All Stories

  1. Two Roads to Arylstannanes: Arynes and Stannylpotassiums
  2. A Catalyst for Sodium Borohydride Dehydrogenation Based on a Mixed-Valent Iron Hydroxide Platform
  3. Stannylation of alkyl chlorides with stannylpotassium
  4. Modulating Lewis acidity with boronamides and boronates: effect on behavior in borylation and cross-coupling
  5. Weak Base-Promoted Direct Cross-Coupling of Naphthalene-1,8-diaminato-substituted Arylboron Compounds
  6. Modulation of Lewis Acidity and Steric Parameters in Cyclic Boronates: Copper-Catalyzed Internal-Selective Borylation of Challenging Terminal Alkynes
  7. Exclusive Papers of the Editorial Board Members and Topical Advisory Panel Members of Catalysts in Section “Catalysis in Organic and Polymer Chemistry”
  8. Copper-catalyzed silylation of aryl and alkenyl triflates with silylboronic esters avoiding base-mediated borylation
  9. Surefire generation of stannylpotassium: highly reactive stannyl anions and applications
  10. Ethynyl‐B(dan) in [3+2] Cycloaddition and Larock Indole Synthesis: Synthesis of Stable Boron‐Containing Heteroaromatic Compounds
  11. Complexation‐Triggered Fluctuation of π‐Conjugation on an Antiaromatic Dicyanoanthracene Dianion
  12. Selective S-Arylation of Sulfenamides with Arynes: Access to Sulfilimines
  13. Computed ammonia affinity for evaluating Lewis acidity of organoboronates and organoboronamides
  14. Efficient one-pot synthesis of dan-substituted organo- and silyl-boron compounds
  15. Direct Suzuki‐Miyaura Coupling of Naphthalene‐1,8‐diaminato (dan)‐Substituted Cyclopropylboron Compounds
  16. Main-Group Organometallics Containing Boron or Tin that Open New Frontiers in Organic Synthesis
  17. A stable silylborane with diminished boron Lewis acidity
  18. Origins of Internal Regioselectivity in Copper-Catalyzed Borylation of Terminal Alkynes
  19. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  20. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  21. Borylation and Stannylation Reactions with Tuning of Lewis Acidity
  22. A leap forward in sulfonium salt and sulfur ylide chemistry
  23. Synthetic Chemistry with Lewis Acidity‐Diminished B(aam) and B(dan) Groups: Borylation Reactions and Direct Cross‐Couplings
  24. Dithiazolylthienothiophene Bisimide-Based π-Conjugated Polymers: Improved Synthesis and Application to Organic Photovoltaics as P-Type Semiconductor
  25. Transition metal-free B(dan)-installing reaction (dan: naphthalene-1,8-diaminato): H–B(dan) as a B(dan) electrophile
  26. Direct Suzuki–Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons
  27. One-pot Sequential Fluorostannylation–Arylstannylation of Arynes
  28. Dithiazolylthienothiophene Bisimide: A Novel Electron-Deficient Building Unit for N-Type Semiconducting Polymers
  29. Ni/Co-Catalyzed Homo-Coupling of Alkyl Tosylates
  30. Copper‐Catalyzed B(dan)‐Installing Allylic Borylation of Allylic Phosphates
  31. An anthranilamide-substituted borane [H–B(aam)]: its stability and application to iridium-catalyzed stereoselective hydroboration of alkynes
  32. Anthranilamide (aam)-substituted arylboranes in direct carbon–carbon bond-forming reactions
  33. Copper-catalyzed arylstannylation of arynes in a sequence
  34. Copper-catalyzed Borylation of Bromoaryl Triflates with Diborons: Chemoselective Replacement of an Ar–Br Bond
  35. Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective B(aam) transfer
  36. B(MIDA)-Containing Diborons
  37. NHC-catalyzed cleavage of vicinal diketones and triketones followed by insertion of enones and ynones
  38. Naphthobispyrazine as an Electron-deficient Building Unit for π-Conjugated Polymers: Efficient Synthesis and Polymer Properties
  39. Aryne-Imine-Aryne Coupling Reaction via [4+2] Cycloaddition between Aza-o -Quinone Methides and Arynes
  40. Correction to “Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes”
  41. Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes
  42. Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides
  43. Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes
  44. Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan)
