All Stories

  1. Chemoselectively Functionalized Ketoesters by Halogenative C–C Bond Cleavage of Cyclic Diketones
  2. 14 Recent Advances in Hypervalent Halogen Catalysis
  3. Synthesis of Heterocyclic Sulfonium Triflates by Cu-catalyzed Selective S-arylation with Aryl(mesityl)iodonium Salts
  4. Metal-Free Synthesis of Benzimidazolinones via Oxidative Cyclization Under Hypervalent Iodine Catalysis
  5. Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations
  6. Front Cover: Divergent Synthesis of 4‐Aminotriazoles Through Click Cycloaddition and Generation of Iodonium(III) Triazoles (Eur. J. Org. Chem. 6/2025)
  7. Divergent Synthesis of 4‐Aminotriazoles Through Click Cycloaddition and Generation of Iodonium(III) Triazoles
  8. Recent advances in non-conventional synthesis of N-heterocyclic compounds: emerging strategies and biological perspectives
  9. Transition-metal-free dibenzoxazepinone synthesis by hypervalent iodine-mediated chemoselective arylocyclizations of N-functionalized salicylamides
  10. Metal-Free Synthesis of Benzisoxazolones Utilizing ortho-Ester and ortho-Cyano-Functionalized Diaryliodonium Salts with Protected Hydroxylamines
  11. Practical Synthesis of N-Anilinylphenothiazines Using a Cyclic Hypervalent Iodine Coupling Reagent
  12. Triflic acid-promoted Friedel–Crafts-type carbocyclization of alkenylated biphenyl derivatives: Synthesis and photophysical studies of novel 9,10-dihydrophenanthrenes
  13. Silver-Catalyzed Coupling of Unreactive Carboxylates: Synthesis of α-Fluorinated O-Aryl Esters
  14. Auxiliary strategy for the general and practical synthesis of diaryliodonium(III) salts with diverse organocarboxylate counterions
  15. Borate-mediated aryl polyfluoroalkoxylation under transition-metal-free conditions
  16. Organohypervalent heterocycles
  17. Efficient Metal-Free Oxidative C–H Amination for Accessing Dibenzoxazepinones via μ-Oxo Hypervalent Iodine Catalysis
  18. Iodine(V)-Based Oxidants in Oxidation Reactions
  19. Transition Metal‐Free O‐Arylation of N‐Alkoxybenzamides Enabled by Aryl(trimethoxyphenyl)iodonium Salts
  20. 1,3‐Dipolar Cycloaddition of 3‐Chromonyl‐Substituted Glycine Imino Esters with Arylidenes and in situ Diastereodivergent via Retrocycloaddition
  21. Decarboxylative arylation with diaryliodonium(iii) salts: alternative approach for catalyst-free difluoroenolate coupling to aryldifluoromethyl ketones
  22. Transition-Metal-Free N-Arylation of N-Methoxysulfonamides and N,O-Protected Hydroxylamines with Trimethoxyphenyliodonium (III) Acetates
  23. Cyclic Hypervalent Iodine-Induced Oxidative Phenol and Aniline Couplings with Phenothiazines
  24. Palladium-Catalyzed Organic Reactions Involving Hypervalent Iodine Reagents
  25. Recyclable Hypervalent Iodine Reagents in Modern Organic Synthesis
  26. Ligand- and Counterion-Assisted Phenol O-Arylation with TMP-Iodonium(III) Acetates
  27. Cover Feature: Asymmetric Direct/Stepwise Dearomatization Reactions Involving Hypervalent Iodine Reagents (Chem. Asian J. 4/2022)
  28. Diaryliodonium(iii) salts in one-pot double functionalization of C–IIII and ortho C–H bonds
  29. Iodine(iii) reagents for oxidative aromatic halogenation
  30. Asymmetric Direct/Stepwise Dearomatization Reactions Involving Hypervalent Iodine Reagents
  31. [3 + 2] Coupling of Quinone Monoacetals with Vinyl Ethers Effected by Tetrabutylammonium Triflate: Regiocontrolled Synthesis of 2-Oxygenated Dihydrobenzofurans
  32. Special Issue on Hypervalent Iodine Reagents in Organic Synthesis
  33. Practical Synthesis of 2-Iodosobenzoic Acid (IBA) without Contamination by Hazardous 2-Iodoxybenzoic Acid (IBX) under Mild Conditions
  34. Nucleophilic Aromatic Substitution of Polyfluoroarene to Access Highly Functionalized 10-Phenylphenothiazine Derivatives
  35. Nucleophilic Aromatic Substitution of Polyfluoroarene to Access Highly Functionalized 10-Phenylphenothiazine Derivatives
  36. Halogen-Induced Controllable Cyclizations as Diverse Heterocycle Synthetic Strategy
