All Stories

  1. CPAPhosAuCl as Dual Chiral Organocatalyst and Au(I)-Complex for Relay Catalysis: Application in the Synthesis of Chiral Indole Alkaloids

    Article • ACS Catalysis, December 2025, American Chemical Society (ACS)

    Gilles Frison

  2. Tunable Charge Transfer In Functionalised Betainoïd Pyridinium‐Benzimidazole Scaffolds: Computational and Experimental Insights Into Optical Properties

    Article • ChemPhotoChem, September 2025, Wiley

    Gilles Frison

  3. Bio-inspired total synthesis of daphnepapytone A

    Article • Chemical Science, January 2025, Royal Society of Chemistry

    Gilles Frison

  4. Correlation Between NMR Coupling Constants and σ‐Donating Properties of N‐Heterocyclic Carbenes and Their Derivatives

    Article • Chemistry - A European Journal, December 2024, Wiley

    Gilles Frison

  5. Controlling Diastereoselectivity in Dearomatizing Diels‐Alder Reactions of Nitroarenes with 2‐Trimethylsilyloxycyclohexadiene

    Article • Chemistry - A European Journal, May 2024, Wiley

    Gilles Frison

  6. Tandem Hock and Friedel–Crafts reactions allowing an expedient synthesis of a cyclolignan-type scaffold

    Article • Beilstein Journal of Organic Chemistry, January 2024, Beilstein Institut

    Gilles Frison

  7. Theoretical Investigation of the Mechanism of the Hock Rearrangement with InCl 3 as Catalyst**

    Article • ChemCatChem, July 2023, Wiley

    Gilles Frison

  8. Tandem InCl 3 -Promoted Hydroperoxide Rearrangements and Nucleophilic Additions: A Straightforward Entry to Benzoxacycles

    Article • The Journal of Organic Chemistry, June 2023, American Chemical Society (ACS)

    Gilles Frison

  9. Enantioselective Au( i )-catalyzed tandem reactions between 2-alkynyl enones and naphthols by the tethered counterion-directed catalysis strategy

    Article • Organic Chemistry Frontiers, January 2023, Royal Society of Chemistry

    Gilles Frison

  10. Total Synthesis of (+)‐Cinereain and (−)‐Janoxepin through a Fragment Coupling/Retro‐Claisen Rearrangement Cascade

    Article • Angewandte Chemie, October 2022, Wiley

    Gilles Frison

  11. Total Synthesis of (+)‐Cinereain and (−)‐Janoxepin through a Fragment Coupling/Retro‐Claisen Rearrangement Cascade

    Article • Angewandte Chemie, October 2022, Wiley

    Gilles Frison

  12. Enantioselective Au(I)-Catalyzed Multicomponent Annulations via Tethered Counterion-Directed Catalysis

    Article • ACS Catalysis, March 2022, American Chemical Society (ACS)

    Gilles Frison

  13. Microbiological versus Chemical Reductive Sulfidation: An Experimental and Theoretical Study

    Article • ACS Omega, March 2021, American Chemical Society (ACS)

    Gilles Frison

  14. Enantioselective Au(i)-catalyzed dearomatization of 1-naphthols with allenamides through Tethered Counterion-Directed Catalysis

    Article • Chemical Communications, January 2021, Royal Society of Chemistry

    Gilles Frison

  15. Comparison of Chemical and Interpretative Methods: the Carbon–Boron π‐Bond as a Test Case**

    Article • Chemistry - A European Journal, November 2020, Wiley

    Gilles Frison

  16. Insights into the Ochratoxin A/Aptamer Interactions on a Functionalized Silicon Surface by Fourier Transform Infrared and UV–Vis Studies

    Article • Langmuir, November 2020, American Chemical Society (ACS)

    Gilles Frison

  17. Comparison of Chemical and Interpretative Methods: The Carbon-boron π-Bond as a Test Case

    Article • August 2020, American Chemical Society (ACS)

    Gilles Frison

  18. Can an Elusive Platinum(III) Oxidation State be Exposed in an Isolated Complex?

    Article • Angewandte Chemie, August 2020, Wiley

    Gilles Frison

  19. Can an Elusive Platinum(III) Oxidation State be Exposed in an Isolated Complex?

    Article • Angewandte Chemie, August 2020, Wiley

    Gilles Frison

  20. [(dcpp)Ni(η2-Arene)] Precursors: Synthesis, Reactivity, and Catalytic Application to the Suzuki–Miyaura Reaction

