What is it about?

Biomimetics and bioinspiration is one of the most progressive, recently developed science, that deals with nature and living systems in order to provide a sustainable life for future generations. With a more complex penetration into the inside of living organisms and understanding their functions, the ability to mimic nature has increased dramatically since several decades and thus nature-driven solutions have forwarded technological progress into a higher level. Nevertheless, the abovementioned discipline offers then substantial scientific portfolio for the development of current material chemistry, specifically for the novel and innovative adsorbent synthesis. It is supposed that basic constructional processes of matter like biomineralisation, biomimetics, supramolecular preorganisation or interfacial molecular recognition (templating) and other recently frequent techniques and new advanced adsorption materials contribute to the certain portfolio for potential Green Chemistry of future. Moreover, there is a gradual insistence that clean industrial production, water reuse and solid waste recycling provide a sustainable living to the next generations

Featured Image

Why is it important?

Industrially utilized adsorbents are predominantly characterized with uniformly accessible pores, an interlinked pore system, a high surface area and physical and/or chemical stability. In general, most industrial adsorbents fall into one of the three classes, i.e. oxygen containing compounds, which are typically hydrophilic and polar adsorbents, such as silica gel, zeolites, clays, alumina; carbon-based compounds, which are typically hydrophobic and non-polar, such as activated carbon, carbonaceous materials, fullerenes, graphite and polymer-based adsorbents with polar or non-polar functional groups in a porous polymer matrix. It is generally known that long period of commercial activated carbon and synthetic ion exchange resins produced from petroleum-based raw materials and under not environmentally friendly processing, may slowly replace some alternative, probably nature mimic or waste products. Some of the very important features of such products or perspective potential adsorbents are characteristics of their functional groups, able to bind a broad range of environmental pollutants from contaminated media, however at a low cost. Many, more or less mainly developing countries, prefer now economically feasible and locally available natural materials such as chitosan, zeolites, clay and certain industrial or agricultural waste products, i.e. fly ash, low rank coal, lignite, natural metal oxides, peat, sawdust, waste slurry, lignine, shungite, coconut shell charcoal, waste biomass and cork (Quercus suber L.)

Perspectives

Natural zeolite, especially clinoptilolite species, as one of the most popular and cost-effective inorganic resource, present today some alternative to other offered adsorbents for environmental remediation processes, mainly for countries which are rich on zeolite deposits. Thus, in water treatment and water purification sector, besides the metallic nanoparticles, carbon materials and recently explored dendrimers, zeolites are being evaluated as the most progressive functional and nanosized materials in the last few decades. Zeolites belong to highly porous, hydrated aluminosilicates, which consist of a rigid crystalline skeleton including a honeycomb-like network of tunnels and cages. Their three-dimensional framework is negatively charged balanced by exchangeable positive cations. According to another definition, lately published, zeolites are clathrates or inclusion compounds, potentially hosting various guest components in their versatile structure. Aluminosilicate surfaces obviously encounter van der Waals attractive forces, hydrogen bounds and dipol-dipol interactions. Moreover, their skeletons possess neighboring SiO- and SiOH groups. Zeolites are classified according to geometry (internal pore structure) and connectivity (bonding network) and therefore the difference between zeolite topologies and structures is for zeolite classification characteristic. The topology of a zeolite means the spatial connectivity of the nodes, although the exact chemical make-up of the compound means the structure. However, different structures can be of the same topology. Till today, over 200 unique zeolite topologies have been recognized and over 80 naturally occurring zeolite species have been found (Figs. 3b and 4). Approximately 15 novel structures are estimated to be synthesised annually, however, only a few of them were decoded

Prof. M.Eng. PhD. Eva Chmielewská
Comenius University

Read the Original

This page is a summary of: Current Progress in Designing Environmental Adsorbents, Current Green Chemistry, April 2019, Bentham Science Publishers,
DOI: 10.2174/221334610601190329164505.
You can read the full text:

Read

Contributors

The following have contributed to this page