All Stories

  1. Cover Picture: An Ultrastable, Small {Ag 7 } 5+ Nanocluster within a Triangular Hollow Polyoxometalate Framework (Angew. Chem. Int. Ed. 38/2020)
  2. An Ultrastable, Small {Ag 7 } 5+ Nanocluster within a Triangular Hollow Polyoxometalate Framework
  3. An Ultrastable, Small {Ag 7 } 5+ Nanocluster within a Triangular Hollow Polyoxometalate Framework
  4. An Ultrastable, Small {Ag 7 } 5+ Nanocluster within a Triangular Hollow Polyoxometalate Framework
  5. Selectivity switch in the aerobic oxygenation of sulfides photocatalysed by visible-light-responsive decavanadate
  6. Supersilyl as an effective monodentate ligand to stabilize four-coordinate manganese(ii) complexes
  7. Controlled Assembly Synthesis of Atomically Precise Ultrastable Silver Nanoclusters with Polyoxometalates
  8. Methyl‐Selective α‐Oxygenation of Tertiary Amines to Formamides by Employing Copper/Moderately Hindered Nitroxyl Radical (DMN‐AZADO or 1‐Me‐AZADO)
  9. Self-Assembly of Anionic Polyoxometalate–Organic Architectures Based on Lacunary Phosphomolybdates and Pyridyl Ligands
  10. Ring-Shaped Polyoxometalates Possessing Multiple 3d Metal Cation Sites: [{M2(OH2)2}2{M(OH2)2}4P8W48O176(OCH3)8]16– (M = Mn, Co, Ni, Cu, Zn)
  11. Exploring orientationally aligned anisotropic large spin molecules with unusual long-distance intermolecular ferromagnetic interactions
  12. Hexavacant γ-Dawson-type phosphotungstates supporting an edge-sharing bis(square-pyramidal) {O2M(μ3-O)2(μ-OAc)MO2} core (M = Mn2+, Co2+, Ni2+, Cu2+, or Zn2+
  13. Polyoxometalate Photocatalysis for Liquid-Phase Selective Organic Functional Group Transformations
  14. Porous Cubic Cesium Salts of Silicododecatungstate(molybdate)/Borododecatungstate Blends: Synthesis and Molecular Adsorption Properties
  15. Effect of Heteroatoms on Field-Induced Slow Magnetic Relaxation of Mononuclear FeIII (S = 5/2) Ions within Polyoxometalates
  16. Aerobic Oxygenation of Alkylarenes over Ultrafine Transition-Metal-Containing Manganese-Based Oxides
  17. CuCl/TMEDA/nor-AZADO-catalyzed aerobic oxidative acylation of amides with alcohols to produce imides
  18. Polyoxometalate LUMO engineering: a strategy for visible-light-responsive aerobic oxygenation photocatalysts
  19. Photoredox Catalysis of Visible-light-responsive Divacant Lacunary Silicotungstate for Selective Reduction of Aldehydes
  20. Cover Feature: Alkoxides of Trivacant Lacunary Polyoxometalates (Chem. Eur. J. 57/2017)
  21. Alkoxides of Trivacant Lacunary Polyoxometalates
  22. “Release and catch” catalysis by tungstate species for the oxidative cleavage of olefins
  23. A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates
  24. Creation of bismuth–tungsten oxide nanoclusters using lacunary polyoxometalates
  25. Phosphovanadomolybdic acid catalyzed direct C–H trifluoromethylation of (hetero)arenes using NaSO2CF3 as the CF3 source and O2 as the terminal oxidant
  26. Platinum-supporting hollandite-type vanadium–chromium mixed oxides as efficient heterogeneous catalysts for deoxygenation of sulfoxides under atmospheric H2 pressure
  27. Visible-light-responsive catalysis of a zinc-introduced lacunary disilicoicosatungstate for the deoxygenation of pyridine N-oxides
  28. Organozirconium Complex with Keggin-Type Mono-Aluminum-Substituted Silicotungstate: Synthesis, Molecular Structure, and Catalytic Performance for Meerwein–Ponndorf–Verley Reduction
  29. Synthesis and Disassembly/Reassembly of Giant Ring-Shaped Polyoxotungstate Oligomers
  30. Rational Low-Temperature Synthesis of Ultrasmall Nanocrystalline Manganese Binary Oxide Catalysts under Controlled Metal Cation Hydration in Organic Media
  31. Sequential Synthesis of 3d–3d′–4f Heterometallic Heptanuclear Clusters in between Lacunary Polyoxometalates
  32. Synthesis of N-Acylsulfenamides through Aerobic Cross Dehydrogenative Coupling of Thiols and Amides by Supported Copper Hydroxide Catalyst
  33. Water- and Temperature-Triggered Reversible Structural Transformation of Tetranuclear Cobalt(II) Cores Sandwiched by Polyoxometalates
  34. Photoredox catalysis for oxygenation/deoxygenation between sulfides and sulfoxides by visible-light-responsive polyoxometalates
  35. Molybdenum-doped α-MnO2 as an efficient reusable heterogeneous catalyst for aerobic sulfide oxygenation
  36. Hexanuclear tin(ii) and mixed valence tin(ii,iv) oxide clusters within polyoxometalates
  37. Phosphovanadomolybdic acid catalyzed desulfurization–oxygenation of secondary and tertiary thioamides into amides using molecular oxygen as the terminal oxidant
  38. Synthesis of ultrasmall Li–Mn spinel oxides exhibiting unusual ion exchange, electrochemical and catalytic properties
  39. Composites of [γ-H2PV2W10O40]3− and [α-SiW12O40]4− supported on Fe2O3 as heterogeneous catalysts for selective oxidation with aqueous hydrogen...
