All Stories

  1. Operando XAFS of supported Pd nanoparticles in flowing ethanol/water mixtures: implications for catalysis
  2. Chemo- and Diastereoselectivities in the Electrochemical Reduction of Maleimides
  3. Electronic structures of cyclometalated palladium complexes in the higher oxidation states
  4. Structure and bonding of [(SIPr)AgX] (X = Cl, Br, I and OTf)
  5. Atropisomeric [(diphosphine)Au2Cl2] Complexes and their Catalytic Activity Towards Asymmetric Cycloisomerisation of 1,6-Enynes
  6. (1R,5R,6R)-Spiro[4.4]nonane-1,6-diyl Diphenylphosphinous Acid Ester
  7. Catalysis in flow: Operando study of Pd catalyst speciation and leaching
  8. ChemInform Abstract: Silver-Catalyzed Intramolecular Hydroamination of Alkynes with Trichloroacetimidates.
  9. ChemInform Abstract: Methylene-Bridged Bis(imidazoline)-Derived 2-Oxopyrimidinium Salts as Catalysts for Asymmetric Michael Reactions.
  10. ChemInform Abstract: Levonantradol: Asymmetric Synthesis and Structural Analysis.
  11. ChemInform Abstract: Coinage Metal Catalysts for the Addition of O-H to C=C Bonds.
  12. Methylene-Bridged Bis(imidazoline)-Derived 2-Oxopyrimidinium Salts as Catalysts for Asymmetric Michael Reactions
  13. Methylene-Bridged Bis(imidazoline)-Derived 2-Oxopyrimidinium Salts as Catalysts for Asymmetric Michael Reactions
  14. New Chiral Zwitterionic Phosphorus Heterocycles: Synthesis, Structure, Properties and Application as Chiral Solvating Agents
  15. Coinage Metal Catalysts for the Addition of O-H to C=C Bonds
  16. Levonantradol: asymmetric synthesis and structural analysis
  17. Silver-catalysed intramolecular hydroamination of alkynes with trichloroacetimidates
  18. ChemInform Abstract: Asymmetric Synthesis of 2-Alkyl-substituted Tetrahydroquinolines by an Enantioselective Aza-Michael Reaction.
  19. PhanePhos and Related Derivatives
  20. Preparation of dicationic palladium catalysts for asymmetric catalytic reactions
  21. Silver-Catalysed Enantioselective Addition of OH and NH Bonds to Allenes: A New Model for Stereoselectivity Based on Noncovalent Interactions
  22. Gold(I) Complexes of Conformationally Constricted Chiral Ferrocenyl Phosphines
  23. Deconvolution of the Mechanism of Homogeneous Gold-Catalyzed Reactions
  24. ChemInform Abstract: Palladium-Catalyzed Heterofunctionalization of C-H, C:C, and CC Bonds
  25. Asymmetric synthesis of 2-alkyl-substituted tetrahydroquinolines by an enantioselective aza-Michael reaction
  26. Speciation of Pd(OAc)2in ligandless Suzuki–Miyaura reactions
  27. Catalysis in flow: Au-catalysed alkylation of amines by alcohols
  28. Alternative to Benzoquinone for Room-Temperature Fujiwara–Moritani Reactions
  29. Palladium-Catalyzed Heterofunctionalization of C-H, C=C and C≡ C Bonds
  30. ChemInform Abstract: Transition Metal Catalyzed Enantioselective α-Heterofunctionalization of Carbonyl Compounds
  31. ChemInform Abstract: Catalysis in Flow: The Practical and Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones.
  32. Transition Metal Catalyzed Enantioselective α-Heterofunctionalization of Carbonyl Compounds
  33. An Expedient Synthesis of Olfactory Lactones by Intramolecular Hydroacylalkoxylation Reactions
  34. ChemInform Abstract: Oxidative Amidation of Activated Alkenes Using Pd(OAc)2 as a Catalyst Precursor.
  35. Oxidative Amidation of Activated Alkenes Using Pd(OAc)2 as a Catalyst Precursor
  36. ChemInform Abstract: Hydroamination Reactions by Metal Triflates: Broensted Acid versus Metal Catalysis?
  37. ChemInform Abstract: Scope and Limitations of the Preparation of Aminophosphines R-NH(CH2CH2PPh2) and Aminodiphosphines R-N(CH2CH2PPh2)2 via Michael Addition of Amines to Vinylphosphines.