  37. Halogen-Induced Controllable Cyclizations as Diverse Heterocycle Synthetic Strategy
  38. Practical synthesis of diaryliodonium(iii) triflates using ArI(OAc)2/TfOH/MeCN reaction system
  39. Heteroaryliodonium(III) Salts as Highly Reactive Electrophiles
  40. Recent Topics in Organohalogen Reagents and Compounds
  41. New syntheses of haloketo acid methyl esters and their transformation to halolactones by reductive cyclization
  42. Progress in [18F]Fluorination by Using Aryliodonium(III) Compounds and Application for PET Tracer Syntheses
  43. Regiodivergent oxidation of alkoxyarenes by hypervalent iodine/oxone® system
  44. Benzylic Oxidation and Functionalizations of Xanthenes by Ligand Trasfer Reactions of Hypervalent Iodine Reagents
  45. Nucleophilic Arylation of Halopurines Facilitated by Brønsted Acid in Fluoroalcohol
  46. Synthesis of Uracil-Iodonium(III) Salts for Practical Utilization as Nucleobase Synthetic Modules
  47. Dataset on synthesis and crystallographic structure of phenyl(TMP)iodonium(III) acetate
  48. Recyclable synthesis of mesityl iodonium(III) salts
  49. Efficient N-arylation of azole compounds utilizing selective aryl-transfer TMP-iodonium(III) reagents
  50. Controlled-Coupling of Quinone Monoacetals by New Activation Methods: Regioselective Synthesis of Phenol-Derived Compounds
  51. Oxidative Coupling of N-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst
  52. Asymmetric Construction of Heterocycles via Dearomative Coupling and Addition Reactions of Phenol and Aniline Derivatives
  53. Vicinal Functionalization of Uracil Heterocycles with Base Activation of Iodonium(III) Salts
  54. Selective carboxylation of reactive benzylic C–H bonds by a hypervalent iodine(III)/inorganic bromide oxidation system
  55. Facile Synthesis of Stable Uracil-Iodonium(III) Salts with Various Counterions
  56. Metal-Free Oxidative Cross-Coupling of Pyrroles with Electron-Rich Arenes Using Recyclable Hypervalent Iodine(III) Reagent
  57. Oxidative Biaryl Coupling of N-Aryl Anilines by Using a Hypervalent Iodine(III) Reagent
  58. Chiral Atropisomeric 8,8′-Diiodobinaphthalene for Asymmetric Dearomatizing Spirolactonizations in Hypervalent Iodine Oxidations
  59. Metal-FreeO-Arylation of Carboxylic Acid by Active Diaryliodonium(III) Intermediates Generatedin situfrom Iodosoarenes
  60. Atropisomeric Chiral Diiododienes (Z,Z)-2,3-Di(1-iodoalkylidene)tetralins: Synthesis, Enantiomeric Resolution, and Application in Asymmetric Catalysis
  61. Metal-free Oxidative Cross-Coupling Reaction of Aromatic Compounds Containing Heteroatoms
  62. Selective Aryl Radical Transfers into N-Heteroaromatics from Diaryliodonoium Salts with Trimethoxybenzene Auxiliary
  63. Front Cover Picture: Site-Selective Iron(III) Chloride-Catalyzed Arylation of 4-Aryl-4-methoxy-2,5-cyclohexadienones for the Synthesis of Polyarylated Phenols (Adv. Synth. Catal. 23/2016)
  64. Efficient Coupling Reaction of Quinone Monoacetal with Phenols Leading to Phenol Biaryls
  65. Site-Selective Iron(III) Chloride-Catalyzed Arylation of 4-Aryl-4-methoxy-2,5-cyclohexadienones for the Synthesis of Polyarylated Phenols
  66. Metal-Free Oxidative Cross-Coupling Reaction of Thiophene Iodonium Salts with Pyrroles
  67. Organo-Iodine(III)-Catalyzed Oxidative Phenol-Arene and Phenol-Phenol Cross-Coupling Reaction
  68. Glycosylation Reaction of <i>Thioglycosides</i> by Using Hypervalent Iodine(III) Reagent as an Excellent Promoter
  69. Hypervalent Iodine-Induced Oxidative Couplings (New Metal-Free Coupling Advances and Their Applications in Natural Product Syntheses)
  70. New Synthesis of Tetrahydrobenzodifurans by Iterative Coupling of Quinone Monoacetals with Alkene Nucleophiles
  71. Stabilized pyrrolyl iodonium salts and metal-free oxidative cross-coupling
  72. Metal-Free Oxidative Biaryl Coupling by Hypervalent Iodine Reagents
  73. Pioneering Metal-Free Oxidative Coupling Strategy of Aromatic Compounds Using Hypervalent Iodine Reagents
