All Stories

  1. A chromatographic study on the retention behavior of the amylose tris(3-chloro-5-methylphenylcarbamate) chiral stationary phase under aqueous conditions

    Article • Journal of Separation Science, October 2018, Wiley

    Professor Marco Pierini

  2. Enantiomers of triclabendazole sulfoxide: Analytical and semipreparative HPLC separation, absolute configuration assignment, and transformation into sodium salt

    Article • Journal of Pharmaceutical and Biomedical Analysis, June 2017, Elsevier

    Professor Marco Pierini

  3. 3-(Phenyl-4-oxy)-5-phenyl-4,5-dihydro-(1 H )-pyrazole: A fascinating molecular framework to study the enantioseparation ability of the amylose (3,5-dimethylphenylcarbamate) chiral stationary phase. Part II. Solvophobic effects in enantiorecognition pro...

    Article • Journal of Chromatography A, April 2017, Elsevier

    Professor Marco Pierini

  4. BITHIENOLs: PromisingC2-Symmetric Biheteroaromatic Diols for Organic Transformation

    Article • European Journal of Organic Chemistry, January 2017, Wiley

    Professor Marco Pierini

  5. “Inherently Chiral” Ionic-Liquid Media: Effective Chiral Electroanalysis on Achiral Electrodes

    Article • Angewandte Chemie International Edition, January 2017, Wiley

    Professor Marco Pierini

  6. 3-(Phenyl-4-oxy)-5-phenyl-4,5-dihydro-(1H)-pyrazole: A fascinating molecular framework to study the enantioseparation ability of the amylose (3,5-dimethylphenylcarbamate) chiral stationary phase. Part I. Structure-enantioselectivity relationships

    Article • Journal of Chromatography A, October 2016, Elsevier

    Professor Marco Pierini

  7. Synthetic Strategies to Serine-Proline Chimeras: An Overview

    Article • Current Bioactive Compounds, June 2016, Bentham Science Publishers

    Professor Marco Pierini

  8. Elucidation of the mechanisms governing the thermal diastereomerization of bioactive chiral 1,3,4-thiadiazoline spiro-cyclohexyl derivatives towards their anancomeric stereoisomers

    Article • RSC Advances, January 2016, Royal Society of Chemistry

    Professor Marco Pierini

  9. Ultra-fast high-efficiency enantioseparations by means of a teicoplanin-based chiral stationary phase made on sub-2μm totally porous silica particles of narrow size distribution

    Article • Journal of Chromatography A, January 2016, Elsevier

    Professor Marco Pierini, Claudio Villani

  10. The Anancomeric Character of the Pharmacophore 1,3,4-Thiadiazoline Framework in Chiral Spiro-Cyclohexyl Derivatives: Effects on Stereochemistry and Spiro-Junction Lability. Thermodynamic Aspects

    Article • The Journal of Organic Chemistry, December 2015, American Chemical Society (ACS)

    Professor Marco Pierini

  11. Electrochemistry and Chirality in Bibenzimidazole Systems

    Article • Electrochimica Acta, October 2015, Elsevier

    Professor Marco Pierini

  12. Determination of the Enantiomerization Barrier of the Residual Enantiomers ofC3-Symmetric Tris[3-(1-Methyl-2-Alkyl)Indolyl]Phosphane Oxides: Case Study of a Multitasking HPLC Investigation Based on an Immobilized Polysaccharide Stationary Phase

    Article • Chirality, September 2015, Wiley

    Professor Marco Pierini

  13. Stereolability of Chiral Ruthenium Catalysts With Frozen NHC Ligand Conformations Investigated by Dynamic-HPLC

    Article • Chirality, August 2015, Wiley

    Professor Marco Pierini

  14. Dynamic high performance liquid chromatography on chiral stationary phases. Low temperature separation of the interconverting enantiomers of diazepam, flunitrazepam, prazepam and tetrazepam

    Article • Journal of Chromatography A, October 2014, Elsevier

    Professor Marco Pierini, Claudio Villani

  15. Influence of the nature of alkyl substituents on the high-performance liquid chromatography enantioseparation and retention of new atropisomeric 1,1′-bibenzimidazole derivatives on amylose tris(3,5-dimethylphenylcarbamate) chiral stationary phase

    Article • Journal of Chromatography A, October 2014, Elsevier

    Professor Marco Pierini

  16. ChemInform Abstract: Ph‐tetraMe‐Bithienine, the First Member of the Class of Chiral Heterophosphepines: Synthesis, Electronic and Steric Properties, Metal Complexes and Catalytic Activity.

