All Stories

  1. Exposing the Origins of Irreproducibility in Fluorine NMR Spectroscopy
  2. Fluor-NMR-Spektroskopie rekalibriert
  3. Exposing the Origins of Irreproducibility in Fluorine NMR Spectroscopy
  4. Fluor-NMR-Spektroskopie rekalibriert
  5. Supramolecular Aggregation of Perfluoroorganyl Iodane Reagents in the Solid State and in Solution
  6. Perfluoroalkyl Cobaloximes: Preparation Using Hypervalent Iodine Reagents, Molecular Structures, Thermal and Photochemical Reactivity
  7. Importance of Nonclassical σ-Hole Interactions for the Reactivity of λ3-Iodane Complexes
  8. Synthesis and Characterization of Fluorinated Hypervalent Tellurium Derivatives
  9. Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes
  10. Magnesium-Catalyzed Electrophilic Trifluoromethylation: Facile Access to All-Carbon Quaternary Centers in Oxindoles
  11. Cover Picture: Magnesium-Catalyzed Electrophilic Trifluoromethylation: Facile Access to All-Carbon Quaternary Centers in Oxindoles (Chem. Eur. J. 35/2017)
  12. Magnesium-Catalyzed Electrophilic Trifluoromethylation: Facile Access to All-Carbon Quaternary Centers in Oxindoles
  13. S-Trifluoromethylation of Thiols by Hypervalent Iodine Reagents: A Joint Experimental and Computational Study
  14. Synthesis of quaternary α-perfluoroalkyl lactams via electrophilic perfluoroalkylation
  15. P-Trifluoromethyl ligands derived from Josiphos in the Ir-catalysed hydrogenation of 3,4-dihydroisoquinoline hydrochlorides
  16. “Why and How it Works”: The Development of Hypervalent Iodine Reagents as an Illustration for the Collaboration of Chemical Synthesis with Modeling and Simulation
  17. The solvent effect on two competing reaction mechanisms involving hypervalent iodine reagents (λ3-iodanes): Facing the limit of the stationary quantum chemical approach
  18. Rapid and Selective Electrophilic Trifluoromethylation of the 4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) Scaffold
  19. Vanadium-Catalyzed Solvent-Free Synthesis of Quaternary α-Trifluoromethyl Nitriles by Electrophilic Trifluoromethylation
  20. O-Trifluoromethylation ofN,N-Disubstituted Hydroxylamines with Hypervalent Iodine Reagents
  21. Synthesis, characterization and initial evaluation of 5-nitro-1-(trifluoromethyl)-3 H -1λ 3 ,2-benziodaoxol-3-one
  22. Confusing Quantitative Descriptions ofBrønstedLowryAcidBase Equilibria in Chemistry Textbooks - A Critical Review and Clarifications for Chemical Educators
  23. Enantioselective 1,3-Dipolar Cycloaddition of C , N -Cyclic Azomethine Imines to Unsaturated Nitriles Catalyzed by Ni II –Pigiphos
  24. One-Pot Synthesis of Hypervalent Iodine Reagents for Electrophilic Trifluoromethylation
  25. Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Rhenium Complexes with Chiral Ferrocenylphosphane Ligands
  26. Additive Effects of Amines on Asymmetric Hydrogenation of Quinoxalines Catalyzed by Chiral Iridium Complexes
  27. Reductive Eliminations from λ 3 -Iodanes: Understanding Selectivity and the Crucial Role of the Hypervalent Bond
  28. Direct Electrophilic N-Trifluoromethylation of Azoles by a Hypervalent Iodine Reagent
  29. Gold(I) Complexes of Conformationally Constricted Chiral Ferrocenyl Phosphines
  30. Rhenium-Catalyzed Trifluoromethylation of Arenes and Heteroarenes by Hypervalent Iodine Reagents
  31. Substrate Range of the Titanium TADDOLate Catalyzed Asymmetric Fluorination of Activated Carbonyl Compounds
  32. Reactivity of an electrophilic hypervalent iodine trifluoromethylation reagent with hydrogen phosphates—A mechanistic study
  33. P-Stereogenic Trifluoromethyl Derivatives of Josiphos: Synthesis, Coordination Properties, and Applications in Asymmetric Catalysis
  34. Synthesis of α-CF3-Substituted Carbonyl Compounds with Relative and Absolute Stereocontrol Using Electrophilic CF3-Transfer Reagents
  35. Development of the titanium–TADDOLate-catalyzed asymmetric fluorination of β-ketoesters
  36. Secondary Ferrocenyl Phosphines: Versatile Precursors for the Synthesis of Bi- and Tridentate Ligands
