Magnetic Properties of Cobalt-Doped ZnAl2O4 Nanosheets Prepared by Hydrothermal Synthesis.

What is it about?

Nanomaterials with collective optical and magnetic properties are called smart or functional materials and have promising applications in many fields of science and technology. Undoped and Co-doped ZnAl2O4 were prepared using a co-precipitation-assisted hydrothermal method. A systematic investigation was carried out to understand the effects of the Co concentration on the crystalline phase, morphology, and optical and magnetic properties of Co-doped ZnAl2O4. X-ray diffraction confirmed the cubic spinel structure with the Fd3m space group, and there was no impurity phase. X-ray photoelectron spectroscopy of Co-doped ZnAl2O4 confirmed the existence of Zn, Al and O, and the Co in the optimized sample of ZAO-Co-3 confirmed the oxidation state of cobalt as Co2+. Transmission electron microscopy of pure and Co-doped ZnAl2O4 revealed micro-hexagons and nanosheets, respectively. The optical absorption results showed that the bandgap of ZnAl2O4 decreased with increasing Co concentration. The hysteresis loop of Co-doped ZnAl2O4 revealed clear ferromagnetic behavior at room temperature. The as-prepared materials are suitable for energy storage applications, such as in supercapacitors and fuel cells. This work aims to focus on the effect of cobalt ions in different concentrations on structural, optical and magnetic properties.

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Why is it important?

Transmission electron microscopy of pure and Co-doped ZnAl2O4 revealed micro-hexagons and nanosheets, respectively. The optical absorption results showed that the bandgap of ZnAl2O4 decreased with increasing Co concentration. Spinel semiconductors are comprised of a group of metal oxides having a chemical complex AB2O4, where A and B are di- and trivalent cations, respectively. Among the many spinel-based nanomaterials known, zinc aluminate (ZnAl2O4) has attracted interest owing to its utility in various fields, such as ceramics, sensors, catalysts, aerospace, lubricants, optical coatings, transparent conducting oxides (TCO), dielectrics, electronics, and optoelectronic devices.

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