All Stories

  1. Dinuclear p -cymene ruthenium hydrido complexes as active catalysts for the hydrogenation of levulinic acid to γ-valerolactone with formic acid as the hydrogen source
  2. Dynamic covalent switching between a 1,1′-ruthenocene macrocycle and a ruthenocenophane through a transimination reaction
  3. Tetramethylphosphorinones as Functional Alternatives to Di- tert -butylphosphino Substituents in Ligand Design
  4. Benzimidazolinylidene-Amide and -Imine Ligands: Donor Strength Determination and Catalytic Studies
  5. Flash Communication: Heterobimetallic Palladium–Gold Complexes of Janus Di-N-Heterocyclic Carbenes
  6. Dinuclear Gold(I) and Gold(III) Complexes of Janus Di-N-heterocyclic Carbenes
  7. Revisiting Isomerism in Square Planar Palladium NHC Complexes with NacAc Chelators
  8. Donor Strength Determination of Buchwald-Type Phosphines
  9. Mesoionic Janus‐Type Dicarbene: Complexes, Adducts, and Catalytic Studies
  10. Electronic Profiling of N-Phosphine Oxide-Substituted Imidazolin-2-ylidenes (PoxIms) and Imidazolidin-2-ylidenes (SPoxIms)
  11. Design of a Mesoionic Janus-type Dicarbene
  12. Diverse Post-Metathesis Reactivities of Mixed Amido-Isothiocyanato Molybdenum Complexes
  13. Donor Strength Determination of Anionic Ligands
  14. Stereoelectronic Profiling of Neutral and Monoanionic Biimidazoles and Mixed Diimines
  15. Versatile halogenation via a CNHC^Csp3 palladacycle intermediate
  16. Stereoelectronic Mapping of Dithiocarbamates and Xanthates
  17. Controlled Access to Four- and Six-Membered Palladacycles via Modifying Donor Abilities of β-Ketiminato Ligands (“NacAcs”)
  18. Palladium hetero‐di(N‐heterocyclic carbene) complexes and their catalytic activities in direct C–H arylation of heteroarenes
  19. Synthesis, Characterization, and Catalytic Study of Caffeine-Derived N-heterocyclic Carbene Palladium Complexes
  20. Gauging the donor strength of iron(0) complexesviatheir N-heterocyclic carbene gold(i) adducts
  21. Reactivity Studies and Electronic Properties of an N-Arylated Acyclic Amino Carbene
  22. Mixed NHC–thiolato complexes of palladium: understanding the formation of di-versus mononuclear complexes
  23. Controlling the Coordination Modes of Pyridyl-Functionalized N-Heterocyclic Dicarbene Ligands
  24. Mixed Arylolefin/NHC Complexes of Platinum(II): Syntheses, Characterizations, and In Vitro Cytotoxicities
  25. Donor Strength Determination of Pyridinylidene-amide Ligands using Their Palladium–NHC Complexes
  26. Platinum(II) 1,2,4-Triazolin-5-ylidene Complexes: Stereoelectronic Influences on Their Catalytic Activity in Hydroelementation Reactions
  27. Stereoelectronic Profiling of Acyclic Diamino Carbenes (ADCs)
  28. Fused azole-thiazolines via one-pot cyclization of functionalized N-heterocyclic carbene precursors
  29. Gold(I) and Gold(III) Complexes of Expanded-Ring N-Heterocyclic Carbenes: Structure, Reactivity, and Catalytic Applications
  30. Donor Strengths Determination of Pnictogen and Chalcogen Ligands by the Huynh Electronic Parameter and Its Correlation to Sigma Hammett Constants
  31. Rational Design of Penta-Coordinated Nickel(II) Dicarbene Complexes
  32. Stereoelectronic Profiling of Expanded-Ring N-Heterocyclic Carbenes
  33. (Hetero)bimetallic and Tetranuclear Complexes of Pincer-Bridged N-Heterocyclic Carbene Ligands
  34. Stereoelectronic Flexibility of Ammonium-Functionalized Triazole-Derived Carbenes: Palladation and Catalytic Activities in Water
  35. Gold(I) bis(N-heterocyclic carbene) complexes: Metabolic stability, in vitro inhibition, and genotoxicity
  36. Electronic Properties of N-Heterocyclic Carbenes and Their Experimental Determination
  37. A palladacyclic N-heterocyclic carbene system used to probe the donating abilities of monoanionic chelators
  38. Anion influences on reactivity and NMR spectroscopic features of NHC precursors
  39. Ring-expanded N-heterocyclic carbenes as ligands in iron-catalysed cross-coupling reactions of arylmagnesium reagents and aryl chlorides
  40. Cyclometallated Platinum(II) Complexes with a Phenylpropene-Derived π/σ-Chelator and N-Heterocyclic Carbenes
