All Stories

  1. Hypervalent Iodine(III)-Mediated Oxidative C–H Amination of Phenols and Anilines with Azoles
  2. Functionalized Diaryliodonium Salts with N ‐Reactive Amides: Versatile Reactivity for Constructing Benzo‐Fused Nitrogen Heterocycles
  3. Iron-Catalyzed Nucleophilic Substitution Reactions: An Overview
  4. Isocoumarin Synthesis via Metal-Free C-Arylation of Acetoacetates with ortho-Ester-Functionalized Diaryliodonium Salts
  5. Metal‐Free Intermolecular C–H Imidation of Anilines and Phenols With Sulfonimides
  6. Chemoselectively Functionalized Ketoesters by Halogenative C–C Bond Cleavage of Cyclic Diketones
  7. 14 Recent Advances in Hypervalent Halogen Catalysis
  8. Synthesis of Heterocyclic Sulfonium Triflates by Cu-catalyzed Selective S-arylation with Aryl(mesityl)iodonium Salts
  9. Metal-Free Synthesis of Benzimidazolinones via Oxidative Cyclization Under Hypervalent Iodine Catalysis
  10. Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations
  11. Front Cover: Divergent Synthesis of 4‐Aminotriazoles Through Click Cycloaddition and Generation of Iodonium(III) Triazoles (Eur. J. Org. Chem. 6/2025)
  12. Divergent Synthesis of 4‐Aminotriazoles Through Click Cycloaddition and Generation of Iodonium(III) Triazoles
  13. Recent advances in non-conventional synthesis of N-heterocyclic compounds: emerging strategies and biological perspectives
  14. Transition-metal-free dibenzoxazepinone synthesis by hypervalent iodine-mediated chemoselective arylocyclizations of N-functionalized salicylamides
  15. Metal-Free Synthesis of Benzisoxazolones Utilizing ortho-Ester and ortho-Cyano-Functionalized Diaryliodonium Salts with Protected Hydroxylamines
  16. Practical Synthesis of N-Anilinylphenothiazines Using a Cyclic Hypervalent Iodine Coupling Reagent
  17. Triflic acid-promoted Friedel–Crafts-type carbocyclization of alkenylated biphenyl derivatives: Synthesis and photophysical studies of novel 9,10-dihydrophenanthrenes
  18. Silver-Catalyzed Coupling of Unreactive Carboxylates: Synthesis of α-Fluorinated O-Aryl Esters
  19. Auxiliary strategy for the general and practical synthesis of diaryliodonium(III) salts with diverse organocarboxylate counterions
  20. Borate-mediated aryl polyfluoroalkoxylation under transition-metal-free conditions
  21. Organohypervalent heterocycles
  22. Efficient Metal-Free Oxidative C–H Amination for Accessing Dibenzoxazepinones via μ-Oxo Hypervalent Iodine Catalysis
  23. Iodine(V)-Based Oxidants in Oxidation Reactions
  24. Transition Metal‐Free O‐Arylation of N‐Alkoxybenzamides Enabled by Aryl(trimethoxyphenyl)iodonium Salts
  25. 1,3‐Dipolar Cycloaddition of 3‐Chromonyl‐Substituted Glycine Imino Esters with Arylidenes and in situ Diastereodivergent via Retrocycloaddition
  26. Decarboxylative arylation with diaryliodonium(iii) salts: alternative approach for catalyst-free difluoroenolate coupling to aryldifluoromethyl ketones
  27. Transition-Metal-Free N-Arylation of N-Methoxysulfonamides and N,O-Protected Hydroxylamines with Trimethoxyphenyliodonium (III) Acetates
  28. Cyclic Hypervalent Iodine-Induced Oxidative Phenol and Aniline Couplings with Phenothiazines
  29. Palladium-Catalyzed Organic Reactions Involving Hypervalent Iodine Reagents
  30. Recyclable Hypervalent Iodine Reagents in Modern Organic Synthesis