    Article • ChemInform, May 2014, Wiley

    Professor Marco Pierini

  17. Chirality in the Absence of Rigid Stereogenic Elements: Steric and Electronic Effects on the Configurational Stability of C3 Symmetric Residual Tris‐Aryl Phosphanes

    Article • Chirality, March 2014, Wiley

    Professor Marco Pierini

  18. Potential‐Driven Chirality Manifestations and Impressive Enantioselectivity by Inherently Chiral Electroactive Organic Films

    Article • Angewandte Chemie, February 2014, Wiley

    Professor Marco Pierini

  19. Potential‐Driven Chirality Manifestations and Impressive Enantioselectivity by Inherently Chiral Electroactive Organic Films

    Article • Angewandte Chemie International Edition, February 2014, Wiley

    Professor Marco Pierini

  20. Unexpected different chemoselectivity in the aerobic oxidation of methylated planar catechin and bent epicatechin derivatives catalysed by the Trametes villosa laccase/1-hydroxybenzotriazole system

    Article • RSC Advances, January 2014, Royal Society of Chemistry

    Professor Marco Pierini, Professor Roberta Bernini, Dr Gentili Patrizia

  21. Thermodynamic and kinetic investigation of monoketo-aldehyde-peroxyhemiacetal (MKA), a stereolabile degradation product of dihydroartemisinin

    Article • RSC Advances, January 2014, Royal Society of Chemistry

    Professor Marco Pierini, Claudio Villani, Professor Walter Cabri

  22. Ph‐tetraMe‐Bithienine, the First Member of the Class of Chiral Heterophosphepines: Synthesis, Electronic and Steric Properties, Metal Complexes and Catalytic Activity

    Article • European Journal of Organic Chemistry, November 2013, Wiley

    Professor Marco Pierini

  23. Reaction of Nitrosonium Cation with Resorc[4]arenes Activated by Supramolecular Control: Covalent Bond Formation

    Article • The Journal of Organic Chemistry, July 2013, American Chemical Society (ACS)

    Professor Marco Pierini

  24. Chiral Supramolecular Selectors for Enantiomer Differentiation in Liquid Chromatography

    Article • January 2013, Springer Science + Business Media

    Professor Marco Pierini, Claudio Villani

  25. Corrigendum: Steric and Electronic Effects on the Configurational Stability of Residual Chiral Phosphorus‐Centered Three‐Bladed Propellers: Tris‐aryl Phosphanes

    Article • Chemistry - A European Journal, December 2012, Wiley

    Professor Marco Pierini

  26. 3-Methylcyclohexanone thiosemicarbazone: Determination of E/Z isomerization barrier by dynamic high-performance liquid chromatography, configuration assignment and theoretical study of the mechanisms involved by the spontaneous, acid and base catalyzed...

    Article • Journal of Chromatography A, December 2012, Elsevier

    Professor Marco Pierini

  27. Steric and Electronic Effects on the Configurational Stability of Residual Chiral Phosphorus‐Centered Three‐Bladed Propellers: Tris‐aryl Phosphane Oxides

    Article • Chemistry - A European Journal, November 2012, Wiley

    Professor Marco Pierini

  28. Steric and Electronic Effects on the Configurational Stability of Residual Chiral Phosphorus‐Centered Three‐Bladed Propellers: Tris‐aryl Phosphanes

    Article • Chemistry - A European Journal, November 2012, Wiley

    Professor Marco Pierini

  29. 2-(Alkyl/Aryl)Amino-6-Benzylpyrimidin-4(3H)-ones as Inhibitors of Wild-Type and Mutant HIV-1: Enantioselectivity Studies

    Article • Journal of Medicinal Chemistry, March 2012, American Chemical Society (ACS)

    Professor Marco Pierini

  30. Effect of Ring Size on the Tautomerization and Ionization Reaction of Cyclic 2-Nitroalkanones: An Experimental and Theoretical Study

    Article • The Journal of Organic Chemistry, January 2012, American Chemical Society (ACS)

    professor Antonella Fontana, Professor Marco Pierini

  31. The dynamic chromatographic behavior of tri-o-thymotide on HPLC chiral stationary phases

    Article • Chemical Communications, January 2012, Royal Society of Chemistry

    Professor Marco Pierini, Claudio Villani

  32. Absolute configuration and biological profile of two thiazinooxadiazol-3-ones with L-type calcium channel activity: a study of the structural effects

    Article • Organic & Biomolecular Chemistry, January 2012, Royal Society of Chemistry

    Professor Marco Pierini

  33. Erratum to “Efficient organic monoliths prepared by γ-radiation induced polymerization in the evaluation of histone deacetylase inhibitors by capillary(nano)-high performance liquid chromatography and ion trap mass spectrometry” [J. Chromatogr. A 1218 ...

