All Stories

  1. Ligand Effects in Regio‐ and Enantioselective Cobalt‐Catalyzed Intramolecular [4+2]‐ and [2+2]‐Cycloaddition Reactions of Unactivated 1,3‐Diene‐8‐ynes and 1,3‐Diene‐8‐enes

    Article • Angewandte Chemie, September 2025, Wiley

    Professor T V RajanBabu

  2. Ligand Effects in Regio‐ and Enantioselective Cobalt‐Catalyzed Intramolecular [4+2]‐ and [2+2]‐Cycloaddition Reactions of Unactivated 1,3‐Diene‐8‐ynes and 1,3‐Diene‐8‐enes

    Article • Angewandte Chemie, September 2025, Wiley

    Professor T V RajanBabu

  3. Ligand Effects in Carboxylic Ester- and Aldehyde-Assisted β-C–H Activation in Regiodivergent and Enantioselective Cycloisomerization–Hydroalkenylation and Cycloisomerization–Hydroarylation, and [2 + 2 + 2]-Cycloadditions of 1,6-Enynes

    Article • Journal of the American Chemical Society, June 2024, American Chemical Society (ACS)

    Professor T V RajanBabu

  4. Cobalt-Catalyzed Enantioselective Hydroboration of α-Substituted Acrylates

    Article • Journal of the American Chemical Society, March 2024, American Chemical Society (ACS)

    Professor T V RajanBabu

  5. Ligand Control in Co-Catalyzed Regio- and Enantioselective Hydroboration: Homoallyl Secondary Boronates via Uncommon 4,3-Hydroboration of 1,3-Dienes

    Article • Journal of the American Chemical Society, March 2023, American Chemical Society (ACS)

    Professor T V RajanBabu

  6. Chemodivergent, Regio‐ and Enantioselective Cycloaddition Reactions between 1,3‐Dienes and Alkynes

    Article • Angewandte Chemie, January 2023, Wiley

    Professor T V RajanBabu

  7. Chemodivergent, Regio‐ and Enantioselective Cycloaddition Reactions between 1,3‐Dienes and Alkynes

    Article • Angewandte Chemie, January 2023, Wiley

    Professor T V RajanBabu

  8. γ C–H Functionalization of Amines via Triple H-Atom Transfer of a Vinyl Sulfonyl Radical Chaperone

    Article • Journal of the American Chemical Society, July 2022, American Chemical Society (ACS)

    Professor T V RajanBabu

  9. Catalytic Enantioselective Hydrovinylation of Trialkylsilyloxy and Acetoxy-1,3-Dienes: Cationic Co(I) Complexes for the Synthesis of Chiral Enolate Surrogates and Their Applications for Synthesis of Ketones and Cross-Coupling Reagents in High Enantiome...

    Article • ACS Catalysis, April 2022, American Chemical Society (ACS)

    Professor T V RajanBabu

  10. Activator-free single-component Co(i)-catalysts for regio- and enantioselective heterodimerization and hydroacylation reactions of 1,3-dienes. New reduction procedures for synthesis of [L]Co(i)-complexes and comparison to in si...

    Article • Dalton Transactions, January 2022, Royal Society of Chemistry

    Professor T V RajanBabu

  11. A New Paradigm in Enantioselective Cobalt Catalysis: Cationic Cobalt(I) Catalysts for Heterodimerization, Cycloaddition, and Hydrofunctionalization Reactions of Olefins

    Article • Accounts of Chemical Research, November 2021, American Chemical Society (ACS)

    Professor T V RajanBabu

  12. α- and β-Functionalized Ketones from 1,3-Dienes and Aldehydes: Control of Regio- and Enantioselectivity in Hydroacylation of 1,3-Dienes

    Article • Journal of the American Chemical Society, August 2021, American Chemical Society (ACS)

    Professor T V RajanBabu

  13. Cationic Co(I) Catalysts for Regiodivergent Hydroalkenylation of 1,6-Enynes: An Uncommon cis-β-C–H Activation Leads to Z-Selective Coupling of Acrylates

    Article • ACS Catalysis, July 2021, American Chemical Society (ACS)

    Professor T V RajanBabu

  14. Four Mechanistic Mysteries: The Benefits of Writing a Critical Review

    Article • Angewandte Chemie, December 2020, Wiley

    Professor T V RajanBabu

  15. Four Mechanistic Mysteries: The Benefits of Writing a Critical Review

    Article • Angewandte Chemie, December 2020, Wiley

    Professor T V RajanBabu

  16. Mechanism of Cobalt-Catalyzed Heterodimerization of Acrylates and 1,3-Dienes. A Potential Role of Cationic Cobalt(I) Intermediates

    Article • ACS Catalysis, March 2020, American Chemical Society (ACS)

    Professor T V RajanBabu

  17. Catalytic Enantioselective Synthesis of Cyclobutenes from Alkynes and Alkenyl Derivatives

    Article • Journal of the American Chemical Society, September 2019, American Chemical Society (ACS)

    Professor T V RajanBabu

  18. Cationic Co(I)-Intermediates for Hydrofunctionalization Reactions: Regio- and Enantioselective Cobalt-Catalyzed 1,2-Hydroboration of 1,3-Dienes

    Article • Journal of the American Chemical Society, April 2019, American Chemical Society (ACS)

    Professor T V RajanBabu

  19. Demystifying Cp2Ti(H)Cl and Its Enigmatic Role in the Reactions of Epoxides with Cp2TiCl

    Article • Organometallics, November 2018, American Chemical Society (ACS)

    Professor T V RajanBabu

  20. Broadly Applicable Stereoselective Syntheses of Serrulatane, Amphilectane Diterpenes, and Their Diastereoisomeric Congeners Using Asymmetric Hydrovinylation for Absolute Stereochemical Control

    Article • Journal of the American Chemical Society, July 2018, American Chemical Society (ACS)

    Professor T V RajanBabu

  21. Tandem catalysis for asymmetric coupling of ethylene and enynes to functionalized cyclobutanes

    Article • Science, July 2018, American Association for the Advancement of Science

    Professor T V RajanBabu

  22. Retraction of “Chemoselective Reactions of (E)-1,3-Dienes: Cobalt-Mediated Isomerization to (Z)-1,3-Dienes and Reactions with Ethylene”

    Article • Journal of the American Chemical Society, February 2018, American Chemical Society (ACS)

    Professor T V RajanBabu

  23. Catalytic Enantioselective Hetero-dimerization of Acrylates and 1,3-Dienes

    Article • Journal of the American Chemical Society, November 2017, American Chemical Society (ACS)

    Professor T V RajanBabu

  24. Examining the Scope and Thermodynamics of Assembly in Nesting Complexes Comprising Molecular Baskets and TPA Ligands

    Article • Organic Letters, August 2017, American Chemical Society (ACS)

    Professor T V RajanBabu

  25. Control of Selectivity through Synergy between Catalysts, Silanes, and Reaction Conditions in Cobalt-Catalyzed Hydrosilylation of Dienes and Terminal Alkenes

    Article • ACS Catalysis, February 2017, American Chemical Society (ACS)

    Professor T V RajanBabu

  26. Coupling of Propylene Oxide and Lactide at a Porphyrin Chromium(III) Center

    Article • Journal of the American Chemical Society, February 2015, American Chemical Society (ACS)

    Professor T V RajanBabu

  27. Antimicrobial Peptides from Marine Organisms

    Article • January 2015, Springer Science + Business Media

    Professor T V RajanBabu

  28. Cobalt-catalysed asymmetric hydrovinylation of 1,3-dienes

    Article • Chemical Science, January 2015, Royal Society of Chemistry

    Professor T V RajanBabu

  29. ChemInform Abstract: Triarylphosphine Ligands with Hemilabile Alkoxy Groups: Ligands for Nickel(II)-Catalyzed Olefin Dimerization Reactions. Hydrovinylation of Vinylarenes, 1,3-Dienes, and Cycloisomerization of 1,6-Dienes.

