladium(II)-Catalyzed Dehydrogenative CH/CH Cross-Coupling of 2,3-Substituted Indolines with Arenes at the C7 Position
  180. Regio- and Diastereoselective Copper(I)-Catalyzed Allylic Substitution of δ-Hydroxy Allylic Chlorides by a Silicon Nucleophile
  181. SiH Bond Activation: Bridging Lewis Acid Catalysis with Brookhart’s Iridium(III) Pincer Complex and B(C6F5)3
  182. Si-H-Bindungsaktivierung: Parallelen der Lewis-Säure-Katalyse mit Brookharts Iridium(III)-Pincerkomplex und B(C6F5)3
  183. Asymmetrische Synthese α-chiraler Allylsilane durch enantiokonvergente γ-selektive Kupfer(I)-katalysierte allylische Silylierung
  184. Asymmetric Synthesis of α-Chiral Allylic Silanes by Enantioconvergent γ-Selective Copper(I)-Catalyzed Allylic Silylation
  185. C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle
  186. The Renaissance of Silicon-Stereogenic Silanes: A Personal Account
  187. Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis
  188. Catalytic dehydrogenative Si–N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base
  189. Aerobic Palladium(II)-Catalyzed Dehydrogenation of Cyclohexene-1-carbonyl Indole Amides: An Indole-Directed Aromatization
  190. Reversible Heterolytic Si–H Bond Activation by an Intramolecular Frustrated Lewis Pair
  191. Illuminating the Mechanism of the Borane-Catalyzed Hydrosilylation of Imines with Both an Axially Chiral Borane and Silane
  192. 1,2,3,4-Tetrahydro-1-(1,1-dimethylethyl)-1-silanaphthalene
  193. 1,2,3,4-Tetrahydro-1-(1-methylethyl)-1-silanaphthalene
  194. Hemilabile BINAP(O) as a Chiral Ligand in Desymmetrizing Mizoroki-Heck Cyclizations
  195. Copper(I)-Catalyzed Regio- and Chemoselective Single and Double Addition of Nucleophilic Silicon to Propargylic Chlorides and Phosphates
  196. Base-Free Dehydrogenative Coupling of Enolizable Carbonyl Compounds with Silanes
  197. Two-Directional Desymmetrization by Double 1,4-Addition of Silicon and Boron Nucleophiles
  198. Organic Reactions. Volume 75 (Diamond Volume). Herausgegeben von Scott E. Denmark.
  199. Organic Reactions. Volume 75 (Diamond Volume). Edited by Scott E. Denmark.
  200. Catalytic enantioselective dehydrogenative Si–O coupling of oxime ether-functionalized alcohols
  201. Silylium Ion-Catalyzed Challenging Diels–Alder Reactions: The Danger of Hidden Proton Catalysis with Strong Lewis Acids
  202. Ein neuer Weg der C-H-Alkenylierung: Silanol als helfende Hand
  203. A New Direction in CH Alkenylation: Silanol as a Helping Hand
  204. Aerobic Palladium(II)-Catalyzed 5-endo-trig Cyclization: An Entry into the Diastereoselective C-2 Alkenylation of Indoles with Tri- and Tetrasubstituted Double Bonds
  205. Aerobe Palladium(II)-katalysierte 5-endo-trig-Cyclisierung als ein Einstieg in die diastereoselektive C-2-Alkenylierung von Indolen mit tri- und tetrasubstituierten Doppelbindungen
  206. Copper-Catalyzed 1,2-Addition of Nucleophilic Silicon to Aldehydes: Mechanistic Insight and Catalytic Systems
  207. BINAP versus BINAP(O) in Asymmetric Intermolecular Mizoroki-Heck Reactions: Substantial Effects on Selectivities
  208. Copper(I)-Catalyzed Regioselective Propargylic Substitution Involving Si–B Bond Activation
  209. A New Motif for Lewis Base Catalysis: Asymmetric Reduction of β-Enamino Esters
  210. A Unique Transition Metal-Stabilized Silicon Cation
  211. An Axially Chiral, Electron-Deficient Borane: Synthesis, Coordination Chemistry, Lewis Acidity, and Reactivity
  212. Activation of the Si−B Linkage: Copper-Catalyzed Addition of Nucleophilic Silicon to Imines
