All Stories

  1. Halogen-Guided Reconstructive Transformation of Hydroxycoumarin to Coumaranone
  2. Front Cover: Functionalized Diaryliodonium Salts with N ‐Reactive Amides: Versatile Reactivity for Constructing Benzo‐Fused Nitrogen Heterocycles (Adv. Synth. Catal. 10/2026)
  3. New Triazole‐Tethered Iodoarenes: Click‐Mediated Synthesis and Catalytic Activity Toward Oxidative Transformations
  4. Hypervalent Iodine(III)-Mediated Oxidative C–H Amination of Phenols and Anilines with Azoles
  5. Functionalized Diaryliodonium Salts with N ‐Reactive Amides: Versatile Reactivity for Constructing Benzo‐Fused Nitrogen Heterocycles
  6. Iron-Catalyzed Nucleophilic Substitution Reactions: An Overview
  7. Isocoumarin Synthesis via Metal-Free C-Arylation of Acetoacetates with ortho-Ester-Functionalized Diaryliodonium Salts
  8. Metal‐Free Intermolecular C–H Imidation of Anilines and Phenols With Sulfonimides
  9. Chemoselectively Functionalized Ketoesters by Halogenative C–C Bond Cleavage of Cyclic Diketones
  10. 14 Recent Advances in Hypervalent Halogen Catalysis
  11. Synthesis of Heterocyclic Sulfonium Triflates by Cu-catalyzed Selective S-arylation with Aryl(mesityl)iodonium Salts
  12. Metal-Free Synthesis of Benzimidazolinones via Oxidative Cyclization Under Hypervalent Iodine Catalysis
  13. Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations
  14. Front Cover: Divergent Synthesis of 4‐Aminotriazoles Through Click Cycloaddition and Generation of Iodonium(III) Triazoles (Eur. J. Org. Chem. 6/2025)
  15. Divergent Synthesis of 4‐Aminotriazoles Through Click Cycloaddition and Generation of Iodonium(III) Triazoles
  16. Recent advances in non-conventional synthesis of N-heterocyclic compounds: emerging strategies and biological perspectives
  17. Transition-metal-free dibenzoxazepinone synthesis by hypervalent iodine-mediated chemoselective arylocyclizations of N-functionalized salicylamides
  18. Metal-Free Synthesis of Benzisoxazolones Utilizing ortho-Ester and ortho-Cyano-Functionalized Diaryliodonium Salts with Protected Hydroxylamines
  19. Practical Synthesis of N-Anilinylphenothiazines Using a Cyclic Hypervalent Iodine Coupling Reagent
  20. Triflic acid-promoted Friedel–Crafts-type carbocyclization of alkenylated biphenyl derivatives: Synthesis and photophysical studies of novel 9,10-dihydrophenanthrenes
  21. Silver-Catalyzed Coupling of Unreactive Carboxylates: Synthesis of α-Fluorinated O-Aryl Esters
  22. Auxiliary strategy for the general and practical synthesis of diaryliodonium(III) salts with diverse organocarboxylate counterions
  23. Borate-mediated aryl polyfluoroalkoxylation under transition-metal-free conditions
  24. Organohypervalent heterocycles
  25. Efficient Metal-Free Oxidative C–H Amination for Accessing Dibenzoxazepinones via μ-Oxo Hypervalent Iodine Catalysis
  26. Iodine(V)-Based Oxidants in Oxidation Reactions
  27. Transition Metal‐Free O‐Arylation of N‐Alkoxybenzamides Enabled by Aryl(trimethoxyphenyl)iodonium Salts
  28. 1,3‐Dipolar Cycloaddition of 3‐Chromonyl‐Substituted Glycine Imino Esters with Arylidenes and in situ Diastereodivergent via Retrocycloaddition
  29. Decarboxylative arylation with diaryliodonium(iii) salts: alternative approach for catalyst-free difluoroenolate coupling to aryldifluoromethyl ketones
