All Stories

  1. Flash Communication: A Lewis Acidity-Diminished, Stable Diborylethyne
  2. Two Roads to Arylstannanes: Arynes and Stannylpotassiums
  3. A Catalyst for Sodium Borohydride Dehydrogenation Based on a Mixed-Valent Iron Hydroxide Platform
  4. Stannylation of alkyl chlorides with stannylpotassium
  5. Modulating Lewis acidity with boronamides and boronates: effect on behavior in borylation and cross-coupling
  6. Weak Base-Promoted Direct Cross-Coupling of Naphthalene-1,8-diaminato-substituted Arylboron Compounds
  7. Modulation of Lewis Acidity and Steric Parameters in Cyclic Boronates: Copper-Catalyzed Internal-Selective Borylation of Challenging Terminal Alkynes
  8. Exclusive Papers of the Editorial Board Members and Topical Advisory Panel Members of Catalysts in Section “Catalysis in Organic and Polymer Chemistry”
  9. Copper-catalyzed silylation of aryl and alkenyl triflates with silylboronic esters avoiding base-mediated borylation
  10. Surefire generation of stannylpotassium: highly reactive stannyl anions and applications
  11. Ethynyl‐B(dan) in [3+2] Cycloaddition and Larock Indole Synthesis: Synthesis of Stable Boron‐Containing Heteroaromatic Compounds
  12. Complexation‐Triggered Fluctuation of π‐Conjugation on an Antiaromatic Dicyanoanthracene Dianion
  13. Selective S-Arylation of Sulfenamides with Arynes: Access to Sulfilimines
  14. Computed ammonia affinity for evaluating Lewis acidity of organoboronates and organoboronamides
  15. Efficient one-pot synthesis of dan-substituted organo- and silyl-boron compounds
  16. Direct Suzuki‐Miyaura Coupling of Naphthalene‐1,8‐diaminato (dan)‐Substituted Cyclopropylboron Compounds
  17. Main-Group Organometallics Containing Boron or Tin that Open New Frontiers in Organic Synthesis
  18. A stable silylborane with diminished boron Lewis acidity
  19. Origins of Internal Regioselectivity in Copper-Catalyzed Borylation of Terminal Alkynes
  20. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  21. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  22. Borylation and Stannylation Reactions with Tuning of Lewis Acidity
  23. A leap forward in sulfonium salt and sulfur ylide chemistry
  24. Synthetic Chemistry with Lewis Acidity‐Diminished B(aam) and B(dan) Groups: Borylation Reactions and Direct Cross‐Couplings
  25. Dithiazolylthienothiophene Bisimide-Based π-Conjugated Polymers: Improved Synthesis and Application to Organic Photovoltaics as P-Type Semiconductor
  26. Transition metal-free B(dan)-installing reaction (dan: naphthalene-1,8-diaminato): H–B(dan) as a B(dan) electrophile
  27. Direct Suzuki–Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons
  28. One-pot Sequential Fluorostannylation–Arylstannylation of Arynes
  29. Dithiazolylthienothiophene Bisimide: A Novel Electron-Deficient Building Unit for N-Type Semiconducting Polymers
  30. Ni/Co-Catalyzed Homo-Coupling of Alkyl Tosylates
  31. Copper‐Catalyzed B(dan)‐Installing Allylic Borylation of Allylic Phosphates
  32. An anthranilamide-substituted borane [H–B(aam)]: its stability and application to iridium-catalyzed stereoselective hydroboration of alkynes
  33. Anthranilamide (aam)-substituted arylboranes in direct carbon–carbon bond-forming reactions
  34. Copper-catalyzed arylstannylation of arynes in a sequence
  35. Copper-catalyzed Borylation of Bromoaryl Triflates with Diborons: Chemoselective Replacement of an Ar–Br Bond
  36. Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective B(aam) transfer
  37. B(MIDA)-Containing Diborons
  38. NHC-catalyzed cleavage of vicinal diketones and triketones followed by insertion of enones and ynones
  39. Naphthobispyrazine as an Electron-deficient Building Unit for π-Conjugated Polymers: Efficient Synthesis and Polymer Properties
  40. Aryne-Imine-Aryne Coupling Reaction via [4+2] Cycloaddition between Aza-o -Quinone Methides and Arynes
  41. Correction to “Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes”
  42. Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes
  43. Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides
  44. Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes
  45. Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan)