    Article • ChemInform, December 2014, Wiley

    Professor T V RajanBabu

  30. Implementing a reliable cryptography based security tool for communication networks

    Article • November 2014, Institute of Electrical & Electronics Engineers (IEEE)

    Professor T V RajanBabu

  31. ChemInform Abstract: Chemoselective Reactions of (E)-1,3-Dienes: Cobalt-Mediated Isomerization to (Z)-1,3-Dienes and Reactions with Ethylene.

    Article • ChemInform, October 2014, Wiley

    Professor T V RajanBabu

  32. ChemInform Abstract: Bimetallic Catalysis in the Highly Enantioselective Ring-Opening Reactions of Aziridines.

    Article • ChemInform, July 2014, Wiley

    Professor T V RajanBabu

  33. Triarylphosphine Ligands with Hemilabile Alkoxy Groups: Ligands for Nickel(II)-Catalyzed Olefin Dimerization Reactions. Hydrovinylation of Vinylarenes, 1,3-Dienes, and Cycloisomerization of 1,6-Dienes

    Article • Advanced Synthesis & Catalysis, June 2014, Wiley

    Professor T V RajanBabu

  34. ChemInform Abstract: Highly Efficient Catalytic Dimerization of Styrenes via Cationic Palladium(II) Complexes.

    Article • ChemInform, May 2014, Wiley

    Professor T V RajanBabu

  35. Chemoselective Reactions of ( E )-1,3-Dienes: Cobalt-Mediated Isomerization to ( Z )-1,3-Dienes and Reactions with Ethylene

    Article • Journal of the American Chemical Society, April 2014, American Chemical Society (ACS)

    Professor T V RajanBabu

  36. Bimetallic catalysis in the highly enantioselective ring–opening reactions of aziridines

    Article • Chemical Science, January 2014, Royal Society of Chemistry

    Professor T V RajanBabu

  37. 5.36 Hydrocyanation in Organic Synthesis

    Article • January 2014, Elsevier

    Professor T V RajanBabu

  38. 5.32 Hydrovinylation Reactions in Organic Synthesis

    Article • January 2014, Elsevier

    Professor T V RajanBabu

  39. Highly Efficient Catalytic Dimerization of StyrenesviaCationic Palladium(II) Complexes

    Article • Advanced Synthesis & Catalysis, December 2013, Wiley

    Professor T V RajanBabu

  40. ChemInform Abstract: Phosphinite and Phosphonite Ligands

    Article • ChemInform, April 2013, Wiley

    Professor T V RajanBabu

  41. Asymmetric Hydrovinylation of Alkenes

    Article • January 2013, Wiley

    Professor T V RajanBabu

  42. Conformation and reactivity in dibenzocyclooctadienes (DBCOD). A general approach to the total synthesis of fully substituted DBCOD lignans via borostannylative cyclization of α,ω-diynes

    Article • Chemical Science, January 2013, Royal Society of Chemistry

    Professor T V RajanBabu

  43. ChemInform Abstract: Asymmetric Hydrovinylation of 1-Vinylcycloalkenes. Reagent Control of Regio- and Stereoselectivity.

    Article • ChemInform, August 2012, Wiley

    Professor T V RajanBabu

  44. Phosphinite and Phosphonite Ligands

    Article • May 2012, Wiley

    Professor T V RajanBabu

  45. Asymmetric Hydrovinylation of 1-Vinylcycloalkenes. Reagent Control of Regio- and Stereoselectivity

    Article • Journal of the American Chemical Society, April 2012, American Chemical Society (ACS)

    Professor T V RajanBabu

  46. Asymmetric Hydrovinylation of Vinylindoles. A Facile Route to Cyclopenta[ g ]indole Natural Products (+)- cis -Trikentrin A and (+)- cis -Trikentrin B

    Article • Journal of the American Chemical Society, March 2012, American Chemical Society (ACS)

    Professor T V RajanBabu

  47. On the stereochemistry of acetylide additions to highly functionalized biphenylcarbaldehydes and multi-component cyclization of 1,n-diynes. Syntheses of dibenzocyclooctadiene lignans

    Article • Chemical Science, January 2012, Royal Society of Chemistry

    Professor T V RajanBabu

  48. NAGATA Aluminium Cyanide Reagent to NUGENT–RAJANBABU Epoxide Homolysis

    Article • January 2012, Elsevier

    Irishi Namboothiri, Professor T V RajanBabu

  49. 5.16 Reduction: Enantioselective Hydrovinylation of Alkenes

    Article • January 2012, Elsevier

    Professor T V RajanBabu

  50. Ethylene in Organic Synthesis: A New Route to Anticholenergic Pyrrolidinoindolines, and Other Molecules with All Carbon-Quaternary Centers via Asymmetric Hydrovinylation

    Article • Organic Letters, December 2011, American Chemical Society (ACS)

    Professor T V RajanBabu

  51. Hydrocyanation of Alkenes and Alkynes

    Article • July 2011, Wiley

    Professor T V RajanBabu

  52. Ethylene in Organic Synthesis. Repetitive Hydrovinylation of Alkenes for Highly Enantioselective Syntheses of Pseudopterosins

    Article • Journal of the American Chemical Society, April 2011, American Chemical Society (ACS)

    Professor T V RajanBabu

  53. Applications of antimicrobial peptides from fish and perspectives for the future

    Article • Peptides, February 2011, Elsevier

    Professor T V RajanBabu

  54. Reactivity and Selectivity in Hydrovinylation of Strained Alkenes

    Article • The Journal of Organic Chemistry, November 2010, American Chemical Society (ACS)

    Professor T V RajanBabu

  55. ChemInform Abstract: Borostannylation of Alkynes and Enynes. Scope and Limitations of the Reaction and Utility of the Adducts.