  40. Field-induced slow magnetic relaxation of octahedrally coordinated mononuclear Fe(iii)-, Co(ii)-, and Mn(iii)-containing polyoxometalates
  41. A cascade approach to hetero-pentanuclear manganese-oxide clusters in polyoxometalates and their single-molecule magnet properties
  42. Synthesis and structural characterization of BINOL-modified chiral polyoxometalates
  43. Regioselective direct oxidative C–H cyanation of quinoline and its derivatives catalyzed by vanadium-containing heteropoly acids
  44. Synthesis and oxidation catalysis of a Ti-substituted phosphotungstate, and identification of the active oxygen species
  45. Visible-Light-Responsive Multielectron Redox Catalysis of Lacunary Polyoxometalates Induced by Substrate Coordination to Their Lacuna
  46. Hydrogen Evolution Using the Visible-light-induced Metal-to-polyoxometalate Multiple Electron Transfer
  47. Visible-Light-Induced Photoredox Catalysis with a Tetracerium-Containing Silicotungstate
  48. Synthesis of α-Dawson-Type Silicotungstate [α-Si2W18O62]8−and Protonation and Deprotonation Inside the Aperture through Intramolecular Hydrogen Bonds
  49. Heterodinuclear Lanthanoid-Containing Polyoxometalates: Stepwise Synthesis and Single-Molecule Magnet Behavior
  50. Synthesis, Structure Characterization, and Reversible Transformation of a Cobalt Salt of a Dilacunary γ-Keggin Silicotungstate and Sandwich-Type Di- and Tetracobalt-Containing Silicotungstate Dimers
  51. A discrete octahedrally shaped [Ag6]4+cluster encapsulated within silicotungstate ligands
  52. Reversible switching of single-molecule magnet behaviors by transformation of dinuclear dysprosium cores in polyoxometalates
  53. Synthesis and Reversible Transformation of Cun-Bridged (n = 1, 2, or 4) Silicodecatungstate Dimers
  54. Emission Color Trajectory and White Electroluminescence Through Supramolecular Control of Energy Transfer and Exciplex Formation in Binary Blends of Conjugated Polyrotaxanes
  55. Strategic Design and Refinement of Lewis Acid–Base Catalysis by Rare-Earth-Metal-Containing Polyoxometalates
  56. Incarceration of (PdO)nand PdnClusters by Cage-Templated Synthesis of Hollow Silica Nanoparticles
  57. Synthesis of a Bridging Ligand with a Non-denatured Protein Pendant: Toward Protein Encapsulation in a Coordination Cage
  58. Cyanosilylation of Carbonyl Compounds with Trimethylsilyl Cyanide Catalyzed by an Yttrium-Pillared Silicotungstate Dimer
  59. Three-Dimensional Ordered Arrays of 58×58×58 Å3 Hollow Frameworks in Ionic Crystals of M2Zn2-Substituted Polyoxometalates
  60. Protein encapsulation within synthetic molecular hosts
  61. Coronene Nanophase within Coordination Spheres: Increased Solubility of C60
  62. Self-assembly of an M6L12 coordination cube
  63. Discrete and Well‐Defined Hydrophobic Phases Confined in Self‐Assembled Spherical Complexes
  64. Endohedral Peptide Lining of a Self-Assembled Molecular Sphere To Generate Chirality-Confined Hollows
  65. Solvato-Controlled Assembly of Pd3L6 and Pd4L8 Coordination “Boxes”
  66. Fluorous Nanodroplets Structurally Confined in an Organopalladium Sphere
  67. 24-Fold Endohedral Functionalization of a Self-Assembled M12L24Coordination Nanoball