All Stories

  1. A hydroxyl group dictates handedness, pitch, and mechanics in a crystalline covalent helical polymer
  2. Topochemical Synthesis of a Syndiotactic Polymer from a Racemic Monomer
  3. Making Polymers Inside Crystals: A New Chemical Reaction for Solid-State Materials
  4. Topochemical Alkyne Nitrile Oxide Cycloaddition for Polymer Synthesis
  5. Single-Crystal-to-Single-Crystal Synthesis of an Adaptive Two-Dimensional Polymer with Dynamic Pores
  6. Topochemical Polymerization of Retro‐Isomeric Peptides for Tuning the Polymer Structure and Properties
  7. Topochemical Polymerization of Retro‐Isomeric Peptides for Tuning the Polymer Structure and Properties
  8. Absolute Asymmetric Synthesis of a Homochiral Polymer from an Achiral Monomer
  9. Absolute Asymmetric Synthesis of a Homochiral Polymer from an Achiral Monomer
  10. Single‐Crystal‐to‐Single‐Crystal Synthesis of a Rope‐Ladder Polymer
  11. Single‐Crystal‐to‐Single‐Crystal Synthesis of a Rope‐Ladder Polymer
  12. Single‐Crystal‐to‐Single‐Crystal Synthesis of a Polymer in Two Distinct Topologies
  13. Single‐Crystal‐to‐Single‐Crystal Synthesis of a Polymer in Two Distinct Topologies
  14. Supramolecular Preorganization of Amine‐functionalized Diacetylene Monomers in their Crystals Allows their Topochemical Polymerization to Polydiacetylenes Capable of CO2 Capture
  15. A Malleable Collagen‐Mimic that Undergoes Moisture‐Induced Hardening for Gluing Hydrophilic Surfaces
  16. A Malleable Collagen‐Mimic that Undergoes Moisture‐Induced Hardening for Gluing Hydrophilic Surfaces
  17. Isomer-dependent reactivity in the solid state: topochemical [4 + 4] vs. [4 + 2] cycloaddition reactions
  18. Light‐Induced Transformation of a Supramolecular Gel to a Stronger Covalent Polymeric Gel
  19. Unclicking the Click: A Depolymerizable Clicked Polymer via Two Consecutive Single‐Crystal‐to‐Single‐Crystal Reactions
  20. Unclicking the Click: A Depolymerizable Clicked Polymer via Two Consecutive Single‐Crystal‐to‐Single‐Crystal Reactions
  21. A Syndiotactic Polymer via Spontaneous Exoselective Single-Crystal-To-Single-Crystal Topochemical Diels–Alder Cycloaddition Reaction
  22. A Self-Healing Crystal That Repairs Multiple Cracks
  23. Large Molecular Rotation in Crystal Changes the Course of a Topochemical Diels–Alder Reaction from a Predicted Polymerization to an Unexpected Intramolecular Cyclization
  24. Large Molecular Rotation in Crystal Changes the Course of a Topochemical Diels–Alder Reaction from a Predicted Polymerization to an Unexpected Intramolecular Cyclization
  25. Hierarchical single-crystal-to-single-crystal transformations of a monomer to a 1D-polymer and then to a 2D-polymer
  26. Simultaneous and in situ syntheses of an enantiomeric pair of homochiral polymers as their perfect stereocomplex in a crystal
  27. Sequential and hierarchical single-crystal-to-single-crystal transformations of a monomer to a 1D-polymer and then to a 2D-polymer
  28. Innentitelbild: Massive Molecular Motion in Crystal Leads to an Unexpected Helical Covalent Polymer in a Solid‐state Polymerization (Angew. Chem. 9/2024)
