What is it about?
Simple synthesis of cyclic compounds from easily accessible pre-organised acyclic starting material.
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Why is it important?
Gives first entry into novel class of Pyrazolo[3,4-d]pyrimidinophanes: Closely related to purinophanes based on purine constituent of DNA.
Perspectives
High yield of cyclophane is direct consequence of pre-organised shape of starting material in solution without resorting to high dilution and syringe pump technique.
kamlakar avasthi
Central Drug Research Institute
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This page is a summary of: Pyrazolo[3,4-d]pyrimidinophanes: Convenient Synthesis of a New Class of Cyclophane and X-ray Structure of the First Representative, Organic Letters, October 2009, American Chemical Society (ACS),
DOI: 10.1021/ol902264t.
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