All Stories

  1. Synthesis and DPPH radical scavenging activity of novel compounds obtained from tyrosol and cinnamic acid derivatives

    Article • New Journal of Chemistry, January 2014, Royal Society of Chemistry

    Professor Roberta Bernini, Dr Gentili Patrizia

  2. Unexpected different chemoselectivity in the aerobic oxidation of methylated planar catechin and bent epicatechin derivatives catalysed by the Trametes villosa laccase/1-hydroxybenzotriazole system

    Article • RSC Advances, January 2014, Royal Society of Chemistry

    Professor Marco Pierini, Professor Roberta Bernini, Dr Gentili Patrizia

  3. Concerted Electron/Proton Transfer Mechanism in the Oxidation of Phenols by Laccase

    Article • ChemBioChem, October 2013, Wiley

    Dr Gentili Patrizia

  4. ChemInform Abstract: A Remarkably Simple α-Oximation of Aldehydes via Organo-SOMO Catalysis.

    Article • ChemInform, September 2012, Wiley

    Dr Gentili Patrizia

  5. Convenient Synthesis of 1-Aryl-dihydroxyisochromans Exhibiting Antioxidant Activity

    Article • Current Organic Chemistry, April 2012, Bentham Science Publishers

    Dr Gentili Patrizia

  6. A remarkably simple α-oximation of aldehydes via organo-SOMO catalysis

    Article • Chemical Communications, January 2012, Royal Society of Chemistry

    Dr Gentili Patrizia

  7. The Rabe amination after a century: direct addition of N-heterocycles to carbonyl compounds

    Article • Organic & Biomolecular Chemistry, January 2012, Royal Society of Chemistry

    Dr Gentili Patrizia

  8. Hydrogen abstraction from H-donor substrates by the 6-CF3-benzotriazol-N-oxyl radical (TFNO)

    Article • Journal of Physical Organic Chemistry, September 2010, Wiley

    Dr Gentili Patrizia

  9. ChemInform Abstract: An Oxidation of Alcohols by Oxygen with the Enzyme Laccase and Mediation by TEMPO.

    Article • ChemInform, May 2010, Wiley

    Dr Gentili Patrizia

  10. ChemInform Abstract: Hydrogen Abstraction and Electron Transfer with Aminoxyl Radicals: Synthetic and Mechanistic Issues

    Article • ChemInform, October 2008, Wiley

    Dr Gentili Patrizia

  11. Hydrogen Abstraction and Electron Transfer with Aminoxyl Radicals: Synthetic and Mechanistic Issues

    Article • Angewandte Chemie International Edition, June 2008, Wiley

    Dr Gentili Patrizia

  12. Phenolic compounds as likely natural mediators of laccase: A mechanistic assessment

    Article • Journal of Molecular Catalysis B Enzymatic, April 2008, Elsevier

    Dr Gentili Patrizia

  13. An assessment of the relative contributions of redox and steric issues to laccase specificity towards putative substrates

    Article • Organic & Biomolecular Chemistry, January 2008, Royal Society of Chemistry

    Dr Gentili Patrizia, Ph.D Alessandro D'Annibale

  14. Oxidation of amides by laccase-generated aminoxyl radicals

    Article • Journal of Molecular Catalysis B Enzymatic, January 2008, Elsevier

    Dr Gentili Patrizia

  15. Chemoselective and efficient carbomethoxylation of the alcoholic chain of phenols by dimethyl carbonate (DMC)

    Article • Tetrahedron Letters, September 2007, Elsevier

    Dr Gentili Patrizia

  16. Oxidation of phenols employing polyoxometalates as biomimetic models of the activity of phenoloxidase enzymes

    Article • New Journal of Chemistry, January 2007, Royal Society of Chemistry

    Dr Gentili Patrizia

  17. Stereoelectronic effects in radical processes

    Article • Journal of Physical Organic Chemistry, January 2006, Wiley

    Dr Gentili Patrizia

  18. Kinetic Study of the Hydrogen Abstraction Reaction of the Benzotriazole- N -oxyl Radical (BTNO) with H-Donor Substrates

