All Stories

  1. Synthesis of Heterocyclic Sulfonium Triflates by Cu-catalyzed Selective S-arylation with Aryl(mesityl)iodonium Salts
  2. Metal-Free Synthesis of Benzimidazolinones via Oxidative Cyclization Under Hypervalent Iodine Catalysis
  3. Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations
  4. Front Cover: Divergent Synthesis of 4‐Aminotriazoles Through Click Cycloaddition and Generation of Iodonium(III) Triazoles (Eur. J. Org. Chem. 6/2025)
  5. Divergent Synthesis of 4‐Aminotriazoles Through Click Cycloaddition and Generation of Iodonium(III) Triazoles
  6. Recent advances in non-conventional synthesis of N-heterocyclic compounds: emerging strategies and biological perspectives
  7. Transition-metal-free dibenzoxazepinone synthesis by hypervalent iodine-mediated chemoselective arylocyclizations of N-functionalized salicylamides
  8. Metal-Free Synthesis of Benzisoxazolones Utilizing ortho-Ester and ortho-Cyano-Functionalized Diaryliodonium Salts with Protected Hydroxylamines
  9. Practical Synthesis of N-Anilinylphenothiazines Using a Cyclic Hypervalent Iodine Coupling Reagent
  10. Triflic acid-promoted Friedel–Crafts-type carbocyclization of alkenylated biphenyl derivatives: Synthesis and photophysical studies of novel 9,10-dihydrophenanthrenes
  11. Silver-Catalyzed Coupling of Unreactive Carboxylates: Synthesis of α-Fluorinated O-Aryl Esters
  12. Auxiliary strategy for the general and practical synthesis of diaryliodonium(III) salts with diverse organocarboxylate counterions
  13. Borate-mediated aryl polyfluoroalkoxylation under transition-metal-free conditions
  14. Organohypervalent heterocycles
  15. Efficient Metal-Free Oxidative C–H Amination for Accessing Dibenzoxazepinones via μ-Oxo Hypervalent Iodine Catalysis
  16. Iodine(V)-Based Oxidants in Oxidation Reactions
  17. Transition Metal‐Free O‐Arylation of N‐Alkoxybenzamides Enabled by Aryl(trimethoxyphenyl)iodonium Salts
  18. 1,3‐Dipolar Cycloaddition of 3‐Chromonyl‐Substituted Glycine Imino Esters with Arylidenes and in situ Diastereodivergent via Retrocycloaddition
  19. Decarboxylative arylation with diaryliodonium(iii) salts: alternative approach for catalyst-free difluoroenolate coupling to aryldifluoromethyl ketones
  20. Transition-Metal-Free N-Arylation of N-Methoxysulfonamides and N,O-Protected Hydroxylamines with Trimethoxyphenyliodonium (III) Acetates
  21. Cyclic Hypervalent Iodine-Induced Oxidative Phenol and Aniline Couplings with Phenothiazines
  22. Palladium-Catalyzed Organic Reactions Involving Hypervalent Iodine Reagents
  23. Recyclable Hypervalent Iodine Reagents in Modern Organic Synthesis
  24. Ligand- and Counterion-Assisted Phenol O-Arylation with TMP-Iodonium(III) Acetates
  25. Cover Feature: Asymmetric Direct/Stepwise Dearomatization Reactions Involving Hypervalent Iodine Reagents (Chem. Asian J. 4/2022)
  26. Diaryliodonium(iii) salts in one-pot double functionalization of C–IIII and ortho C–H bonds
  27. Iodine(iii) reagents for oxidative aromatic halogenation
  28. Asymmetric Direct/Stepwise Dearomatization Reactions Involving Hypervalent Iodine Reagents
  29. [3 + 2] Coupling of Quinone Monoacetals with Vinyl Ethers Effected by Tetrabutylammonium Triflate: Regiocontrolled Synthesis of 2-Oxygenated Dihydrobenzofurans
  30. Special Issue on Hypervalent Iodine Reagents in Organic Synthesis
  31. Practical Synthesis of 2-Iodosobenzoic Acid (IBA) without Contamination by Hazardous 2-Iodoxybenzoic Acid (IBX) under Mild Conditions
  32. Nucleophilic Aromatic Substitution of Polyfluoroarene to Access Highly Functionalized 10-Phenylphenothiazine Derivatives
  33. Nucleophilic Aromatic Substitution of Polyfluoroarene to Access Highly Functionalized 10-Phenylphenothiazine Derivatives
  34. Halogen-Induced Controllable Cyclizations as Diverse Heterocycle Synthetic Strategy
  35. Halogen-Induced Controllable Cyclizations as Diverse Heterocycle Synthetic Strategy