  37. Rhenium Complexes Containing the Chiral Tridentate Ferrocenyl Ligand Pigiphos
  38. Probing the interactions of an acyl carrier protein domain from the 6-deoxyerythronolide B synthase
  39. Iron(II)-Catalyzed Asymmetric Hydrosilylation of Acetophenone
  40. Electrophilic Trifluoromethylation of S -Hydrogen Phosphorothioates
  41. Josiphos Ligands: From Discovery to Technical Applications
  42. Chiral trifluoromethylphosphines: a new stereoselective synthesis of Josiphos-type ligands containing two stereogenic phosphorus atoms
  43. PREPARATION OF A TRIFLUOROMETHYL TRANSFER AGENT: 1-TRIFLUOROMETHYL-1,3-DIHYDRO-3,3-DIMETHYL-1,2-BENZIODOXOLE
  44. A Ritter-Type Reaction: Direct Electrophilic Trifluoromethylation at Nitrogen Atoms Using Hypervalent Iodine Reagents
  45. P-Stereogenic Ferrocene-Based (Trifluoromethyl)phosphanes: Synthesis, Structure, Coordination Properties and Catalysis
  46. Organofluorine Chemistry: Taking the Next Steps
  47. Electrophilic trifluoromethylation of arenes and N-heteroarenes using hypervalent iodine reagents
  48. New hypervalent iodine reagents for electrophilic trifluoromethylation and their precursors: synthesis, structure, and reactivity
  49. Remote C−F−Metal Interactions in Late-Transition-Metal Complexes
  50. Electrophilic Trifluoromethylation of Primary Phosphines: Synthesis of a P -Bis(trifluoromethyl) Derivative of BINAP
  51. Reactivity of a Hypervalent Iodine Trifluoromethylating Reagent toward THF: Ring Opening and Formation of Trifluoromethyl Ethers
  52. NMR-Solution Structures and Affinities for the Human Somatostatin G-Protein-Coupled Receptors hsst1–5 of CF3 Derivatives of Sandostatin® (Octreotide)
  53. Asymmetric oxidative α-fluorination of 2-alkylphenylacetaldehydes with AgHF2 and ruthenium/PNNP catalysts
  54. A Concise Synthesis of ortho-Iodobenzyl Alcohols via Addition of ortho-Iodophenyl Grignard Reagent to Aldehydes and Ketones
  55. Zinc-Mediated Formation of Trifluoromethyl Ethers from Alcohols and Hypervalent Iodine Trifluoromethylation Reagents
  56. Acid-mediated formation of trifluoromethyl sulfonates from sulfonic acids and a hypervalent iodine trifluoromethylating agent
  57. ElectrophilicS-Trifluoromethylation of Cysteine Side Chains inα- andβ-Peptides: Isolation of Trifluoro-methylatedSandostatin®(Octreotide) Derivatives
  58. Asymmetric hydroamination of acrylonitrile derivatives catalyzed by Ni(II)-complexes
  59. Reactivity of a 10-I-3 Hypervalent Iodine Trifluoromethylation Reagent With Phenols
  60. Palladium-Catalyzed Enantioselective Allylic Phosphination
  61. Recent Advances in Electrophilic CF3-Transfer Using Hypervalent Iodine(III) Reagents
  62. Ni(ii)-catalyzed enantioselective Nazarov cyclizations
  63. Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)–CF3 reagents
  64. TiIV-Catalyzed Asymmetric Sulfenylation of 1,3-Dicarbonyl Compounds
  65. Ruthenium-Catalyzed Asymmetric Electrophilic Fluorination of 1,3-Dicarbonyl Compounds
  66. Gold(I)- and Brønsted Acid-Catalyzed Ring-Opening of Unactivated Vinylcyclopropanes with Sulfonamides
  67. Synthesis and Characterization of Palladium(II) π-Allyl Complexes with Chiral Phosphinocarbene Ligands. Kinetics and Mechanism of Allylic Amination
  68. Cationic Vanadium(IV) Complexes as Efficient Catalysts for Nazarov Cyclizations
  69. Asymmetric Electrophilic Fluorination of α-Nitro Esters
  70. Asymmetric Catalytic Hydroamination of Activated Olefins in Ionic Liquids
  71. Mild Electrophilic Trifluoromethylation of Carbon- and Sulfur-Centered Nucleophiles by a Hypervalent Iodine(III)–CF3 Reagent
  72. Phthalimide-N-sulfenyl chloride in the Ti-catalyzed asymmetric sulfenylation of β-keto esters
  73. Structural and stereochemical aspects of the enantioselective halogenation of 1,3-dicarbonyl compounds catalyzed by Ti(TADDOLato) complexes
  74. Interactions of Cationic Palladium(II)- and Platinum(II)-η3-Allyl Complexes with Fluoride: Is Asymmetric Allylic Fluorination a Viable Reaction?