  29. Inside Cover: Massive Molecular Motion in Crystal Leads to an Unexpected Helical Covalent Polymer in a Solid‐state Polymerization (Angew. Chem. Int. Ed. 9/2024)
  30. Massive Molecular Motion in Crystal Leads to an Unexpected Helical Covalent Polymer in a Solid‐state Polymerization
  31. Massive Molecular Motion in Crystal Leads to an Unexpected Helical Covalent Polymer in a Solid‐state Polymerization
  32. Topochemistry for Difficult Peptide–Polymer Synthesis: Single-Crystal-to-Single-Crystal Synthesis of an Isoleucine-Based Polymer, a Hydrophobic Coating Material
  33. Single‐Crystal‐to‐Single‐Crystal Topochemical Synthesis of a Collagen‐inspired Covalent Helical Polymer
  34. Single‐Crystal‐to‐Single‐Crystal Topochemical Synthesis of a Collagen‐inspired Covalent Helical Polymer
  35. Two Structurally Different Polymers from a Single Monomer
  36. Massive Molecular Motion in Crystal Lattice Leads to an Unexpected Product in a Topochemical Polymerization
  37. A promising marriage between polymorphism and topochemistry: Synthesis of a polymer in two different secondary structures
  38. Topochemical Syntheses of Polyarylopeptides Involving Large Molecular Motions: Frustrated Monomer Packing Leads to the Formation of Polymer Blends
  39. Topochemical Syntheses of Polyarylopeptides Involving Large Molecular Motions: Frustrated Monomer Packing Leads to the Formation of Polymer Blends
  40. A self-healing crystal that repairs multiple cracks
  41. Adamantoid Scaffolds for Multiple Cargo Loading and Cellular Delivery as β‐Cyclodextrin Inclusion Complexes
  42. Adamantoid Scaffolds for Multiple Cargo Loading and Cellular Delivery as β‐Cyclodextrin Inclusion Complexes
  43. Regiospecific Synthesis of a Reprocessable Galactan-Mimic via Topochemical Polymerization
  44. Cascading Effect of Large Molecular Motion in Crystals: A Topotactic Polymorphic Transition Paves the Way to Topochemical Polymerization
  45. Rational design and topochemical synthesis of polymorphs of a polymer
  46. Tuning the Regioselectivity of Topochemical Polymerization through Cocrystallization of the Monomer with an Inert Isostere
  47. Tuning the Regioselectivity of Topochemical Polymerization through Cocrystallization of the Monomer with an Inert Isostere
  48. Topochemical Cycloaddition Reaction between an Azide and an Internal Alkyne
  49. Topochemical Cycloaddition Reaction between an Azide and an Internal Alkyne
  50. Single-crystal-to-single-crystal translation of a helical supramolecular polymer to a helical covalent polymer
  51. Frontispiece: Topochemical Postulates: Are They Relevant for Topochemical Reactions Occurring at Elevated Temperatures?
  52. Frontispiz: Topochemical Postulates: Are They Relevant for Topochemical Reactions Occurring at Elevated Temperatures?
  53. A Biomaterial‐Based Porous Core–Shell Sorbent for Practical and Efficient Marine Oil Spill Recovery
  54. Azide–Alkyne Interactions: A Crucial Attractive Force for Their Preorganization for Topochemical Cycloaddition Reaction
