All Stories

  1. Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent
  2. Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer: a highly efficient catalyst for biomimetic oxygenation reactions
  3. Hypoiodite-Mediated Catalytic Cyclopropanation of Alkenes with Malononitrile
  4. Development of new hypervalent iodine reagents with improved properties and reactivity by redirecting secondary bonds at iodine center
  5. Synthesis of 1,2,4-Thiadiazoles by Oxidative Dimerization of Carbothioamides by Using Oxone
  6. The IX (X=O,N,C) Double Bond in Hypervalent Iodine Compounds: Is it Real?
  7. The IX (X=O,N,C) Double Bond in Hypervalent Iodine Compounds: Is it Real?
  8. Hypoiodite-Mediated Cyclopropanation of Alkenes
  9. Hypervalent Iodine Chemistry
  10. Hypervalent Iodine Catalyzed Generation of Nitrile Oxides from Oximes and their Cycloaddition with Alkenes or Alkynes
  11. Preparation and X-ray Structural Study of 1-Arylbenziodoxolones
  12. Hypoiodite mediated synthesis of isoxazolines from aldoximes and alkenes using catalytic KI and Oxone as the terminal oxidant
  13. 2-Iodoxybenzoic acid organosulfonates: preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(v) oxidants
  14. Hypervalent Iodine Catalyzed Hofmann Rearrangement of Carboxamides Using Oxone as Terminal Oxidant
  15. Iodosylbenzene
  16. Potassium 4-Iodylbenzenesulfonate: Preparation, Structure, and Application as a Reagent for Oxidative Iodination of Arenes
  17. Hypoiodite-Mediated Metal-Free Catalytic Aziridination of Alkenes
  18. Hypoiodite-Mediated Metal-Free Catalytic Aziridination of Alkenes
  19. Design, Preparation, X-ray Crystal Structure, and Reactivity of o -Alkoxyphenyliodonium Bis(methoxycarbonyl)methanide, a Highly Soluble Carbene Precursor
  20. Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: a convenient recyclable reagent for catalytic oxidation
  21. (Tosylimino)phenyl-λ 3 -iodane as a Reagent for the Synthesis of Methyl Carbamates via Hofmann Rearrangement of Aromatic and Aliphatic Carboxamides
  22. New highly soluble dimedone-derived iodonium ylides: preparation, X-ray structure, and reaction with carbodiimide leading to oxazole derivatives
  23. Preparation and X-ray Crystal Study of Benziodoxaborole Derivatives: New Hypervalent Iodine Heterocycles
  24. Recyclable silica-supported iodoarene–RuCl3 bifunctional catalysts for oxidation of alcohols and alkylarenes
  25. o‐ Alkoxyphenyliminoiodanes: Highly Efficient Reagents for the Catalytic Aziridination of Alkenes and the Metal‐Free Amination of Organic Substrates
  26. Preparation and Reactivity of Polystyrene-Supported Iodosylbenzene: Convenient Recyclable Oxidizing Reagent and Catalyst
  27. Preparation, X-ray Structure, and Reactivity of 2-Iodylpyridines: Recyclable Hypervalent Iodine(V) Reagents
  28. Facile preparation and reactivity of polystyrene-supported (dichloroiodo)benzene: a convenient recyclable reagent for chlorination and oxidation
  29. Organoiodine(V) Reagents in Organic Synthesis
  30. SiO2-supported RuCl3/3-(dichloroiodo)benzoic acid: green catalytic system for the oxidation of alcohols and sulfides in water
  31. Binuclear iron(III) phthalocyanine(μ-oxodimer)/tetrabutylammonium oxone: a powerful catalytic system for oxidation of hydrocarbons in organic solution
  32. Preparation and Reactivity of Polystyrene-Supported Iodosylbenzene Sulfate: An Efficient Recyclable Oxidizing System
  33. Hofmann Rearrangement of Carboxamides Mediated by Hypervalent Iodine Species Generated in Situ from Iodobenzene and Oxone: Reaction Scope and Limitations
  34. m-Iodosylbenzoic Acid as a Convenient Recyclable Hypervalent Iodine Oxidant for the Synthesis of α-Iodo Ketones by Oxidative Iodination of Ketones
  35. Transition metal-mediated oxidations utilizing monomeric iodosyl- and iodylarene species