  31. Ligand- and Counterion-Assisted Phenol O-Arylation with TMP-Iodonium(III) Acetates
  32. Cover Feature: Asymmetric Direct/Stepwise Dearomatization Reactions Involving Hypervalent Iodine Reagents (Chem. Asian J. 4/2022)
  33. Diaryliodonium(iii) salts in one-pot double functionalization of C–IIII and ortho C–H bonds
  34. Iodine(iii) reagents for oxidative aromatic halogenation
  35. Asymmetric Direct/Stepwise Dearomatization Reactions Involving Hypervalent Iodine Reagents
  36. [3 + 2] Coupling of Quinone Monoacetals with Vinyl Ethers Effected by Tetrabutylammonium Triflate: Regiocontrolled Synthesis of 2-Oxygenated Dihydrobenzofurans
  37. Special Issue on Hypervalent Iodine Reagents in Organic Synthesis
  38. Practical Synthesis of 2-Iodosobenzoic Acid (IBA) without Contamination by Hazardous 2-Iodoxybenzoic Acid (IBX) under Mild Conditions
  39. Nucleophilic Aromatic Substitution of Polyfluoroarene to Access Highly Functionalized 10-Phenylphenothiazine Derivatives
  40. Nucleophilic Aromatic Substitution of Polyfluoroarene to Access Highly Functionalized 10-Phenylphenothiazine Derivatives
  41. Halogen-Induced Controllable Cyclizations as Diverse Heterocycle Synthetic Strategy
  42. Halogen-Induced Controllable Cyclizations as Diverse Heterocycle Synthetic Strategy
  43. Practical synthesis of diaryliodonium(iii) triflates using ArI(OAc)2/TfOH/MeCN reaction system
  44. Heteroaryliodonium(III) Salts as Highly Reactive Electrophiles
  45. Recent Topics in Organohalogen Reagents and Compounds
  46. New syntheses of haloketo acid methyl esters and their transformation to halolactones by reductive cyclization
  47. Progress in [18F]Fluorination by Using Aryliodonium(III) Compounds and Application for PET Tracer Syntheses
  48. Regiodivergent oxidation of alkoxyarenes by hypervalent iodine/oxone® system
  49. Benzylic Oxidation and Functionalizations of Xanthenes by Ligand Trasfer Reactions of Hypervalent Iodine Reagents
  50. Nucleophilic Arylation of Halopurines Facilitated by Brønsted Acid in Fluoroalcohol
  51. Synthesis of Uracil-Iodonium(III) Salts for Practical Utilization as Nucleobase Synthetic Modules
  52. Dataset on synthesis and crystallographic structure of phenyl(TMP)iodonium(III) acetate
  53. Recyclable synthesis of mesityl iodonium(III) salts
  54. Efficient N-arylation of azole compounds utilizing selective aryl-transfer TMP-iodonium(III) reagents
  55. Controlled-Coupling of Quinone Monoacetals by New Activation Methods: Regioselective Synthesis of Phenol-Derived Compounds
  56. Oxidative Coupling of N-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst
  57. Asymmetric Construction of Heterocycles via Dearomative Coupling and Addition Reactions of Phenol and Aniline Derivatives
  58. Vicinal Functionalization of Uracil Heterocycles with Base Activation of Iodonium(III) Salts
  59. Selective carboxylation of reactive benzylic C–H bonds by a hypervalent iodine(III)/inorganic bromide oxidation system
  60. Facile Synthesis of Stable Uracil-Iodonium(III) Salts with Various Counterions
  61. Metal-Free Oxidative Cross-Coupling of Pyrroles with Electron-Rich Arenes Using Recyclable Hypervalent Iodine(III) Reagent
  62. Oxidative Biaryl Coupling of N-Aryl Anilines by Using a Hypervalent Iodine(III) Reagent