    Article • Journal of Chromatography A, December 2011, Elsevier

    Professor Marco Pierini, Claudio Villani, Professor Walter Cabri

  34. Inductive and Mesomeric Effects of the [60]Fulleropyrrolidine Fragment and [60]Fullerene Sphere: A Quantitative Evaluation Based on Theory and Experiments

    Article • European Journal of Organic Chemistry, November 2011, Wiley

    professor Antonella Fontana, Professor Marco Pierini, Claudio Villani

  35. NMR and Computational Investigations of the Chiral Discrimination Processes Involving a Cyclic Tetraamidic Chiral Selector

    Article • European Journal of Organic Chemistry, June 2011, Wiley

    Professor Marco Pierini, Claudio Villani

  36. Efficient organic monoliths prepared by γ-radiation induced polymerization in the evaluation of histone deacetylase inhibitors by capillary(nano)-high performance liquid chromatography and ion trap mass spectrometry

    Article • Journal of Chromatography A, June 2011, Elsevier

    Professor Marco Pierini, Claudio Villani, Professor Walter Cabri

  37. Facial control of gas-phase enantioselectivity of strapped tetra-amide macrocycles

    Article • RENDICONTI LINCEI, May 2011, Springer Science + Business Media

    Professor Marco Pierini, Claudio Villani

  38. Stereolability of Dihydroartemisinin, an Antimalarial Drug: A Comprehensive Kinetic Investigation. Part 2

    Article • The Journal of Organic Chemistry, May 2011, American Chemical Society (ACS)

    Professor Marco Pierini, Claudio Villani, Professor Walter Cabri

  39. Correction to Chemoselective C-4 Aerobic Oxidation of Catechin Derivatives Catalyzed by the Trametes villosa Laccase/1-Hydroxybenzotriazole System: Synthetic and Mechanistic Aspects

    Article • The Journal of Organic Chemistry, April 2011, American Chemical Society (ACS)

    Professor Marco Pierini

  40. Stereolability of Dihydroartemisinin, an Antimalarial Drug: A Comprehensive Thermodynamic Investigation. Part 1

    Article • The Journal of Organic Chemistry, February 2011, American Chemical Society (ACS)

    Professor Marco Pierini, Claudio Villani, Professor Walter Cabri

  41. The “Bridge” Game: Role of the Fourth Player in Chiral Recognition

    Article • Chemistry - A European Journal, February 2011, Wiley

    Professor Marco Pierini, Claudio Villani

  42. Chemoselective C-4 Aerobic Oxidation of Catechin Derivatives Catalyzed by the Trametes villosa Laccase/1-Hydroxybenzotriazole System: Synthetic and Mechanistic Aspects

    Article • The Journal of Organic Chemistry, January 2011, American Chemical Society (ACS)

    Professor Marco Pierini

  43. An effective multipurpose building block for 3D electropolymerisation: 2,2′-Bis(2,2′-bithiophene-5-yl)-3,3′-bithianaphthene

    Article • Electrochimica Acta, November 2010, Elsevier

    Professor Marco Pierini

  44. Enantioselective HPLC combined with spectroscopic methods: A valid strategy to determine the absolute configuration of potential β-secretase inhibitors

    Article • Talanta, September 2010, Elsevier

    Professor Marco Pierini

  45. Stereomutation of Axially Chiral Aryl Coumarins

    Article • The Journal of Organic Chemistry, August 2010, American Chemical Society (ACS)

    Professor Marco Pierini

  46. Basicity of Pyridine and Some Substituted Pyridines in Ionic Liquids

    Article • The Journal of Organic Chemistry, May 2010, American Chemical Society (ACS)

    professor Antonella Fontana, Professor Marco Pierini, Professor Cinzia Chiappe

  47. Stereodynamic Investigation of Labile Stereogenic Centres in Dihydroartemisinin

    Article • Molecules, March 2010, MDPI AG

    Professor Marco Pierini, Claudio Villani, Professor Walter Cabri

  48. Transition from enantioselective high performance to ultra-high performance liquid chromatography: A case study of a brush-type chiral stationary phase based on sub-5-micron to sub-2-micron silica particles

    Article • Journal of Chromatography A, February 2010, Elsevier

    Professor Marco Pierini, Claudio Villani

  49. Perturbing Effects of Chiral Stationary Phase on Enantiomerization Second-Order Rate Constants Determined by Enantioselective Dynamic High-Performance Liquid Chromatography: A Practical Tool to Quantify the Accessible Acid and Basic Catalytic Sites Bon...