  74. The Multiple Reactions in the Monochlorodimedone Assay: Discovery of Unique Dehalolactonizations under Mild Conditions
  75. Suppression Mechanism for Enol-Enol Isomerization of 2-Substituted Dimedones
  76. A new arylation of silyl enol ethers by quinone monoacetal substitution
  77. Phenyliodine Bis(trifluoroacetate) (PIFA) as an Excellent Promoter of 2-Deoxy-2-phthalimido-1-thioglycosides in the Presence of Triflic Acid in Glycosylation Reactions
  78. Clean Synthesis of <i>N</i>-Pyrrolyl Azoles by Metal-Free Oxidative Cross-Coupling Using Recyclable Hypervalent Iodine Reagent
  79. Phenol and Aniline Oxidative Coupling with Alkenes by Using Hypervalent Iodine Dimer for the Rapid Access to Dihydrobenzofurans and Indolines
  80. N1-Selective Oxidative CN Coupling of Azoles with Pyrroles Using a Hypervalent Iodine Reagent
  81. Iodoarene-catalyzed fluorination and aminofluorination by an Ar-I/HF·pyridine/mCPBA system
  82. Efficient Oxidative Spirolactamization by μ-Oxo Bridged Heterocyclic Hypervalent Iodine Compound
  83. New Site-Selective Organoradical Based on Hypervalent Iodine Reagent for Controlled Alkane sp3CH Oxidations
  84. Single-Electron-Transfer (SET)-Induced Oxidative Biaryl Coupling by Polyalkoxybenzene-Derived Diaryliodonium(III) Salts
  85. Organocatalytic C–H/C–H′ Cross-Biaryl Coupling: C-Selective Arylation of Sulfonanilides with Aromatic Hydrocarbons
  86. Brønsted Acid-Controlled [3 + 2] Coupling Reaction of Quinone Monoacetals with Alkene Nucleophiles: A Catalytic System of Perfluorinated Acids and Hydrogen Bond Donor for the Construction of Benzofurans
  87. Metal-Free OxidativeparaCross-Coupling of Phenols
  88. Asymmetric Dearomatizing Spirolactonization of Naphthols Catalyzed by Spirobiindane-Based Chiral Hypervalent Iodine Species
  89. Oxidative Trimerization of Catechol to Hexahydroxytriphenylene
  90. Efficient Synthesis of a Regioregular Oligothiophene Photovoltaic Dye Molecule, MK-2, and Related Compounds: A Cooperative Hypervalent Iodine and Metal-Catalyzed Synthetic Route
  91. Synthesis of Boron-Substituted Diaryliodonium Salts and Selective Transformation into Functionalized Aryl Boronates
  92. Controlled couplings of quinone monoacetals using reusable polystyrene-anchored specific proton catalyst
  93. Efficient Synthesis of Oxygenated Terphenyls and Other Oligomers: Sequential Arylation Reactions Through Phenol Oxidation-Rearomatization
  94. μ-Oxo-Bridged Hypervalent Iodine(III) Compound as an Extreme Oxidant for Aqueous Oxidations
  95. An excellent dual recycling strategy for the hypervalent iodine/nitroxyl radical mediated selective oxidation of alcohols to aldehydes and ketones
  96. HYPERVALENT IODINE INDUCED OXIDATIVE CROSS COUPLING VIA Thiophene CATION RADICAL INTERMEDIATE
  97. Speedy and Clean Hypervalent Iodine/Nitroxyl Radical Mediated Oxidation of Alcohols Using Recyclable Adamantane Reagent with Highly Active 2-Azaadamantane-<i>N</i>-oxyl Organocatalyst
  98. Metal-Free C–H Cross-Coupling toward Oxygenated Naphthalene-Benzene Linked Biaryls
  99. Metal-Free Oxidative Coupling Reactions via σ-Iodonium Intermediates: The Efficient Synthesis of Bithiophenes Using Hypervalent Iodine Reagents
  100. [3 + 2] Coupling of Quinone Monoacetals by Combined Acid–Hydrogen Bond Donor
  101. Coupling of Quinone Monoacetals Promoted by Sandwiched Brønsted Acids: Synthesis of Oxygenated Biaryls
  102. Efficient phenolic oxidations using μ-oxo-bridged phenyliodine trifluoroacetate
  103. Discovery of Stabilized Bisiodonium Salts as Intermediates in the Carbon-Carbon Bond Formation of Alkynes
  104. New synthesis of spirocycles by utilizing in situ forming hypervalent iodine species
  105. Hypervalent Iodine Induced Metal-Free C-H Cross Couplings to Biaryls
  106. One-Pot Syntheses of Diaryliodonium Salts from Aryl Iodides Using Peracetic Acid as Green Oxidant
  107. Metal-Free Regioselective Oxidative Biaryl Coupling Leading to Head-to-Tail Bithiophenes: Reactivity Switching, a Concept Based on the Iodonium(III) Intermediate
