What is it about?
According to the results of the experiments, it was found that the possibility of selective reduction of iron in the composition of complex oxides with carbon monoxide gas. The samples used were Brazilian mono-manganese ore rich in manganese oxide, ferromanganese ore from the Selezenskoye deposit (Russia) with a high phosphorus content and concentrate from the Zhayremsky GOK (Kazakhstan). Experiments have shown the possibility of selective reduction of iron from complex manganese ores to a metallic state not only with solid carbon, but also with carbon monoxide. According to the results of experiments at a temperature of 1000 °C in the CO atmosphere, iron and phosphorus can be selectively reduced without reducing Mn, and the use of solid carbon as a reducing agent promotes the transition of manganese to the metal part. In all experiments, the oxides of manganese, silicon, and calcium remain mainly in the oxide part.
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Why is it important?
The purpose of this work is to evaluate the possibility of separating solid-phase reduction products in a CO atmosphere to produce metal and slag with the highest possible content of manganese oxides.
Perspectives
Manganese is an important auxiliary metal for the production of steel, as it is used as a deoxidizer, alloying element and desulfurizer. In this regard, in the production of steel, manganese is used in an amount greater than any other metal except iron itself. Approximately 56 countries around the world have resources and reserves of manganese ores. It is known that the total world reserve of manganese ores is about 15.175 billion tons, the confirmed reserves are 5.268 billion tons. High-quality manganese ores are located unevenly – more than half of the rich manganese ores are located in South Africa, the Kalahari deposit, Gabon, Australia and Brazil , in these ores the concentration of manganese oxides is 40-45%. The rest of the countries have medium-and low-quality raw materials where the content of manganese is 20-30%. For example, China's manganese ores are of low quality, difficult to enrich, carbonate, with a high phosphorus content, despite this, China is the leader in the world market for the extraction of manganese ores. The quality of China's manganese ores allows it to occupy only the fifth place in the world market, with the production of standard ores with a content of (48-50% Mn). In China, more than 70% of manganese ores contain iron with a ratio ratio of less than three percent. In India, the ores are mainly of the low or medium grade with low phosphorus content, unlike other manganese deposits. In the deposits of India, there are three varieties of low-grade manganese ores, siliceous, ferruginous and alumina. In India, selective extraction of manganese ores of the best quality has been going on for decades. Kazakhstan, as well as China, has huge reserves of manganese ores, but these ores are not always suitable for smelting standard grades of manganese alloys, about 70% of them are ferromanganese. In Russia, the State Balance of mineral Reserves currently includes 21 deposits of manganese ores, but manganese ores of good quality have to be imported. The manganese ores of Russia are, in fact, complex, containing iron and manganese minerals. In addition to the separation of manganese and iron in the production of manganese alloys from such ores, the removal of phosphorus is also a problem. In this regard, according to the current technology, it is impossible to obtain standard grades of manganese ferroalloys during metallurgical processing.
Nurlybay Kosdauletov
South Ural State University
Read the Original
This page is a summary of: Evaluation of metallurgical properties of manganese ores of different genesis, January 2022, American Institute of Physics,
DOI: 10.1063/5.0074715.
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