  30. Transition-Metal-Free N-Arylation of N-Methoxysulfonamides and N,O-Protected Hydroxylamines with Trimethoxyphenyliodonium (III) Acetates
  31. Cyclic Hypervalent Iodine-Induced Oxidative Phenol and Aniline Couplings with Phenothiazines
  32. Palladium-Catalyzed Organic Reactions Involving Hypervalent Iodine Reagents
  33. Recyclable Hypervalent Iodine Reagents in Modern Organic Synthesis
  34. Ligand- and Counterion-Assisted Phenol O-Arylation with TMP-Iodonium(III) Acetates
  35. Cover Feature: Asymmetric Direct/Stepwise Dearomatization Reactions Involving Hypervalent Iodine Reagents (Chem. Asian J. 4/2022)
  36. Diaryliodonium(iii) salts in one-pot double functionalization of C–IIII and ortho C–H bonds
  37. Iodine(iii) reagents for oxidative aromatic halogenation
  38. Asymmetric Direct/Stepwise Dearomatization Reactions Involving Hypervalent Iodine Reagents
  39. [3 + 2] Coupling of Quinone Monoacetals with Vinyl Ethers Effected by Tetrabutylammonium Triflate: Regiocontrolled Synthesis of 2-Oxygenated Dihydrobenzofurans
  40. Special Issue on Hypervalent Iodine Reagents in Organic Synthesis
  41. Practical Synthesis of 2-Iodosobenzoic Acid (IBA) without Contamination by Hazardous 2-Iodoxybenzoic Acid (IBX) under Mild Conditions
  42. Nucleophilic Aromatic Substitution of Polyfluoroarene to Access Highly Functionalized 10-Phenylphenothiazine Derivatives
  43. Nucleophilic Aromatic Substitution of Polyfluoroarene to Access Highly Functionalized 10-Phenylphenothiazine Derivatives
  44. Halogen-Induced Controllable Cyclizations as Diverse Heterocycle Synthetic Strategy
  45. Halogen-Induced Controllable Cyclizations as Diverse Heterocycle Synthetic Strategy
  46. Practical synthesis of diaryliodonium(iii) triflates using ArI(OAc)2/TfOH/MeCN reaction system
  47. Heteroaryliodonium(III) Salts as Highly Reactive Electrophiles
  48. Recent Topics in Organohalogen Reagents and Compounds
  49. New syntheses of haloketo acid methyl esters and their transformation to halolactones by reductive cyclization
  50. Progress in [18F]Fluorination by Using Aryliodonium(III) Compounds and Application for PET Tracer Syntheses
  51. Regiodivergent oxidation of alkoxyarenes by hypervalent iodine/oxone® system
  52. Benzylic Oxidation and Functionalizations of Xanthenes by Ligand Trasfer Reactions of Hypervalent Iodine Reagents
  53. Nucleophilic Arylation of Halopurines Facilitated by Brønsted Acid in Fluoroalcohol
  54. Synthesis of Uracil-Iodonium(III) Salts for Practical Utilization as Nucleobase Synthetic Modules
  55. Dataset on synthesis and crystallographic structure of phenyl(TMP)iodonium(III) acetate
  56. Recyclable synthesis of mesityl iodonium(III) salts
  57. Efficient N-arylation of azole compounds utilizing selective aryl-transfer TMP-iodonium(III) reagents
  58. Controlled-Coupling of Quinone Monoacetals by New Activation Methods: Regioselective Synthesis of Phenol-Derived Compounds
  59. Oxidative Coupling of N-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst
  60. Asymmetric Construction of Heterocycles via Dearomative Coupling and Addition Reactions of Phenol and Aniline Derivatives
  61. Vicinal Functionalization of Uracil Heterocycles with Base Activation of Iodonium(III) Salts
  62. Selective carboxylation of reactive benzylic C–H bonds by a hypervalent iodine(III)/inorganic bromide oxidation system
  63. Facile Synthesis of Stable Uracil-Iodonium(III) Salts with Various Counterions
