All Stories

  1. Stannylation of alkyl chlorides with stannylpotassium
  2. Modulating Lewis acidity with boronamides and boronates: effect on behavior in borylation and cross-coupling
  3. Weak Base-Promoted Direct Cross-Coupling of Naphthalene-1,8-diaminato-substituted Arylboron Compounds
  4. Modulation of Lewis Acidity and Steric Parameters in Cyclic Boronates: Copper-Catalyzed Internal-Selective Borylation of Challenging Terminal Alkynes
  5. Exclusive Papers of the Editorial Board Members and Topical Advisory Panel Members of Catalysts in Section “Catalysis in Organic and Polymer Chemistry”
  6. Copper-catalyzed silylation of aryl and alkenyl triflates with silylboronic esters avoiding base-mediated borylation
  7. Surefire generation of stannylpotassium: highly reactive stannyl anions and applications
  8. Ethynyl‐B(dan) in [3+2] Cycloaddition and Larock Indole Synthesis: Synthesis of Stable Boron‐Containing Heteroaromatic Compounds
  9. Complexation‐Triggered Fluctuation of π‐Conjugation on an Antiaromatic Dicyanoanthracene Dianion
  10. Selective S-Arylation of Sulfenamides with Arynes: Access to Sulfilimines
  11. Computed ammonia affinity for evaluating Lewis acidity of organoboronates and organoboronamides
  12. Efficient one-pot synthesis of dan-substituted organo- and silyl-boron compounds
  13. Direct Suzuki‐Miyaura Coupling of Naphthalene‐1,8‐diaminato (dan)‐Substituted Cyclopropylboron Compounds
  14. Main-Group Organometallics Containing Boron or Tin that Open New Frontiers in Organic Synthesis
  15. A stable silylborane with diminished boron Lewis acidity
  16. Origins of Internal Regioselectivity in Copper-Catalyzed Borylation of Terminal Alkynes
  17. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  18. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  19. Borylation and Stannylation Reactions with Tuning of Lewis Acidity
  20. A leap forward in sulfonium salt and sulfur ylide chemistry
  21. Synthetic Chemistry with Lewis Acidity‐Diminished B(aam) and B(dan) Groups: Borylation Reactions and Direct Cross‐Couplings
  22. Dithiazolylthienothiophene Bisimide-Based π-Conjugated Polymers: Improved Synthesis and Application to Organic Photovoltaics as P-Type Semiconductor
  23. Transition metal-free B(dan)-installing reaction (dan: naphthalene-1,8-diaminato): H–B(dan) as a B(dan) electrophile
  24. Direct Suzuki–Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons
  25. One-pot Sequential Fluorostannylation–Arylstannylation of Arynes
  26. Dithiazolylthienothiophene Bisimide: A Novel Electron-Deficient Building Unit for N-Type Semiconducting Polymers
  27. Ni/Co-Catalyzed Homo-Coupling of Alkyl Tosylates
  28. Copper‐Catalyzed B(dan)‐Installing Allylic Borylation of Allylic Phosphates
  29. An anthranilamide-substituted borane [H–B(aam)]: its stability and application to iridium-catalyzed stereoselective hydroboration of alkynes
  30. Anthranilamide (aam)-substituted arylboranes in direct carbon–carbon bond-forming reactions
  31. Copper-catalyzed arylstannylation of arynes in a sequence
  32. Copper-catalyzed Borylation of Bromoaryl Triflates with Diborons: Chemoselective Replacement of an Ar–Br Bond
  33. Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective B(aam) transfer
  34. B(MIDA)-Containing Diborons
  35. NHC-catalyzed cleavage of vicinal diketones and triketones followed by insertion of enones and ynones
  36. Naphthobispyrazine as an Electron-deficient Building Unit for π-Conjugated Polymers: Efficient Synthesis and Polymer Properties
  37. Aryne-Imine-Aryne Coupling Reaction via [4+2] Cycloaddition between Aza-o -Quinone Methides and Arynes
  38. Correction to “Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes”
  39. Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes
  40. Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides
  41. Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes
  42. Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan)