    Article • ChemInform, September 2010, Wiley

    Professor T V RajanBabu

  56. Stereoselective Cyclization of Functionalized 1, n -Diynes Mediated by [X−Y] Reagents [X−Y = R 3 Si−SnR′ 3 or (R 2 N) 2 B−SnR′ 3 ]: Synthesis and Properties of Atropisomeric 1,3-Dienes

    Article • Journal of the American Chemical Society, September 2010, American Chemical Society (ACS)

    Professor T V RajanBabu

  57. ChemInform Abstract: Stereochemistry of Intramolecular Free-Radical Cyclization Reactions

    Article • ChemInform, August 2010, Wiley

    Professor T V RajanBabu

  58. ChemInform Abstract: Tailored Ligands for Asymmetric Catalysis: The Hydrocyanation of Vinylarenes.

    Article • ChemInform, August 2010, Wiley

    Professor T V RajanBabu

  59. ChemInform Abstract: Beyond Nature′s Chiral Pool: Enantioselective Catalysis in Industry

    Article • ChemInform, August 2010, Wiley

    Professor T V RajanBabu

  60. ChemInform Abstract: Selective Generation of Free Radicals from Epoxides Using a Transition- Metal Radical. A Powerful New Tool for Organic Synthesis.

    Article • ChemInform, August 2010, Wiley

    Professor T V RajanBabu

  61. ChemInform Abstract: Electronic Amplification of Selectivity in Rh-Catalyzed Hydrogenations: D-Glucose-Derived Ligands for the Synthesis of D- or L-Amino Acids.

    Article • ChemInform, August 2010, Wiley

    Professor T V RajanBabu

  62. ChemInform Abstract: Electronic Effects in Asymmetric Catalysis: Enantioselective Carbon- Carbon Bond Forming Processes

    Article • ChemInform, August 2010, Wiley

    Professor T V RajanBabu

  63. ChemInform Abstract: Electronic Effects in Asymmetric Catalysis: Hydroformylation of Olefins.

    Article • ChemInform, August 2010, Wiley

    Professor T V RajanBabu

  64. ChemInform Abstract: Role of Electronic Asymmetry in the Design of New Ligands: The Asymmetric Hydrocyanation Reaction.

    Article • ChemInform, August 2010, Wiley

    Professor T V RajanBabu

  65. ChemInform Abstract: Unprecedented Electronic and Steric Effects in Palladium-Catalyzed Asymmetric Allylation: Switching of Enantioselectivity with a Single Chiral Backbone.

    Article • ChemInform, August 2010, Wiley

    Professor T V RajanBabu

  66. ChemInform Abstract: Functionalized Carbocyclic Derivatives from Carbohydrates: Free Radical and Organometallic Methods

    Article • ChemInform, August 2010, Wiley

    Professor T V RajanBabu

  67. ChemInform Abstract: Asymmetric Hydrovinylation of Unactivated Linear 1,3-Dienes.

    Article • ChemInform, July 2010, Wiley

    Professor T V RajanBabu

  68. ChemInform Abstract: The Hydrovinylation Reaction: A New Highly Selective Protocol Amenable to Asymmetric Catalysis.

    Article • ChemInform, June 2010, Wiley

    Professor T V RajanBabu

  69. ChemInform Abstract: Ligand Tuning in Asymmetric Catalysis: Hydrocyanation and Hydrogenation Reactions

    Article • ChemInform, June 2010, Wiley

    Professor T V RajanBabu

  70. ChemInform Abstract: Catalyzed Cyclization of α,ω-Dienes: A Versatile Protocol for the Synthesis of Functionalized Carbocyclic and Heterocyclic Compounds.

    Article • ChemInform, June 2010, Wiley

    Professor T V RajanBabu

  71. ChemInform Abstract: Synergistic Effects of Hemilabile Coordination and Counterions in Homogeneous Catalysis: New Tunable Monophosphine Ligands for Hydrovinylation Reactions.

    Article • ChemInform, June 2010, Wiley

    Professor T V RajanBabu

  72. ChemInform Abstract: Ligand Tuning in Asymmetric Catalysis: Mono- and Bis-phospholanes for a Prototypical Pd-Catalyzed Asymmetric Allylation Reaction.

    Article • ChemInform, June 2010, Wiley

    Professor T V RajanBabu

  73. ChemInform Abstract: Hydrovinylation of Carbon-Carbon Double Bonds

    Article • ChemInform, June 2010, Wiley

    Professor T V RajanBabu

  74. ChemInform Abstract: Hydrocyanation of Carbon-Carbon Double Bonds

    Article • ChemInform, June 2010, Wiley

    Professor T V RajanBabu

  75. ChemInform Abstract: Highly Flexible Synthetic Routes to Functionalized Phospholanes from Carbohydrates.

    Article • ChemInform, June 2010, Wiley

    Professor T V RajanBabu

  76. ChemInform Abstract: Low Pressure Vinylation of Aryl and Vinyl Halides via Heck-Mizoroki Reactions Using Ethylene.

    Article • ChemInform, June 2010, Wiley

    Professor T V RajanBabu

  77. ChemInform Abstract: Practical Catalysts for Asymmetric Synthesis: Ligands from Natural Sugars for Rh-Catalyzed Asymmetric Synthesis of D- and L-Amino Acids

    Article • ChemInform, June 2010, Wiley

    Professor T V RajanBabu

  78. ChemInform Abstract: First Chelated Chiral N-Heterocyclic Bis-carbene Complexes.

    Article • ChemInform, June 2010, Wiley

    Professor T V RajanBabu

  79. ChemInform Abstract: Metal-Catalyzed Acyl Transfer Reactions of Enol Esters: Role of Y5(OiPr)13O and (thd)2Y(OiPr) as Transesterification Catalysts.

    Article • ChemInform, June 2010, Wiley

    Professor T V RajanBabu

  80. Borostannylation of Alkynes and Enynes. Scope and Limitations of the Reaction and Utility of the Adducts

    Article • Organic Letters, June 2010, American Chemical Society (ACS)

    Professor T V RajanBabu

  81. ChemInform Abstract: Water-Soluble Organometallic Catalysts from Carbohydrates. Part 2. A Strategy for the Preparation of Catalysts (I) with Pendant Quaternary Ammonium Groups Using D-Salicin.

    Article • ChemInform, May 2010, Wiley

    Professor T V RajanBabu

  82. ChemInform Abstract: Asymmetric Synthesis of Functionalized 1,2,3,4-Tetrahydroquinolines.

    Article • ChemInform, May 2010, Wiley

    Professor T V RajanBabu

  83. ChemInform Abstract: Regio- and Stereochemical Control in Bis-Functionalization-Cyclization: Use of Alleneyne Precursors for Carbocyclic and Heterocyclic Synthesis.

    Article • ChemInform, May 2010, Wiley

    Professor T V RajanBabu

  84. ChemInform Abstract: Synthesis, Characterization, and Applicability of Neutral Polyhydroxy Phospholane Derivatives and Their Rhodium(I) Complexes for Reactions in Organic and Aqueous Media.

    Article • ChemInform, May 2010, Wiley

    Professor T V RajanBabu

  85. ChemInform Abstract: Tunable Ligands for Asymmetric Catalysis: Readily Available Carbohydrate-Derived Diarylphosphinites Induce High Selectivity in the Hydrovinylation of Styrene Derivatives

    Article • ChemInform, May 2010, Wiley

    Professor T V RajanBabu

  86. Asymmetric Hydrovinylation of 1,3-Dienes

    Article • Synfacts, May 2010, Thieme Publishing Group

    Professor T V RajanBabu

  87. ChemInform Abstract: Ligand-Assisted Rate Acceleration in Transacylation by an Yttrium-Salen Complex. Demonstration of a Conceptually New Strategy for Metal-Catalyzed Kinetic Resolution of Alcohols.