  63. Chiral Atropisomeric 8,8′-Diiodobinaphthalene for Asymmetric Dearomatizing Spirolactonizations in Hypervalent Iodine Oxidations
  64. Metal-FreeO-Arylation of Carboxylic Acid by Active Diaryliodonium(III) Intermediates Generatedin situfrom Iodosoarenes
  65. Atropisomeric Chiral Diiododienes (Z,Z)-2,3-Di(1-iodoalkylidene)tetralins: Synthesis, Enantiomeric Resolution, and Application in Asymmetric Catalysis
  66. Metal-free Oxidative Cross-Coupling Reaction of Aromatic Compounds Containing Heteroatoms
  67. Selective Aryl Radical Transfers into N-Heteroaromatics from Diaryliodonoium Salts with Trimethoxybenzene Auxiliary
  68. Front Cover Picture: Site-Selective Iron(III) Chloride-Catalyzed Arylation of 4-Aryl-4-methoxy-2,5-cyclohexadienones for the Synthesis of Polyarylated Phenols (Adv. Synth. Catal. 23/2016)
  69. Efficient Coupling Reaction of Quinone Monoacetal with Phenols Leading to Phenol Biaryls
  70. Site-Selective Iron(III) Chloride-Catalyzed Arylation of 4-Aryl-4-methoxy-2,5-cyclohexadienones for the Synthesis of Polyarylated Phenols
  71. Metal-Free Oxidative Cross-Coupling Reaction of Thiophene Iodonium Salts with Pyrroles
  72. Organo-Iodine(III)-Catalyzed Oxidative Phenol-Arene and Phenol-Phenol Cross-Coupling Reaction
  73. Glycosylation Reaction of <i>Thioglycosides</i> by Using Hypervalent Iodine(III) Reagent as an Excellent Promoter
  74. Hypervalent Iodine-Induced Oxidative Couplings (New Metal-Free Coupling Advances and Their Applications in Natural Product Syntheses)
  75. New Synthesis of Tetrahydrobenzodifurans by Iterative Coupling of Quinone Monoacetals with Alkene Nucleophiles
  76. Stabilized pyrrolyl iodonium salts and metal-free oxidative cross-coupling
  77. Metal-Free Oxidative Biaryl Coupling by Hypervalent Iodine Reagents
  78. Pioneering Metal-Free Oxidative Coupling Strategy of Aromatic Compounds Using Hypervalent Iodine Reagents
  79. The Multiple Reactions in the Monochlorodimedone Assay: Discovery of Unique Dehalolactonizations under Mild Conditions
  80. Suppression Mechanism for Enol-Enol Isomerization of 2-Substituted Dimedones
  81. A new arylation of silyl enol ethers by quinone monoacetal substitution
  82. Phenyliodine Bis(trifluoroacetate) (PIFA) as an Excellent Promoter of 2-Deoxy-2-phthalimido-1-thioglycosides in the Presence of Triflic Acid in Glycosylation Reactions
  83. Clean Synthesis of <i>N</i>-Pyrrolyl Azoles by Metal-Free Oxidative Cross-Coupling Using Recyclable Hypervalent Iodine Reagent
  84. Phenol and Aniline Oxidative Coupling with Alkenes by Using Hypervalent Iodine Dimer for the Rapid Access to Dihydrobenzofurans and Indolines
  85. N1-Selective Oxidative CN Coupling of Azoles with Pyrroles Using a Hypervalent Iodine Reagent
  86. Iodoarene-catalyzed fluorination and aminofluorination by an Ar-I/HF·pyridine/mCPBA system
  87. Efficient Oxidative Spirolactamization by μ-Oxo Bridged Heterocyclic Hypervalent Iodine Compound
  88. New Site-Selective Organoradical Based on Hypervalent Iodine Reagent for Controlled Alkane sp3CH Oxidations
  89. Single-Electron-Transfer (SET)-Induced Oxidative Biaryl Coupling by Polyalkoxybenzene-Derived Diaryliodonium(III) Salts
  90. Organocatalytic C–H/C–H′ Cross-Biaryl Coupling: C-Selective Arylation of Sulfonanilides with Aromatic Hydrocarbons