  38. ChemInform Abstract: Palladium-Catalyzed Addition of R2NH to Double Bonds. Synthesis of α-Amino Tetrahydrofuran and Pyran Rings.
  39. ChemInform Abstract: Advances in the Heck Chemistry of Aryl Bromides and Chlorides
  40. Delineating Origins of Stereocontrol in Asymmetric Pd-Catalyzed α-Hydroxylation of 1,3-Ketoesters
  41. ChemInform Abstract: Copper-Catalyzed Intramolecular O-H Addition to Unactivated Alkenes.
  42. ChemInform Abstract: Unusual Regiodivergence in Metal-Catalyzed Intramolecular Cyclization of γ-Allenols.
  43. ChemInform Abstract: Synthesis of Terphenyls
  44. Hydroamination reactions by metal triflates: Brønsted acid vs. metal catalysis?
  45. Catalysis in flow: the practical and selective aerobic oxidation of alcohols to aldehydes and ketones
  46. Copper-catalysed intramolecular O–H addition to unactivated alkenes
  47. ChemInform Abstract: Palladium-Catalyzed Enantioselective α-Hydroxylation of β-Ketoesters.
  48. Synthesis of Terphenyls
  49. [Pd{2-CH2-5-MeC6H3C(H)NNC(S)NHEt}]3: An unprecedented trinuclear cyclometallated palladium(II) cluster through induced flexibility in the metallated ring
  50. Unusual regiodivergence in metal-catalysed intramolecular cyclisation of γ-allenols
  51. Palladium-catalysed enantioselective α-hydroxylation of β-ketoesters
  52. Delineating ligand effects in intramolecular aryl amidation reactions: formation of a novel spiro-heterocycle by a tandem cyclisation process
  53. ChemInform Abstract: A Recyclable Copper(II) Catalyst for the Annulation of Phenols with 1,3-Dienes.
  54. A recyclable copper(ii) catalyst for the annulation of phenols with 1,3-dienes
  55. A Concise Asymmetric Synthesis of Torcetrapib (I).
  56. Preparation of Macrocyclon Analogues: Calix[8]arenes with Extended Polyethylene Glycol Chains.
  57. Preparation of macrocyclon analogues: calix[8]arenes with extended polyethylene glycol chains
  58. A Practical and General Synthesis of Unsymmetrical Terphenyls
  59. A Concise Asymmetric Synthesis of Torcetrapib
  60. Applications of Phosphine-Functionalized Polymers in Organic Synthesis
  61. Enabling Ligand Screening for Palladium-Catalysed Enantioselective Aza-Michael Addition Reactions
  62. Elucidating the Mechanism of the Asymmetric Aza-Michael Reaction
  63. Applications of phosphine-functionalised polymers in organic synthesis
  64. Copper-Catalyzed Intermolecular Hydroamination of Alkenes.
  65. Practical Synthesis of Chiral Vinylphosphine Oxides by Direct Nucleophilic Substitution. Stereodivergent Synthesis of Aminophosphine Ligands.
  66. Development of Palladium Catalysts for Asymmetric Hydroamination Reactions
  67. Copper-Catalyzed Intermolecular Hydroamination of Alkenes
  68. Enabling Ligand Screening for Palladium-Catalyzed Enantioselective aza-Michael Addition Reactions.
  69. Ligand Effects in the Synthesis of N-Heterocycles by Intramolecular Heck Reactions.
  70. Synthesis of P-Chirogenic Diarylphosphinoacetic Acids and Their Proline Derivatives for Palladium-Catalyzed Allylic Alkylation Reactions.
  71. Enabling Ligand Screening for Palladium-Catalysed Enantioselective Aza-Michael Addition Reactions
  72. Practical Synthesis of Chiral Vinylphosphine Oxides by Direct Nucleophilic Substitution. Stereodivergent Synthesis of Aminophosphine Ligands
  73. Copper(II)-Catalyzed Addition of O—H Bonds to Norbornene.
  74. Ligand Effects in the Synthesis of N -Heterocycles by Intramolecular Heck Reactions
  75. Mechanisms That Interchange Axial and Equatorial Atoms in Fluxional Processes: Illustration of the Berry Pseudorotation, the Turnstile, and the Lever Mechanisms via Animation of Transition State Normal Vibrational Modes
  76. Recyclable Polymer-Supported Pd Catalysts for Aryl Amination Reactions.
  77. Reversal of Aryl Bromide Reactivity in Pd-Catalyzed Aryl Amination Reactions Promoted by a Hemilabile Aminophosphine Ligand.