    Article • Organometallics, May 2020, American Chemical Society (ACS)

    Gilles Frison

  21. Comparison of Chemical and Interpretative Methods: The Carbon-boron π-Bond as a Test Case

    Article • April 2020, American Chemical Society (ACS)

    Gilles Frison

  22. Comparison of Chemical and Interpretative Methods: The Carbon-boron π-Bond as a Test Case

    Article • April 2020, American Chemical Society (ACS)

    Gilles Frison

  23. Tethered Counterion-Directed Catalysis: Merging the Chiral Ion-Pairing and Bifunctional Ligand Strategies in Enantioselective Gold(I) Catalysis

    Article • Journal of the American Chemical Society, February 2020, American Chemical Society (ACS)

    Gilles Frison

  24. One‐Pot Synthesis of Metastable 2,5‐Dihydrooxepines through Retro‐Claisen Rearrangements: Method and Applications

    Article • Chemistry - A European Journal, May 2019, Wiley

    Gilles Frison

  25. Structure of Electronically Reduced N-Donor Bidentate Ligands and Their Heteroleptic Four-Coordinate Zinc Complexes: A Survey of Density Functional Theory Results

    Article • Inorganic Chemistry, May 2019, American Chemical Society (ACS)

    Gilles Frison

  26. A Self-Assembling Ligand Switch That Involves Hydroxide Addition to an sp2 Hybridised Phosphorus Atom - A System Allowing OH- Mediated Uptake of [MCl2 ] (M = Pd, Pt) Centres

    Article • European Journal of Inorganic Chemistry, February 2019, Wiley

    Gilles Frison

  27. Structure of Electronically Reduced N-Donor Bidentate Ligands and Their Heteroleptic Four-Coordinate Zinc Complexes: A Survey of DFT Results

    Article • December 2018, American Chemical Society (ACS)

    Gilles Frison

  28. Structure of Electronically Reduced N-Donor Bidentate Ligands and Their Heteroleptic Four-Coordinate Zinc Complexes: A Survey of DFT Results

    Article • December 2018, American Chemical Society (ACS)

    Gilles Frison

  29. Multifaceted Study on a Cytochalasin Scaffold: Lessons on Reactivity, Multidentate Catalysis, and Anticancer Properties

    Article • Chemistry - A European Journal, October 2018, Wiley

    Gilles Frison, Pr Alexandre E Escargueil

  30. Iron and Cobalt Metallotropism in Remote-Substituted NHC Ligands: Metalation to Abnormal NHC Complexes or NHC Ring Opening

    Article • Angewandte Chemie, September 2018, Wiley

    Gilles Frison

  31. Iron and Cobalt Metallotropism in Remote-Substituted NHC Ligands: Metalation to Abnormal NHC Complexes or NHC Ring Opening

    Article • Angewandte Chemie, September 2018, Wiley

    Gilles Frison

  32. Revised Theoretical Model on Enantiocontrol in Phosphoric Acid Catalyzed H-Transfer Hydrogenation of Quinoline

    Article • The Journal of Organic Chemistry, February 2018, American Chemical Society (ACS)

    Gilles Frison

  33. Quantum-Chemical Modeling of the First Steps of the Strecker Synthesis: From the Gas-Phase to Water Solvation

    Article • The Journal of Physical Chemistry A, February 2018, American Chemical Society (ACS)

    Gilles Frison

  34. Csp2–Csp2 and Csp2–N Bond Formation in a One-Pot Reaction between N-Tosylhydrazones and Bromonitrobenzenes: An Unexpected Cyclization to Substituted Indole Derivatives

    Article • Organic Letters, December 2017, American Chemical Society (ACS)

    Gilles Frison

  35. Frontispiece: Improved Infrared Spectra Prediction by DFT from a New Experimental Database

    Article • Chemistry - A European Journal, June 2017, Wiley

    Gilles Frison

  36. Improved Infrared Spectra Prediction by DFT from a New Experimental Database

    Article • Chemistry - A European Journal, April 2017, Wiley

    Gilles Frison

  37. Heteroleptic, two-coordinate [M(NHC){N(SiMe3)2}] (M = Co, Fe) complexes: synthesis, reactivity and magnetism rationalized by an unexpected metal oxidation state