  91. Brønsted Acid-Controlled [3 + 2] Coupling Reaction of Quinone Monoacetals with Alkene Nucleophiles: A Catalytic System of Perfluorinated Acids and Hydrogen Bond Donor for the Construction of Benzofurans
  92. Metal-Free OxidativeparaCross-Coupling of Phenols
  93. Asymmetric Dearomatizing Spirolactonization of Naphthols Catalyzed by Spirobiindane-Based Chiral Hypervalent Iodine Species
  94. Oxidative Trimerization of Catechol to Hexahydroxytriphenylene
  95. Efficient Synthesis of a Regioregular Oligothiophene Photovoltaic Dye Molecule, MK-2, and Related Compounds: A Cooperative Hypervalent Iodine and Metal-Catalyzed Synthetic Route
  96. Synthesis of Boron-Substituted Diaryliodonium Salts and Selective Transformation into Functionalized Aryl Boronates
  97. Controlled couplings of quinone monoacetals using reusable polystyrene-anchored specific proton catalyst
  98. Efficient Synthesis of Oxygenated Terphenyls and Other Oligomers: Sequential Arylation Reactions Through Phenol Oxidation-Rearomatization
  99. μ-Oxo-Bridged Hypervalent Iodine(III) Compound as an Extreme Oxidant for Aqueous Oxidations
  100. An excellent dual recycling strategy for the hypervalent iodine/nitroxyl radical mediated selective oxidation of alcohols to aldehydes and ketones
  101. HYPERVALENT IODINE INDUCED OXIDATIVE CROSS COUPLING VIA Thiophene CATION RADICAL INTERMEDIATE
  102. Speedy and Clean Hypervalent Iodine/Nitroxyl Radical Mediated Oxidation of Alcohols Using Recyclable Adamantane Reagent with Highly Active 2-Azaadamantane-<i>N</i>-oxyl Organocatalyst
  103. Metal-Free C–H Cross-Coupling toward Oxygenated Naphthalene-Benzene Linked Biaryls
  104. Metal-Free Oxidative Coupling Reactions via σ-Iodonium Intermediates: The Efficient Synthesis of Bithiophenes Using Hypervalent Iodine Reagents
  105. [3 + 2] Coupling of Quinone Monoacetals by Combined Acid–Hydrogen Bond Donor
  106. Coupling of Quinone Monoacetals Promoted by Sandwiched Brønsted Acids: Synthesis of Oxygenated Biaryls
  107. Efficient phenolic oxidations using μ-oxo-bridged phenyliodine trifluoroacetate
  108. Discovery of Stabilized Bisiodonium Salts as Intermediates in the Carbon-Carbon Bond Formation of Alkynes
  109. New synthesis of spirocycles by utilizing in situ forming hypervalent iodine species
  110. Hypervalent Iodine Induced Metal-Free C-H Cross Couplings to Biaryls
  111. One-Pot Syntheses of Diaryliodonium Salts from Aryl Iodides Using Peracetic Acid as Green Oxidant
  112. Metal-Free Regioselective Oxidative Biaryl Coupling Leading to Head-to-Tail Bithiophenes: Reactivity Switching, a Concept Based on the Iodonium(III) Intermediate
  113. Fluoroalcohols: versatile solvents in hypervalent iodine chemistry and syntheses of diaryliodonium(III) salts
  114. Unusual ipso Substitution of Diaryliodonium Bromides Initiated by a Single-Electron-Transfer Oxidizing Process
  115. Enhanced Reactivity of [Hydroxy(tosyloxy)iodo]benzene in Fluoroalcohol Media. Efficient Direct Synthesis of Thienyl(aryl)iodonium Salts
  116. Designer μ-oxo-bridged hypervalent iodine(iii) organocatalysts for greener oxidations
  117. Efficient Phenolic Oxidations to Construct ortho-Spirolactone Structures Using Oxo-Bridged Hypervalent Iodine(III) Compound