  45. Stannylation Reactions under Base Metal Catalysis: Some Recent Advances
  46. Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments
  47. Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si
  48. ChemInform Abstract: N-Heterocyclic Carbene-Catalyzed Double Acylation of Enones with Benzils.
  49. Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron
  50. Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide
  51. Copper-catalyzed α-selective hydrostannylation of alkynes for the synthesis of branched alkenylstannanes
  52. Copper-Catalyzed Metallation Reactions of Unsaturated Carbon-Carbon Bonds
  53. ChemInform Abstract: Three-Component Carboboration of Alkenes under Copper Catalysis.
  54. ChemInform Abstract: A Masked Diboron in Cu-Catalyzed Borylation Reaction: Highly Regioselective Formal Hydroboration of Alkynes for Synthesis of Branched Alkenylborons.
  55. ChemInform Abstract: Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes.
  56. Facile Access to vic-Borylstannylalkanes via Copper-Catalyzed Three-Component Borylstannylation of Alkenes
  57. Aryne-Based Multicomponent Reactions
  58. Direct Synthesis of Boron-Protected Alkenyl- and Alkylborons via Copper-Catalyzed Formal Hydroboration of Alkynes and Alkenes
  59. Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes
  60. Three-Component Carboboration of Alkenes under Copper Catalysis
  61. Convenient Synthesis of 2-Amino-4H-chromenes from Photochemically Generatedo-Quinone Methides and Malononitrile
  62. ChemInform Abstract: Copper-Catalyzed Distannylation of Alkynes.
  63. ChemInform Abstract: Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of Arynes.
  64. A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons
  65. N-Heterocyclic carbene-catalyzed double acylation of enones with benzils
  66. Dearomatization-Aromatization Sequence
  67. Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes
  68. Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes
  69. ChemInform Abstract: Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes.
  70. ChemInform Abstract: Copper-Catalyzed Three-Component Borylstannylation of Alkynes.
  71. Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes
  72. Copper-catalyzed distannylation of alkynes
  73. ChemInform Abstract: Hetero-Diels-Alder Reaction of Photochemically Generated α-Hydroxy-o-quinodimethanes with Trifluoromethyl Ketones.
  74. Copper-Catalyzed Three-Component Borylstannylation of Alkynes
  75. ChemInform Abstract: Aryne Insertion Reactions into Carbon-Carbon σ-Bonds
  76. ChemInform Abstract: Multicomponent Coupling Reaction of Arynes for Construction of Heterocyclic Skeletons
  77. Hetero-Diels–Alder reaction of photochemically generated α-hydroxy-o-quinodimethanes with trifluoromethyl ketones
  78. Aryne Insertion Reactions into Carbon-Carbon σ-Bonds
  79. ChemInform Abstract: Copper-Catalyzed Borylation Reactions of Alkynes and Arynes.
  80. ChemInform Abstract: An ortho-Quinodimethane Route to Lasofoxifene and U23469.
  81. ChemInform Abstract: Three-Component Coupling of Arynes and Organic Bromides.
  82. Multicomponent Coupling Reaction of Arynes for Construction of Heterocyclic Skeletons
  83. SYNTHESIS AND REACTIONS OF SILICON-BRIDGED DITHIENYLBIPHENYLS. FINE TUNING OF ELECTRONIC STATES BY BRIDGING SILICON CHAIN LENGTHS
  84. ChemInform Abstract: Aryne Inertion Reactions into σ-Bonds
  85. Copper-Catalyzed Borylation Reactions of Alkynes and Arynes
  86. Copper-Catalyzed Borylation Reactions of Alkynes and Arynes
  87. ChemInform Abstract: Aryne Reaction with Trifluoromethyl Ketones in Three Modes: C-C Bond Cleavage, [2 + 2] Cycloaddition and O-Arylation.
  88. ChemInform Abstract: Three-Component Coupling Using Arynes and DMF: Straightforward Access to Coumarins via ortho-Quinone Methides.