    Article • ChemInform, May 2010, Wiley

    Professor T V RajanBabu

  88. Annulated Diketopiperazines from Dipeptides or Schöllkopf Reagents via Tandem Cyclization−Intramolecular N-Arylation

    Article • Organic Letters, May 2010, American Chemical Society (ACS)

    Professor T V RajanBabu

  89. Mechanism and Stereoselection in a Y-Catalyzed Transacylation Reaction. A Computational Modeling Study

    Article • The Journal of Organic Chemistry, April 2010, American Chemical Society (ACS)

    Professor T V RajanBabu

  90. Asymmetric Hydrovinylation of Unactivated Linear 1,3-Dienes

    Article • Journal of the American Chemical Society, March 2010, American Chemical Society (ACS)

    Professor T V RajanBabu

  91. Low pressure vinylation of aryl and vinyl halides via Heck–Mizoroki reactions using ethylene

    Article • Tetrahedron, January 2010, Elsevier

    Professor T V RajanBabu

  92. Regiodivergent Ring Opening of Chiral Aziridines

    Article • Science, December 2009, American Association for the Advancement of Science

    Professor T V RajanBabu

  93. ChemInform Abstract: Seleniranium Ion Triggered Reactions: New Aspects of Friedel-Crafts and N-Detosylative Cyclizations.

    Article • ChemInform, November 2009, Wiley

    Professor T V RajanBabu

  94. ChemInform Abstract: Facile Pd(II)- and Ni(II)-Catalyzed Isomerization of Terminal Alkenes into 2-Alkenes.

    Article • ChemInform, November 2009, Wiley

    Professor T V RajanBabu

  95. ChemInform Abstract: Tunable Phosphoramidite Ligands for Asymmetric Hydrovinylation: Ligands par excellence for Generation of All-Carbon Quaternary Centers.

    Article • ChemInform, October 2009, Wiley

    Professor T V RajanBabu

  96. ChemInform Abstract: Catalytic Asymmetric Synthesis Using Feedstocks: An Enantioselective Route to 2-Arylpropionic Acids and 1-Arylethyl Amines via Hydrovinylation of Vinyl Arenes

    Article • ChemInform, September 2009, Wiley

    Professor T V RajanBabu

  97. Metal-Mediated Isomerization of Terminal Olefins

    Article • Synfacts, August 2009, Thieme Publishing Group

    Professor T V RajanBabu

  98. ChemInform Abstract: In Pursuit of an Ideal Carbon-Carbon Bond-Forming Reaction: Development and Applications of the Hydrovinylation of Olefins

    Article • ChemInform, July 2009, Wiley

    Professor T V RajanBabu

  99. Catalytic Asymmetric Synthesis Using Feedstocks: An Enantioselective Route to 2-Arylpropionic Acids and 1-Arylethyl Amines via Hydrovinylation of Vinyl Arenes

    Article • The Journal of Organic Chemistry, July 2009, American Chemical Society (ACS)

    Professor T V RajanBabu

  100. Seleniranium Ion-Triggered Reactions: New Aspects of Friedel−Crafts and N-Detosylative Cyclizations

    Article • Organic Letters, July 2009, American Chemical Society (ACS)

    Professor T V RajanBabu

  101. A Theoretical Investigation of the Ni(II)-Catalyzed Hydrovinylation of Styrene

    Article • Organometallics, June 2009, American Chemical Society (ACS)

    Professor T V RajanBabu, Eluvathingal Jemmis

  102. Facile Pd(II)- and Ni(II)-Catalyzed Isomerization of Terminal Alkenes into 2-Alkenes

    Article • The Journal of Organic Chemistry, June 2009, American Chemical Society (ACS)

    Professor T V RajanBabu

  103. ChemInform Abstract: Enantioselective Desymmetrization of meso-Aziridines with TMSN3or TMSCN Catalyzed by Discrete Yttrium Complexes.

    Article • ChemInform, June 2009, Wiley

    Professor T V RajanBabu

  104. Tunable Phosphoramidite Ligands for Asymmetric Hydrovinylation: Ligands par excellence for Generation of All-Carbon Quaternary Centers

    Article • Synthesis, May 2009, Thieme Publishing Group

    Professor T V RajanBabu

  105. Catalytic Asymmetric Synthesis Using Feedstocks: An Enantioselective Route to 2-Arylpropionic Acids and 1-Arylethyl Amines via Hydrovinylation of Vinyl Arenes

    Article • The Journal of Organic Chemistry, April 2009, American Chemical Society (ACS)

    Professor T V RajanBabu

  106. Yttrium-Catalyzed Desymmetrization of Aziridines

    Article • Synfacts, March 2009, Thieme Publishing Group

    Professor T V RajanBabu

  107. In Pursuit of an Ideal Carbon-Carbon Bond-Forming Reaction: Development and Applications of the Hydrovinylation of Olefins

    Article • Synlett, March 2009, Thieme Publishing Group

    Professor T V RajanBabu

  108. Enantioselective Desymmetrization ofmeso-Aziridines with TMSN3or TMSCN Catalyzed by Discrete Yttrium Complexes

    Article • Angewandte Chemie, January 2009, Wiley

    Professor T V RajanBabu

  109. Innentitelbild: Enantioselective Desymmetrization ofmeso-Aziridines with TMSN3or TMSCN Catalyzed by Discrete Yttrium Complexes (Angew. Chem. 6/2009)

    Article • Angewandte Chemie, January 2009, Wiley

    Professor T V RajanBabu

  110. Enantioselective Desymmetrization ofmeso-Aziridines with TMSN3or TMSCN Catalyzed by Discrete Yttrium Complexes

    Article • Angewandte Chemie, January 2009, Wiley

    Professor T V RajanBabu

  111. Inside Cover: Enantioselective Desymmetrization ofmeso-Aziridines with TMSN3or TMSCN Catalyzed by Discrete Yttrium Complexes (Angew. Chem. Int. Ed. 6/2009)

    Article • Angewandte Chemie, January 2009, Wiley

    Professor T V RajanBabu

  112. (R)-3-Methyl-3-Phenyl-1-PenteneViaCatalytic Asymmetric Hydrovinylation

    Article • October 2008, Wiley

    Professor T V RajanBabu

  113. (R)-2,2′-Binaphthoyl-(S,S)-DI(1-Phenylethyl) Aminophosphine. Scalable Protocols for The Syntheses of Phosphoramidite (Feringa) Ligands

    Article • October 2008, Wiley

    Professor T V RajanBabu

  114. ChemInform Abstract: Efficient, Selective, and Green: Catalyst Tuning for Highly Enantioselective Reactions of Ethylene.