  36. Development of new recyclable reagents and catalytic systems based on hypervalent iodine compounds
  37. Metalloporphyrin/Iodine(III)-Cocatalyzed Oxygenation of Aromatic Hydrocarbons
  38. A General and Convenient Preparation of [Bis(trifluoroacetoxy)iodo]perfluoroalkanes and [Bis(trifluoroacetoxy)iodo]arenes by Oxidation of Organic Iodides Using Oxone and Trifluoroacetic Acid
  39. Overview
  40. Structure of Small and Large Rings
  41. Reactivity of Six-membered Rings
  42. Structure of Six-membered Rings
  43. Reactivity of Five-Membered Rings with One Heteroatom
  44. Reactivity of Small and Large Rings
  45. Synthesis of Monocyclic Rings with One Heteroatom
  46. Synthesis of Monocyclic Rings with Two or More Heteroatoms
  47. Synthesis of Bicyclic Ring Systems Without Ring Junction Heteroatoms
  48. Structure of Five-Membered Rings with One Heteroatom
  49. Synthesis of Fused Ring Systems with Ring Junction Heteroatoms
  50. Structure of Five-membered Rings with Two or More Heteroatoms
  51. Reactivity of Five-membered Rings with Two or More Heteroatoms
  52. Synthesis of Tri- and Polycyclic Ring Systems Without Ring Junction Heteroatoms
  53. Foreword
  54. Preparation, X-ray Structure, and Oxidative Reactivity of N -(2-Iodylphenyl)tosylamides and 2-Iodylphenyl Tosylate: Iodylarenes Stabilized by Ortho-Substitution with a Sulfonyl Group
  55. Iodine(V)/Ruthenium(III)-Cocatalyzed Oxidations: A Highly Efficient Tandem Catalytic System for the Oxidation of Alcohols and Hydrocarbons with Oxone
  56. Oligomeric Iodosylbenzene Sulfate: A Convenient Hypervalent Iodine Reagent for Oxidation of Organic Sulfides and Alkenes
  57. Self-Assembly of Hydroxy(phenyl)iodonium Ions in Acidic Aqueous Solution: Preparation, and X-ray Crystal Structures of Oligomeric Phenyliodine(III) Sulfates
  58. Comparative Reactivity of Hypervalent Iodine Oxidants in Metalloporphyrin-Catalyzed Oxygenation of Hydrocarbons: Iodosylbenzene Sulfate and 2-Iodylbenzoic Acid Ester as Safe and Convenient Alternatives to Iodosylbenzene
  59. Hypervalent iodine(III) reagents in organic synthesis
  60. Chemistry of Polyvalent Iodine
  61. Organic iodine(V) compounds as terminal oxidants in iron(III) phthalocyanine catalyzed oxidation of alcohols
  62. Synthesis of Tricyclic Phosphonopyrrolidines via IMDAF: Experimental and Theoretical Investigation of the Observed Stereoselectivity
  63. Heptadecafluorooctyl[bis(trifluoroacetoxy)]iodine
  64. Preparation and X-ray crystal structure of 2-iodyl-N,N-dialkylaniline oxides: first entry into the heterocyclic system of benziodoxazole
  65. Preparation and X-ray Structures of 3-[Bis(trifluoroacetoxy)iodo]benzoic Acid and 3-[Hydroxy(tosyloxy)iodo]benzoic Acid:  New Recyclable Hypervalent Iodine Reagents
  66. Oxidation by Polymer-Supported 2-Iodylphenol Ethers
  67. A copper-catalyzed domino radical cyclization route to benzospiro-indolizidinepyrrolidinones
  68. Preparation and Reactivity of Polymer-Supported 2-Iodylphenol Ethers, an Efficient Recyclable Oxidizing System
  69. Iodosylbenzene
  70. Practical synthesis and applications of benzoboroxoles
  71. Preparation and Structure of Oligomeric Iodosylbenzene Sulfate (PhIO)3·SO3: Stable and Water-Soluble Analog of Iodosylbenzene
  72. N-(2-Iodylphenyl)acylamides — New Pentavalent Iodine Oxidizing Reagents
  73. Oxidation of Alcohols with RuCl 3 and m -Iodobenzoic Acid
  74. Solvent‐Free Iodination of Arenes using Iodine–Silver Nitrate Combination
  75. N -(2-Iodylphenyl)acylamides - New Pentavalent Iodine Oxidizing Reagents
  76. m -Iodosylbenzoic Acid as a Convenient Recyclable Reagent for Highly ­Efficient RuCl 3 -Catalyzed Oxidation of Alcohols to Carbonyl Compounds
  77. trans Influences on Hypervalent Bonding of Aryl λ3‐Iodanes: Their Stabilities and Isodesmic Reactions of Benziodoxolones and Benziodazolones