    Article • Dalton Transactions, January 2017, Royal Society of Chemistry

    Gilles Frison

  38. Preparation, Structural Analysis, and Reactivity Studies of Phosphenium Dications

    Article • Organometallics, February 2016, American Chemical Society (ACS)

    Gilles Frison

  39. Direct synthesis of doubly deprotonated, dearomatised lutidine PNP Cr and Zr pincer complexes based on isolated K and Li ligand transfer reagents

    Article • Dalton Transactions, January 2016, Royal Society of Chemistry

    Gilles Frison

  40. H-atom loss and migration in hydrogen-rich peptide cation radicals: The role of chemical environment

    Article • International Journal of Mass Spectrometry, November 2015, Elsevier

    Gilles Frison

  41. Microhydration of Protonated Nα-Acetylhistidine: A Theoretical Approach

    Article • The Journal of Physical Chemistry, August 2015, American Chemical Society (ACS)

    Gilles Frison

  42. Building a Lewis Acidic Phosphorus

    Article • Phosphorus Sulfur and Silicon and the Related Elements, June 2015, Taylor & Francis

    Gilles Frison

  43. Estimating π binding energy of N-Heterocyclic carbenes: The role of polarization

    Article • Journal of Computational Chemistry, February 2015, Wiley

    Gilles Frison, Dr Elixabete Rezabal

  44. Unprecedented directed lateral lithiations of tertiary carbons on NHC platforms

    Article • Chemical Communications, January 2015, Royal Society of Chemistry

    Gilles Frison, Dr Elixabete Rezabal

  45. Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand

    Article • Physical Chemistry Chemical Physics, January 2015, Royal Society of Chemistry

    Gilles Frison

  46. Copper-Catalyzed Coupling ofN-Tosylhydrazones with Amines: Synthesis of Fluorene Derivatives

    Article • ACS Catalysis, December 2014, American Chemical Society (ACS)

    Gilles Frison

  47. Vibrational Signatures ofS-Nitrosoglutathione as Gaseous, Protonated Species

    Article • The Journal of Physical Chemistry, October 2014, American Chemical Society (ACS)

    Gilles Frison

  48. Planar Chiral Phosphoric Acids with Biphenylene-Tethered Paracyclophane Scaffolds: Synthesis, Characterization, and Catalytic Screening

    Article • The Journal of Organic Chemistry, October 2014, American Chemical Society (ACS)

    Gilles Frison

  49. Benchmarking DFT and TD-DFT Functionals for the Ground and Excited States of Hydrogen-Rich Peptide Radicals

    Article • Journal of Chemical Theory and Computation, August 2014, American Chemical Society (ACS)

    Gilles Frison

  50. Pincer versus pseudopincer: isomerism in palladium(ii) complexes bearing κ3C,S,C ligands

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Gilles Frison, Associate Professor Han Vinh Huynh

  51. Development of Chiral Phosphoric Acids based on Ferrocene‐Bridged Paracyclophane Frameworks

    Article • Advanced Synthesis & Catalysis, December 2013, Wiley

    Gilles Frison

  52. Noncovalent Chalcogen Bonds and Disulfide Conformational Change in the Cystamine‐Based Hybrid Perovskite [H3N(CH2)2SS(CH2)2NH3]PbIII4

    Article • European Journal of Inorganic Chemistry, December 2013, Wiley

    Gilles Frison

  53. Gold versus Palladium: A Regioselective Cycloisomerization of Aromatic Enynes

    Article • Advanced Synthesis & Catalysis, November 2013, Wiley

    Gilles Frison

  54. Electronic Structure Trends in N‐Heterocyclic Carbenes (NHCs) with Varying Number of Nitrogen Atoms and NHCTransition‐Metal Bond Properties

    Article • Chemistry - A European Journal, August 2013, Wiley

    Gilles Frison

  55. Csp2–N Bond Formation via Ligand-Free Pd-Catalyzed Oxidative Coupling Reaction of N-Tosylhydrazones and Indole Derivatives