  43. Stannylation Reactions under Base Metal Catalysis: Some Recent Advances
  44. Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments
  45. Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si
  46. ChemInform Abstract: N-Heterocyclic Carbene-Catalyzed Double Acylation of Enones with Benzils.
  47. Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron
  48. Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide
  49. Copper-catalyzed α-selective hydrostannylation of alkynes for the synthesis of branched alkenylstannanes
  50. Copper-Catalyzed Metallation Reactions of Unsaturated Carbon-Carbon Bonds
  51. ChemInform Abstract: Three-Component Carboboration of Alkenes under Copper Catalysis.
  52. ChemInform Abstract: A Masked Diboron in Cu-Catalyzed Borylation Reaction: Highly Regioselective Formal Hydroboration of Alkynes for Synthesis of Branched Alkenylborons.
  53. ChemInform Abstract: Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes.
  54. Facile Access to vic-Borylstannylalkanes via Copper-Catalyzed Three-Component Borylstannylation of Alkenes
  55. Aryne-Based Multicomponent Reactions
  56. Direct Synthesis of Boron-Protected Alkenyl- and Alkylborons via Copper-Catalyzed Formal Hydroboration of Alkynes and Alkenes
  57. Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes
  58. Three-Component Carboboration of Alkenes under Copper Catalysis
  59. Convenient Synthesis of 2-Amino-4H-chromenes from Photochemically Generatedo-Quinone Methides and Malononitrile
  60. ChemInform Abstract: Copper-Catalyzed Distannylation of Alkynes.
  61. ChemInform Abstract: Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of Arynes.
  62. A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons
  63. N-Heterocyclic carbene-catalyzed double acylation of enones with benzils
  64. Dearomatization-Aromatization Sequence
  65. Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes
  66. Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes
  67. ChemInform Abstract: Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes.
  68. ChemInform Abstract: Copper-Catalyzed Three-Component Borylstannylation of Alkynes.
  69. Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes
  70. Copper-catalyzed distannylation of alkynes
  71. ChemInform Abstract: Hetero-Diels-Alder Reaction of Photochemically Generated α-Hydroxy-o-quinodimethanes with Trifluoromethyl Ketones.
  72. Copper-Catalyzed Three-Component Borylstannylation of Alkynes
  73. ChemInform Abstract: Aryne Insertion Reactions into Carbon-Carbon σ-Bonds
  74. ChemInform Abstract: Multicomponent Coupling Reaction of Arynes for Construction of Heterocyclic Skeletons
  75. Hetero-Diels–Alder reaction of photochemically generated α-hydroxy-o-quinodimethanes with trifluoromethyl ketones
  76. Aryne Insertion Reactions into Carbon-Carbon σ-Bonds
  77. ChemInform Abstract: Copper-Catalyzed Borylation Reactions of Alkynes and Arynes.
  78. ChemInform Abstract: An ortho-Quinodimethane Route to Lasofoxifene and U23469.
  79. ChemInform Abstract: Three-Component Coupling of Arynes and Organic Bromides.
  80. Multicomponent Coupling Reaction of Arynes for Construction of Heterocyclic Skeletons
  81. SYNTHESIS AND REACTIONS OF SILICON-BRIDGED DITHIENYLBIPHENYLS. FINE TUNING OF ELECTRONIC STATES BY BRIDGING SILICON CHAIN LENGTHS
  82. ChemInform Abstract: Aryne Inertion Reactions into σ-Bonds
  83. Copper-Catalyzed Borylation Reactions of Alkynes and Arynes
  84. Copper-Catalyzed Borylation Reactions of Alkynes and Arynes
  85. ChemInform Abstract: Aryne Reaction with Trifluoromethyl Ketones in Three Modes: C-C Bond Cleavage, [2 + 2] Cycloaddition and O-Arylation.
  86. ChemInform Abstract: Three-Component Coupling Using Arynes and DMF: Straightforward Access to Coumarins via ortho-Quinone Methides.