  75. Novel 10-I-3 Hypervalent Iodine-Based Compounds for Electrophilic Trifluoromethylation
  76. Enantioselective Palladium-Catalyzed Hydrosilylation of Styrene:  Influence of Electronic and Steric Effects on Enantioselectivity and Catalyst Design via Hybrid QM/MM Molecular Dynamics Simulations
  77. Consecutive catalytic electrophilic fluorination/amination of β-keto esters: toward α-fluoro-α-amino acids?
  78. Chiral Ru/PNNP complexes in catalytic and stoichiometric electrophilic O- and F-atom transfer to 1,3-dicarbonyl compounds
  79. A Novel Chiral Ferrocene-Based Amidine/Amidinato Ligand and Its Rhodium Complexes
  80. PdII Complexes of Tridentate PCP N-Heterocyclic Carbene Ligands: Structural Aspects and Application in Asymmetric Hydroamination of Cyano Olefins
  81. Enantioselective Addition of Secondary Phosphines to Methacrylonitrile:  Catalysis and Mechanism
  82. Titanium(IV)-Catalyzed Enantioselective Sulfenylation of β-Ketoesters
  83. N-Ferrocenyl-Substituted Planar-Chiral N-Heterocyclic Carbenes and Their PdII Complexes
  84. A Dinuclear Copper(I) Complex Containing a Bridging Chiral Tridentate Carbene Ligand
  85. Nickel(II)-Catalyzed Highly Enantioselective Hydrophosphination of Methacrylonitrile
  86. Relative Electrophilic Fluorinating Power as Assayed by Competitive Catalytic Halogenation Reactions
  87. Iridium-Imine and -Amine Complexes Relevant to the (S)-Metolachlor Process: Structures, Exchange Kinetics, and C?H Activation by IrI Causing Racemization
  88. Novel silica gel supported chiral biaryl-diphosphine ligands for enantioselective hydrogenation
  89. Enantioselective Palladium-Catalyzed Hydrosilylation of Styrene:  Detailed Reaction Mechanism from First-Principles and Hybrid QM/MM Molecular Dynamics Simulations
  90. Synthesis and Coordination Chemistry of a New Chiral Tridentate PCP N -Heterocyclic Carbene Ligand Based on a Ferrocene Backbone
  91. Expanding the scope of asymmetric electrophilic atom-transfer reactions: Titanium- and ruthenium-catalyzed hydroxylation of β-ketoesters
  92. Catalytic Asymmetric Chlorination ofβ-Keto Esters with Hypervalent Iodine Compounds
  93. Chiral Xyliphos Complexes for the Catalytic Imine Hydrogenation Leading to the Metolachlor Herbicide: Isolation of Catalyst–Substrate Adducts
  94. Novel chiral ferrocenyl-imino phosphine ligands and their use in palladium catalyzed allylic alkylations
  95. Titanium-Catalyzed Stereoselective Geminal Heterodihalogenation of β-Ketoesters
  96. Ni(ii) Complexes containing chiral tridentate phosphines as new catalysts for the hydroamination of activated olefins
  97. Synthesis and Structure of an Enantiomerically Pure C2 Symmetric Ferrocenyl Carbene
  98. TitaniumLewis Acids for Asymmetric Catalysis: Synthesis and Structural Characterization of Dichloro[diolato(2−)-κO,κO′]bis(solvent)titanium ([TiCl2(diolato)(solvent)2]) Complexes
  99. The Mechanism of Catalytic Enantioselective Fluorination: Computational and Experimental Studies
  100. Structural Aspects of Palladium and Platinum Complexes With Chiral Diphosphinoferrocenes Relevant to the Regio- and Stereoselective Copolymerization of CO with Propene
  101. Catalytic Fluorination by Halide Exchange with 16-Electron Ruthenium(II) Complexes. X-ray Structure of [Tl(μ-F) 2 Ru(dppe) 2 ]PF 6
  102. Synthesis, characterization, and application in asymmetric catalysis of dendrimers containing chiral ferrocenyl diphosphines