  55. Topochemical Postulates: Are They Relevant for Topochemical Reactions Occurring at Elevated Temperatures?
  56. Topochemical Postulates: Are They Relevant for Topochemical Reactions Occurring at Elevated Temperatures?
  57. Topochemical Synthesis of a Heterochiral Peptide Polymer in Different Polymorphic Forms from Crystals and Aerogels
  58. Topochemical Synthesis of a Heterochiral Peptide Polymer in Different Polymorphic Forms from Crystals and Aerogels
  59. Frontispiece: Secondary Structure Tuning of a Pseudoprotein Between β‐Meander and α‐Helical Forms in the Solid‐State
  60. Frontispiz: Secondary Structure Tuning of a Pseudoprotein Between β‐Meander and α‐Helical Forms in the Solid‐State
  61. Secondary Structure Tuning of a Pseudoprotein Between β‐Meander and α‐Helical Forms in the Solid‐State
  62. Secondary Structure Tuning of a Pseudoprotein Between β‐Meander and α‐Helical Forms in the Solid‐State
  63. Topochemical Ene–Azide Cycloaddition Reaction
  64. Topochemical Ene–Azide Cycloaddition Reaction
  65. Azide⋅⋅⋅Oxygen Interaction: A Crystal Engineering Tool for Conformational Locking
  66. Azide⋅⋅⋅Oxygen Interaction: A Crystal Engineering Tool for Conformational Locking
  67. Innenrücktitelbild: Topochemical Ene–Azide Cycloaddition Reaction (Angew. Chem. 47/2021)
  68. Inside Back Cover: Topochemical Ene–Azide Cycloaddition Reaction (Angew. Chem. Int. Ed. 47/2021)
  69. Solvent-Free and Catalyst-Free Synthesis of Cross-Linkable Polyfumaramides via Topochemical Azide-Alkyne Cycloaddition Polymerization
  70. Novel Substrates for Kinases Involved in the Biosynthesis of Inositol Pyrophosphates and Their Enhancement of ATPase Activity of a Kinase
  71. Quantification of Noncovalent Interactions in Azide–Pnictogen, –Chalcogen, and –Halogen Contacts
  72. Polymers with advanced structural and supramolecular features synthesized through topochemical polymerization
  73. Single-crystal-to-single-crystal synthesis of a pseudostarch via topochemical azide–alkyne cycloaddition polymerization
  74. Topochemical polymerizations for the solid-state synthesis of organic polymers
  75. Scalable Topochemical Synthesis of a Pseudoprotein in Aerogel for Water-Capturing Applications
  76. How Far Are We in Combating Marine Oil Spills by Using Phase‐Selective Organogelators?
  77. Designed Synthesis of a 1D Polymer in Twist‐Stacked Topology via Single‐Crystal‐to‐Single‐Crystal Polymerization
  78. Designed Synthesis of a 1D Polymer in Twist‐Stacked Topology via Single‐Crystal‐to‐Single‐Crystal Polymerization
  79. β‐Sheet to Helical‐Sheet Evolution Induced by Topochemical Polymerization: Cross‐α‐Amyloid‐like Packing in a Pseudoprotein with Gly‐Phe‐Gly Repeats
  80. β‐Sheet to Helical‐Sheet Evolution Induced by Topochemical Polymerization: Cross‐α‐Amyloid‐like Packing in a Pseudoprotein with Gly‐Phe‐Gly Repeats
  81. Topochemical synthesis of different polymorphs of polymers as a paradigm for tuning properties of polymers
  82. Crystal‐to‐Crystal Synthesis of Helically Ordered Polymers of Trehalose by Topochemical Polymerization
  83. Crystal‐to‐Crystal Synthesis of Helically Ordered Polymers of Trehalose by Topochemical Polymerization
  84. Topochemical Azide–Alkyne Cycloaddition Reaction
  85. Sugar-Based Organogelators for Various Applications
  86. Solid‐State Synthesis of Two Different Polymers in a Single Crystal: A Miscible Polymer Blend from a Topochemical Reaction
  87. Spontaneous Single‐Crystal‐to‐Single‐Crystal Evolution of Two Cross‐Laminated Polymers
  88. Kana M. Sureshan
  89. Kana M. Sureshan
  90. Synthesis and Reversible Hydration of a Pseudoprotein, a Fully Organic Polymeric Desiccant by Multiple Single‐Crystal‐to‐Single‐Crystal Transformations
  91. Synthesis and Reversible Hydration of a Pseudoprotein, a Fully Organic Polymeric Desiccant by Multiple Single‐Crystal‐to‐Single‐Crystal Transformations
  92. Tunable Mechanical Response from a Crystal Undergoing Topochemical Dimerization: Instant Explosion at a Faster Rate and Chemical Storage of a Harvestable Explosion at a Slower Rate
  93. Chirality-controlled spontaneous twisting of crystals due to thermal topochemical reaction
  94. Model molecules to classify CH⋯O hydrogen-bonds
  95. Three-way competition in a topochemical reaction: permutative azide–alkyne cycloaddition reactions leading to a vast library of products in the crystal
  96. A Library of Multipurpose Supramolecular Supergelators: Fabrication of Structured Silica, Porous Plastics, and Fluorescent Gels
  97. Organogelator–Cellulose Composite for Practical and Eco‐Friendly Marine Oil‐Spill Recovery
  98. Organogelator–Cellulose Composite for Practical and Eco‐Friendly Marine Oil‐Spill Recovery
  99. Topochemical Azide–Alkyne Cycloaddition Reaction in Gels: Size-Tunable Synthesis of Triazole-Linked Polypeptides
  100. Regioselective SN2 reactions for rapid syntheses of azido-inositols by one-pot sequence-specific nucleophilysis
  101. Carbasugar Synthesis via Vinylogous Ketal: Total Syntheses of (+)-MK7607, (−)-MK7607, (−)-Gabosine A, (−)-Epoxydine B, (−)-Epoxydine C, epi-(+)-Gabosine E and epi-(+)-MK7607
  102. Crystal-to-Crystal Synthesis of Triazole-Linked Pseudo-proteins via Topochemical Azide–Alkyne Cycloaddition Reaction