  78. trans Influences on Hypervalent Bonding of Aryl λ3‐Iodanes: Their Stabilities and Isodesmic Reactions of Benziodoxolones and Benziodazolones
  79. RuCl 3 -Catalyzed Oxidation of Iodoarenes with Peracetic Acid:  New Facile Preparation of Iodylarenes
  80. Preparation and Reductive Decomposition of 2-Iodoxybenzenesulfonic Acid. X-ray Crystal Structure of 1-Hydroxy-1H-1,2,3-benziodoxathiole 3,3-Dioxide
  81. 2-Iodylphenol Ethers:  Preparation, X-ray Crystal Structure, and Reactivity of New Hypervalent Iodine(V) Oxidizing Reagents
  82. 1-Hydroxy-1,2-benziodoxol-3(1H)-one
  83. Synthesis and oxidative reactivity of new chiral hypervalent iodine(V) reagents based on (S)-proline
  84. Highly efficient RuCl3-catalyzed disproportionation of (diacetoxyiodo)benzene to iodylbenzene and iodobenzene; leading to the efficient oxidation of alcohols to carbonyl compounds
  85. The Pyroglutamate Hydantoin Rearrangement
  86. Facile Preparation and Reactivity of Polymer-Supported N -(2-Iodyl-phenyl)-acylamide, an Efficient Oxidizing System
  87. Synthesis, Structure, and Chemoselective Reactivity ofN-(2-Iodylphenyl)acylamides: Hypervalent Iodine Reagents Bearing a Pseudo-Six-Membered Ring Scaffold
  88. Synthesis, Structure, and Chemoselective Reactivity ofN-(2-Iodylphenyl)acylamides: Hypervalent Iodine Reagents Bearing a Pseudo-Six-Membered Ring Scaffold
  89. 1,2-Benziodoxol-3(1H)-one Derivative
  90. Esters of 2-Iodoxybenzoic Acid:  Hypervalent Iodine Oxidizing Reagents with a Pseudobenziodoxole Structure
  91. Intra- and intermolecular interactions in the solid state structure of 2-iodylbenzenesulfonamides: a heptacoordinated organic iodine(v) compound
  92. Benziodoxole-Based Hypervalent Iodine Reagents in Organic Synthesis
  93. Selective Oxidation of Sulfides to Sulfoxides Using IBX-Esters
  94. Iodosylbenzene
  95. Derivatives of 2-iodoxybenzenesulfonic acid: new pseudocyclic hypervalent iodine reagents
  96. Amino Acid-Derived Iodobenzene Dicarboxylates: Reagents for Oxidative Conversion of Alkenes to Amino Acid Esters
  97. 2-Iodoxybenzenesulfamides: new pseudobenziodoxole-based hypervalent iodine reagents
  98. Preparation and structure of 2-iodoxybenzoate esters: soluble and stable periodinane oxidizing reagentsElectronic Supplementary Information (ESI) available: synthetic and characterization data for all new compounds; general procedures for the oxidation...
  99. 4,4′-Bis(dichloroiodo)biphenyl and 3-(Dichloroiodo)benzoic Acid: New Recyclable Hypervalent Iodine Reagents for Vicinal Halomethoxylation of Unsaturated Compounds
  100. IBX Amides: A New Family of Hypervalent Iodine Reagents
  101. Synthesis and Structure of Amino Acid-Derived Benziodazoles: New Hypervalent Iodine Heterocycles
  102. Preparation and Chemistry of Phosphoranyl-Derived Iodanes
  103. A Tribute to Prof. Anastasios Varvoglis
  104. C-C-Bond Forming Reactions
  105. Preparation, Structure, and Unexpected Chemistry of Phosphoranyl-Derived Benziodoxoles
  106. Complexes of hypervalent iodine compounds with nitrogen ligands
  107. Preparation, structure, and chemistry of phosphorane-derived phenyliodonium sulfonates
  108. Secondary Bonding-Directed Self-Assembly of Amino Acid Derived Benziodazoles:  Synthesis and Structure of Novel Hypervalent Iodine Macrocycles
  109. Lithium Phenylethynolate
  110. Functionalization of buckminsterfullerene by hypervalent iodine reagents
  111. Synthesis and reactions of amino acid-derived benziodazole oxides: new chiral oxidizing reagents
  112. Synthesis and structure of benzoboroxoles: novel organoboron heterocycles
  113. Chemistry of Hypervalent Compounds Edited by Kin-ya Akiba (Hiroshima University). Wiley-VCH:  New York. 1998. xvi + 414 pp. $135.00. ISBN 0-471-24019-2.