    Article • ChemInform, September 2008, Wiley

    Professor T V RajanBabu

  115. Catalyzed Cyclizations Leading to Enrichment of Functionality and Chirality. A General Approach to Dibenzocyclooctadiene Lignans from α,ω-Diynes

    Article • Organic Letters, August 2008, American Chemical Society (ACS)

    Professor T V RajanBabu

  116. Formation of a Chiral Quaternary Centers via Asymmetric Hydrovinylation

    Article • Synfacts, July 2008, Thieme Publishing Group

    Professor T V RajanBabu

  117. Ligand Tuning in Asymmetric Hydrovinylation of 1,3-Dienes: A Stereoselective Route to Either Steroid-C 20 ( S ) or -C 20 ( R ) Derivatives

    Article • Journal of the American Chemical Society, July 2008, American Chemical Society (ACS)

    Professor T V RajanBabu

  118. Conformationally Driven Asymmetric Induction of a Catalytic Dendrimer

    Article • Journal of the American Chemical Society, June 2008, American Chemical Society (ACS)

    Professor T V RajanBabu

  119. Efficient, Selective, and Green:  Catalyst Tuning for Highly Enantioselective Reactions of Ethylene

    Article • Organic Letters, April 2008, American Chemical Society (ACS)

    Professor T V RajanBabu

  120. ChemInform Abstract: Exceptionally Active Yttrium—Salen Complexes for the Catalyzed Ring Opening of Epoxides by TMSCN and TMSN3.

    Article • ChemInform, March 2008, Wiley

    Professor T V RajanBabu

  121. Yttrium-Salen Catalyst for the Enantioselective Opening of Epoxides

    Article • Synfacts, February 2008, Thieme Publishing Group

    Professor T V RajanBabu

  122. Exceptionally Active Yttrium−Salen Complexes for the Catalyzed Ring Opening of Epoxides by TMSCN and TMSN 3

    Article • The Journal of Organic Chemistry, November 2007, American Chemical Society (ACS)

    Professor T V RajanBabu

  123. Tris(dimethylamino)sulfonium Difluorotrimethylsilicate

    Article • September 2007, Wiley

    Professor T V RajanBabu

  124. Syntheses and Applications of 2-Phosphino-2′-alkoxy-1,1′-binaphthyl Ligands. Development of a Working Model for Asymmetric Induction in Hydrovinylation Reactions.

    Article • ChemInform, August 2007, Wiley

    Professor T V RajanBabu

  125. A Working Model for Asymmetric Induction in Hydrovinylation Reactions

    Article • Synfacts, May 2007, Thieme Publishing Group

    Professor T V RajanBabu

  126. Syntheses and Applications of 2-Phosphino-2‘-alkoxy-1,1‘-binaphthyl Ligands. Development of a Working Model for Asymmetric Induction in Hydrovinylation Reactions

    Article • The Journal of Organic Chemistry, March 2007, American Chemical Society (ACS)

    Professor T V RajanBabu

  127. Nickel(0)-Catalyzed Asymmetric Hydrocyanation of 1,3-Dienes.

    Article • ChemInform, January 2007, Wiley

    Professor T V RajanBabu

  128. Radicals in Synthesis I:  Methods and Mechanisms. Topics in Current Chemistry, 263 Edited by Andreas Gansäuer (Universität Bonn, Germany) Springer:  Berlin, Heidelberg, New York. 2006. xii + 204 pp. $ 209. ISBN 3-540-31329-X.

    Article • Journal of the American Chemical Society, December 2006, American Chemical Society (ACS)

    Professor T V RajanBabu

  129. All-Carbon Quaternary Centers via Catalytic Asymmetric Hydrovinylation. New Approaches to the Exocyclic Side Chain Stereochemistry Problem.

    Article • ChemInform, September 2006, Wiley

    Professor T V RajanBabu

  130. Nickel(0)-Catalyzed Asymmetric Hydrocyanation of 1,3-Dienes

    Article • Organic Letters, September 2006, American Chemical Society (ACS)

    Professor T V RajanBabu

  131. All-Carbon Quaternary Centers via Catalytic Asymmetric Hydrovinylation

    Article • Synfacts, August 2006, Thieme Publishing Group

    Professor T V RajanBabu

  132. Hydrovinylation of 1,3-Dienes: A New Protocol, and Asymmetric Variation, and a Potential Solution to the Exocyclic Side Chain Stereochemistry Problem.

    Article • ChemInform, May 2006, Wiley

    Professor T V RajanBabu

  133. All-Carbon Quaternary Centers via Catalytic Asymmetric Hydrovinylation. New Approaches to the Exocyclic Side Chain Stereochemistry Problem

    Article • Journal of the American Chemical Society, May 2006, American Chemical Society (ACS)

    Professor T V RajanBabu

  134. Trimethylsilyltributylstannane

    Article • April 2006, Wiley

    Professor T V RajanBabu

  135. Fouling and cleaning of seawater reverse osmosis membranes in Kalpakkam nuclear desalination plant

    Article • International Journal of Nuclear Desalination, January 2006, Inderscience Publishers

    Professor T V RajanBabu

  136. Hydrovinylation of 1,3-Dienes:  A New Protocol, an Asymmetric Variation, and a Potential Solution to the Exocyclic Side Chain Stereochemistry Problem

    Article • Journal of the American Chemical Society, January 2006, American Chemical Society (ACS)

    Professor T V RajanBabu

  137. Transition Metal Catalyzed Alkene and Alkyne Hydrocyanations

    Article • ChemInform, November 2005, Wiley

    Professor T V RajanBabu

  138. 1,1-Di-t-butyl Peroxide

    Article • October 2005, Wiley

    Professor T V RajanBabu

  139. 1,1-Di-tert-butyl Peroxide

    Article • October 2005, Wiley

    Professor T V RajanBabu

  140. Dibenzoyl Peroxide

    Article • October 2005, Wiley

    Professor T V RajanBabu

  141. Dibenzoyl Peroxide

    Article • October 2005, Wiley

    Professor T V RajanBabu

  142. Di-n-butyltin Oxide

    Article • October 2005, Wiley

    Professor T V RajanBabu

  143. Di-n-butyltin Oxide

    Article • October 2005, Wiley

    Professor T V RajanBabu

  144. Tunable phosphinite, phosphite and phosphoramidite ligands for the asymmetric hydrovinylation reactions

    Article • Tetrahedron, June 2005, Elsevier

    Professor T V RajanBabu

  145. Silylstannylation of Highly Functionalized Acetylenes. Synthesis of Precursors for Annulations via Radical or Heck Reactions.

    Article • ChemInform, February 2005, Wiley

    Professor T V RajanBabu

  146. Silylstannylation of Allenes and Silylstannylation?Cyclization of Allenynes. Synthesis of Highly Functionalized Allylstannanes and Carbocyclic and Heterocyclic Compounds.