  41. Postmodification Approach to Charge-Tagged 1,2,4-Triazole-Derived NHC Palladium(II) Complexes and Their Applications
  42. Iron-Catalyzed Cross-Coupling Reactions of Arylmagnesium Reagents with Aryl Chlorides and Tosylates: Influence of Ligand Structural Parameters and Identification of a General N-Heterocyclic Carbene Ligand
  43. A unified ligand electronic parameter based on 13C NMR spectroscopy of N-heterocyclic carbene complexes
  44. Heteroleptic nickel(ii)–diNHC complexes and an unusual ‘reverse’ carbene-transfer reaction to silver(i)
  45. Donor Strength Determination of Benzoxazolin-2-ylidene, Benzobisoxazolin-2-ylidene, and Their Isocyanide Precursors by 13C NMR Spectroscopy of Their PdII and AuI Complexes
  46. Controlled access to a heterometallic N-heterocyclic carbene helicate
  47. 1,2,4-Triazole-derived carbene complexes of gold: characterization, solid-state aggregation and ligand disproportionation
  48. Cyclometallated ruthenium(ii) complexes with ditopic thienyl–NHC ligands: syntheses and alkyne annulations
  49. Pincer versus pseudopincer: isomerism in palladium(ii) complexes bearing κ3C,S,C ligands
  50. Electronic Structural Trends in Divalent Carbon Compounds
  51. Cationic gold(i) heteroleptic complexes bearing a pyrazole-derived N-heterocyclic carbene: syntheses, characterizations, and cytotoxic activities
  52. Syntheses, Characterizations, and a Preliminary Comparative Cytotoxicity Study of Gold(I) and Gold(III) Complexes Bearing Benzimidazole- and Pyrazole-Derived N-Heterocyclic Carbenes
  53. Pyrazolin-5-ylidene Palladium(II) Complexes: Synthesis, Characterization, and Application in the Direct Arylation of Pentafluorobenzene
  54. Dipalladium Complexes with Triazolidin-Diylidene Bridges and Their Catalytic Activities
  55. Sulfur-Functionalized N-Heterocyclic Carbene Complexes of Pd(II): Syntheses, Structures and Catalytic Activities
  56. Gold Complexes of an Alicyclic Indazole-Derived N-Heterocyclic Carbene: Syntheses, Characterizations, and Ligand Disproportionation
  57. Correlation of spectroscopically determined ligand donor strength and nucleophilicity of substituted pyrazoles
  58. 1,2,3-Triazolin-5-ylidenes: Synthesis of Hetero-bis(carbene) Pd(II) Complexes, Determination of Donor Strengths, and Catalysis
  59. Syntheses and catalytic activities of Pd(II) dicarbene and hetero-dicarbene complexes
  60. ChemInform Abstract: Pyrazolin-4-ylidenes: A New Class of Intriguing Ligands
  61. Reactivity Differences of Palladium(II) Dimers Bearing Heterocyclic Carbenes with Two, One, or No α-Nitrogen Atoms toward Isocyanides
  62. [2]Rotaxanes with Palladium(ii)-NHC stoppers
  63. Syntheses and characterizations of thiolato-functionalized N-heterocyclic carbene Pd(ii) complexes with normal and mesoionic binding modes
  64. Pd–carbene catalyzed carbonylation reactions of aryl iodides
  65. CSC-pincer versus pseudo-pincer complexes of palladium(ii): a comparative study on complexation and catalytic activities of NHC complexes
  66. Pyrazolin-4-ylidenes: a new class of intriguing ligands
  67. Co-ligand effects in the catalytic activity of Pd(II)–NHC complexes
  68. Dinuclear and Tetranuclear Palladium(II) Complexes of a Thiolato-Functionalized, Benzannulated N-Heterocyclic Carbene Ligand and Their Activities toward Suzuki−Miyaura Coupling
  69. Synthesis ofcis- andtrans-Diisothiocyanato−Bis(NHC) Complexes of Nickel(II) and Applications in the Kumada−Corriu Reaction
  70. Synthesis, structural characterization and catalytic activity of a palladium(II) complex bearing a new ditopic thiophene-N-heterocyclic carbene ligand
  71. Syntheses, Structures, and Catalytic Activities of Hemilabile Thioether-Functionalized NHC Complexes
  72. Versatile coordination chemistry of indazole-derived carbenes
  73. Pyrazole-Derived Remote Dicarbenes: Versatile Ligands for Di- and Tetranuclear Complexes
  74. Benzothiazolin-2-ylidene and Azole Mixed-Ligand Complexes of Palladium
  75. 13C NMR Spectroscopic Determination of Ligand Donor Strengths Using N-Heterocyclic Carbene Complexes of Palladium(II)
  76. ChemInform Abstract: Formation of Homoleptic Tetracarbene versus cis-Chelating Dicarbene Complexes of Nickel(II) and Applications in Kumada-Corriu Couplings.