  64. Metal-Free Oxidative Cross-Coupling of Pyrroles with Electron-Rich Arenes Using Recyclable Hypervalent Iodine(III) Reagent
  65. Oxidative Biaryl Coupling of N-Aryl Anilines by Using a Hypervalent Iodine(III) Reagent
  66. Chiral Atropisomeric 8,8′-Diiodobinaphthalene for Asymmetric Dearomatizing Spirolactonizations in Hypervalent Iodine Oxidations
  67. Metal-FreeO-Arylation of Carboxylic Acid by Active Diaryliodonium(III) Intermediates Generatedin situfrom Iodosoarenes
  68. Atropisomeric Chiral Diiododienes (Z,Z)-2,3-Di(1-iodoalkylidene)tetralins: Synthesis, Enantiomeric Resolution, and Application in Asymmetric Catalysis
  69. Metal-free Oxidative Cross-Coupling Reaction of Aromatic Compounds Containing Heteroatoms
  70. Selective Aryl Radical Transfers into N-Heteroaromatics from Diaryliodonoium Salts with Trimethoxybenzene Auxiliary
  71. Front Cover Picture: Site-Selective Iron(III) Chloride-Catalyzed Arylation of 4-Aryl-4-methoxy-2,5-cyclohexadienones for the Synthesis of Polyarylated Phenols (Adv. Synth. Catal. 23/2016)
  72. Efficient Coupling Reaction of Quinone Monoacetal with Phenols Leading to Phenol Biaryls
  73. Site-Selective Iron(III) Chloride-Catalyzed Arylation of 4-Aryl-4-methoxy-2,5-cyclohexadienones for the Synthesis of Polyarylated Phenols
  74. Metal-Free Oxidative Cross-Coupling Reaction of Thiophene Iodonium Salts with Pyrroles
  75. Organo-Iodine(III)-Catalyzed Oxidative Phenol-Arene and Phenol-Phenol Cross-Coupling Reaction
  76. Glycosylation Reaction of <i>Thioglycosides</i> by Using Hypervalent Iodine(III) Reagent as an Excellent Promoter
  77. Hypervalent Iodine-Induced Oxidative Couplings (New Metal-Free Coupling Advances and Their Applications in Natural Product Syntheses)
  78. New Synthesis of Tetrahydrobenzodifurans by Iterative Coupling of Quinone Monoacetals with Alkene Nucleophiles
  79. Stabilized pyrrolyl iodonium salts and metal-free oxidative cross-coupling
  80. Metal-Free Oxidative Biaryl Coupling by Hypervalent Iodine Reagents
  81. Pioneering Metal-Free Oxidative Coupling Strategy of Aromatic Compounds Using Hypervalent Iodine Reagents
  82. The Multiple Reactions in the Monochlorodimedone Assay: Discovery of Unique Dehalolactonizations under Mild Conditions
  83. Suppression Mechanism for Enol-Enol Isomerization of 2-Substituted Dimedones
  84. A new arylation of silyl enol ethers by quinone monoacetal substitution
  85. Phenyliodine Bis(trifluoroacetate) (PIFA) as an Excellent Promoter of 2-Deoxy-2-phthalimido-1-thioglycosides in the Presence of Triflic Acid in Glycosylation Reactions
  86. Clean Synthesis of <i>N</i>-Pyrrolyl Azoles by Metal-Free Oxidative Cross-Coupling Using Recyclable Hypervalent Iodine Reagent
  87. Phenol and Aniline Oxidative Coupling with Alkenes by Using Hypervalent Iodine Dimer for the Rapid Access to Dihydrobenzofurans and Indolines
  88. N1-Selective Oxidative CN Coupling of Azoles with Pyrroles Using a Hypervalent Iodine Reagent
  89. Iodoarene-catalyzed fluorination and aminofluorination by an Ar-I/HF·pyridine/mCPBA system
  90. Efficient Oxidative Spirolactamization by μ-Oxo Bridged Heterocyclic Hypervalent Iodine Compound
  91. New Site-Selective Organoradical Based on Hypervalent Iodine Reagent for Controlled Alkane sp3CH Oxidations