  103. A Molecular‐Level Study of Metamorphosis and Strengthening of Gels by Spontaneous Polymorphic Transitions
  104. A Sugar‐Based Gelator for Marine Oil‐Spill Recovery
  105. A Sugar‐Based Gelator for Marine Oil‐Spill Recovery
  106. DNA Synthesis in Solid State
  107. Our paper on CO2 fixation.
  108. A versatile glycosylation strategy via Au( iii ) catalyzed activation of thioglycoside donors
  109. Organogel-assisted topochemical synthesis of multivalent glyco-polymer for high-affinity lectin binding
  110. Synthesis of dimeric analogs of adenophostin A that potently evoke Ca2+release through IP3receptors
  111. Semiconducting Fabrics by In Situ Topochemical Synthesis of Polydiacetylene: A New Dimension to the Use of Organogels
  112. Semiconducting Fabrics by In Situ Topochemical Synthesis of Polydiacetylene: A New Dimension to the Use of Organogels
  113. Stoichiometric Sensing to Opt between Gelation and Crystallization
  114. Stoichiometric Sensing to Opt between Gelation and Crystallization
  115. ChemInform Abstract: Total Syntheses of Five Uvacalols: Structural Validation of Uvacalol A, Uvacalol B and Uvacalol C and Disproval of the Structures of Uvacalol E and Uvacalol G.
  116. ChemInform Abstract: Total Syntheses and Structural Validation of Lincitol A (Ia), Lincitol B (Ib), Uvacalol I (IIa), Uvacalol J (IIb), and Uvacalol K (IIc).
  117. A Spontaneous Single-Crystal-to-Single-Crystal Polymorphic Transition Involving Major Packing Changes
  118. ChemInform Abstract: Total Synthesis and Glycosidase Inhibition Studies of (‐)‐Gabosine J and Its Derivatives.
  119. First total synthesis of five natural products from mannitol
  120. Synthesis of Calcium releasing Agents
  121. Hopping-Mediated Anion Transport through a Mannitol-Based Rosette Ion Channel
  122. Synthesis of Triazole‐linked Homonucleoside Polymers through Topochemical Azide–Alkyne Cycloaddition
  123. Synthesis of Triazole‐linked Homonucleoside Polymers through Topochemical Azide–Alkyne Cycloaddition
  124. Strength from Weakness: Conformational Divergence between Solid and Solution States of Substituted Cyclitols Facilitated by CH···O Hydrogen Bonding
  125. Total Synthesis and Glycosidase Inhibition Studies of (–)‐Gabosine J and Its Derivatives
  126. Reverse-CD mimics with flexible linkages offer adaptable cavity sizes for guest encapsulation
  127. Bio-inspired synthesis of carbohydrates and cyclitols
  128. Total syntheses and structural validation of lincitol A, lincitol B, uvacalol I, uvacalol J, and uvacalol K
  129. Vinylogy in Orthoester Hydrolysis: Total Syntheses of Cyclophellitol, Valienamine, Gabosine K, Valienone, Gabosine G, 1-epi-Streptol, Streptol, and Uvamalol A