  213. Shortened Synthesis of a Silicon-Stereogenic Cyclic Silane
  214. Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism
  215. Organische Chemie 2010
  216. All-Carbon-Substituted Quaternary Carbon Atoms in Oxindoles by an Aerobic Palladium(II)-Catalyzed Ring Closure onto Tri- and Tetrasubstituted Double Bonds
  217. Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles
  218. Self-regeneration of a silylium ion catalyst in carbonyl reduction
  219. Stereochemical Surprises in the Lewis Acid-Mediated Allylation of Isatins
  220. Kupferkatalysierte Si-B-Bindungsaktivierung in der verzweigtselektiven allylischen Substitution linearer Allylchloride
  221. Copper-Catalyzed SiB Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides
  222. Base-Catalyzed Dehydrogenative Si-O Coupling of Dihydrosilanes: Silylene Protection of Diols
  223. Transition-Metal-Catalyzed C-P Cross-Coupling Reactions
  224. Der asymmetrische konjugierte Silyltransfer in iterativen katalytischen Sequenzen: Synthese des C7-C16-Fragments von (+)-Neopeltolid
  225. Asymmetric Conjugate Silyl Transfer in Iterative Catalytic Sequences: Synthesis of the C7-C16 Fragment of (+)-Neopeltolide
  226. Expeditious synthesis of TADDOL-derived phosphoramidite and phosphonite ligands
  227. Katalytische asymmetrische Si-O-Kupplung einfacher achiraler Silane und chiraler donorfunktionalisierter Alkohole
  228. Catalytic Asymmetric SiO Coupling of Simple Achiral Silanes and Chiral Donor-Functionalized Alcohols
  229. Organische Chemie 2009
  230. Enantioselektive konjugierte Borylierung
  231. Enantioselective Conjugate Borylation
  232. Silicon- and Tin-Based Cuprates: Now Catalytic in Copper!
  233. Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides
  234. Asymmetric Si–O coupling of alcohols
  235. Silylium ions in catalysis
  236. Enantioselective Fujiwara-Moritani Indole and Pyrrole Annulations Catalyzed by Chiral Palladium(II)-NicOx Complexes
  237. Ein gezähmtes Silyliumion für Diels-Alder-Reaktionen bei niedrigen Temperaturen
  238. Taming the Silylium Ion for Low-Temperature Diels-Alder Reactions
  239. B(C 6 F 5 ) 3 -Catalyzed Reduction of Ketones and Imines Using Silicon-Stereogenic Silanes: Stereoinduction by Single-Point Binding
  240. Conjugate phosphination of cyclic and acyclic acceptors using Rh(I)–phosphine or Rh(I)–carbene complexes. Probing the mechanism with chirality at the silicon atom or the phosphorus atom of the Si–P reagent
  241. Rhodium(I)-catalyzed enantioselective 1,4-addition of nucleophilic silicon
  242. Enantiospezifische Synthese und Allylierung ausschließlich Kohlenstoff-substituierter, α-chiraler Allylstannane
  243. Enantiospecific Synthesis and Allylation of All-Carbon-Substituted α-Chiral Allylic Stannanes
  244. Asymmetrische Ringschlussmetathese mit Pfiff
  245. Asymmetric Ring-Closing Metathesis with a Twist
  246. Palladium(II)-Catalyzed Conjugate Phosphination of Electron-Deficient Acceptors
  247. Potassiumtert-Butoxide-Catalyzed Dehydrogenative SiO Coupling: Reactivity Pattern and Mechanism of an Underappreciated Alcohol Protection
  248. Organische Chemie 2008
  249. The Mizoroki–Heck Reaction
  250. Facile preparation of CF3-substituted carbinols with an azine donor and subsequent kinetic resolution through stereoselective Si–O coupling
  251. Stereoselective Alcohol Silylation by Dehydrogenative Si-O Coupling: Scope, Limitations, and Mechanism of the Cu-H-Catalyzed Non-Enzymatic Kinetic Resolution with Silicon-Stereogenic Silanes