    Article • The Journal of Organic Chemistry, August 2013, American Chemical Society (ACS)

    Gilles Frison

  56. A PdII Complex Bearing a Benzimidazole‐Derived Ligand with Potentially “Mesoionic and Remote” Character and Its Catalytic Activity

    Article • European Journal of Inorganic Chemistry, July 2013, Wiley

    Gilles Frison

  57. Electronic Structural Trends in Divalent Carbon Compounds

    Article • The Journal of Organic Chemistry, January 2013, American Chemical Society (ACS)

    Gilles Frison, Associate Professor Han Vinh Huynh

  58. Guiding the synthesis of pentazole derivatives and their mono- and di-oxides with quantum modeling

    Article • New Journal of Chemistry, January 2013, Royal Society of Chemistry

    Gilles Frison, Dr Gilles Ohanessian

  59. Stepwise syntheses of tri- and tetraphosphaporphyrinogens

    Article • Chemical Communications, January 2012, Royal Society of Chemistry

    Gilles Frison

  60. Dissociation Channel Dependence on Peptide Size Observed in Electron Capture Dissociation of Tryptic Peptides

    Article • Journal of the American Society for Mass Spectrometry, June 2011, American Chemical Society (ACS)

    Gilles Frison

  61. Ground Electronic State of Peptide Cation Radicals: A Delocalized Unpaired Electron?

    Article • The Journal of Physical Chemistry Letters, May 2011, American Chemical Society (ACS)

    Gilles Frison

  62. Comparison of Microhydration Methods: Protonated Glycine as a Working Example

    Article • The Journal of Physical Chemistry, April 2011, American Chemical Society (ACS)

    Gilles Frison

  63. An Easy, Stereoselective Synthesis of Hexahydroisoindol‐4‐ones under Phosphine Catalysis

    Article • Advanced Synthesis & Catalysis, February 2011, Wiley

    Gilles Frison

  64. Acid–base thermochemistry of gaseous oxygen and sulfur substituted amino acids (Ser, Thr, Cys, Met)

    Article • Physical Chemistry Chemical Physics, January 2011, Royal Society of Chemistry

    Gilles Frison

  65. Comparison between α- and β-carbonic anhydrases: can Zn(His)3(H2O) and Zn(His)(Cys)2(H2O) sites lead to equivalent enzymes?

    Article • Dalton Transactions, January 2011, Royal Society of Chemistry

    Gilles Frison, Dr Gilles Ohanessian

  66. Reactivity of polynuclear zinc‐thiolate sites

    Article • International Journal of Quantum Chemistry, August 2010, Wiley

    Gilles Frison, Dr Gilles Ohanessian

  67. Thermodynamic Stability Versus Kinetic Lability of ZnS4 Core

    Article • Chemistry - An Asian Journal, May 2010, Wiley

    Gilles Frison, Dr Gilles Ohanessian

  68. ChemInform Abstract: Bend the Coin Your Way: Ligand Design and Main Group Element Chemistry.

    Article • ChemInform, May 2010, Wiley

    Gilles Frison

  69. Expanding the Scope of Enantioselective FerroPHANE‐Promoted [3+2] Annulations with α,β‐Unsaturated Ketones

    Article • Chemistry - A European Journal, January 2010, Wiley

    Gilles Frison

  70. Nucleophilicity of zinc-bound thiolates

    Article • Comptes Rendus Chimie, May 2009, Cellule MathDoc/CEDRAM

    Gilles Frison, Dr Gilles Ohanessian

  71. Metal-histidine-glutamate as a regulator of enzymatic cycles: a case study of carbonic anhydrase

    Article • Physical Chemistry Chemical Physics, January 2009, Royal Society of Chemistry

    Gilles Frison, Dr Gilles Ohanessian

  72. Platinum(II) Complexes Featuring Chiral Diphosphines and N-Heterocyclic Carbene Ligands: Synthesis and Evaluation as Cycloisomerization Catalysts

    Article • Organometallics, December 2008, American Chemical Society (ACS)

    Gilles Frison

  73. Structure of Electron-Capture Dissociation Fragments from Charge-Tagged Peptides Probed by Tunable Infrared Multiple Photon Dissociation