  130. Polysaccharide synthesis in Crystals!
  131. A Crystal‐to‐Crystal Synthesis of Triazolyl‐Linked Polysaccharide
  132. A versatile solvent-free azide–alkyne click reaction catalyzed by in situ generated copper nanoparticles
  133. Supramolecular design of a bicomponent topochemical reaction between two non-identical molecules
  134. H2SO4-silica: an eco-friendly heterogeneous catalyst for the differential protection of myo-inositol hydroxyl groups
  135. Weak becomes strong: remarkable strength of C–H⋯π hydrogen bond in the presence of O–H⋯O hydrogen bonds in the crystal stabilization
  136. Chemoselective alcoholysis/acetolysis of trans-ketals over cis-ketals and its application in the total synthesis of the cellular second messenger, d-myo-inositol-1,4,5-trisphosphate
  137. ChemInform Abstract: Regioselectivity Among Six Secondary Hydroxyl Groups: Selective Acylation of the Least Reactive Hydroxyl Groups of Inositol
  138. Topochemical Click Reaction: Spontaneous Self‐Stitching of a Monosaccharide to Linear Oligomers through Lattice‐Controlled Azide–Alkyne Cycloaddition
  139. Topochemical Click Reaction: Spontaneous Self‐Stitching of a Monosaccharide to Linear Oligomers through Lattice‐Controlled Azide–Alkyne Cycloaddition
  140. Contribution of Phosphates and Adenine to the Potency of Adenophostins at the IP3Receptor: Synthesis of All Possible Bisphosphates of Adenophostin A
  141. Weak is strong
  142. Regioselectivity among six secondary hydroxyl groups: selective acylation of the least reactive hydroxyl groups of inositol
  143. Cleaning of Oil spills using gels
  144. Strength from weakness: The role of CH…N hydrogen bond in the formation of wave-like topology in crystals of aza-heterocycles
  145. Soft Optical Devices from Self‐Healing Gels Formed by Oil and Sugar‐Based Organogelators
  146. Soft Optical Devices from Self‐Healing Gels Formed by Oil and Sugar‐Based Organogelators
  147. Selective determinants of inositol 1,4,5‐trisphosphate and adenophostin A interactions with type 1 inositol 1,4,5‐trisphosphate receptors
  148. Total syntheses of cyclitol based natural products from myo-inositol: brahol and pinpollitol
  149. Regioselective O-acylation of myo-inositol 1,3,5-orthoesters: dependence of regioselectivity on the stoichiometry of the base
  150. Activation of IP3 receptors by synthetic bisphosphate ligands
  151. ChemInform Abstract: 2‐Position Base‐Modified Analogues of Adenophostin A as High‐Affinity Agonists of the D‐myo‐Inositol Trisphosphate Receptor: In vitro Evaluation and Molecular Modeling.
  152. Efficient syntheses of optically pure chiro- and allo-inositol derivatives, azidocyclitols and aminocyclitols from myo-inositol
  153. 2-Position Base-Modified Analogues of Adenophostin A as High-Affinity Agonists of the d-myo-Inositol Trisphosphate Receptor:  In Vitro Evaluation and Molecular Modeling
  154. Strength from weakness: CH⋯π stabilized conformational tuning of benzyl ethers and a consequent co-operative edge-to-face CH⋯π network
  155. Rapid and efficient routes to phosphatidylinositol 3,4,5-trisphosphates via myo-inositol orthobenzoate
  156. Guanophostin A: Synthesis and Evaluation of a High Affinity Agonist of the D‐myo‐Inositol 1,4,5‐Triphosphate Receptor.
  157. Guanophostin A: Synthesis and evaluation of a high affinity agonist of the d-myo-inositol 1,4,5-trisphosphate receptor
  158. Establishment of the Structure of Pinpollitol (I) by Total Synthesis of the Proposed Putative Structures.
  159. Establishment of the Structure of Pinpollitol by Total Synthesis of the Proposed Putative Structure
  160. Sulfonate protecting groups. Synthesis of O- and C-methylated inositols: d- and l-ononitol, d- and l-laminitol, mytilitol and scyllo-inositol methyl ether
  161. Short SO···CO Contacts Associate Diastereomers of 2,4(6)-Di-O-benzoyl-6(4)-O-[(1S)-10-camphorsulfonyl]-myo-inositol 1,3,5-Orthoformate in Their Inclusion Complexes
  162. Efficient Routes to Optically Active Azido‐, Amino‐, Di‐azido‐ and Di‐amino‐cyclitols with chiro‐ and allo‐Configuration from myo‐Inositol.
