What is it about?

Formation of biaryl compounds via Suzuki-Miyaura cross coupling reactions without the use of ligands. This describes developments in Suzuki–Miyaura cross-coupling reaction, regarding a ligand-free catalysis. The catalysts outlined here enables a cleaner pathways in forming Carbon–Carbon bonds. They enable the synthesis of biaryls by coupling arylboronic acids with aryl halides.

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Why is it important?

Cost effective and greener approach in cross coupling reactions.


A literature guide for catalytic development in Suzuki Miyaura cross coupling reactions without need of ligands.

Dr Jaworski C. Capricho
Henkel AG und Co KGaA

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This page is a summary of: Synthesis of BiarylsviaLigand-Free Suzuki-Miyaura Cross-Coupling Reactions: A Review of Homogeneous and Heterogeneous Catalytic Developments, September 2016, Wiley,
DOI: 10.1002/adsc.201600354.
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