  89. Three-Component Coupling of Arynes and Organic Bromides
  90. Three-Component Coupling of Arynes and Organic Bromides
  91. Synthesis of Dithienogermole-Containing π-Conjugated Polymers and Applications to Photovoltaic Cells
  92. Aryne reaction with trifluoromethyl ketones in three modes: C–C bond cleavage, [2+2] cycloaddition and O-arylation
  93. Three-component coupling using arynes and DMF: straightforward access to coumarins via ortho-quinone methides
  94. An ortho-Quinodimethane Route to Lasofoxifene and U23469
  95. Synthesis and Optical Properties of Pyridino End-Capped Oligothiophenes
  96. Hybridization of Carbon Nanotubes with Si–π Polymers and Attachment of Resulting Hybrids to TiO2 Surface
  97. Aryne Insertion Reactions into .SIGMA.-Bonds
  98. ChemInform Abstract: Facile Access to Boryltetralins and Borylnaphthalenes via a Cycloaddition Using o-Quinodimethanes.
  99. ChemInform Abstract: An Aryne Route to Cytosporone B and Phomopsin C.
  100. ChemInform Abstract: Platinum-Catalyzed Diborylation of Arynes: Synthesis and Reaction of 1,2-Diborylarenes.
  101. ChemInform Abstract: Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates
  102. ChemInform Abstract: Palladium-Catalyzed Dimerization-Carbostannylation of Alkynes: Synthesis of Highly Conjugated Alkenylstannanes.
  103. ChemInform Abstract: Nickel-Catalyzed Carbostannylation of Alkynes with Allyl-, Acyl-, and Alkynylstannanes: Stereoselective Synthesis of Trisubstituted Vinylstannanes.
  104. ChemInform Abstract: Copper-Catalyzed Bromoalkynylation of Arynes.
  105. ChemInform Abstract: Dimerization-Carbostannylation of Alkynes Catalyzed by a Palladium-Diimine Complex: Regioselectivity, Stereoselectivity and Mechanism.
  106. ChemInform Abstract: Palladium-Iminophosphine-Catalyzed Carbostannylation of Arynes: Synthesis of ortho-Substituted Arylstannanes.
  107. ChemInform Abstract: Insertion of Arynes into Carbon-Chlorine Bonds of Chlorotriazines.
  108. ChemInform Abstract: Facile Synthesis of N-Alkyl-N′-arylimidazolium Salts via Addition of Imidazoles to Arynes.
  109. Copper-catalysed bromoalkynylation of arynes
  110. Facile access to boryltetralins and borylnaphthalenes via a cycloaddition using o-quinodimethanes
  111. Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes
  112. An Aryne Route to Cytosporone B and Phomopsin C
  113. Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates
  114. Does Water Liquid Phase Intrude into Hydrophobic Nanospaces of Alkyl-grafted Mesoporous Silica Immersed in Water? Detection by 13C CP-MAS NMR
  115. ChemInform Abstract: Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes.
  116. ChemInform Abstract: Fluorenes as New Molecular Scaffolds for Carbon-Carbon σ-Bond Cleavage Reaction: Acylfluorenylation of Arynes.
  117. Diphenyl-2-Pyridylphosphine
  118. ChemInform Abstract: Palladium-Catalyzed Disilylation of o-Quinodimethanes: Synthesis of 9- and 10-Membered Disilacarbocycles.
  119. Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes
  120. ChemInform Abstract: Direct Access to Anthranilic Acid Derivatives via CO2Incorporation Reaction Using Arynes.
  121. Insertion of Arynes into Carbon–Chlorine Bonds of Chlorotriazines
  122. ChemInform Abstract: Three-Component Coupling Using Arynes and Aminosilanes for ortho-Selective Double Functionalization of Aromatic Skeletons.
  123. Palladium-Catalyzed Disilylation of o -Quinodimethanes: Synthesis of 9- and 10-Membered Disilacarbocycles
  124. Direct Access to Anthranilic Acid Derivatives via CO 2 Incorporation Reaction Using Arynes
  125. Three-Component Coupling Using Arynes and Aminosilanes for ortho-Selective Double Functionalization of Aromatic Skeletons
  126. Fluorenes as new molecular scaffolds for carbon–carbon σ-bond cleavage reaction: acylfluorenylation of arynes
  127. Three-Component Coupling of Arynes, Aminosilanes, and Aldehydes.
  128. Insertion of Arynes into Carbon—Halogen σ-Bonds: Regioselective Acylation of Aromatic Rings.
  129. Three-Component Coupling Using Arynes and Isocyanides: Straightforward Access to Benzo-Annulated Nitrogen or Oxygen Heterocycles.