  163. Establishment of the Structure of Pinpollitol by Total Synthesis of the Proposed Putative Structures
  164. Resolution of synthetically useful myo-inositol derivatives using the chiral auxiliary O-acetylmandelic acid
  165. O-Acetylmandelic acid as a reliable chiral anisotropy reagent for the determination of absolute configuration of alcohols
  166. Efficient routes to optically active azido-, amino-, di-azido- and di-amino-cyclitols with chiro- and allo-configuration from myo-inositol
  167. Probing Gelation at the Molecular Level: Head‐to‐Tail Hydrogen‐Bonded Self‐Assembly of an Inositol‐Based Organogelator
  168. Topochemical Transketalization Reaction Driven by Hydrogen Bonding
  169. Total Synthesis of the Proposed Structure of ′Brahol′ and the Structural Revision.
  170. Solid and solution state conformation of 1l-1-O-acetyl-2,3:5,6-di-O-isopropylidene-chiro-inositol
  171. Crystal structure of 1l-1,2:4,5-di-O-isopropylidene-allo-inositol; A comparison of its conformation in solid and solution states
  172. An efficient route to optically active inositol derivatives via the resolution of myo-inositol 1,3,5-orthoformate: a short synthesis of d-myo-inositol-4-phosphate
  173. Total synthesis of the proposed structure of `brahol' and the structural revision
  174. Crystal structure, solid state and solution conformation of 1d-1,4-di-O-[(S)-O-acetylmandeloyl]-2,3:5,6-di-O-isopropylidene-myo-inositol
  175. Regioselective Protection and Deprotection of Inositol Hydroxyl Groups
  176. Is O-acetylmandelic acid a reliable chiral anisotropy reagent?
  177. Simple and Efficient Routes to Optically Active chiro - and allo -Inositol Derivatives from myo -Inositol
  178. Regioselective Protection and Deprotection of Inositol Hydroxyl Groups
  179. A simple and practical resolution of 1,2:4,5-di-O-isopropylidene-myo-inositol
  180. Corrigendum to “Sulfonate protecting groups. Regioselective sulfonylation of myo-inositol orthoesters—improved synthesis of precursors of d- and l-myo-inositol 1,3,4,5-tetrakisphosphate, myo-inositol 1,3,4,5,6-pentakisphosphate and related derivatives”
  181. Sulfonate Protecting Groups: Synthesis of D‐ and L‐myo‐Inositol‐1,3,4,5‐tetrakisphosphate Precursors by a Novel Silver(I) Oxide‐Mediated O‐Alkylation of 2,4(6)‐Di‐O‐acyl‐6(4)‐O‐sulfonyl‐my...
  182. Sulfonate protecting groups. Regioselective sulfonylation of myo-inositol orthoesters—improved synthesis of precursors of d- and l-myo-inositol 1,3,4,5-tetrakisphosphate, myo-inositol 1,3,4,5,6-pentakisphosphate and related derivatives
  183. Cyclitol-Based Metal-Complexing Agents. Effect of the Relative Orientation of Oxygen Atoms in the Ionophoric Ring on the Cation-Binding Ability of myo-Inositol-Based Crown Ethers
  184. Silver(i) oxide–silver halide mediated alcoholysis of O-benzoyl-myo-inositol 1,3,5-orthoformates: intramolecular assistance by the sulfonyl group
  185. Neutral complexing agents with a cyclitol core. Effect of the relative orientation of the sidearms and end groups on the cation binding ability of myo-inositol based podands
  186. Sulfonate Protecting Groups. Regioselective O‐Sulfonylation of myo‐Inositol Orthoesters.
  187. Sulfonate protecting groups. Regioselective O -sulfonylation of myo -inositol orthoesters
  188. A highly selective host–guest system formed and stabilized due to concerted halogen‥oxygen and C-H‥O non-bonded interactions: X-ray structures of racemic 1,2,3,4,5-penta-O-benzoyl-6-O-tosyl myo-inositol–dihalomethane (CH2X2, X = Cl and Br) inclusion co...
  189. ChemInform Abstract: Regioselective O‐Acylation of myo‐Inositol 1,3,5‐Orthoesters: The Role of Acyl Migration.
  190. Regioselective O-acylation of myo-inositol 1,3,5-orthoesters: the role of acyl migration