What is it about?
In the paper, we wish to report an efficient one-pot synthesis of α-alkylated β-ketothioesters based on H2SO4-catalyzed tandem alkylation/hydrolysis reaction between acyclic α-oxo ketene dithioacetals and alcohols.
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Why is it important?
The use of very small amounts of catalyst, good generality, low cost of the reagents, excellent yield and mild reaction conditions outline the notable features of the reaction.
Perspectives
The method developed in this manuscript should be of great interest to chemists
haifeng yu
Read the Original
This page is a summary of: Efficient One-Pot Synthesis of α-Alkylated β-Ketothioesters from H2SO4- Catalyzed Tandem Alkylation/Hydrolysis Reaction of Acyclic α-Oxo Ketene Dithioacetals with Alcohols, Letters in Organic Chemistry, October 2018, Bentham Science Publishers,
DOI: 10.2174/1570178615666180326161157.
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