  87. Three-Component Coupling of Arynes and Organic Bromides
  88. Three-Component Coupling of Arynes and Organic Bromides
  89. Synthesis of Dithienogermole-Containing π-Conjugated Polymers and Applications to Photovoltaic Cells
  90. Aryne reaction with trifluoromethyl ketones in three modes: C–C bond cleavage, [2+2] cycloaddition and O-arylation
  91. Three-component coupling using arynes and DMF: straightforward access to coumarins via ortho-quinone methides
  92. An ortho-Quinodimethane Route to Lasofoxifene and U23469
  93. Synthesis and Optical Properties of Pyridino End-Capped Oligothiophenes
  94. Hybridization of Carbon Nanotubes with Si–π Polymers and Attachment of Resulting Hybrids to TiO2 Surface
  95. Aryne Insertion Reactions into .SIGMA.-Bonds
  96. ChemInform Abstract: Facile Access to Boryltetralins and Borylnaphthalenes via a Cycloaddition Using o-Quinodimethanes.
  97. ChemInform Abstract: An Aryne Route to Cytosporone B and Phomopsin C.
  98. ChemInform Abstract: Platinum-Catalyzed Diborylation of Arynes: Synthesis and Reaction of 1,2-Diborylarenes.
  99. ChemInform Abstract: Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates
  100. ChemInform Abstract: Palladium-Catalyzed Dimerization-Carbostannylation of Alkynes: Synthesis of Highly Conjugated Alkenylstannanes.
  101. ChemInform Abstract: Nickel-Catalyzed Carbostannylation of Alkynes with Allyl-, Acyl-, and Alkynylstannanes: Stereoselective Synthesis of Trisubstituted Vinylstannanes.
  102. ChemInform Abstract: Copper-Catalyzed Bromoalkynylation of Arynes.
  103. ChemInform Abstract: Dimerization-Carbostannylation of Alkynes Catalyzed by a Palladium-Diimine Complex: Regioselectivity, Stereoselectivity and Mechanism.
  104. ChemInform Abstract: Palladium-Iminophosphine-Catalyzed Carbostannylation of Arynes: Synthesis of ortho-Substituted Arylstannanes.
  105. ChemInform Abstract: Insertion of Arynes into Carbon-Chlorine Bonds of Chlorotriazines.
  106. ChemInform Abstract: Facile Synthesis of N-Alkyl-N′-arylimidazolium Salts via Addition of Imidazoles to Arynes.
  107. Copper-catalysed bromoalkynylation of arynes
  108. Facile access to boryltetralins and borylnaphthalenes via a cycloaddition using o-quinodimethanes
  109. Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes
  110. An Aryne Route to Cytosporone B and Phomopsin C
  111. Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates
  112. Does Water Liquid Phase Intrude into Hydrophobic Nanospaces of Alkyl-grafted Mesoporous Silica Immersed in Water? Detection by 13C CP-MAS NMR
  113. ChemInform Abstract: Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes.
  114. ChemInform Abstract: Fluorenes as New Molecular Scaffolds for Carbon-Carbon σ-Bond Cleavage Reaction: Acylfluorenylation of Arynes.
  115. Diphenyl-2-Pyridylphosphine
  116. ChemInform Abstract: Palladium-Catalyzed Disilylation of o-Quinodimethanes: Synthesis of 9- and 10-Membered Disilacarbocycles.
  117. Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes
  118. ChemInform Abstract: Direct Access to Anthranilic Acid Derivatives via CO2Incorporation Reaction Using Arynes.
  119. Insertion of Arynes into Carbon–Chlorine Bonds of Chlorotriazines
  120. ChemInform Abstract: Three-Component Coupling Using Arynes and Aminosilanes for ortho-Selective Double Functionalization of Aromatic Skeletons.
  121. Palladium-Catalyzed Disilylation of o -Quinodimethanes: Synthesis of 9- and 10-Membered Disilacarbocycles
  122. Direct Access to Anthranilic Acid Derivatives via CO 2 Incorporation Reaction Using Arynes
  123. Three-Component Coupling Using Arynes and Aminosilanes for ortho-Selective Double Functionalization of Aromatic Skeletons
  124. Fluorenes as new molecular scaffolds for carbon–carbon σ-bond cleavage reaction: acylfluorenylation of arynes
  125. Three-Component Coupling of Arynes, Aminosilanes, and Aldehydes.
  126. Insertion of Arynes into Carbon—Halogen σ-Bonds: Regioselective Acylation of Aromatic Rings.
  127. Three-Component Coupling Using Arynes and Isocyanides: Straightforward Access to Benzo-Annulated Nitrogen or Oxygen Heterocycles.