  130. Three-Component Coupling Using Arynes and Isocyanides: Straightforward Access to Benzo-Annulated Nitrogen or Oxygen Heterocycles.
  131. Straightforward Construction of Diarylmethane Skeletons via Aryne Insertion into Carbon—Carbon σ-Bonds.
  132. Three-Component Coupling of Arynes, Aminosilanes, and Aldehydes
  133. Three-component coupling using arynes and isocyanides: straightforward access to benzo-annulated nitrogen or oxygen heterocycles
  134. Synthesis of diarylenenaphthylene- and diaryleneanthrylene-containing organosilicon polymers and their applications to organic EL devices
  135. Palladium-Catalyzed Distannylation of ortho-Quinodimethanes.
  136. CO2 Incorporation Reaction Using Arynes: Straightforward Access to Benzoxazinone.
  137. Straightforward construction of diarylmethane skeletons via aryne insertion into carbon–carbon σ-bonds
  138. Insertion of arynes into carbon–halogen σ-bonds: regioselective acylation of aromatic rings
  139. Synthesis of organosilicon polymers containing donor–acceptor type π-conjugated units and their applications to dye-sensitized solar cells
  140. Palladium-Catalyzed Distannylation of o rtho -Quinodimethanes
  141. CO 2 Incorporation Reaction Using Arynes:  Straightforward Access to Benzoxazinone
  142. Carbophosphinylation of Arynes with Cyanomethyldiphenylphosphine Oxide.
  143. Palladium-Catalyzed Dimerization—Distannylation of Arynes: Synthesis and Reaction of 2,2′-Distannylbiaryls.
  144. Aryne Insertion into α-Cyanocarbonyl Compounds: Direct Introduction of Carbonyl and Cyanomethyl Moieties into the Aromatic Skeletons.
  145. Aminosilylation of Arynes with Aminosilanes: Synthesis of 2-Silylaniline Derivatives.
  146. Transition Metal Catalyzed Reactions or Electrophilic Coupling Reactions Using Arynes
  147. Facile Insertion Reaction of Arynes into Carbon—Carbon σ-Bonds.
  148. Aryne insertion into α-cyanocarbonyl compounds: direct introduction of carbonyl and cyanomethyl moieties into the aromatic skeletons
  149. Sonogashira coupling of diethynylsilane and dibromoarene in wet solvent for the formation of poly[(ethynylenearylene)-co-(diethynylenesilylenearylene)]
  150. Facile Synthesis of Polycyclic Aromatic Hydrocarbons via a Trisaryne Equivalent.
  151. Addition of Silicon?Silicon ?-Bonds to Arynes or Bisarynes Catalyzed by a Palladium Complex.
  152. Straightforward Access to 2-Iminoisoindolines via Three-Component Coupling of Arynes, Isocyanides and Imines.
  153. Cyclic voltammetry and theoretical calculations of silyl-substituted 1,4-benzoquinones
  154. A 2:1 Coupling Reaction of Arynes with Aldehydes via o-Quinone Methides: Straightforward Synthesis of 9-Arylxanthenes.