  77. Palladium(II) Pyrazolin-4-ylidenes: Substituent Effects on the Formation and Catalytic Activity of Pyrazole-Based Remote NHC Complexes
  78. Formation of Homoleptic Tetracarbene versuscis-Chelating Dicarbene Complexes of Nickel(II) and Applications in Kumada-Corriu Couplings
  79. Mixed Azido-N-Heterocyclic Carbene Complexes of Nickel(II) as a Template for New Organometallics Bearing Carbodiimido, Tetrazolato, and Abnormal Tetrazolin-5-ylidene Ligands
  80. Rotamers of palladium complexes bearing IR active N-heterocyclic carbene ligands: Synthesis, structural characterization and catalytic activities
  81. Formation and structures of Pd(II) N,S-heterocyclic carbene-pyridyl mixed-ligand complexes
  82. Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii)
  83. Syntheses and catalytic activities of pseudo-pincer and CSC pincer-type Pd(II) complexes derived from benzannulated N-heterocyclic carbenes
  84. Mixed carbene–isocyanide Pd(ii) complexes: synthesis, structures and reactivity towards nucleophiles
  85. Structures and Suzuki-Coupling of N-Heterocyclic Carbene Complexes of PdII with Coordinated Solvent and PPh3
  86. Synthesis and Structural Characterization of Palladium Dicarbene Complexes Bearing Labile Co-Ligands
  87. Ag(I) and Pd(II) complexes of a 1,3-dibenzhydryl substituted benzannulated N-heterocyclic carbene: Unexpected rearrangement, structures and catalytic studies
  88. Catalytic Annulation of Heterocycles via a Novel Redox Process Involving the Imidazolium Salt N-Heterocyclic Carbene Couple
  89. Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)
  90. Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)
  91. Au(I) and Au(III) complexes of a sterically bulky benzimidazole-derived N-heterocyclic carbene
  92. Pd(ii) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalytic activities toward C–C coupling reactions
  93. Palladium(II) Pyrazolin-4-ylidenes: Remote N-Heterocyclic Carbene Complexes and Their Catalytic Application in Aqueous Suzuki−Miyaura Coupling
  94. Syntheses and Characterizations of Pd(II) Complexes Incorporating aN-Heterocyclic Carbene and AromaticN-Heterocycles
  95. Dipalladium Bis(μ-isopropylthiolato) Complexes with a [Pd2S2] Core Supported by N-Heterocyclic Carbenes
  96. Mono- vs Bis(carbene) Complexes:  A Detailed Study on Platinum(II)−Benzimidazolin-2-ylidenes
  97. Pd(II) complexes of a sterically bulky, benzannulated N-heterocyclic carbene and their catalytic activities in the Mizoroki–Heck reaction
  98. A single-molecular pathway from heterometallic MM′ (M = Baii, Mnii; M′ = Criii) oxalato complexes to intermetallic composite oxides
  99. Dinuclear PCP pincer complexes from Lewis acidic [Pd(OTf)(PCP)] and basic [Pd(4-Spy)(PCP)] (OTf = triflate; 4-Spy = 4-pyridinethiolate; PCP = –CH(CH2CH2PPh2)2)
  100. Pd(ii) complexes of N,S-heterocyclic carbenes with pendant and coordinated allyl function and their Suzuki coupling activities
  101. Preparation and characterization of the first pyrazole-based remote N-heterocyclic carbene complexes of palladium(ii)
  102. Convenient Entry to Mono- and Dinuclear Palladium(II) Benzothiazolin-2-ylidene Complexes and Their Activities toward Heck Coupling
  103. Metallosupramolecular Chemistry with Bis(benzene-o-dithiolato) Ligands
  104. Palladium(II) Complexes of a Sterically Bulky, Benzannulated N-Heterocyclic Carbene with Unusual Intramolecular C−H···Pd and Ccarbene···Br Interactions and Their Catalytic Activities
  105. Benzothiazolin-2-ylidene Complexes of Iridium(I)
  106. New Highly Efficient Method for the Synthesis of tert -Alkyl Nitroso Compounds
  107. Synthesis and properties of N,N′-dialkylimidazolium bis(nonafluorobutane-1-sulfonyl)imides: a new subfamily of ionic liquids
  108. Mixed Dicarboxylato−Bis(carbene) Complexes of Palladium(II):  Synthesis, Structures, Trans−Cis Isomerism, and Catalytic Activity
  109. Hemilabile behavior of a thioether-functionalized N-heterocyclic carbene ligand
  110. Synthesis and Structural Characterization of the First Bis(benzimidazolin-2-ylidene) Complexes of Nickel(II)
  111. Solvent-controlled selective synthesis of a trans-configured benzimidazoline-2-ylidene palladium(II) complex and investigations of its Heck-type catalytic activity
  112. Synthesis and structural characterization of mixed carbene-carboxylate complexes of palladium(II)
  113. Dinuclear Complexes with Bis(benzenedithiolate) Ligands