  78. In situ investigation of the oxidative addition in homogeneous Pd catalysts by synchronised time resolved UV-Vis/EXAFS
  79. Development of palladium catalysts for asymmetric hydroamination reactions
  80. Enantioselective Addition of Amines to Alkenoyl-N-oxazolidinones.
  81. Palladium-Catalysed Enantioselective Conjugate Addition of Aromatic Amines to α,β-UnsaturatedN-Imides. Effect of the Chelating Moiety
  82. Synthesis of P-chirogenic diarylphosphinoacetic acids and their proline derivatives for palladium-catalysed allylic alkylation reactions
  83. Recyclable polymer-supported Pd catalysts for aryl amination reactions
  84. Phosphine-functionalised polymer resins as Pd scavengers
  85. Reversal of aryl bromide reactivity in Pd-catalysed aryl amination reactions promoted by a hemilabile aminophosphine ligand
  86. Conformation Analyses, Dynamic Behavior and Amide Bond Distortions of Medium-Sized Heterocycles. Part 1. Partially and Fully Reduced 1-Benzazepines.
  87. Conformation Analyses, Dynamic Behavior, and Amide Bond Distortions of Medium-Sized Heterocycles. Part 2. Partially and Fully Reduced 1-Benzazocines, Benzazonines, and Benzazecines.
  88. Enantioselective addition of amines to alkenoyl-N-oxazolidinones
  89. Conformation Analyses, Dynamic Behavior and Amide Bond Distortions of Medium-sized Heterocycles. 1. Partially and Fully Reduced 1-Benzazepines
  90. Conformation Analyses, Dynamic Behavior, and Amide Bond Distortions of Medium-sized Heterocycles. 2. Partially and Fully Reduced 1-Benzazocines, Benzazonines, and Benzazecines
  91. Polymer-supported manganese porphyrin catalysts—peptide-linker promoted chemoselectivity
  92. Copper(ii)-catalysed addition of O–H bonds to norbornene
  93. Wang-aldehyde resin as a recyclable support for the synthesis of α,α-disubstituted amino acid derivatives
  94. Aminohydroxy Phosphine Oxide Ligands in Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation Reactions.
  95. Mixed Donor Aminophosphine Oxide Ligands in Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation Reactions.
  96. Chemoselective Epoxidation of Dienes Using Polymer-Supported Manganese Porphyrin Catalysts.
  97. Asymmetric Synthesis of β-Amino Acid and Amide Derivatives by Catalytic Conjugate Addition of Aromatic Amines to N-Alkenoylcarbamates.
  98. Chemoselective epoxidation of dienes using polymer-supported manganese porphyrin catalysts
  99. Aminohydroxy phosphine oxide ligands in ruthenium-catalysed asymmetric transfer hydrogenation reactions
  100. Conformationally Restricted Arene Intermediates in the Intermolecular Heck Arylation of Vinylarenes
  101. Phosphorus—Nitrogen—Phosphorus Ligands: Cooperative Effects Between Nitrogen and Phosphorus Substituents on Catalytic Activity.
  102. Mixed donor aminophosphine oxide ligands in ruthenium-catalysed asymmetric transfer hydrogenation reactions
  103. Asymmetric Synthesis ofβ-Amino Acid and Amide Derivatives by Catalytic Conjugate Addition of Aromatic Amines toN-Alkenoylcarbamates
  104. Multigram Synthesis of Well-Defined Extended Bifunctional Polyethylene Glycol (PEG) Chains
  105. Phosphorus–nitrogen–phosphorus ligands: cooperative effects between nitrogen and phosphorus substituents on catalytic activity
  106. Unsymmetrical Terdentate Phosphorus-Nitrogen-Nitrogen (PNN) Ligands: Effect of the M/L Ratio and the Pendant Group on Stereoselectivity.