    Article • Analytical Chemistry, March 2009, American Chemical Society (ACS)

    Professor Marco Pierini, Roberto Di Santo

  50. Towards enzyme-like enantioselectivity in the gas phase: conformational control of selectivity in chiral macrocyclic dimers

    Article • Chemical Communications, January 2009, Royal Society of Chemistry

    Claudio Villani, Professor Marco Pierini

  51. Gas-phase structure and relative stability of proton-bound homo- and heterochiral clusters of tetra-amide macrocycles with amines

    Article • Collection of Czechoslovak Chemical Communications, January 2009, Institute of Organic Chemistry & Biochemistry

    Professor Marco Pierini, Claudio Villani

  52. Dynamic HPLC of stereolabile iron(II) complexes on chiral stationary phases

    Article • Chirality, July 2008, Wiley

    Professor Marco Pierini, Claudio Villani

  53. Enantiomerization of Chiral Uranyl−Salophen Complexes via Unprecedented Ligand Hemilability: Toward Configurationally Stable Derivatives

    Article • The Journal of Organic Chemistry, July 2008, American Chemical Society (ACS)

    Professor Marco Pierini, Professor Antonella Dalla Cort

  54. Synthesis of Amino and Ammonium Resorcin[4]arenes as Potential Receptors

    Article • Synthesis, July 2008, Thieme Publishing Group

    Professor Marco Pierini

  55. A rational approach to predict and modulate stereolability of chiral α substituted ketones

    Article • Chirality, June 2008, Wiley

    Professor Marco Pierini, Roberto Di Santo

  56. Solvent effects on the rate of the keto–enol interconversion of 2-nitrocyclohexanone

    Article • Organic & Biomolecular Chemistry, January 2008, Royal Society of Chemistry

    professor Antonella Fontana, Professor Marco Pierini

  57. HPLC Chiral Stationary Phases Containing Macrocyclic Antibiotics

    Article • November 2007, Taylor & Francis

    Professor Marco Pierini, Claudio Villani

  58. Nitrosonium Complexes of Resorc[4]arenes:  Spectral, Kinetic, and Theoretical Studies

    Article • Journal of the American Chemical Society, August 2007, American Chemical Society (ACS)

    Professor Marco Pierini

  59. Ionization and Tautomerization of 2-Nitrocyclohexanone in Aqueous Solution

    Article • The Journal of Organic Chemistry, April 2007, American Chemical Society (ACS)

    professor Antonella Fontana, Professor Marco Pierini

  60. Dynamic HPLC on Chiral Stationary Phases: A Powerful Tool for the Investigation of Stereomutation Processes

    Article • ChemInform, January 2007, Wiley

    Professor Marco Pierini, Claudio Villani

  61. Dynamic HPLC on chiral stationary phases: A powerful tool for the investigation of stereomutation processes

    Article • Journal of Separation Science, July 2006, Wiley

    Professor Marco Pierini, Claudio Villani

  62. Stereomutations of Atropisomers of Sterically Hindered Salophen Ligands.

    Article • ChemInform, January 2006, Wiley

    Professor Marco Pierini

  63. Stereomutations of Atropisomers of Sterically Hindered Salophen Ligands

    Article • The Journal of Organic Chemistry, September 2005, American Chemical Society (ACS)

    Professor Marco Pierini, Professor Antonella Dalla Cort

  64. Determination of the Polarities of Some Ionic Liquids Using 2-Nitrocyclohexanone as the Probe

    Article • The Journal of Organic Chemistry, September 2005, American Chemical Society (ACS)

    professor Antonella Fontana, Professor Marco Pierini, Professor Cinzia Chiappe

  65. Exceptional Gas-Phase Enantioselectivity of Chiral Tetramide Macrocycles

    Article • Journal of the American Chemical Society, August 2005, American Chemical Society (ACS)

    Professor Marco Pierini, Claudio Villani

  66. The Associative Properties of Some Amphiphilic Fullerene Derivatives

    Article • European Journal of Organic Chemistry, April 2005, Wiley

    professor Antonella Fontana, Professor Marco Pierini, Claudio Villani

  67. An Effective Simulation of Aqueous Micellar Aggregates by Computational Models

    Article • Journal of Computer-Aided Molecular Design, April 2005, Springer Science + Business Media