    Article • Journal of the American Chemical Society, October 2008, American Chemical Society (ACS)

    Gilles Frison

  74. The Alkylation Mechanism of Zinc-Bound Thiolates Depends upon the Zinc Ligands

    Article • Inorganic Chemistry, August 2008, American Chemical Society (ACS)

    Gilles Frison, Dr Gilles Ohanessian

  75. Electron capture in charge-tagged peptides. Evidence for the role of excited electronic states

    Article • Journal of the American Society for Mass Spectrometry, December 2007, American Chemical Society (ACS)

    Gilles Frison

  76. A comparative study of semiempirical, ab initio, and DFT methods in evaluating metal–ligand bond strength, proton affinity, and interactions between first and second shell ligands in Zn‐biomimetic complexes

    Article • Journal of Computational Chemistry, July 2007, Wiley

    Gilles Frison, Dr Gilles Ohanessian

  77. A Stable Aminyl Radical Metal Complex

    Article • Science, January 2005, American Association for the Advancement of Science

    Gilles Frison

  78. New perspectives for olefin complexes: Synthesis and characterisation of stable rhodium(0) and iridium(0) complexes

    Article • December 2003, Royal Society of Chemistry

    Gilles Frison

  79. Dibenzophosphasemibullvalen

    Article • Angewandte Chemie, August 2003, Wiley

    Gilles Frison

  80. Dibenzophosphasemibullvalene

    Article • Angewandte Chemie, August 2003, Wiley

    Gilles Frison

  81. TROPDAD: A New Ligand for the Synthesis of Water‐Stable Paramagnetic [16+1]‐Electron Rhodium and Iridium Complexes

    Article • Chemistry - A European Journal, August 2003, Wiley

    Gilles Frison

  82. Binding of Specialty Phosphines to Metals:  Synthesis, Structure, and Solution Calorimetry of the Phosphirane Complex [PtMe2(iPrBABAR-Phos)2]

    Article • Organometallics, April 2003, American Chemical Society (ACS)

    Gilles Frison

  83. Electronegativity Versus Lone Pair Shape:  A Comparative Study of Phosphaferrocenes and Azaferrocenes

    Article • The Journal of Physical Chemistry A, May 2002, American Chemical Society (ACS)

    Gilles Frison

  84. A 1,1’-ferrocenylene-bridged analogue of BIPNOR

    Article • Comptes Rendus Chimie, April 2002, Cellule MathDoc/CEDRAM

    Gilles Frison

  85. Substituent effects in polarized phosphaalkenes: a theoretical study of aminocarbene–phosphinidene adducts

    Article • Journal of Organometallic Chemistry, February 2002, Elsevier

    Gilles Frison

  86. De-aromatizing Phosphole

    Article • The Journal of Organic Chemistry, February 2002, American Chemical Society (ACS)

    Gilles Frison

  87. Coordinated olefins, H2CCHR, and phosphanes, PH2R: a theoretical study of the R substituent effect

    Article • Journal of Organometallic Chemistry, February 2002, Elsevier

    Gilles Frison

  88. Theoretical study of the bonding between aminocarbene and main group elements

    Article • Journal of the Chemical Society Perkin Transactions 2, January 2002, Royal Society of Chemistry

    Gilles Frison

  89. Synthesis and X-ray Crystal Structure Analysis of a Cp-Substituted Phosphaferrocene

    Article • Organometallics, November 2001, American Chemical Society (ACS)

    Gilles Frison

  90. A DFT/Electron Localization Function (ELF) Study of the Bonding of Phosphinidenes with N-Heterocyclic Carbenes

    Article • The Journal of Physical Chemistry A, November 1999, American Chemical Society (ACS)

    Gilles Frison

  91. The CH by N Replacement Effects on the Aromaticity and Reactivity of Phosphinines

    Article • The Journal of Organic Chemistry, July 1999, American Chemical Society (ACS)

    Gilles Frison

  92. Theoretical study of electrophilic versus nucleophilic character of transition metal complexes of phosphinidene

    Article • Journal of Organometallic Chemistry, November 1998, Elsevier

    Gilles Frison

  93. Some difficulties encountered with AM1 and PM3 calculations

    Article • Tetrahedron, October 1998, Elsevier

    Gilles Frison