    Article • The Journal of Organic Chemistry, November 2005, American Chemical Society (ACS)

    Dr Gentili Patrizia

  19. Kinetics of oxidation of benzyl alcohols by the dication and radical cation of ABTS. Comparison with laccase–ABTS oxidations: an apparent paradox

    Article • Organic & Biomolecular Chemistry, January 2005, Royal Society of Chemistry

    Dr Gentili Patrizia

  20. Chemical messengers: mediated oxidations with the enzyme laccase

    Article • Journal of Physical Organic Chemistry, July 2004, Wiley

    Dr Gentili Patrizia

  21. Oxidation of Non-Phenolic Substrates with the Laccase/N-Hydroxyacetanilide System: Structure of the Key Intermediate from the Mediator and Mechanistic Insight.

    Article • ChemInform, June 2004, Wiley

    Dr Gentili Patrizia

  22. Oxidation of non-phenolic substrates with the laccase/N-hydroxyacetanilide system: Structure of the key intermediate from the mediator and mechanistic insight

    Article • New Journal of Chemistry, January 2004, Royal Society of Chemistry

    Dr Gentili Patrizia

  23. Free radical versus electron-transfer routes of oxidation of hydrocarbons by laccase/mediator systems

    Article • Journal of Molecular Catalysis B Enzymatic, June 2003, Elsevier

    Dr Gentili Patrizia

  24. Promoting laccase activity towards non-phenolic substrates: a mechanistic investigation with some laccase–mediator systems

    Article • Organic & Biomolecular Chemistry, January 2003, Royal Society of Chemistry

    Dr Gentili Patrizia

  25. Radical or electron-transfer mechanism of oxidation with some laccase/mediator systems

    Article • Journal of Molecular Catalysis B Enzymatic, September 2002, Elsevier

    Dr Gentili Patrizia

  26. Reactivity of Aryl and Vinyl Radicals: Abstraction of Hydrogen Atom or Reaction with a Nucleophile

    Article • European Journal of Organic Chemistry, August 2002, Wiley

    Dr Gentili Patrizia

  27. A Search for Unambiguous Vinylic SRN1 Reactions

    Article • European Journal of Organic Chemistry, July 2002, Wiley

    Dr Gentili Patrizia

  28. Comparing the catalytic efficiency of some mediators of laccase

    Article • Journal of Molecular Catalysis B Enzymatic, February 2002, Elsevier

    Dr Gentili Patrizia

  29. A radical route in the biomimetic oxidation of a tertiary amine

    Article • Journal of Physical Organic Chemistry, January 2002, Wiley

    Dr Gentili Patrizia

  30. An oxidation of alcohols by oxygen with the enzyme laccase and mediation by TEMPO

    Article • Tetrahedron Letters, October 2001, Elsevier

    Dr Gentili Patrizia

  31. Aromatic iodination: a new investigation on the nature of the mechanism†

    Article • Journal of the Chemical Society Perkin Transactions 2, January 2001, Royal Society of Chemistry

    Dr Gentili Patrizia

  32. Competition of Mechanisms in the Photochemical Cleavage of the C−X Bond of Aryl-Substituted Vinyl Halides

    Article • The Journal of Organic Chemistry, December 1998, American Chemical Society (ACS)

    Dr Gentili Patrizia

  33. Competition of Mechanisms in Nucleophilic Substitution of Vinyl Halides. An Unequivocal Example of the Vinylic SRN1 Route1

    Article • The Journal of Organic Chemistry, November 1994, American Chemical Society (ACS)

    Dr Gentili Patrizia

  34. Alkynylic SRN 1 reaction: feasible or not?

    Article • Journal of the Chemical Society Chemical Communications, January 1994, Royal Society of Chemistry

    Dr Gentili Patrizia

  35. A new insight into the SRN1 vinylic substitution

    Article • Journal of the Chemical Society Chemical Communications, January 1993, Royal Society of Chemistry

    Dr Gentili Patrizia

  36. Catalysis by ferrous ion in nucleophilic aromatic substitution reactions

    Article • Journal of the Chemical Society Perkin Transactions 2, January 1993, Royal Society of Chemistry

    Dr Gentili Patrizia