  92. Single-Electron-Transfer (SET)-Induced Oxidative Biaryl Coupling by Polyalkoxybenzene-Derived Diaryliodonium(III) Salts
  93. Organocatalytic C–H/C–H′ Cross-Biaryl Coupling: C-Selective Arylation of Sulfonanilides with Aromatic Hydrocarbons
  94. Brønsted Acid-Controlled [3 + 2] Coupling Reaction of Quinone Monoacetals with Alkene Nucleophiles: A Catalytic System of Perfluorinated Acids and Hydrogen Bond Donor for the Construction of Benzofurans
  95. Metal-Free OxidativeparaCross-Coupling of Phenols
  96. Asymmetric Dearomatizing Spirolactonization of Naphthols Catalyzed by Spirobiindane-Based Chiral Hypervalent Iodine Species
  97. Oxidative Trimerization of Catechol to Hexahydroxytriphenylene
  98. Efficient Synthesis of a Regioregular Oligothiophene Photovoltaic Dye Molecule, MK-2, and Related Compounds: A Cooperative Hypervalent Iodine and Metal-Catalyzed Synthetic Route
  99. Synthesis of Boron-Substituted Diaryliodonium Salts and Selective Transformation into Functionalized Aryl Boronates
  100. Controlled couplings of quinone monoacetals using reusable polystyrene-anchored specific proton catalyst
  101. Efficient Synthesis of Oxygenated Terphenyls and Other Oligomers: Sequential Arylation Reactions Through Phenol Oxidation-Rearomatization
  102. μ-Oxo-Bridged Hypervalent Iodine(III) Compound as an Extreme Oxidant for Aqueous Oxidations
  103. An excellent dual recycling strategy for the hypervalent iodine/nitroxyl radical mediated selective oxidation of alcohols to aldehydes and ketones
  104. HYPERVALENT IODINE INDUCED OXIDATIVE CROSS COUPLING VIA Thiophene CATION RADICAL INTERMEDIATE
  105. Speedy and Clean Hypervalent Iodine/Nitroxyl Radical Mediated Oxidation of Alcohols Using Recyclable Adamantane Reagent with Highly Active 2-Azaadamantane-<i>N</i>-oxyl Organocatalyst
  106. Metal-Free C–H Cross-Coupling toward Oxygenated Naphthalene-Benzene Linked Biaryls
  107. Metal-Free Oxidative Coupling Reactions via σ-Iodonium Intermediates: The Efficient Synthesis of Bithiophenes Using Hypervalent Iodine Reagents
  108. [3 + 2] Coupling of Quinone Monoacetals by Combined Acid–Hydrogen Bond Donor
  109. Coupling of Quinone Monoacetals Promoted by Sandwiched Brønsted Acids: Synthesis of Oxygenated Biaryls
  110. Efficient phenolic oxidations using μ-oxo-bridged phenyliodine trifluoroacetate
  111. Discovery of Stabilized Bisiodonium Salts as Intermediates in the Carbon-Carbon Bond Formation of Alkynes
  112. New synthesis of spirocycles by utilizing in situ forming hypervalent iodine species
  113. Hypervalent Iodine Induced Metal-Free C-H Cross Couplings to Biaryls
  114. One-Pot Syntheses of Diaryliodonium Salts from Aryl Iodides Using Peracetic Acid as Green Oxidant
  115. Metal-Free Regioselective Oxidative Biaryl Coupling Leading to Head-to-Tail Bithiophenes: Reactivity Switching, a Concept Based on the Iodonium(III) Intermediate
  116. Fluoroalcohols: versatile solvents in hypervalent iodine chemistry and syntheses of diaryliodonium(III) salts
  117. Unusual ipso Substitution of Diaryliodonium Bromides Initiated by a Single-Electron-Transfer Oxidizing Process
  118. Enhanced Reactivity of [Hydroxy(tosyloxy)iodo]benzene in Fluoroalcohol Media. Efficient Direct Synthesis of Thienyl(aryl)iodonium Salts
  119. Designer μ-oxo-bridged hypervalent iodine(iii) organocatalysts for greener oxidations
  120. Efficient Phenolic Oxidations to Construct ortho-Spirolactone Structures Using Oxo-Bridged Hypervalent Iodine(III) Compound