    Professor Marco Pierini, Claudio Villani

  68. Enantiomers of C5‐chiral 1‐acetyl‐3,5‐diphenyl‐4,5‐dihydro‐(1H)‐pyrazole derivatives: Analytical and semipreparative HPLC separation, chiroptical properties, absolute configuration, and inhibitory activity against monoamine oxidase

    Article • Chirality, January 2004, Wiley

    Professor Marco Pierini

  69. Natural and Totally Synthetic Receptors in the Innovative Design of HPLC Chiral Stationary Phases

    Article • ChemInform, September 2003, Wiley

    Professor Marco Pierini

  70. Enantiomerization Study of Some α-Nitroketones by Dynamic High-Resolution Gas Chromatography

    Article • The Journal of Organic Chemistry, March 2003, American Chemical Society (ACS)

    professor Antonella Fontana, Professor Marco Pierini, Claudio Villani

  71. A Chiral A2B2 Macrocyclic Minireceptor with Extreme Enantioselectivity

    Article • Organic Letters, October 2002, American Chemical Society (ACS)

    Professor Marco Pierini, Claudio Villani

  72. Asymmetric synthesis of (S)-ibuprofen by esterification with amides of (S)-lactic acid as chiral auxiliaries: experimental and theoretical results

    Article • Tetrahedron Letters, June 2002, Elsevier

    Professor Marco Pierini, Dr Letizia Giampietro

  73. Conformational Studies by Dynamic NMR. 89.1 Stereomutation and Cryogenic Enantioseparation of Conformational Antipodes of Hindered Aryl Oximes

    Article • The Journal of Organic Chemistry, March 2002, American Chemical Society (ACS)

    Professor Marco Pierini

  74. Ab initio analysis on metal ion catalysis in the enolization reactions of some acetylheterocycles: kinetics of the enolization reactions of 3‐acetyl‐5‐methylisoxazole, 5‐acetyl‐3‐methylisoxazole and 3(5)‐acetylpyrazole

    Article • Journal of Physical Organic Chemistry, February 2002, Wiley

    professor Antonella Fontana, Professor Marco Pierini

  75. Conformational Studies by Dynamic NMR. 86.1Structure, Stereodynamics, and Cryogenic Enantioseparation of the Stereolabile Isomers ofo-Dinaphthylphenyl Derivatives

    Article • The Journal of Organic Chemistry, February 2002, American Chemical Society (ACS)

    Professor Marco Pierini, Claudio Villani

  76. Enantioselective semi-preparative HPLC of two 2-arylpropionic acids on glycopeptides containing chiral stationary phases

    Article • Tetrahedron Asymmetry, February 2002, Elsevier

    Professor Marco Pierini, Claudio Villani

  77. Chromatographic resolution and enantiomerization barriers of axially chiral 1-naphthamides

    Article • Journal of Separation Science, December 2001, Wiley

    Professor Marco Pierini, Claudio Villani

  78. Study of the Aggregation Properties of a Novel Amphiphilic C60 Fullerene Derivative

    Article • Langmuir, September 2001, American Chemical Society (ACS)

    professor Antonella Fontana, Professor Marco Pierini

  79. Stereoselective synthesis of 2-substituted 3-azabicyclo[3.2.0]heptan-2-ones by [2+2]-cycloaddition of N -allyl-β- N -keteniminium salts derived from ( R )-vinylglycinol

    Article • Tetrahedron Asymmetry, July 2000, Elsevier

    Professor Marco Pierini

  80. Equilibrium Constants for Ionisation and Enolisation of 3-Nitrobutan-2-one

    Article • European Journal of Organic Chemistry, April 2000, Wiley

    Professor Marco Pierini, professor Antonella Fontana

  81. Die Unterscheidung von Enantiomeren chiraler Moleküle in der Gasphase: Nachweis der chiralen Erkennung bei der Bildung von 1‐Phenyl‐1‐propanol/2‐Butanol‐Clustern mit resonant erhöhter Multiphotonen‐Ionisierungs‐Spektroskopie

    Article • Angewandte Chemie, August 1997, Wiley

    Professor Marco Pierini

  82. Enantiomerization barriers by dynamic HPLC. Stationary phase effects

    Article • Tetrahedron Asymmetry, June 1997, Elsevier

    Professor Marco Pierini, Claudio Villani

  83. Enantioselective chromatography on brush-type chiral stationary phases containing totally synthetic selectors theoretical aspects and practical applications

    Article • Journal of Chromatography A, February 1996, Elsevier

    Professor Marco Pierini, Claudio Villani