  46. Stannylation Reactions under Base Metal Catalysis: Some Recent Advances
  47. Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments
  48. Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si
  49. ChemInform Abstract: N-Heterocyclic Carbene-Catalyzed Double Acylation of Enones with Benzils.
  50. Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron
  51. Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide
  52. Copper-catalyzed α-selective hydrostannylation of alkynes for the synthesis of branched alkenylstannanes
  53. Copper-Catalyzed Metallation Reactions of Unsaturated Carbon-Carbon Bonds
  54. ChemInform Abstract: Three-Component Carboboration of Alkenes under Copper Catalysis.
  55. ChemInform Abstract: A Masked Diboron in Cu-Catalyzed Borylation Reaction: Highly Regioselective Formal Hydroboration of Alkynes for Synthesis of Branched Alkenylborons.
  56. ChemInform Abstract: Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes.
  57. Facile Access to vic-Borylstannylalkanes via Copper-Catalyzed Three-Component Borylstannylation of Alkenes
  58. Aryne-Based Multicomponent Reactions
  59. Direct Synthesis of Boron-Protected Alkenyl- and Alkylborons via Copper-Catalyzed Formal Hydroboration of Alkynes and Alkenes
  60. Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes
  61. Three-Component Carboboration of Alkenes under Copper Catalysis
  62. Convenient Synthesis of 2-Amino-4H-chromenes from Photochemically Generatedo-Quinone Methides and Malononitrile
  63. ChemInform Abstract: Copper-Catalyzed Distannylation of Alkynes.
  64. ChemInform Abstract: Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of Arynes.
  65. A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons
  66. N-Heterocyclic carbene-catalyzed double acylation of enones with benzils
  67. Dearomatization-Aromatization Sequence
  68. Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes
  69. Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes
  70. ChemInform Abstract: Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes.
  71. ChemInform Abstract: Copper-Catalyzed Three-Component Borylstannylation of Alkynes.
  72. Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes
  73. Copper-catalyzed distannylation of alkynes
  74. ChemInform Abstract: Hetero-Diels-Alder Reaction of Photochemically Generated α-Hydroxy-o-quinodimethanes with Trifluoromethyl Ketones.
  75. Copper-Catalyzed Three-Component Borylstannylation of Alkynes
  76. ChemInform Abstract: Aryne Insertion Reactions into Carbon-Carbon σ-Bonds
  77. ChemInform Abstract: Multicomponent Coupling Reaction of Arynes for Construction of Heterocyclic Skeletons
  78. Hetero-Diels–Alder reaction of photochemically generated α-hydroxy-o-quinodimethanes with trifluoromethyl ketones
  79. Aryne Insertion Reactions into Carbon-Carbon σ-Bonds
  80. ChemInform Abstract: Copper-Catalyzed Borylation Reactions of Alkynes and Arynes.
  81. ChemInform Abstract: An ortho-Quinodimethane Route to Lasofoxifene and U23469.
  82. ChemInform Abstract: Three-Component Coupling of Arynes and Organic Bromides.
  83. Multicomponent Coupling Reaction of Arynes for Construction of Heterocyclic Skeletons
  84. SYNTHESIS AND REACTIONS OF SILICON-BRIDGED DITHIENYLBIPHENYLS. FINE TUNING OF ELECTRONIC STATES BY BRIDGING SILICON CHAIN LENGTHS
  85. ChemInform Abstract: Aryne Inertion Reactions into σ-Bonds
  86. Copper-Catalyzed Borylation Reactions of Alkynes and Arynes
  87. Copper-Catalyzed Borylation Reactions of Alkynes and Arynes
  88. ChemInform Abstract: Aryne Reaction with Trifluoromethyl Ketones in Three Modes: C-C Bond Cleavage, [2 + 2] Cycloaddition and O-Arylation.
  89. ChemInform Abstract: Three-Component Coupling Using Arynes and DMF: Straightforward Access to Coumarins via ortho-Quinone Methides.