  36. Practical synthesis of diaryliodonium(iii) triflates using ArI(OAc)2/TfOH/MeCN reaction system
  37. Heteroaryliodonium(III) Salts as Highly Reactive Electrophiles
  38. Recent Topics in Organohalogen Reagents and Compounds
  39. New syntheses of haloketo acid methyl esters and their transformation to halolactones by reductive cyclization
  40. Progress in [18F]Fluorination by Using Aryliodonium(III) Compounds and Application for PET Tracer Syntheses
  41. Regiodivergent oxidation of alkoxyarenes by hypervalent iodine/oxone® system
  42. Benzylic Oxidation and Functionalizations of Xanthenes by Ligand Trasfer Reactions of Hypervalent Iodine Reagents
  43. Nucleophilic Arylation of Halopurines Facilitated by Brønsted Acid in Fluoroalcohol
  44. Synthesis of Uracil-Iodonium(III) Salts for Practical Utilization as Nucleobase Synthetic Modules
  45. Dataset on synthesis and crystallographic structure of phenyl(TMP)iodonium(III) acetate
  46. Recyclable synthesis of mesityl iodonium(III) salts
  47. Efficient N-arylation of azole compounds utilizing selective aryl-transfer TMP-iodonium(III) reagents
  48. Controlled-Coupling of Quinone Monoacetals by New Activation Methods: Regioselective Synthesis of Phenol-Derived Compounds
  49. Oxidative Coupling of N-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst
  50. Asymmetric Construction of Heterocycles via Dearomative Coupling and Addition Reactions of Phenol and Aniline Derivatives
  51. Vicinal Functionalization of Uracil Heterocycles with Base Activation of Iodonium(III) Salts
  52. Selective carboxylation of reactive benzylic C–H bonds by a hypervalent iodine(III)/inorganic bromide oxidation system
  53. Facile Synthesis of Stable Uracil-Iodonium(III) Salts with Various Counterions
  54. Metal-Free Oxidative Cross-Coupling of Pyrroles with Electron-Rich Arenes Using Recyclable Hypervalent Iodine(III) Reagent
  55. Oxidative Biaryl Coupling of N-Aryl Anilines by Using a Hypervalent Iodine(III) Reagent
  56. Chiral Atropisomeric 8,8′-Diiodobinaphthalene for Asymmetric Dearomatizing Spirolactonizations in Hypervalent Iodine Oxidations
  57. Metal-FreeO-Arylation of Carboxylic Acid by Active Diaryliodonium(III) Intermediates Generatedin situfrom Iodosoarenes
  58. Atropisomeric Chiral Diiododienes (Z,Z)-2,3-Di(1-iodoalkylidene)tetralins: Synthesis, Enantiomeric Resolution, and Application in Asymmetric Catalysis
  59. Metal-free Oxidative Cross-Coupling Reaction of Aromatic Compounds Containing Heteroatoms
  60. Selective Aryl Radical Transfers into N-Heteroaromatics from Diaryliodonoium Salts with Trimethoxybenzene Auxiliary
  61. Front Cover Picture: Site-Selective Iron(III) Chloride-Catalyzed Arylation of 4-Aryl-4-methoxy-2,5-cyclohexadienones for the Synthesis of Polyarylated Phenols (Adv. Synth. Catal. 23/2016)
  62. Efficient Coupling Reaction of Quinone Monoacetal with Phenols Leading to Phenol Biaryls
  63. Site-Selective Iron(III) Chloride-Catalyzed Arylation of 4-Aryl-4-methoxy-2,5-cyclohexadienones for the Synthesis of Polyarylated Phenols
  64. Metal-Free Oxidative Cross-Coupling Reaction of Thiophene Iodonium Salts with Pyrroles
  65. Organo-Iodine(III)-Catalyzed Oxidative Phenol-Arene and Phenol-Phenol Cross-Coupling Reaction
  66. Glycosylation Reaction of <i>Thioglycosides</i> by Using Hypervalent Iodine(III) Reagent as an Excellent Promoter
  67. Hypervalent Iodine-Induced Oxidative Couplings (New Metal-Free Coupling Advances and Their Applications in Natural Product Syntheses)
  68. New Synthesis of Tetrahydrobenzodifurans by Iterative Coupling of Quinone Monoacetals with Alkene Nucleophiles
  69. Stabilized pyrrolyl iodonium salts and metal-free oxidative cross-coupling
  70. Metal-Free Oxidative Biaryl Coupling by Hypervalent Iodine Reagents
  71. Pioneering Metal-Free Oxidative Coupling Strategy of Aromatic Compounds Using Hypervalent Iodine Reagents
