What is it about?

Three new technologies in the field of energy management were developed in 21st Century - Fuel Cells, Sorption Transformation and Nano Technologies stimulated by the energy crisis and nature protection. The combination of all these technologies with the heat pipe thermal management give a chance to significantly increase their efficiency and ensure sustainability of human life. Fuel cells and thermally powered adsorption heating/cooling technologies are the fundament of co-called co-generation and tri-generation of energy. They guarantee the reductions in energy consumption and environment security. Nano Technologies (nano fluids and nano coatings) improve the thermal properties of working fluids and heat pipe wick parameters. This chapter deals with some aspects of the heat pipe based thermal control of fuel cells, solid sorption transformers, and electronic components, air-condition devices in a renewable energy context. Firstly, it briefly relates heat pipe design for fuel cells application, adsorption cooling and heating (including solar cooling), snow melting, ground heating and cooling. Finally it outlines different heat pipe designs based on nano fluid and nano coating application. The combination fuel cell and solid sorption transformer is shown and discussed.

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Why is it important?

Actually fuel cells are considered as modern source of heat and power generation and have various advantages for residential applications, such as low emissions, low noise level, high potential efficiency (Amir Faghri, Zhen Guo, 2005; P.T Garrity, J.F. Klausner, R. Mei, 2007; M. G. Izenson, and R. W. Hill 2004; S. Rogg, et al, 2003). Thermally activated adsorption heat pumping technology is energy efficient method for converting low-temperature waste heat into useful mean such as heating storage, cooling, freezing and desalination based on the evaporation/condensation process (B.B. Saha, A. Akisawa, T. Kashiwagi, 2001; Z. Tamainot-Telto, S. J. Metcalf, R.E. Critoph, 2010). Combination fuel cell + solid sorption transformer significantly increase the fuel cell efficiency (L.Vasiliev, 2007). The increasing efficiency of new power sources (co-generation, tri-generation systems, fuel cells, photovoltaic systems) is considered to be performed with the help of solid sorption heat pumps, refrigerators, accumulators of the heat and cold, heat transformers, fuel gas (natural gas and hydrogen) storage systems and efficient heat exchangers (Advances in Adsorption Technologies, ed. B. Saha, and K.S. Ng, 2010. Singapore: Nova Science Publishers). This nature friendly technology has been widely discussed since the last decade and some adsorption machines are already in the market (Wang and Oliveira 2006, Jakob and Kohlenbach 2010). Fuel cells, solid sorption transformers with complex compound sorbent material (active carbon fibre and micro/nano chemical particles on the surface of the fibre) now are considered together with heat pipe thermal control system. Recently fuel cell development, modeling and performance analysis has obtained much attention due to their potential for distributed power which is a critical issue for energy security and environmental protection (US Patent 6,355,368 B1, Mar.12, 2002; US Patent 20030141045, July 31, 2003; US Patent 6,817,097 B2, Nov. 16, 2004; US Patent 2005/0026015 A1, Feb. 3, 2005). A generalize diagram of a tri-generation system, based of the fuel cell application as a source of power in combination with low-grade heat and solid sorption heat pump and heat pipe heat exchangers is shown on Fig. 6.1. Low temperature power systems are generally significantly less expensive to build than high temperature ones.

Perspectives

Heat pipes are very flexible systems with regards to the effective thermal control of different heat loaded devices. Their heat transfer coefficient in the evaporator and condenser zones is 103 - 105 W/m2K, heat pipe thermal resistance is 0.01-0.03 K/W, therefore lead to smaller area and mass of heat exchangers. Heat pipes and thermosyphons are easily integrated into fuel cells, simple and multistage adsorption systems and ensure the heat and mass recovery from one stage to another. In this chapter different types of heat pipes are considered, including miniature and micro heat pipes for fuel cells, electronic components cooling and space two-phase thermal control systems, loop heat pipes, pulsating heat pipes and sorption heat pipes. Vapordynamic thermosyphons are suggested as the novelty for modern heat exchangers and air-conditioning systems. The new stream in the heat pipe technology is related also with nano fluid application and nano coating of the heat pipe evaporators, You M., Kim J.H, Kim K.H., 2003; Das S.K, Putra N., Roetzel, W., 2003. The generation of engineered nanomaterials represents a major breakthrough in material science and nanotechnology-based materials. Recent advances in nanotechnology have allowed development of a new nanofluids (NF), to describe liquid suspensions containing nanoparticles (NP) with thermal conductivities, orders of magnitudes higher than the base liquids, and with sizes significantly smaller than 100 nm, Vassallo, P., Kumar, R., Amico, S. 2004; Bang, I.C, Chang, S.H., 2005. Considering the rapid increase in energy demand worldwide, intensifying heat transfer processes and reducing energy losses due to ineffective use have become increasingly important task (Wen, D., Ding, Y. 2005). NFs and NPs have some interest to be applied as the means to increase the heat transfer intensity in heat pipes and thermosyphons, Mitrovic. J.,2006; Vasiliev L.L.,et al, 2004. NFs are very stable due to the small size and volume fraction of NPs needed for heat transfer enhancement. When the NPs are properly dispersed, NFs can offer numerous benefits besides the anomalously high effective thermal conductivity, such as improved heat transfer and stability, microchannel cooling without clogging, the possibility of miniaturizing systems scaling, or reduction in pumping power, among others, Vasiliev, L., Lapotko, D., et al.,2007. Thus, NFs have a wide range of industrial, engineering, and medical applications in fields ranging from transportation, micromechanics, heating, ventilating and air conditioning systems, biomolecules trapping, or enhanced drug delivery. Nanostructures and nanomaterials are getting more and more commonly used in various industrial sectors like cosmetics, aerospace, communication and computer electronics. Nanocoatings (NCs) have a grand potential to increase the wettability and heat transfer intensity in small size heat transfer devices as mini heat pipes, miniature heat exchangers. In addition to the associated technological problems, there are plenty of unresolved scientific issues that need to be properly addressed. Nucleate boiling of NFs is the subject of numerous studies, which cover questions related with formation of bubble nuclei in metastable liquids and on the micro/nano porous coatings. Some further detailed investigations are necessary to understand the phenomena of boiling of NFs. In particular experiments are lacking on the effects of NPs material and heat loaded surface on the boiling heat transfer from horizontal smooth tubes. The general conclusion is that micro and nano particles on the heat loaded surface initiate a bubble generation and enhance two phase heat transfer, You M., Kim J.H, Kim K.H. 2003; Das S.K, Putra N., Roetzel, W. 2003. Some experimental investigations have revealed that NFs have remarkably higher thermal conductivity and greater heat transfer characteristics than conventional pure fluids, Vassallo, P., Kumar, R., Amico, S. 2004; Bang, I.C, Chang, S.H. 2005. Till now all above mentioned experiments with nanofluids are performed in conventional heat pipes, Wen, D., Ding, Y. 2005.

Professor, Dr.Sci. Leonard L.eonidovich Vasiliev
Luikov Institute

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This page is a summary of: Heat Pipes and Nanotechnologies, January 2016, Taylor & Francis,
DOI: 10.1201/b19261-9.
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