  128. Three-Component Coupling Using Arynes and Isocyanides: Straightforward Access to Benzo-Annulated Nitrogen or Oxygen Heterocycles.
  129. Straightforward Construction of Diarylmethane Skeletons via Aryne Insertion into Carbon—Carbon σ-Bonds.
  130. Three-Component Coupling of Arynes, Aminosilanes, and Aldehydes
  131. Three-component coupling using arynes and isocyanides: straightforward access to benzo-annulated nitrogen or oxygen heterocycles
  132. Synthesis of diarylenenaphthylene- and diaryleneanthrylene-containing organosilicon polymers and their applications to organic EL devices
  133. Palladium-Catalyzed Distannylation of ortho-Quinodimethanes.
  134. CO2 Incorporation Reaction Using Arynes: Straightforward Access to Benzoxazinone.
  135. Straightforward construction of diarylmethane skeletons via aryne insertion into carbon–carbon σ-bonds
  136. Insertion of arynes into carbon–halogen σ-bonds: regioselective acylation of aromatic rings
  137. Synthesis of organosilicon polymers containing donor–acceptor type π-conjugated units and their applications to dye-sensitized solar cells
  138. Palladium-Catalyzed Distannylation of o rtho -Quinodimethanes
  139. CO 2 Incorporation Reaction Using Arynes:  Straightforward Access to Benzoxazinone
  140. Carbophosphinylation of Arynes with Cyanomethyldiphenylphosphine Oxide.
  141. Palladium-Catalyzed Dimerization—Distannylation of Arynes: Synthesis and Reaction of 2,2′-Distannylbiaryls.
  142. Aryne Insertion into α-Cyanocarbonyl Compounds: Direct Introduction of Carbonyl and Cyanomethyl Moieties into the Aromatic Skeletons.
  143. Aminosilylation of Arynes with Aminosilanes: Synthesis of 2-Silylaniline Derivatives.
  144. Transition Metal Catalyzed Reactions or Electrophilic Coupling Reactions Using Arynes
  145. Facile Insertion Reaction of Arynes into Carbon—Carbon σ-Bonds.
  146. Aryne insertion into α-cyanocarbonyl compounds: direct introduction of carbonyl and cyanomethyl moieties into the aromatic skeletons
  147. Sonogashira coupling of diethynylsilane and dibromoarene in wet solvent for the formation of poly[(ethynylenearylene)-co-(diethynylenesilylenearylene)]
  148. Facile Synthesis of Polycyclic Aromatic Hydrocarbons via a Trisaryne Equivalent.
  149. Addition of Silicon?Silicon ?-Bonds to Arynes or Bisarynes Catalyzed by a Palladium Complex.
  150. Straightforward Access to 2-Iminoisoindolines via Three-Component Coupling of Arynes, Isocyanides and Imines.
  151. Cyclic voltammetry and theoretical calculations of silyl-substituted 1,4-benzoquinones
  152. A 2:1 Coupling Reaction of Arynes with Aldehydes via o-Quinone Methides: Straightforward Synthesis of 9-Arylxanthenes.