  90. Three-Component Coupling of Arynes and Organic Bromides
  91. Three-Component Coupling of Arynes and Organic Bromides
  92. Synthesis of Dithienogermole-Containing π-Conjugated Polymers and Applications to Photovoltaic Cells
  93. Aryne reaction with trifluoromethyl ketones in three modes: C–C bond cleavage, [2+2] cycloaddition and O-arylation
  94. Three-component coupling using arynes and DMF: straightforward access to coumarins via ortho-quinone methides
  95. An ortho-Quinodimethane Route to Lasofoxifene and U23469
  96. Synthesis and Optical Properties of Pyridino End-Capped Oligothiophenes
  97. Hybridization of Carbon Nanotubes with Si–π Polymers and Attachment of Resulting Hybrids to TiO2 Surface
  98. Aryne Insertion Reactions into .SIGMA.-Bonds
  99. ChemInform Abstract: Facile Access to Boryltetralins and Borylnaphthalenes via a Cycloaddition Using o-Quinodimethanes.
  100. ChemInform Abstract: An Aryne Route to Cytosporone B and Phomopsin C.
  101. ChemInform Abstract: Platinum-Catalyzed Diborylation of Arynes: Synthesis and Reaction of 1,2-Diborylarenes.
  102. ChemInform Abstract: Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates
  103. ChemInform Abstract: Palladium-Catalyzed Dimerization-Carbostannylation of Alkynes: Synthesis of Highly Conjugated Alkenylstannanes.
  104. ChemInform Abstract: Nickel-Catalyzed Carbostannylation of Alkynes with Allyl-, Acyl-, and Alkynylstannanes: Stereoselective Synthesis of Trisubstituted Vinylstannanes.
  105. ChemInform Abstract: Copper-Catalyzed Bromoalkynylation of Arynes.
  106. ChemInform Abstract: Dimerization-Carbostannylation of Alkynes Catalyzed by a Palladium-Diimine Complex: Regioselectivity, Stereoselectivity and Mechanism.
  107. ChemInform Abstract: Palladium-Iminophosphine-Catalyzed Carbostannylation of Arynes: Synthesis of ortho-Substituted Arylstannanes.
  108. ChemInform Abstract: Insertion of Arynes into Carbon-Chlorine Bonds of Chlorotriazines.
  109. ChemInform Abstract: Facile Synthesis of N-Alkyl-N′-arylimidazolium Salts via Addition of Imidazoles to Arynes.
  110. Copper-catalysed bromoalkynylation of arynes
  111. Facile access to boryltetralins and borylnaphthalenes via a cycloaddition using o-quinodimethanes
  112. Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes
  113. An Aryne Route to Cytosporone B and Phomopsin C
  114. Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates
  115. Does Water Liquid Phase Intrude into Hydrophobic Nanospaces of Alkyl-grafted Mesoporous Silica Immersed in Water? Detection by 13C CP-MAS NMR
  116. ChemInform Abstract: Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes.
  117. ChemInform Abstract: Fluorenes as New Molecular Scaffolds for Carbon-Carbon σ-Bond Cleavage Reaction: Acylfluorenylation of Arynes.
  118. Diphenyl-2-Pyridylphosphine
  119. ChemInform Abstract: Palladium-Catalyzed Disilylation of o-Quinodimethanes: Synthesis of 9- and 10-Membered Disilacarbocycles.
  120. Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes
  121. ChemInform Abstract: Direct Access to Anthranilic Acid Derivatives via CO2Incorporation Reaction Using Arynes.
  122. Insertion of Arynes into Carbon–Chlorine Bonds of Chlorotriazines
  123. ChemInform Abstract: Three-Component Coupling Using Arynes and Aminosilanes for ortho-Selective Double Functionalization of Aromatic Skeletons.
  124. Palladium-Catalyzed Disilylation of o -Quinodimethanes: Synthesis of 9- and 10-Membered Disilacarbocycles
  125. Direct Access to Anthranilic Acid Derivatives via CO 2 Incorporation Reaction Using Arynes
  126. Three-Component Coupling Using Arynes and Aminosilanes for ortho-Selective Double Functionalization of Aromatic Skeletons
  127. Fluorenes as new molecular scaffolds for carbon–carbon σ-bond cleavage reaction: acylfluorenylation of arynes
  128. Three-Component Coupling of Arynes, Aminosilanes, and Aldehydes.
  129. Insertion of Arynes into Carbon—Halogen σ-Bonds: Regioselective Acylation of Aromatic Rings.
  130. Three-Component Coupling Using Arynes and Isocyanides: Straightforward Access to Benzo-Annulated Nitrogen or Oxygen Heterocycles.