  155. Thiostannylation of Arynes with Stannyl Sulfides: Synthesis and Reaction of 2-(Arylthio)arylstannanes.
  156. Distannylation of Strained Carbon?Carbon Triple Bonds Catalyzed by a Palladium Complex.
  157. Aminosilylation of arynes with aminosilanes: synthesis of 2-silylaniline derivatives
  158. Facile insertion reaction of arynes into carbon–carbon σ-bonds
  159. Palladium-catalysed dimerisation–distannylation of arynes: synthesis and reaction of 2,2′-distannylbiaryls
  160. Facile Synthesis of Polycyclic Aromatic Hydrocarbons via a Trisaryne Equivalent
  161. Carbophosphinylation of Arynes with Cyanomethyldiphenylphosphine Oxide
  162. Addition of Silicon−Silicon σ-Bonds to Arynes or Bisarynes Catalyzed by a Palladium Complex
  163. Transition Metal-Catalyzed Reactions or Electrophilic Coupling Reactions Using Arynes
  164. Arynes in a Three-Component Coupling Reaction: Straightforward Synthesis of Benzoannulated Iminofurans.
  165. Straightforward access to 2-iminoisoindolines via three-component coupling of arynes, isocyanides and imines
  166. A 2:1 Coupling Reaction of Arynes with Aldehydes via o -Quinone Methides: Straightforward Synthesis of 9-Arylxanthenes
  167. Distannylation of Strained Carbon–Carbon Triple Bonds Catalyzed by a Palladium Complex
  168. Distannylation of Strained Carbon–Carbon Triple Bonds Catalyzed by a Palladium Complex
  169. 2,3,5,6-Tetrasilyl- and 2,3,5,6-Tetragermyl-1,4-benzoquinones:  X-ray Crystallographic Analysis, Cyclic Voltammetry, and DFT Calculations
  170. Arynes in a Three-Component Coupling Reaction: Straightforward Synthesis of Benzoannulated Iminofurans
  171. Arynes in a Three-Component Coupling Reaction: Straightforward Synthesis of Benzoannulated Iminofurans
  172. 2,3,5,6-Tetrasilyl- and 2,3,5,6-Tetragermyl-1,4-benzoquinones:  X-ray Crystallographic Analysis, Cyclic Voltammetry, and DFT Calculations
  173. Thiostannylation of arynes with stannyl sulfides: synthesis and reaction of 2-(arylthio)arylstannanesElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/suppdata/cc/b4/b405883f/
  174. Activator-Free Oxidative Homocoupling of Organosilanes Catalyzed by a Palladium—DPPP Complex.
  175. Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes: Synthesis of Benzo-Annulated Disilacarbocycles.
  176. Synthesis of organosilanylene–thienylene alternating oligomers bearing ether side chains
  177. Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes:  Synthesis of Benzo-Annulated Disilacarbocycles
  178. Base-Free Oxidative Homocoupling of Arylboronic Esters.
  179. Base-free oxidative homocoupling of arylboronic esters
  180. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives.
  181. Activator-free oxidative homocoupling of organosilanes catalysed by a palladium–DPPP complex
  182. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives
  183. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives
  184. Facile Synthesis of N -Alkyl- N ‘ -arylimidazolium Salts via Addition of Imidazoles to Arynes
  185. ChemInform Abstract: Palladium-Iminophosphine-Catalyzed Alkynylstannylation of Alkynes.
  186. ChemInform Abstract: Nickel-Catalyzed Acylstannylation of 1,3-Dienes: Synthesis and Reaction of ε-Oxoallylstannanes.
  187. ChemInform Abstract: Diphenylphosphinophenolate: A Ligand for the Palladium-Catalyzed Silylation of Aryl Halides Activating Simultaneously both Palladium and Silicon.
  188. Palladium–iminophosphine-catalysed carbostannylation of arynes: synthesis of ortho-substituted arylstannanes
  189. Dimerization-Carbostannylation of Alkynes Catalyzed by a Palladium-Diimine Complex: Regioselectivity, Stereoselectivity and Mechanism.
  190. Palladium−Iminophosphine-Catalyzed Alkynylstannylation of Alkynes
  191. Nickel-Catalyzed Acylstannylation of 1,3-Dienes:  Synthesis and Reaction of ε-Oxoallylstannanes
  192. Mechanistic Aspects of Palladium-Catalyzed Allylstannylation of Alkynes
  193. Diphenylphosphinophenolate: a ligand for the palladium-catalysed silylation of aryl halides activating simultaneously both palladium and silicon
  194. Nickel-Catalyzed Carbostannylation of Alkynes with Allyl-, Acyl-, and Alkynylstannanes:  Stereoselective Synthesis of Trisubstituted Vinylstannanes
  195. Palladium-Catalyzed Dimerization−Carbostannylation of Alkynes:  Synthesis of Highly Conjugated Alkenylstannanes
  196. Carbostannylation of Alkynes Catalyzed by an Iminophosphine−Palladium Complex
  197. On the catalytic cycle of the palladium-catalyzed cross-coupling reaction of alkynylstannane with aryl iodide
  198. An iminophosphine-palladium catalyst for cross-coupling of aryl halides with organostannanes