  108. Fluoroalcohols: versatile solvents in hypervalent iodine chemistry and syntheses of diaryliodonium(III) salts
  109. Unusual ipso Substitution of Diaryliodonium Bromides Initiated by a Single-Electron-Transfer Oxidizing Process
  110. Enhanced Reactivity of [Hydroxy(tosyloxy)iodo]benzene in Fluoroalcohol Media. Efficient Direct Synthesis of Thienyl(aryl)iodonium Salts
  111. Designer μ-oxo-bridged hypervalent iodine(iii) organocatalysts for greener oxidations
  112. Efficient Phenolic Oxidations to Construct ortho-Spirolactone Structures Using Oxo-Bridged Hypervalent Iodine(III) Compound
  113. Recycling and Catalytic Approaches for the Development of a Rare-Metal-Free Synthetic Method Using Hypervalent Iodine Reagent
  114. Hypervalent iodine(III): selective and efficient single-electron-transfer (SET) oxidizing agent
  115. Development of Rare Metal-Free Synthetic Method Using New Iodine Reagents
  116. Hypervalent iodine(III)/Et4N+Br− combination in water for green and racemization-free aqueous oxidation of alcohols
  117. Metal-Free Oxidative Cross-Coupling of Unfunctionalized Aromatic Compounds
  118. Hypervalent iodine reagents as a new entrance to organocatalysts
  119. Clean and Direct Synthesis of .ALPHA.,.ALPHA.'-Bithiophenes and Bipyrroles by Metal-Free Oxidative Coupling Using Recyclable Hypervalent Iodine(III) Reagents
  120. Organoiodine-Catalyzed Oxidative Spirocyclization of Phenols using Peracetic Acid as a Green and Economic Terminal Oxidant
  121. Clean and Efficient Benzylic C−H Oxidation in Water Using a Hypervalent Iodine Reagent: Activation of Polymeric Iodosobenzene with KBr in the Presence of Montmorillonite-K10
  122. A New H2O2/Acid Anhydride System for the Iodoarene-Catalyzed C−C Bond-Forming Reactions of Phenols
  123. A Chiral Hypervalent Iodine(III) Reagent for Enantioselective Dearomatization of Phenols
  124. Oxidative Cross-Coupling of Arenes Induced by Single-Electron Transfer Leading to Biaryls by Use of Organoiodine(III) Oxidants
  125. Total Synthesis of (±)-γ-Rubromycin on the Basis of Two Aromatic Pummerer-Type Reactions
  126. Regioselective Bipyrrole Coupling of Pyrroles and 3-Substituted Pyrroles Using Phenyliodine(III) Bis(trifluoroacetate)
  127. Direct Lactone Formation by Using Hypervalent Iodine(III) Reagents with KBr via Selective C−H Abstraction Protocol
  128. Versatile direct dehydrative approach for diaryliodonium(iii) salts in fluoroalcohol media
  129. First hypervalent iodine(iii)-catalyzed C–N bond forming reaction: catalytic spirocyclization of amides to N-fused spirolactams
  130. Direct Cyanation of Heteroaromatic Compounds Mediated by Hypervalent Iodine(III) Reagents:  In Situ Generation of PhI(III)−CN Species and Their Cyano Transfer
  131. Development of Environmentally Benign Oxidations Using Hypervalent Iodine (III)Reagents
  132. Direct Synthesis of Bipyrroles Using Phenyliodine Bis(trifluoroacetate) with Bromotrimethylsilane
  133. A Facile and Clean Direct Cyanation of Heteroaromatic Compounds Using a Recyclable Hypervalent Iodine(III) Reagent
  134. Versatile Hypervalent-Iodine(III)-Catalyzed Oxidations withm-Chloroperbenzoic Acid as a Cooxidant
  135. Novel and Direct Oxidative Cyanation Reactions of Heteroaromatic Compounds Mediated by A Hypervalent Iodine(III) Reagent
  136. A unique site-selective reaction of ketones with new recyclable hypervalent iodine(iii) reagents based on a tetraphenylmethane structure
  137. The synthesis of head-to-tail (H–T) dimers of 3-substituted thiophenes by the hypervalent iodine(iii)-induced oxidative biaryl coupling reaction
  138. Preparation and Reactivity of 1,3,5,7-Tetrakis[4-(diacetoxyiodo)phenyl]adamantane, a Recyclable Hypervalent Iodine(III) Reagent
  139. Reaction of Terminal Alkynes with Hydrazines To Give Nitriles, Catalyzed by TpRuCl(PPh3)2:  Novel Catalytic Transformation Involving a Vinylidene Ruthenium Intermediate