  131. Three-Component Coupling Using Arynes and Isocyanides: Straightforward Access to Benzo-Annulated Nitrogen or Oxygen Heterocycles.
  132. Straightforward Construction of Diarylmethane Skeletons via Aryne Insertion into Carbon—Carbon σ-Bonds.
  133. Three-Component Coupling of Arynes, Aminosilanes, and Aldehydes
  134. Three-component coupling using arynes and isocyanides: straightforward access to benzo-annulated nitrogen or oxygen heterocycles
  135. Synthesis of diarylenenaphthylene- and diaryleneanthrylene-containing organosilicon polymers and their applications to organic EL devices
  136. Palladium-Catalyzed Distannylation of ortho-Quinodimethanes.
  137. CO2 Incorporation Reaction Using Arynes: Straightforward Access to Benzoxazinone.
  138. Straightforward construction of diarylmethane skeletons via aryne insertion into carbon–carbon σ-bonds
  139. Insertion of arynes into carbon–halogen σ-bonds: regioselective acylation of aromatic rings
  140. Synthesis of organosilicon polymers containing donor–acceptor type π-conjugated units and their applications to dye-sensitized solar cells
  141. Palladium-Catalyzed Distannylation of o rtho -Quinodimethanes
  142. CO 2 Incorporation Reaction Using Arynes:  Straightforward Access to Benzoxazinone
  143. Carbophosphinylation of Arynes with Cyanomethyldiphenylphosphine Oxide.
  144. Palladium-Catalyzed Dimerization—Distannylation of Arynes: Synthesis and Reaction of 2,2′-Distannylbiaryls.
  145. Aryne Insertion into α-Cyanocarbonyl Compounds: Direct Introduction of Carbonyl and Cyanomethyl Moieties into the Aromatic Skeletons.
  146. Aminosilylation of Arynes with Aminosilanes: Synthesis of 2-Silylaniline Derivatives.
  147. Transition Metal Catalyzed Reactions or Electrophilic Coupling Reactions Using Arynes
  148. Facile Insertion Reaction of Arynes into Carbon—Carbon σ-Bonds.
  149. Aryne insertion into α-cyanocarbonyl compounds: direct introduction of carbonyl and cyanomethyl moieties into the aromatic skeletons
  150. Sonogashira coupling of diethynylsilane and dibromoarene in wet solvent for the formation of poly[(ethynylenearylene)-co-(diethynylenesilylenearylene)]
  151. Facile Synthesis of Polycyclic Aromatic Hydrocarbons via a Trisaryne Equivalent.
  152. Addition of Silicon?Silicon ?-Bonds to Arynes or Bisarynes Catalyzed by a Palladium Complex.
  153. Straightforward Access to 2-Iminoisoindolines via Three-Component Coupling of Arynes, Isocyanides and Imines.
  154. Cyclic voltammetry and theoretical calculations of silyl-substituted 1,4-benzoquinones
  155. A 2:1 Coupling Reaction of Arynes with Aldehydes via o-Quinone Methides: Straightforward Synthesis of 9-Arylxanthenes.