    Article • ChemInform, February 2005, Wiley

    Professor T V RajanBabu

  147. Tuning the Acceptors in Catalyzed Cyclizations Initiated by Allenes. Silylstannylation/Cyclization of Allene-Aldehydes for Synthesis of Polyalkylated Indolizidines Including 223A Congeners

    Article • The Journal of Organic Chemistry, December 2004, American Chemical Society (ACS)

    Professor T V RajanBabu

  148. Tri- n -butylstannane

    Article • October 2004, Wiley

    Professor T V RajanBabu

  149. Tri-n-butylstannane

    Article • October 2004, Wiley

    Professor T V RajanBabu

  150. Silylstannylation of Highly Functionalized Acetylenes. Synthesis of Precursors for Annulations via Radical or Heck Reactions

    Article • Organic Letters, October 2004, American Chemical Society (ACS)

    Professor T V RajanBabu

  151. Silylstannylation of Allenes and Silylstannylation−Cyclization of Allenynes. Synthesis of Highly Functionalized Allylstannanes and Carbocyclic and Heterocyclic Compounds

    Article • The Journal of Organic Chemistry, October 2004, American Chemical Society (ACS)

    Professor T V RajanBabu

  152. Chiral Benzyl Centers through Asymmetric Catalysis. A Three-Step Synthesis of ( R )-(−)-α-Curcumene via Asymmetric Hydrovinylation

    Article • Organic Letters, September 2004, American Chemical Society (ACS)

    Professor T V RajanBabu

  153. Homogeneous Two-Component Polycondensation Without Strict Stoichiometric Balance via the Tsuji—Trost Reaction: Remote Control of Two Reaction Sites by Catalysis.

    Article • ChemInform, August 2004, Wiley

    Professor T V RajanBabu

  154. Asymmetric Catalysis in Water: Prospects and Problems of Using Hydroxyphosphines and Hydroxyphosphinites as Ligands

    Article • ChemInform, July 2004, Wiley

    Professor T V RajanBabu

  155. Homogeneous Two-Component Polycondensation without Strict Stoichiometric Balance via the Tsuji−Trost Reaction:  Remote Control of Two Reaction Sites by Catalysis

    Article • Journal of the American Chemical Society, May 2004, American Chemical Society (ACS)

    Professor T V RajanBabu

  156. Fine-Tuning Monophosphine Ligands for Enhanced Enantioselectivity. Influence of Chiral Hemilabile Pendant Groups

    Article • Organic Letters, April 2004, American Chemical Society (ACS)

    Professor T V RajanBabu

  157. Heterodimerization of Olefins. Part 1. Hydrovinylation Reactions of Olefins that Are Amenable to Asymmetric Catalysis.

    Article • ChemInform, March 2004, Wiley

    Professor T V RajanBabu

  158. Axial Chirality in 1,4-Disubstituted ( ZZ )-1,3-Dienes. Surprisingly Low Energies of Activation for the Enantiomerization in Synthetically Useful Fluxional Molecules

    Article • Journal of the American Chemical Society, December 2003, American Chemical Society (ACS)

    Professor T V RajanBabu

  159. Asymmetric Hydrovinylation Reaction

    Article • ChemInform, November 2003, Wiley

    Professor T V RajanBabu

  160. Hydrovinylation of Norbornene. Ligand-Dependent Selectivity and Asymmetric Variations

    Article • Organic Letters, November 2003, American Chemical Society (ACS)

    Professor T V RajanBabu

  161. Asymmetric Catalysis in Water: Prospects and Problems of Using Hydroxyphosphines and Hydroxyphosphinites as Ligands

    Article • Current Organic Chemistry, November 2003, Bentham Science Publishers

    Professor T V RajanBabu

  162. Stereochemical control in radical cyclization routes to N-glycosides: role of protecting groups and of the configuration (E versus Z) of the acceptors

    Article • Tetrahedron Asymmetry, October 2003, Elsevier

    Professor T V RajanBabu

  163. Heterodimerization of Olefins. 1. Hydrovinylation Reactions of Olefins That Are Amenable to Asymmetric Catalysis

    Article • The Journal of Organic Chemistry, October 2003, American Chemical Society (ACS)

    Professor T V RajanBabu

  164. Ligand Tuning as a Tool for the Discovery of New Catalytic Asymmetric Processes

    Article • ChemInform, September 2003, Wiley

    Professor T V RajanBabu

  165. Asymmetric Hydrovinylation Reaction

    Article • Chemical Reviews, August 2003, American Chemical Society (ACS)

    Professor T V RajanBabu

  166. A New Reaction Manifold for the Barton Radical Intermediates: Synthesis of N-Heterocyclic Furanosides and Pyranosides via the Formation of the C1—C2 Bond.

    Article • ChemInform, July 2003, Wiley

    Professor T V RajanBabu

  167. Ligand Tuning as a Tool for the Discovery of New Catalytic Asymmetric Processes

    Article • Current Organic Chemistry, March 2003, Bentham Science Publishers

    Professor T V RajanBabu

  168. A New Reaction Manifold for the Barton Radical Intermediates:  Synthesis of N -Heterocyclic Furanosides and Pyranosides via the Formation of the C 1 −C 2 Bond

    Article • Journal of the American Chemical Society, February 2003, American Chemical Society (ACS)

    Professor T V RajanBabu

  169. Radicals in Organic Synthesis. Volume 1. Basic Principles; Volume 2. Applications Edited by Philippe Renaud (Université De Fribourg) and Mukund P. Sibi (North Dakota State University). Wiley-VCH:  Weinheim and New York. 2001. xxvi + 518 pp (Vol. 1) and...

    Article • Journal of the American Chemical Society, October 2002, American Chemical Society (ACS)

    Professor T V RajanBabu

  170. Ligand-Assisted Rate Acceleration in Transacylation by a Yttrium−Salen Complex. Demonstration of a Conceptually New Strategy for Metal-Catalyzed Kinetic Resolution of Alcohols

    Article • Organic Letters, May 2002, American Chemical Society (ACS)

    Professor T V RajanBabu

  171. Tunable Ligands for Asymmetric Catalysis:  Readily Available Carbohydrate-Derived Diarylphosphinites Induce High Selectivity in the Hydrovinylation of Styrene Derivatives

    Article • Journal of the American Chemical Society, February 2002, American Chemical Society (ACS)

    Professor T V RajanBabu

  172. Synthesis, Characterization, and Applicability of Neutral Polyhydroxy Phospholane Derivatives and Their Rhodium(I) Complexes for Reactions in Organic and Aqueous Media

    Article • Journal of the American Chemical Society, October 2001, American Chemical Society (ACS)

    Professor T V RajanBabu

  173. Regio- and Stereochemical Control in Bis-functionalization−Cyclization:  Use of Alleneyne Precursors for Carbocyclic and Heterocyclic Synthesis

    Article • Journal of the American Chemical Society, August 2001, American Chemical Society (ACS)

    Professor T V RajanBabu

  174. Asymmetric Synthesis of Functionalized 1,2,3,4-Tetrahydroquinolines

    Article • Organic Letters, June 2001, American Chemical Society (ACS)

    Professor T V RajanBabu

  175. ChemInform Abstract: Ligand Substituent Effects on Asymmetric Induction. Effect of Structural Variations of the DIOP Ligand on the Rh-Catalyzed Asymmetric Hydrogenation of Enamides.