  118. Recycling and Catalytic Approaches for the Development of a Rare-Metal-Free Synthetic Method Using Hypervalent Iodine Reagent
  119. Hypervalent iodine(III): selective and efficient single-electron-transfer (SET) oxidizing agent
  120. Development of Rare Metal-Free Synthetic Method Using New Iodine Reagents
  121. Hypervalent iodine(III)/Et4N+Br− combination in water for green and racemization-free aqueous oxidation of alcohols
  122. Metal-Free Oxidative Cross-Coupling of Unfunctionalized Aromatic Compounds
  123. Hypervalent iodine reagents as a new entrance to organocatalysts
  124. Clean and Direct Synthesis of .ALPHA.,.ALPHA.'-Bithiophenes and Bipyrroles by Metal-Free Oxidative Coupling Using Recyclable Hypervalent Iodine(III) Reagents
  125. Organoiodine-Catalyzed Oxidative Spirocyclization of Phenols using Peracetic Acid as a Green and Economic Terminal Oxidant
  126. Clean and Efficient Benzylic C−H Oxidation in Water Using a Hypervalent Iodine Reagent: Activation of Polymeric Iodosobenzene with KBr in the Presence of Montmorillonite-K10
  127. A New H2O2/Acid Anhydride System for the Iodoarene-Catalyzed C−C Bond-Forming Reactions of Phenols
  128. A Chiral Hypervalent Iodine(III) Reagent for Enantioselective Dearomatization of Phenols
  129. Oxidative Cross-Coupling of Arenes Induced by Single-Electron Transfer Leading to Biaryls by Use of Organoiodine(III) Oxidants
  130. Total Synthesis of (±)-γ-Rubromycin on the Basis of Two Aromatic Pummerer-Type Reactions
  131. Regioselective Bipyrrole Coupling of Pyrroles and 3-Substituted Pyrroles Using Phenyliodine(III) Bis(trifluoroacetate)
  132. Direct Lactone Formation by Using Hypervalent Iodine(III) Reagents with KBr via Selective C−H Abstraction Protocol
  133. Versatile direct dehydrative approach for diaryliodonium(iii) salts in fluoroalcohol media
  134. First hypervalent iodine(iii)-catalyzed C–N bond forming reaction: catalytic spirocyclization of amides to N-fused spirolactams
  135. Direct Cyanation of Heteroaromatic Compounds Mediated by Hypervalent Iodine(III) Reagents:  In Situ Generation of PhI(III)−CN Species and Their Cyano Transfer
  136. Development of Environmentally Benign Oxidations Using Hypervalent Iodine (III)Reagents
  137. Direct Synthesis of Bipyrroles Using Phenyliodine Bis(trifluoroacetate) with Bromotrimethylsilane
  138. A Facile and Clean Direct Cyanation of Heteroaromatic Compounds Using a Recyclable Hypervalent Iodine(III) Reagent
  139. Versatile Hypervalent-Iodine(III)-Catalyzed Oxidations withm-Chloroperbenzoic Acid as a Cooxidant
  140. Novel and Direct Oxidative Cyanation Reactions of Heteroaromatic Compounds Mediated by A Hypervalent Iodine(III) Reagent
  141. A unique site-selective reaction of ketones with new recyclable hypervalent iodine(iii) reagents based on a tetraphenylmethane structure
  142. The synthesis of head-to-tail (H–T) dimers of 3-substituted thiophenes by the hypervalent iodine(iii)-induced oxidative biaryl coupling reaction
  143. Preparation and Reactivity of 1,3,5,7-Tetrakis[4-(diacetoxyiodo)phenyl]adamantane, a Recyclable Hypervalent Iodine(III) Reagent
  144. Reaction of Terminal Alkynes with Hydrazines To Give Nitriles, Catalyzed by TpRuCl(PPh3)2:  Novel Catalytic Transformation Involving a Vinylidene Ruthenium Intermediate