  252. A Catalytic Asymmetric Fujiwara-Moritani Cyclization
  253. Schlüssiger Nachweis eines SN2-Si-Mechanismus in der B(C6F5)3- katalysierten Hydrosilylierung von Carbonylverbindungen: Einsichten in die verwandte Hydrierung
  254. Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation
  255. Transition-Metal-Free Conjugate Stannyl Transfer to α,β-Unsaturated Carbonyl and Carboxyl Compounds in Basic Aqueous Media
  256. Katalytische asymmetrische C-Si-Bindungsknüpfung an acyclischen α,β-ungesättigten Akzeptoren durch RhI-katalysierten konjugierten Silyltransfer mithilfe einer Si-B-Bindung
  257. Catalytic Asymmetric CSi Bond Formation to Acyclic α,β-Unsaturated Acceptors by RhI-Catalyzed Conjugate Silyl Transfer Using a SiB Linkage
  258. Enantio- and Diastereotopos Differentiation in the Palladium(II)-Catalyzed Hydrosilylation of Bicyclo[2.2.1]alkene Scaffolds with Silicon-Stereogenic Silanes
  259. Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane
  260. Kinetic Resolution and Desymmetrization by Stereoselective Silylation of Alcohols
  261. Kinetische Racematspaltung und Desymmetrisierung durch stereoselektive Silylierung von Alkoholen
  262. Chirale Erkennung mit siliciumstereogenen Silanen: außergewöhnliche Selektivitätsfaktoren bei der kinetischen Racematspaltung von donorfunktionalisierten Alkoholen
  263. Chiral Recognition with Silicon-Stereogenic Silanes: Remarkable Selectivity Factors in the Kinetic Resolution of Donor-Functionalized Alcohols
  264. Oxygen Donor-Mediated Equilibration of Diastereomeric Alkene−Palladium(II) Intermediates in Enantioselective Desymmetrizing Heck Cyclizations
  265. Silicon-Stereogenic Silanes in Asymmetric Catalysis
  266. Polishing a Diamond in the Rough: “Cu—H” Catalysis with Silanes
  267. Asymmetric Synthesis - The Essentials
  268. Conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis: A comparative study
  269. Vom Schleifen eines “Rohdiamanten”: die “Cu-H”-Katalyse mit Silanen
  270. Polishing a Diamond in the Rough: “CuH” Catalysis with Silanes
  271. Rhodium(i)-catalysed conjugate phosphination of cyclic α,β-unsaturated ketones with silylphosphines as masked phosphinides
  272. Directed Mizoroki–Heck Reactions
  273. Synthesis by Hydration of Alkynes
  274. Synthesis by Direct Hydration
  275. Intermolecular Chirality Transfer from Silicon to Carbon:  Interrogation of the Two-Silicon Cycle for Pd-Catalyzed Hydrosilylation by Stereoisotopochemical Crossover
  276. Organische Chemie online… und gratis?
  277. Organic Chemistry Online … and for Free?
  278. An Enantioselective Access to an Anthracycline AB Synthon by a ­Desymmetrizing Heck Cyclization
  279. Rhodiumkatalysierter enantioselektiver konjugierter Silyltransfer: 1,4-Addition von Silylboronsäureestern an cyclische Enone und Lactone
  280. Rhodium-Catalyzed Enantioselective Conjugate Silyl Transfer: 1,4-Addition of Silyl Boronic Esters to Cyclic Enones and Lactones
  281. Preparation of a Privileged Silicon-Stereogenic Silane: Classicalversus Kinetic Resolution
  282. Copper-Free and Copper-Promoted Conjugate Addition Reactions of Bis(triorganosilyl) Zincs and Tris(triorganosilyl) Zincates
  283. Organische Chemie 2005
  284. Quaternary Stereocenters. Challenges and Solutions for Organic Synthesis. Herausgegeben von Jens Christoffers und Angelika Baro.
  285. Quaternary Stereocenters. Challenges and Solutions for Organic Synthesis. Edited by Jens Christoffers and Angelika Baro.