    Article • ChemInform, May 2001, Wiley

    Professor T V RajanBabu

  176. Water-Soluble Organometallic Catalysts from Carbohydrates. 2. A Strategy for the Preparation of Catalysts with Pendant Quaternary Ammonium Groups Using d -Salicin

    Article • The Journal of Organic Chemistry, May 2001, American Chemical Society (ACS)

    Professor T V RajanBabu

  177. Galvinoxyl

    Article • April 2001, Wiley

    Professor T V RajanBabu

  178. Electrochemical Methods

    Article • April 2001, Wiley

    Professor T V RajanBabu

  179. Ketene Bis(trimethylsilyl) Acetal

    Article • April 2001, Wiley

    Professor T V RajanBabu

  180. 1-Methoxy-2-methyl-1-(trimethylsilyloxy)propene

    Article • April 2001, Wiley

    Professor T V RajanBabu

  181. Tris(dimethylamino)sulfonium Difluorotrimethylsilicate

    Article • April 2001, Wiley

    Professor T V RajanBabu

  182. ChemInform Abstract: Controlling Asymmetric Catalyzed Reactions Through Ligand Effects

    Article • ChemInform, December 2000, Wiley

    Professor T V RajanBabu

  183. ChemInform Abstract: First Demonstration of Helical Chirality in 1,4-Disubstituted (Z,Z)-1,3-Dienes: R3Si-SnR′3-Mediated Cyclization of 1,6-Diynes.

    Article • ChemInform, December 2000, Wiley

    Professor T V RajanBabu

  184. Ligand Substituent Effects on Asymmetric Induction. Effect of Structural Variations of the DIOP Ligand on the Rh-Catalyzed Asymmetric Hydrogenation of Enamides

    Article • Organic Letters, December 2000, American Chemical Society (ACS)

    Professor T V RajanBabu

  185. First Demonstration of Helical Chirality in 1,4-Disubstituted ( Z,Z )-1,3-Dienes:  R 3 Si−SnR‘ 3 -Mediated Cyclization of 1,6-Diynes

    Article • Journal of the American Chemical Society, September 2000, American Chemical Society (ACS)

    Professor T V RajanBabu

  186. Heterodimerization of Propylene and Vinylarenes: Functional Group Compatibility in a Highly Efficient Ni-Catalyzed Carbon–Carbon Bond-Forming Reaction

    Article • Tetrahedron, April 2000, Elsevier

    Professor T V RajanBabu

  187. First Chelated Chiral N -Heterocyclic Bis- Carbene Complexes

    Article • Organic Letters, April 2000, American Chemical Society (ACS)

    Professor T V RajanBabu

  188. Metal-Catalyzed Acyl Transfer Reactions of Enol Esters: Role of Y 5 (O i Pr) 13 O and (thd) 2 Y(O i Pr) as Transesterification Catalysts

    Article • Organic Letters, April 2000, American Chemical Society (ACS)

    Professor T V RajanBabu

  189. Ligand Tuning in Asymmetric Catalysis: Mono- and Bis-Phospholanes for a Prototypical Pd-Catalyzed Asymmetric Allylation Reaction

    Article • Organic Letters, February 2000, American Chemical Society (ACS)

    Professor T V RajanBabu

  190. Highly Flexible Synthetic Routes to Functionalized Phospholanes from Carbohydrates

    Article • The Journal of Organic Chemistry, February 2000, American Chemical Society (ACS)

    Professor T V RajanBabu

  191. Ligand Tuning in Asymmetric Catalysis: Mono- and Bis-Phospholanes for a Prototypical Pd-Catalyzed Asymmetric Allylation Reaction

    Article • Organic Letters, January 2000, American Chemical Society (ACS)

    Professor T V RajanBabu

  192. Water-Soluble Organometallic Catalysts from Carbohydrates. 1. Diphosphinite−Rh Complexes

    Article • Organic Letters, October 1999, American Chemical Society (ACS)

    Professor T V RajanBabu

  193. Synergistic Effects of Hemilabile Coordination and Counterions in Homogeneous Catalysis:  New Tunable Monophosphine Ligands for Hydrovinylation Reactions

    Article • Journal of the American Chemical Society, October 1999, American Chemical Society (ACS)

    Professor T V RajanBabu

  194. Substituent Effects of Ligands on Asymmetric Induction in a Prototypical Palladium-Catalyzed Allylation Reaction:  Making Both Enantiomers of a Product in High Optical Purity Using the Same Source of Chirality

    Article • The Journal of Organic Chemistry, October 1999, American Chemical Society (ACS)

    Professor T V RajanBabu

  195. Hydrovinylation and Related Reactions: New Protocols and Control Elements in Search of Greater Synthetic Efficiency and Selectivity

    Article • Chemistry - A European Journal, July 1999, Wiley

    Professor T V RajanBabu

  196. Electronic Effects in Asymmetric Catalysis:  Structural Studies of Precatalysts and Intermediates in Rh-Catalyzed Hydrogenation of Dimethyl Itaconate and Acetamidocinnamic Acid Derivatives Using C 2 -Symmetric Diarylphosphinite Ligands

    Article • The Journal of Organic Chemistry, May 1999, American Chemical Society (ACS)

    Professor T V RajanBabu

  197. Catalyzed Cyclization of α,ω-Dienes:  A Versatile Protocol for the Synthesis of Functionalized Carbocyclic and Heterocyclic Compounds

    Article • Journal of the American Chemical Society, August 1998, American Chemical Society (ACS)

    Professor T V RajanBabu

  198. Ligand tuning in asymmetric catalysis

    Article • January 1998, Elsevier

    Professor T V RajanBabu

  199. The Hydrovinylation Reaction:  A New Highly Selective Protocol Amenable to Asymmetric Catalysis

    Article • Journal of the American Chemical Society, January 1998, American Chemical Society (ACS)

    Professor T V RajanBabu

  200. Carbohydrate Phosphinites as Practical Ligands in Asymmetric Catalysis:  Electronic Effects and Dependence of Backbone Chirality in Rh-Catalyzed Asymmetric Hydrogenations. Synthesis of R - or S -Amino Acids Using Natural Sugars as Ligand Precursors

    Article • The Journal of Organic Chemistry, August 1997, American Chemical Society (ACS)

    Professor T V RajanBabu

  201. Nickel-catalyzed asymmetric allylation of alkyl Grignard reagents. Effect of ligands, leaving groups and a kinetic resolution with a hard nucleophile

    Article • Tetrahedron Letters, March 1997, Elsevier

    Professor T V RajanBabu

  202. Unprecedented Electronic and Steric Effects in Palladium-Catalyzed Asymmetric Allylation: Switching of Enantioselectivity with a Single Chiral Backbone

    Article • Synlett, August 1996, Thieme Publishing Group

    Professor T V RajanBabu

  203. Role of Electronic Asymmetry in the Design of New Ligands:  The Asymmetric Hydrocyanation Reaction

    Article • Journal of the American Chemical Society, January 1996, American Chemical Society (ACS)

    Professor T V RajanBabu

  204. Ligand Electronic Effects in Asymmetric Catalysis: Enhanced Enantioselectivity in the Asymmetric Hydrocyanation of Vinylarenes

    Article • Journal of the American Chemical Society, November 1994, American Chemical Society (ACS)

    Professor T V RajanBabu

  205. Electronic effects in asymmetric catalysis: Hydroformylation of olefins

    Article • Tetrahedron Letters, June 1994, Elsevier

    Professor T V RajanBabu

  206. Electronic Amplification of Selectivity in Rh-Catalyzed Hydrogenations: D-Glucose-Derived Ligands for the Synthesis of D- or L-Amino Acids