  153. Thiostannylation of Arynes with Stannyl Sulfides: Synthesis and Reaction of 2-(Arylthio)arylstannanes.
  154. Distannylation of Strained Carbon?Carbon Triple Bonds Catalyzed by a Palladium Complex.
  155. Aminosilylation of arynes with aminosilanes: synthesis of 2-silylaniline derivatives
  156. Facile insertion reaction of arynes into carbon–carbon σ-bonds
  157. Palladium-catalysed dimerisation–distannylation of arynes: synthesis and reaction of 2,2′-distannylbiaryls
  158. Facile Synthesis of Polycyclic Aromatic Hydrocarbons via a Trisaryne Equivalent
  159. Carbophosphinylation of Arynes with Cyanomethyldiphenylphosphine Oxide
  160. Addition of Silicon−Silicon σ-Bonds to Arynes or Bisarynes Catalyzed by a Palladium Complex
  161. Transition Metal-Catalyzed Reactions or Electrophilic Coupling Reactions Using Arynes
  162. Arynes in a Three-Component Coupling Reaction: Straightforward Synthesis of Benzoannulated Iminofurans.
  163. Straightforward access to 2-iminoisoindolines via three-component coupling of arynes, isocyanides and imines
  164. A 2:1 Coupling Reaction of Arynes with Aldehydes via o -Quinone Methides: Straightforward Synthesis of 9-Arylxanthenes
  165. Distannylation of Strained Carbon–Carbon Triple Bonds Catalyzed by a Palladium Complex
  166. Distannylation of Strained Carbon–Carbon Triple Bonds Catalyzed by a Palladium Complex
  167. 2,3,5,6-Tetrasilyl- and 2,3,5,6-Tetragermyl-1,4-benzoquinones:  X-ray Crystallographic Analysis, Cyclic Voltammetry, and DFT Calculations
  168. Arynes in a Three-Component Coupling Reaction: Straightforward Synthesis of Benzoannulated Iminofurans
  169. Arynes in a Three-Component Coupling Reaction: Straightforward Synthesis of Benzoannulated Iminofurans
  170. 2,3,5,6-Tetrasilyl- and 2,3,5,6-Tetragermyl-1,4-benzoquinones:  X-ray Crystallographic Analysis, Cyclic Voltammetry, and DFT Calculations
  171. Thiostannylation of arynes with stannyl sulfides: synthesis and reaction of 2-(arylthio)arylstannanesElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/suppdata/cc/b4/b405883f/
  172. Activator-Free Oxidative Homocoupling of Organosilanes Catalyzed by a Palladium—DPPP Complex.
  173. Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes: Synthesis of Benzo-Annulated Disilacarbocycles.
  174. Synthesis of organosilanylene–thienylene alternating oligomers bearing ether side chains
  175. Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes:  Synthesis of Benzo-Annulated Disilacarbocycles
  176. Base-Free Oxidative Homocoupling of Arylboronic Esters.
  177. Base-free oxidative homocoupling of arylboronic esters
  178. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives.
  179. Activator-free oxidative homocoupling of organosilanes catalysed by a palladium–DPPP complex
  180. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives
  181. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives
  182. Facile Synthesis of N -Alkyl- N ‘ -arylimidazolium Salts via Addition of Imidazoles to Arynes
  183. ChemInform Abstract: Palladium-Iminophosphine-Catalyzed Alkynylstannylation of Alkynes.
  184. ChemInform Abstract: Nickel-Catalyzed Acylstannylation of 1,3-Dienes: Synthesis and Reaction of ε-Oxoallylstannanes.
  185. ChemInform Abstract: Diphenylphosphinophenolate: A Ligand for the Palladium-Catalyzed Silylation of Aryl Halides Activating Simultaneously both Palladium and Silicon.
  186. Palladium–iminophosphine-catalysed carbostannylation of arynes: synthesis of ortho-substituted arylstannanes
  187. Dimerization-Carbostannylation of Alkynes Catalyzed by a Palladium-Diimine Complex: Regioselectivity, Stereoselectivity and Mechanism.
  188. Palladium−Iminophosphine-Catalyzed Alkynylstannylation of Alkynes
  189. Nickel-Catalyzed Acylstannylation of 1,3-Dienes:  Synthesis and Reaction of ε-Oxoallylstannanes
  190. Mechanistic Aspects of Palladium-Catalyzed Allylstannylation of Alkynes
  191. Diphenylphosphinophenolate: a ligand for the palladium-catalysed silylation of aryl halides activating simultaneously both palladium and silicon
  192. Nickel-Catalyzed Carbostannylation of Alkynes with Allyl-, Acyl-, and Alkynylstannanes:  Stereoselective Synthesis of Trisubstituted Vinylstannanes
  193. Palladium-Catalyzed Dimerization−Carbostannylation of Alkynes:  Synthesis of Highly Conjugated Alkenylstannanes
  194. Carbostannylation of Alkynes Catalyzed by an Iminophosphine−Palladium Complex
  195. On the catalytic cycle of the palladium-catalyzed cross-coupling reaction of alkynylstannane with aryl iodide
  196. An iminophosphine-palladium catalyst for cross-coupling of aryl halides with organostannanes