  107. Dicationic [(BINAP)Pd(solvent)2]2+[TfO-]2: Enantioselective Hydroamination Catalyst for Alkenoyl-N-oxazolidinones.
  108. Hydridopalladium Complexes
  109. Mild reduction of chlorophosphine boranes to secondary phosphine boranes
  110. Unsymmetrical terdentate phosphorus-nitrogen-nitrogen (PNN) ligands: effect of the M/L ratio and the pendant group on stereoselectivity
  111. Dicationic [(BINAP)Pd(solvent)2]2+[TfO–]2: enantioselective hydroamination catalyst for alkenoyl-N-oxazolidinones
  112. Air- and moisture-stable cationic (diphosphine)palladium(II) complexes as hydroamination catalysts
  113. Coordination Chemistry and Catalytic Activity of Ruthenium Complexes of Terdentate Phosphorus−Nitrogen−Phosphorus (PNP) and Bidentate Phosphorus−Nitrogen (PNH) Ligands
  114. Examining the effect of hemilabile donor groups in non-C2 symmetrical terdentate ligands
  115. Profound Steric Control of Reactivity in Aryl Halide Addition to Bisphosphane Palladium(0) Complexes
  116. Profound Steric Control of Reactivity in Aryl Halide Addition to Bisphosphane Palladium(0) Complexes
  117. Advances in the Heck chemistry of aryl bromides and chlorides
  118. Palladium-catalyzed addition of R2NH to double bonds. Synthesis of α-amino tetrahydrofuran and pyran rings
  119. The Chatt-Dewar-Duncanson Model Revisited: X-ray, DFT and NMR Studies of Rhodium-Alkene Binding—Deviations from Structural Ideality
  120. Corrigendum to “Examination of Ligand Effects in the Heck Arylation Reaction”
  121. Examination of Ligand Effects in the Heck Arylation Reaction
  122. Scope and Limitations of the Preparation of Aminophosphines R-NH(CH2CH2PPh2) and Aminodiphosphines R-N(CH2CH2PPh2)2 via Michael Addition of Amines to Vinylphosphines
  123. Factors Affecting the Oxidative Addition of Aryl Electrophiles to 1,1‘-Bis(diphenylphosphino)ferrocenepalladium(η 2 -methyl acrylate), an Isolable Pd[0] Alkene Complex
  124. Syntheses and Properties of Palladium Complexes Containing Phosphorus−Nitrogen−Phosphorus Ligands with a Tunable Hemilabile Site
  125. Models for the Carbonyl-ene Cyclization Reaction: Open and Closed Transition States
  126. Modelle für die Carbonyl-En-Cyclisierung: offene und geschlossene Übergangszustände
  127. Modelle für die Carbonyl-En-Cyclisierung: offene und geschlossene Übergangszustände
  128. The Heck olefination reaction; A DFT study of the elimination pathway
  129. Intermediates in the Intermolecular, Asymmetric Heck Arylation of Dihydrofurans
  130. Conformational diastereoisomerism in tris-(2-alkylimino) triphenylphosphines
  131. Characterization of Reactive Intermediates in Palladium-Catalyzed Arylation of Methyl Acrylate(Heck Reaction)
  132. Die Charakterisierung reaktiver Zwischenstufen in der Palladium-katalysierten Arylierung von Methylacrylat (Heck-Reaktion)
  133. Terdentate (P,N,N) complexes of a new pyridyl azine phosphine Z,E-PPh2CH2(But)CN–NC(Me)C5H4N and its deprotonated derivative (an azo phosphine) with transition metals
  134. Terdentate (P–N–O) complexes formed from Z,E-PPh2CH2C-(But)N–NCH(C6H4OH-2) or Z,E-PPh2CH2C(But)N–NCH-[C6H2(OH-2)(OMe)2-4,6] and...
  135. Complexes of the bidentate ligands PPh2CH2C(But)NNR2(R = H or Me) and PPh2CH2C(But)N–NCHPh with palladium and platinum. X-Ray crystal structure of cis-[Pt{PPh2CH...
  136. New bidentate ligands PPh2CH2C(But)NNR2(R = H or Me) and PPh2CH2C(But)NNCHPh and their complexes with Group 6 metal carbonyls
  137. Hydridopalladium Complexes
  138. 1. Catalysis in flow
  139. Application of phosphine ligands in organic synthesis