What is it about?
Oriented gas model assumes the nonlinear optical properties to be additive. We show this assumption is invalidated even by the weak stacking interactions and propose a simple fix.
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Why is it important?
One needs to prevent molecular stacking while designing organic NLO material.
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This page is a summary of: Supramolecular step in design of nonlinear optical materials: Effect of π…π stacking aggregation on hyperpolarizability, The Journal of Chemical Physics, September 2013, American Institute of Physics,
DOI: 10.1063/1.4819265.
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