What is it about?
New magnetically recoverable catalysts have been synthesized by deposition of 1 % palladium (Pd)-metal on the polymer poly(1-oxo-trimethylene), containing 15 % of magnetite. The magnetite allows the complete recovery of the catalyst with the simple application of an external magnetic field. The activity of such a catalyst has been studied under phosphine-free conditions in the alkoxycarbonylation of iodobenzene to the corresponding benzoic acid esters.
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Why is it important?
The magnetite allows the complete recovery of the catalyst with the simple application of an external magnetic field. The reaction is carried out under phosphine-free conditions.
Perspectives
New green method to carried out the alkoxycarbonylation.
Prof. Andrea Vavasori
Ca' Foscari University Venice
Read the Original
This page is a summary of: New magnetically recoverable palladium-based catalysts active in the alkoxycarbonylation of iodobenzene, Pure and Applied Chemistry, May 2016, De Gruyter,
DOI: 10.1515/pac-2016-0204.
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