  72. The Multiple Reactions in the Monochlorodimedone Assay: Discovery of Unique Dehalolactonizations under Mild Conditions
  73. Suppression Mechanism for Enol-Enol Isomerization of 2-Substituted Dimedones
  74. A new arylation of silyl enol ethers by quinone monoacetal substitution
  75. Phenyliodine Bis(trifluoroacetate) (PIFA) as an Excellent Promoter of 2-Deoxy-2-phthalimido-1-thioglycosides in the Presence of Triflic Acid in Glycosylation Reactions
  76. Clean Synthesis of <i>N</i>-Pyrrolyl Azoles by Metal-Free Oxidative Cross-Coupling Using Recyclable Hypervalent Iodine Reagent
  77. Phenol and Aniline Oxidative Coupling with Alkenes by Using Hypervalent Iodine Dimer for the Rapid Access to Dihydrobenzofurans and Indolines
  78. N1-Selective Oxidative CN Coupling of Azoles with Pyrroles Using a Hypervalent Iodine Reagent
  79. Iodoarene-catalyzed fluorination and aminofluorination by an Ar-I/HF·pyridine/mCPBA system
  80. Efficient Oxidative Spirolactamization by μ-Oxo Bridged Heterocyclic Hypervalent Iodine Compound
  81. New Site-Selective Organoradical Based on Hypervalent Iodine Reagent for Controlled Alkane sp3CH Oxidations
  82. Single-Electron-Transfer (SET)-Induced Oxidative Biaryl Coupling by Polyalkoxybenzene-Derived Diaryliodonium(III) Salts
  83. Organocatalytic C–H/C–H′ Cross-Biaryl Coupling: C-Selective Arylation of Sulfonanilides with Aromatic Hydrocarbons
  84. Brønsted Acid-Controlled [3 + 2] Coupling Reaction of Quinone Monoacetals with Alkene Nucleophiles: A Catalytic System of Perfluorinated Acids and Hydrogen Bond Donor for the Construction of Benzofurans
  85. Metal-Free OxidativeparaCross-Coupling of Phenols
  86. Asymmetric Dearomatizing Spirolactonization of Naphthols Catalyzed by Spirobiindane-Based Chiral Hypervalent Iodine Species
  87. Oxidative Trimerization of Catechol to Hexahydroxytriphenylene
  88. Efficient Synthesis of a Regioregular Oligothiophene Photovoltaic Dye Molecule, MK-2, and Related Compounds: A Cooperative Hypervalent Iodine and Metal-Catalyzed Synthetic Route
  89. Synthesis of Boron-Substituted Diaryliodonium Salts and Selective Transformation into Functionalized Aryl Boronates
  90. Controlled couplings of quinone monoacetals using reusable polystyrene-anchored specific proton catalyst
  91. Efficient Synthesis of Oxygenated Terphenyls and Other Oligomers: Sequential Arylation Reactions Through Phenol Oxidation-Rearomatization
  92. μ-Oxo-Bridged Hypervalent Iodine(III) Compound as an Extreme Oxidant for Aqueous Oxidations
  93. An excellent dual recycling strategy for the hypervalent iodine/nitroxyl radical mediated selective oxidation of alcohols to aldehydes and ketones
  94. HYPERVALENT IODINE INDUCED OXIDATIVE CROSS COUPLING VIA Thiophene CATION RADICAL INTERMEDIATE
  95. Speedy and Clean Hypervalent Iodine/Nitroxyl Radical Mediated Oxidation of Alcohols Using Recyclable Adamantane Reagent with Highly Active 2-Azaadamantane-<i>N</i>-oxyl Organocatalyst
  96. Metal-Free C–H Cross-Coupling toward Oxygenated Naphthalene-Benzene Linked Biaryls
  97. Metal-Free Oxidative Coupling Reactions via σ-Iodonium Intermediates: The Efficient Synthesis of Bithiophenes Using Hypervalent Iodine Reagents
  98. [3 + 2] Coupling of Quinone Monoacetals by Combined Acid–Hydrogen Bond Donor
  99. Coupling of Quinone Monoacetals Promoted by Sandwiched Brønsted Acids: Synthesis of Oxygenated Biaryls
  100. Efficient phenolic oxidations using μ-oxo-bridged phenyliodine trifluoroacetate
  101. Discovery of Stabilized Bisiodonium Salts as Intermediates in the Carbon-Carbon Bond Formation of Alkynes
  102. New synthesis of spirocycles by utilizing in situ forming hypervalent iodine species
  103. Hypervalent Iodine Induced Metal-Free C-H Cross Couplings to Biaryls
  104. One-Pot Syntheses of Diaryliodonium Salts from Aryl Iodides Using Peracetic Acid as Green Oxidant
  105. Metal-Free Regioselective Oxidative Biaryl Coupling Leading to Head-to-Tail Bithiophenes: Reactivity Switching, a Concept Based on the Iodonium(III) Intermediate