  103. Catalytic Enantioselective Fluorination ofβ-Ketoesters
  104. Catalytic Enantioselective Chlorination and Bromination of β-Keto Esters
  105. Ligand Electronic Effect in Enantioselective Palladium-Catalyzed Copolymerization of Carbon Monoxide and Propene
  106. Toward Metal-Mediated C−F Bond Formation. Synthesis and Reactivity of the 16-Electron Fluoro Complex [RuF(dppp) 2 ]PF 6 (dppp = 1,3-Bis(diphenylphosphino)propane)
  107. Phosphane lone-pair energies as a measure of ligand donor strengths and relation to activation energies
  108. Toward an Alkene Hydroamination Catalyst:  Static and Dynamic ab Initio DFT Studies
  109. Synthesis and Characterization of Chiral Bis(aminato)iridate(I) and Aminato-Bridged Iridium(I) Complexes
  110. Carbon−Fluorine Bond Formationvia a Five-Coordinate Fluoro Complex of Ruthenium(II), Preliminary Communication
  111. Charge-Transfer Salts of Ferrocene Derivatives with Bis(maleonitriledithiolato)metallate(III) Complexes ([M(mnt)2]−, M=Ni, Pt): A Ground-State High-Spin [(Ni(mnt)2)2]2− Dimer
  112. Synthesis and characterization of chiral bis-ferrocenyl triphosphine Ni(II) and Rh(III) complexes and their use as catalyst precursors for acetalization reactions
  113. Dendrimers Containing Chiral Ferrocenyl Diphosphine Ligands for Asymmetric Catalysis
  114. The [IrCl(Diphosphine)] 2 /Fluoride System. Developing Catalytic Asymmetric Olefin Hydroamination
  115. A remarkable anion effect on the enantioselectivity of the Pd-catalyzed allylic amination using ferrocenyl ligands
  116. Synthesis of P,S,O-ligands incorporating a planar chiral ferrocenyl motif
  117. Palladium-Catalyzed Asymmetric Allylic Amination Using Ferrocenyl Pyrazole Ligands:  Steric Control of η 3 -Allyl Configuration and Site-Selective Nucleophilic Attack
  118. Synthesis and structure of new chiral ferrocenylphosphines for asymmetric catalysis
  119. Asymmetric allylic alkylation with palladium coordinated to a new optically active pyrazolylmethane ligand
  120. The gold(I)-catalyzed aldol reaction utilizing chiral ferrocenylamine ligands: Synthesis of N-benzyl-substituted ligands
  121. Cooperativity of chirality in homogeneous catalysis: The gold(I)-catalyzed aldol reaction and the vanadium(IV)-catalyzed hetero Diels-Alder cycloaddition
  122. Asymmetric allylic alkylation catalyzed by palladium-sparteine complexes
  123. Enantioselective synthesis: Catalysis of the aldol reaction by neutral gold(I)-chiral ferrocenylphosphine complexes. Crystal structure of the complex [{(η5-C5H4PPh2)(η5-C5H3(PPh2)CH(Me)N(Me)CH2CH2NMe2)Fe}2(AuCl)3] · Et2O
  124. Asymmetric synthesis: Modification of chiral ferrocenylamine ligands for the gold(I)-catalyzed aldol reaction
  125. Sterically congested ligands: Synthesis and spectral characterization of the first Pd(II) and Pt(II) complexes of tetra-t-butyl-substituted biaryloxybis(1,3,2-oxazaphospholidines)
  126. Enantioselective synthesis of β-hydroxy-α-aminophosphonic acid precursors
  127. Mono- and di-hydrido-bridged platinum(II)-tungsten(IV) complexes. Synthesis and X-ray crystal structure of [Cp2W(μ-H)2PtPh(PEt3)][BPh4] and [Cp2(H)W(μ-H)PtPh(PEt3)2][BPh4]
  128. Hydrido-1,5-cyclooctadieneiridium(III) complexes stabilized by trichlorostannate ligands and the structure of [IrH2(SnCl3)(PPh3)3]
  129. Planar-Chiral Ferrocenest Synthetic Methods and Applications
  130. Chiral 1,2-Disubstituted Ferrocene Diphosphines for Asymmetric Catalysis