What is it about?

The modulation of the structure might be explained by steric hindrance and a extensive H-bond scheme which do compete with each other.

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Why is it important?

Even though the C—H...F contacts are considered to be weak, they seem to play an important role next to the stronger N—H...O hydrogen bonds.

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This page is a summary of: N—H...O and C—H...F hydrogen bonds in the incommensurately modulated crystal structure of adamantan-1-ammonium 4-fluorobenzoate, Acta Crystallographica Section B Structural Science Crystal Engineering and Materials, July 2014, International Union of Crystallography, DOI: 10.1107/s2052520614007707.
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