    Article • Journal of the American Chemical Society, May 1994, American Chemical Society (ACS)

    Professor T V RajanBabu

  207. Selective Generation of Free Radicals from Epoxides Using a Transition-Metal Radical. A Powerful New Tool for Organic Synthesis

    Article • Journal of the American Chemical Society, February 1994, American Chemical Society (ACS)

    Professor T V RajanBabu

  208. Electronic effects in asymmetric catalysis: Enantioselective carbon-carbon bond forming processes

    Article • Pure and Applied Chemistry, January 1994, De Gruyter

    Professor T V RajanBabu

  209. Beyond Nature's Chiral Pool: Enantioselective Catalysis in Industry

    Article • Science, January 1993, American Association for the Advancement of Science

    Professor T V RajanBabu

  210. Tailored ligands for asymmetric catalysis: the hydrocyanation of vinyl arenes

    Article • Journal of the American Chemical Society, July 1992, American Chemical Society (ACS)

    Professor T V RajanBabu

  211. Stereochemistry of intramolecular free-radical cyclization reactions

    Article • Accounts of Chemical Research, May 1991, American Chemical Society (ACS)

    Professor T V RajanBabu

  212. Free radical-mediated reduction and deoxygenation of epoxides

    Article • Journal of the American Chemical Society, August 1990, American Chemical Society (ACS)

    Professor T V RajanBabu

  213. Intermolecular addition of epoxides to activated olefins: a new reaction

    Article • Journal of the American Chemical Society, June 1989, American Chemical Society (ACS)

    Professor T V RajanBabu

  214. Stereochemical control in hex-5-enyl radical cyclizations: from carbohydrates to carbocycles. 3

    Article • Journal of the American Chemical Society, March 1989, American Chemical Society (ACS)

    Professor T V RajanBabu

  215. Stereochemical control in hex-5-enyl radical cyclizations: axial vs equatorial 2-(1-but-3-enyl)cyclohexyl radicals

    Article • Journal of the American Chemical Society, January 1989, American Chemical Society (ACS)

    Professor T V RajanBabu

  216. Transition-metal-centered radicals in organic synthesis. Titanium(III)-induced cyclization of epoxy olefins

    Article • Journal of the American Chemical Society, December 1988, American Chemical Society (ACS)

    Professor T V RajanBabu

  217. Stereoselective cyclization of enynes mediated by metallocene reagents

    Article • Journal of the American Chemical Society, October 1988, American Chemical Society (ACS)

    Professor T V RajanBabu

  218. From carbohydrates to carbocycles. 2. A free radical route to Corey lactone and other prostanoid intermediates

    Article • The Journal of Organic Chemistry, September 1988, American Chemical Society (ACS)

    Professor T V RajanBabu

  219. Group transfer polymerization with polyunsaturated esters and silyl polyenolates

    Article • Journal of the American Chemical Society, August 1988, American Chemical Society (ACS)

    Professor T V RajanBabu

  220. Stereochemical Control in Hex-5-Enyl Radical Cyclizations

    Article • January 1988, Springer Science + Business Media

    Professor T V RajanBabu

  221. From carbohydrates to optically active carbocycles I: stereochemical control in sugar hex-5-enyl radical cyclization

    Article • Journal of the American Chemical Society, January 1987, American Chemical Society (ACS)

    Professor T V RajanBabu

  222. 1-Methylene sugars as C-glycoside precursors

    Article • The Journal of Organic Chemistry, December 1986, American Chemical Society (ACS)

    Professor T V RajanBabu

  223. .alpha.-Nitroarylation of ketones and esters: an exceptionally facile synthesis of indoles, 2-indolinones and arylacetic acids

    Article • The Journal of Organic Chemistry, May 1986, American Chemical Society (ACS)

    Professor T V RajanBabu

  224. Palladium(0)-catalyzed C-glycosylation: a facile alkylation of trifluoroacetylglucal

    Article • The Journal of Organic Chemistry, September 1985, American Chemical Society (ACS)

    Professor T V RajanBabu

  225. Nucleophilic addition of silyl enol ethers to aromatic nitro compounds: scope and mechanism of reaction

    Article • Journal of the American Chemical Society, September 1985, American Chemical Society (ACS)

    Professor T V RajanBabu

  226. Silyl stannanes: useful reagents for bis-functionalization of .alpha.,.beta.-unsaturated ketones and acetylenes

    Article • The Journal of Organic Chemistry, September 1985, American Chemical Society (ACS)

    Professor T V RajanBabu

  227. Nucleophilic addition of silyl enol ethers to aromatic nitro compounds: a facile synthesis of .alpha.-nitroaryl carbonyl compounds

    Article • The Journal of Organic Chemistry, November 1984, American Chemical Society (ACS)

    Professor T V RajanBabu

  228. Synthesis of Reactive-Ended Acrylic Polymers by Group Transfer Polymerization: Initiation with Silyl Ketene Acetals

    Article • Journal of Macromolecular Science Part A - Chemistry, July 1984, Taylor & Francis

    Professor T V RajanBabu

  229. Addition of ketene trimethylsilyl acetals to .alpha.,.beta.-unsaturated ketones: a new strategy for Michael addition of ester enolates

    Article • The Journal of Organic Chemistry, June 1984, American Chemical Society (ACS)

    Professor T V RajanBabu

  230. Group-transfer polymerization. 1. A new concept for addition polymerization with organosilicon initiators

    Article • Journal of the American Chemical Society, August 1983, American Chemical Society (ACS)

    Professor T V RajanBabu

  231. Chemistry of bridged aromatics. A study of the substituent effect on the course of bond cleavage of 9,10-dihydro-9,10-ethanoanthracenes and an oxyanion-assisted retro-Diels-Alder reaction

    Article • The Journal of Organic Chemistry, March 1983, American Chemical Society (ACS)

    Professor T V RajanBabu

  232. Asymmetric total synthesis of erythromycin. 3. Total synthesis of erythromycin

    Article • Journal of the American Chemical Society, June 1981, American Chemical Society (ACS)

    Professor Dr. Jürgen Martens, Professor T V RajanBabu

  233. Asymmetric total synthesis of erythromycin. 2. Synthesis of an erythronolide A lactone system

    Article • Journal of the American Chemical Society, June 1981, American Chemical Society (ACS)

    Professor Dr. Jürgen Martens, Professor T V RajanBabu

  234. Asymmetric total synthesis of erythromcin. 1. Synthesis of an erythronolide A secoacid derivative via asymmetric induction

    Article • Journal of the American Chemical Society, June 1981, American Chemical Society (ACS)

    Professor Dr. Jürgen Martens, Professor T V RajanBabu

  235. Surprises in base-catalyzed decompositions of bicyclo[4.2.1]nona-2,4,7-trien-9-one hydrazone

    Article • Journal of the American Chemical Society, September 1977, American Chemical Society (ACS)

    Professor T V RajanBabu

  236. Catalyzed Reductions in Aqueous Media

    Article • Wiley

    Professor T V RajanBabu

  237. Transition-Metal-Catalyzed Alkene and Alkyne Hydrocyanations

    Article • Wiley

    Professor T V RajanBabu