  121. Recycling and Catalytic Approaches for the Development of a Rare-Metal-Free Synthetic Method Using Hypervalent Iodine Reagent
  122. Hypervalent iodine(III): selective and efficient single-electron-transfer (SET) oxidizing agent
  123. Development of Rare Metal-Free Synthetic Method Using New Iodine Reagents
  124. Hypervalent iodine(III)/Et4N+Br− combination in water for green and racemization-free aqueous oxidation of alcohols
  125. Metal-Free Oxidative Cross-Coupling of Unfunctionalized Aromatic Compounds
  126. Hypervalent iodine reagents as a new entrance to organocatalysts
  127. Clean and Direct Synthesis of .ALPHA.,.ALPHA.'-Bithiophenes and Bipyrroles by Metal-Free Oxidative Coupling Using Recyclable Hypervalent Iodine(III) Reagents
  128. Organoiodine-Catalyzed Oxidative Spirocyclization of Phenols using Peracetic Acid as a Green and Economic Terminal Oxidant
  129. Clean and Efficient Benzylic C−H Oxidation in Water Using a Hypervalent Iodine Reagent: Activation of Polymeric Iodosobenzene with KBr in the Presence of Montmorillonite-K10
  130. A New H2O2/Acid Anhydride System for the Iodoarene-Catalyzed C−C Bond-Forming Reactions of Phenols
  131. A Chiral Hypervalent Iodine(III) Reagent for Enantioselective Dearomatization of Phenols
  132. Oxidative Cross-Coupling of Arenes Induced by Single-Electron Transfer Leading to Biaryls by Use of Organoiodine(III) Oxidants
  133. Total Synthesis of (±)-γ-Rubromycin on the Basis of Two Aromatic Pummerer-Type Reactions
  134. Regioselective Bipyrrole Coupling of Pyrroles and 3-Substituted Pyrroles Using Phenyliodine(III) Bis(trifluoroacetate)
  135. Direct Lactone Formation by Using Hypervalent Iodine(III) Reagents with KBr via Selective C−H Abstraction Protocol
  136. Versatile direct dehydrative approach for diaryliodonium(iii) salts in fluoroalcohol media
  137. First hypervalent iodine(iii)-catalyzed C–N bond forming reaction: catalytic spirocyclization of amides to N-fused spirolactams
  138. Direct Cyanation of Heteroaromatic Compounds Mediated by Hypervalent Iodine(III) Reagents:  In Situ Generation of PhI(III)−CN Species and Their Cyano Transfer
  139. Development of Environmentally Benign Oxidations Using Hypervalent Iodine (III)Reagents
  140. Direct Synthesis of Bipyrroles Using Phenyliodine Bis(trifluoroacetate) with Bromotrimethylsilane
  141. A Facile and Clean Direct Cyanation of Heteroaromatic Compounds Using a Recyclable Hypervalent Iodine(III) Reagent
  142. Versatile Hypervalent-Iodine(III)-Catalyzed Oxidations withm-Chloroperbenzoic Acid as a Cooxidant
  143. Novel and Direct Oxidative Cyanation Reactions of Heteroaromatic Compounds Mediated by A Hypervalent Iodine(III) Reagent
  144. A unique site-selective reaction of ketones with new recyclable hypervalent iodine(iii) reagents based on a tetraphenylmethane structure
  145. The synthesis of head-to-tail (H–T) dimers of 3-substituted thiophenes by the hypervalent iodine(iii)-induced oxidative biaryl coupling reaction
  146. Preparation and Reactivity of 1,3,5,7-Tetrakis[4-(diacetoxyiodo)phenyl]adamantane, a Recyclable Hypervalent Iodine(III) Reagent
  147. Reaction of Terminal Alkynes with Hydrazines To Give Nitriles, Catalyzed by TpRuCl(PPh3)2:  Novel Catalytic Transformation Involving a Vinylidene Ruthenium Intermediate