  106. Fluoroalcohols: versatile solvents in hypervalent iodine chemistry and syntheses of diaryliodonium(III) salts
  107. Unusual ipso Substitution of Diaryliodonium Bromides Initiated by a Single-Electron-Transfer Oxidizing Process
  108. Enhanced Reactivity of [Hydroxy(tosyloxy)iodo]benzene in Fluoroalcohol Media. Efficient Direct Synthesis of Thienyl(aryl)iodonium Salts
  109. Designer μ-oxo-bridged hypervalent iodine(iii) organocatalysts for greener oxidations
  110. Efficient Phenolic Oxidations to Construct ortho-Spirolactone Structures Using Oxo-Bridged Hypervalent Iodine(III) Compound
  111. Recycling and Catalytic Approaches for the Development of a Rare-Metal-Free Synthetic Method Using Hypervalent Iodine Reagent
  112. Hypervalent iodine(III): selective and efficient single-electron-transfer (SET) oxidizing agent
  113. Development of Rare Metal-Free Synthetic Method Using New Iodine Reagents
  114. Hypervalent iodine(III)/Et4N+Br− combination in water for green and racemization-free aqueous oxidation of alcohols
  115. Metal-Free Oxidative Cross-Coupling of Unfunctionalized Aromatic Compounds
  116. Hypervalent iodine reagents as a new entrance to organocatalysts
  117. Clean and Direct Synthesis of .ALPHA.,.ALPHA.'-Bithiophenes and Bipyrroles by Metal-Free Oxidative Coupling Using Recyclable Hypervalent Iodine(III) Reagents
  118. Organoiodine-Catalyzed Oxidative Spirocyclization of Phenols using Peracetic Acid as a Green and Economic Terminal Oxidant
  119. Clean and Efficient Benzylic C−H Oxidation in Water Using a Hypervalent Iodine Reagent: Activation of Polymeric Iodosobenzene with KBr in the Presence of Montmorillonite-K10
  120. A New H2O2/Acid Anhydride System for the Iodoarene-Catalyzed C−C Bond-Forming Reactions of Phenols
  121. A Chiral Hypervalent Iodine(III) Reagent for Enantioselective Dearomatization of Phenols
  122. Oxidative Cross-Coupling of Arenes Induced by Single-Electron Transfer Leading to Biaryls by Use of Organoiodine(III) Oxidants
  123. Total Synthesis of (±)-γ-Rubromycin on the Basis of Two Aromatic Pummerer-Type Reactions
  124. Regioselective Bipyrrole Coupling of Pyrroles and 3-Substituted Pyrroles Using Phenyliodine(III) Bis(trifluoroacetate)
  125. Direct Lactone Formation by Using Hypervalent Iodine(III) Reagents with KBr via Selective C−H Abstraction Protocol
  126. Versatile direct dehydrative approach for diaryliodonium(iii) salts in fluoroalcohol media
  127. First hypervalent iodine(iii)-catalyzed C–N bond forming reaction: catalytic spirocyclization of amides to N-fused spirolactams
  128. Direct Cyanation of Heteroaromatic Compounds Mediated by Hypervalent Iodine(III) Reagents:  In Situ Generation of PhI(III)−CN Species and Their Cyano Transfer
  129. Development of Environmentally Benign Oxidations Using Hypervalent Iodine (III)Reagents
  130. Direct Synthesis of Bipyrroles Using Phenyliodine Bis(trifluoroacetate) with Bromotrimethylsilane
  131. A Facile and Clean Direct Cyanation of Heteroaromatic Compounds Using a Recyclable Hypervalent Iodine(III) Reagent
  132. Versatile Hypervalent-Iodine(III)-Catalyzed Oxidations withm-Chloroperbenzoic Acid as a Cooxidant
  133. Novel and Direct Oxidative Cyanation Reactions of Heteroaromatic Compounds Mediated by A Hypervalent Iodine(III) Reagent
  134. A unique site-selective reaction of ketones with new recyclable hypervalent iodine(iii) reagents based on a tetraphenylmethane structure
  135. The synthesis of head-to-tail (H–T) dimers of 3-substituted thiophenes by the hypervalent iodine(iii)-induced oxidative biaryl coupling reaction
  136. Preparation and Reactivity of 1,3,5,7-Tetrakis[4-(diacetoxyiodo)phenyl]adamantane, a Recyclable Hypervalent Iodine(III) Reagent
  137. Reaction of Terminal Alkynes with Hydrazines To Give Nitriles, Catalyzed by TpRuCl(PPh3)2:  Novel Catalytic Transformation Involving a Vinylidene Ruthenium Intermediate