  286. Mechanistic insight into copper-catalysed allylic substitutions with bis(triorganosilyl) zincs. Enantiospecific preparation of α-chiral silanes
  287. Silylzincation of carbon–carbon multiple bonds revisited
  288. Chirality Transfer from Silicon to Carbon
  289. Kinetische Racematspaltung von chiralen sekundären Alkoholen durch dehydrierende Kupplung mit zurückgewinnbaren, siliciumstereogenen Silanen
  290. Kinetic Resolution of Chiral Secondary Alcohols by Dehydrogenative Coupling with Recyclable Silicon-Stereogenic Silanes
  291. OMCOS 13
  292. Kaleidoskop der Katalyse: Heidelberger Forum für Molekulare Katalyse 2005
  293. Kaleidoscope of Catalysis: Heidelberg Forum of Molecular Catalysis 2005
  294. Schweizer Leckerli: Bürgenstock 2005
  295. Swiss Delight: Bürgenstock 2005
  296. Chemie-Nachwuchsgruppenleiter in Freiburg
  297. Strategien zur katalytischen asymmetrischen elektrophilen ?-Halogenierung von Carbonylverbindungen
  298. Strategies for Catalytic Asymmetric Electrophilic ? Halogenation of Carbonyl Compounds
  299. Practical Synthesis of Allylic Silanes from Allylic Esters and Carbamates by Stereoselective Copper-Catalyzed Allylic Substitution Reactions
  300. ?Echter? Chiralit�tstransfer von Silicium auf Kohlenstoff: asymmetrische Verst�rkung in einer reagenskontrollierten palladiumkatalysierten Hydrosilylierung
  301. ?True? Chirality Transfer from Silicon to Carbon: Asymmetric Amplification in a Reagent-Controlled Palladium-Catalyzed Hydrosilylation
  302. Neighbouring‐Group Effects in Heck Reactions
  303. Hypervalent Silicon as a Reactive Site in Selective Bond-Forming Processes
  304. Catalytic Desymmetrizing Intramolecular Heck Reaction: Evidence for an Unusual Hydroxy-Directed Migratory Insertion
  305. On the Mechanism of the Reductive Metallation of Asymmetrically Substituted Silyl Chlorides
  306. Katalytische desymmetrisierende intramolekulare Heck-Reaktion: Nachweis einer ungewöhnlichen hydroxydirigierten Alkeninsertion
  307. Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters
  308. 23. Regio-Symposium in Falkau/Schwarzwald
  309. Copper-Catalyzed Conjugate Addition of a Bis(triorganosilyl) Zinc and a Methyl(triorganosilyl) Magnesium
  310. Catalytic Asymmetric Synthesis of Quaternary Carbons Bearing Two Aryl Substituents. Enantioselective Synthesis of 3-Alkyl-3-Aryl Oxindoles by Catalytic Asymmetric Intramolecular Heck Reactions
  311. A Convergent Method for the Synthesis of Highly Enantiomerically Enriched Cyclic Silanes with Silicon-Centered Chirality
  312. Vereitelteβ-Hydrideliminierung: Abfangen der Alkylpalladiumzwischenstufe einer asymmetrischen intramolekularen Heck-Reaktion
  313. Thwartingβ-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction
  314. Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds
  315. Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds
  316. (−)-Sparteine-Mediated Asymmetric Intramolecular Carbolithiation of Alkenes: Synthesis of Enantiopure Cyclopentanes with Three Consecutive Stereogenic Centers
  317. (−)-Sparteine-Mediated Stereoselective Intramolecular Carbolithiation of 4-Substituted 5-Hexynyl Carbamates. Synthesis of Enantiopure 1,3-Difunctionalized Alkylidene Cyclopentanes
  318. Corrigendum
  319. (−)-Sparteine-mediated stereoselective intramolecular conjugate addition reactions of dienes and enynes
  320. (−)-Sparteine-mediated stereoselective intramolecular carbolithiation of alkynes
  321. Stereoselective Preparation and Reactions of Cycloalkylzinc Compounds
  322. Stereoselektive Herstellung und Reaktionen von Cycloalkylzinkverbindungen
  323. Formation of Carbocycles
  324. Palladium-Catalyzed Arylation Reactions of Alkenes (Mizoroki–Heck Reaction and Related Processes)
  325. Taming Super Lewis Acids for Catalysis: The Family of Ferrocene-Stabilized Silicon Cations
  326. Diverse Modes of Silane Activation for the Hydrosilylation of Carbonyl Compounds