  114. New alkyliodonium derivatives stabilized by ammonium or phosphonium groups
  115. Structure and conformation of tri-O-acetyl-D-glucal dimer in solid state and in solution
  116. Alkynyliodonium salts in organic synthesis
  117. Structure and Chemistry of Hypervalent Iodine Heterocycles:  Acid-Catalyzed Rearrangement of Benziodazol-3-ones to 3-Iminiumbenziodoxoles
  118. Novel trifluoroethyliodonium salts from cyclic enaminones and their thermal decomposition
  119. Structure and Chemistry of Acetoxybenziodazole. Acid-Catalyzed Rearrangement of Benziodazoles to 3-Iminobenziodoxoles
  120. Preparation, X-ray Crystal Structure, and Chemistry of ((Arylsulfonyl)methyl)(phenyl)iodonium Triflates. Stable Alkyliodonium Salts
  121. 1-Amido-3-(1H)-1,2-benziodoxoles: Stable amidoiodanes and reagents for direct amidation of organic substrates
  122. Iodosylperfluoroalkanes as Reagents for the Preparation of Perfluoroalkyliodonium Salts under Aprotic Conditions
  123. 1-[Hydroxy(sulfonyloxy)iodo]-1 H ,1 H -perfluoroalkanes:  Stable, Fluoroalkyl Analogs of Koser's Reagent
  124. Synthesis and X-ray crystal structure of l-cyano-3,3-bis(trifluoromethyl)-l,3-dihydro-lλ3,2-benzoiodoxole, a stable cyanoiodolane
  125. 1-(Organosulfonyloxy)-3(1 H )-1,2-benziodoxoles:  Preparation and Reactions with Alkynyltrimethylsilanes
  126. Preparation, X-ray Crystal Structure, and Chemistry of Stable AzidoiodinanesDerivatives of Benziodoxole
  127. Direct Azidation of Adamantane and Norbornane by Stable Azidoiodinanes
  128. 1-Cyano-3-(1H)-1,2-benziodoxols: stable cyanoiodinanes and efficient reagents for direct N-alkyl cyanation of N,N-dialkylarylamines
  129. 1-[Hydroxy(sulfonyloxy)iodo]-2,2,2-trifluoroethanes, CF3CH2I(OH)OSO2R: Stable, fluoroalkyl analogs of Koser's reagent
  130. [Hydroxy(sulfonyloxy)iodo]perfluoroalkanes: New and Convenient Reagents for the Preparation of Fluoroalkyl(aryl)iodonium Salts
  131. Preparation and chemistry of stable azidoiodinanes: 1-Azido-3,3-bis(trifluoromethyl)-3-(1H)-1,2-benziodoxol and 1-Azido-1,2-benziodoxol-3-(1H)-one
  132. Preparation and chemistry of 1-organosulfonyloxy-1,2-benziodoxol-3-(1H)-ones: First example of a stable adduct of 2-iodosobenzoic acid with strong acid
  133. [Hydroxy(sulfonyloxy)iodo]perfluoroalkanes - new hypervalent iodine species and promising reagents for organic synthesis
  134. A General Synthetic Approach to Aryl(perfluoroalkyl)iodonium Sulfonates by the Reaction of [Hydroxy(sulfonyloxy)iodo]perfluoroalkanes with Arylsilanes
  135. Highly effective PQQ inhibition by alkynyl and aryl mono- and diiodonium salts
  136. Organic chemistry of noble gases
  137. A general approach to aryl(cyano)iodonium triflates - versatile iodonium transfer reagents
  138. Preparation and characterization of a macrocyclic tetraaryltetraiodonium compound, cyclo(Ar4I4)4+.cntdot.4X-. A unique, charged, cationic molecular box
  139. Reaction of lithium alkynolates with acid chlorides: A conventional approach to the preparation of ynol esters
  140. Synthesis of Enediynes by Reaction of Bicycloalkenyldiiodonium Salts with Lithium Alkynylcuprates
  141. Iodosyl Fluorosulfate - A New Efficient Reagent for the Direct Synthesis of Diaryliodonium Salts
  142. Reactions of bicycloalkenyldiiodonium salts with nucleophiles
  143. Preparation of bis(heteroaryl)iodonium saltsviaan iodonium transfer reaction between di(cyano)iodonium triflate and organostannes