  156. Thiostannylation of Arynes with Stannyl Sulfides: Synthesis and Reaction of 2-(Arylthio)arylstannanes.
  157. Distannylation of Strained Carbon?Carbon Triple Bonds Catalyzed by a Palladium Complex.
  158. Aminosilylation of arynes with aminosilanes: synthesis of 2-silylaniline derivatives
  159. Facile insertion reaction of arynes into carbon–carbon σ-bonds
  160. Palladium-catalysed dimerisation–distannylation of arynes: synthesis and reaction of 2,2′-distannylbiaryls
  161. Facile Synthesis of Polycyclic Aromatic Hydrocarbons via a Trisaryne Equivalent
  162. Carbophosphinylation of Arynes with Cyanomethyldiphenylphosphine Oxide
  163. Addition of Silicon−Silicon σ-Bonds to Arynes or Bisarynes Catalyzed by a Palladium Complex
  164. Transition Metal-Catalyzed Reactions or Electrophilic Coupling Reactions Using Arynes
  165. Arynes in a Three-Component Coupling Reaction: Straightforward Synthesis of Benzoannulated Iminofurans.
  166. Straightforward access to 2-iminoisoindolines via three-component coupling of arynes, isocyanides and imines
  167. A 2:1 Coupling Reaction of Arynes with Aldehydes via o -Quinone Methides: Straightforward Synthesis of 9-Arylxanthenes
  168. Distannylation of Strained Carbon–Carbon Triple Bonds Catalyzed by a Palladium Complex
  169. Distannylation of Strained Carbon–Carbon Triple Bonds Catalyzed by a Palladium Complex
  170. 2,3,5,6-Tetrasilyl- and 2,3,5,6-Tetragermyl-1,4-benzoquinones:  X-ray Crystallographic Analysis, Cyclic Voltammetry, and DFT Calculations
  171. Arynes in a Three-Component Coupling Reaction: Straightforward Synthesis of Benzoannulated Iminofurans
  172. Arynes in a Three-Component Coupling Reaction: Straightforward Synthesis of Benzoannulated Iminofurans
  173. 2,3,5,6-Tetrasilyl- and 2,3,5,6-Tetragermyl-1,4-benzoquinones:  X-ray Crystallographic Analysis, Cyclic Voltammetry, and DFT Calculations
  174. Thiostannylation of arynes with stannyl sulfides: synthesis and reaction of 2-(arylthio)arylstannanesElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/suppdata/cc/b4/b405883f/
  175. Activator-Free Oxidative Homocoupling of Organosilanes Catalyzed by a Palladium—DPPP Complex.
  176. Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes: Synthesis of Benzo-Annulated Disilacarbocycles.
  177. Synthesis of organosilanylene–thienylene alternating oligomers bearing ether side chains
  178. Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes:  Synthesis of Benzo-Annulated Disilacarbocycles
  179. Base-Free Oxidative Homocoupling of Arylboronic Esters.
  180. Base-free oxidative homocoupling of arylboronic esters
  181. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives.
  182. Activator-free oxidative homocoupling of organosilanes catalysed by a palladium–DPPP complex
  183. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives
  184. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives
  185. Facile Synthesis of N -Alkyl- N ‘ -arylimidazolium Salts via Addition of Imidazoles to Arynes
  186. ChemInform Abstract: Palladium-Iminophosphine-Catalyzed Alkynylstannylation of Alkynes.
  187. ChemInform Abstract: Nickel-Catalyzed Acylstannylation of 1,3-Dienes: Synthesis and Reaction of ε-Oxoallylstannanes.
  188. ChemInform Abstract: Diphenylphosphinophenolate: A Ligand for the Palladium-Catalyzed Silylation of Aryl Halides Activating Simultaneously both Palladium and Silicon.
  189. Palladium–iminophosphine-catalysed carbostannylation of arynes: synthesis of ortho-substituted arylstannanes
  190. Dimerization-Carbostannylation of Alkynes Catalyzed by a Palladium-Diimine Complex: Regioselectivity, Stereoselectivity and Mechanism.
  191. Palladium−Iminophosphine-Catalyzed Alkynylstannylation of Alkynes
  192. Nickel-Catalyzed Acylstannylation of 1,3-Dienes:  Synthesis and Reaction of ε-Oxoallylstannanes
  193. Mechanistic Aspects of Palladium-Catalyzed Allylstannylation of Alkynes
  194. Diphenylphosphinophenolate: a ligand for the palladium-catalysed silylation of aryl halides activating simultaneously both palladium and silicon
  195. Nickel-Catalyzed Carbostannylation of Alkynes with Allyl-, Acyl-, and Alkynylstannanes:  Stereoselective Synthesis of Trisubstituted Vinylstannanes
  196. Palladium-Catalyzed Dimerization−Carbostannylation of Alkynes:  Synthesis of Highly Conjugated Alkenylstannanes
  197. Carbostannylation of Alkynes Catalyzed by an Iminophosphine−Palladium Complex
  198. On the catalytic cycle of the palladium-catalyzed cross-coupling reaction of alkynylstannane with aryl iodide
  199. An iminophosphine-palladium catalyst for cross-coupling of aryl halides with organostannanes