What is it about?
Mayer's relation and the heat capacity ratio are wrong. This is shown experimentally.
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Why is it important?
This is another proof that Cp = Cv (isobaric heat capacity always equals the isochoric one), what was found by me in I. A. Stepanov. Exact calculation of the internal energy of the ideal gas in statistical mechanics. – Physical Science International Journal. 2017. Vol 14. No 2. 1-5..
Perspectives
The failure of Mayer's relation and the heat capacity ratio is shown also in I. A. Stepanov. The isochoric heat capacity of ZrW2O8 and Sc2W3O12 is greater than their isobaric one. – Materials Letters. 2016. Vol 177. 112 115.
Dr Igor Stepanov
Liepajas Universitate
Read the Original
This page is a summary of: Failure of the Identity That Links Thermal Expansion and Isothermal Compressibility in the Case of Condensed Phases, Physical Science International Journal, May 2018, Sciencedomain International,
DOI: 10.9734/psij/2018/41102.
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