  144. (Dicyano)iodonium triflate- novel iodonium species and a versatile reagent for the preparation of iodonium salts via an iodonium transfer reaction with organostannanes
  145. Bis(phenyliodonium) diyne triflates PhIC.tplbond.C(p-C6H4)nC.tplbond.CIPh.cntdot.20Tf and PhIC.tplbond.C(CH2)nC.tplbond.CIPh.cntdot.20Tf: preparation, characterization, and reaction with triphenylphosphine
  146. Preparation, spectral identification and chemical reaction of alkynyl xenonium tetrafluoroborates, R–CC–Xe+BF4–: novel organoxenonium species
  147. Synthesis and X-Ray Structure Determination of 1,4-Bis[trimethylsilylethynyl(trifluoromethanesulfonyloxy)iodo]benzene, Me3SiCCl+C6H4l+CCSiMe3 2CF3SO3−, a Novel Alkynyliodonium Salt
  148. 1,4-Bis(iodosyl)benzene: an Efficient Reagent for the Preparation of (p-Phenylene)bisiodonium Salts
  149. Iodosyl trifluoromethanesulfonate - an efficient reagent for the single step preparation of diaryl iodonium triflate salts
  150. Preparation and molecular structure determination of dialkynyliodonium salts: (RC.tplbond.C)2I+ -OTf
  151. Preparation of functionalized alkynyl(phenyl)iodonium salts via a novel iodonium transfer process between alkynylstannanes and PhI+CN -OTf
  152. Preparation and chemistry of PhI+C.tplbond.CI+Ph.cntdot.2-OTf, bis[phenyl[[(trifluoromethyl)sulfonyl]oxy]iodo]acetylene, a novel difunctional acetylene, bis(iodonium) species and a stable C2-transfer agent
  153. (Dicyanoiodo)benzene - a stable tricoordinate iodine(III) compound with three carbon ligands
  154. Reaction OF E-1,2-bis[triphenyl(trifluoromethanesulfonyloxy)phospho]ethylene, Ph3PCHCHPPh3·20Tfwith bases: Unusual products and evidence for C2-dlylide, Ph3PCCPPh3, formation
  155. Bis[phenyl[(perfluoroalkanesulfonyl)oxy]iodo]acetylene, PhI+C.tplbond.CI+Ph.cntdot.2RFSO3-, and 1,4bis[phenyl[(perfluoroalkanesulfonyl)oxy]iodo]-1,3-butadiyne, PhI+C.tplbond.C-C.tplbond.CI+Ph.cntdot.2RFSO3-
  156. Xenon fluorosulfates and their AdE-reactions with olefins
  157. Cubic reaction coordinate diagram in the nucleophilic substitution process
  158. Introduction of the halonitromethyl framework into aromatic rings via a XeF2 mediated radical process
  159. A general approach to unsymmetrical tricoordinate iodinanes: Single step preparation of mixed iodosobenzene sulfonates Phl(X)OSO2R, via reaction of iodosobenzene with Me3SiX
  160. Iodosobenzene tetrafluoroborate, hexafluoroantimonate, and hexafluorophosphate: stable electrophilic hypervalent iodine reagents without nucleophilic ligands
  161. The Synthesis and Properties of Covalent Organic Perchlorates
  162. Iodosobenzene tetrafluoroborate: First example of a stable electrophilic hypervalent iodine reagent without nucleophilic ligands
  163. Cesium fluoroxysulfate addition to alkenes leading to vicinal fluoroalkylsulfates
  164. Reaction of phIO·HBF4/silyl enol ether adduct with olefins as general approach to carbon—carbon bond formation in AdE reactions using hypervalent iodine reagents
  165. Novel reagents containing hypervalent iodine and their use for electrophilic additions to olefins
  166. Stereochemistry of oxidative deiodination leading to formation of covalent perchlorates
  167. Novel reagents containing hypervalent iodine and their use for electrophilic additions to olefins
  168. Novel method of deoxidation of alcohols and its use in synthesis of covalent perchlorates
  169. Reaction of alkyl iodides with aryliodoso derivatives
  170. Ynol Ethers and Esters