What is it about?

High-performance polymers and composites are well-known for many significant ways. As well, their exceptional chemical resistance to all kinds of acids makes them suitable for a broad range of applications like insulation and industrial carriage equipment. In the present work, an interesting diacid monomer, containing salicylic acid segment, was successfully synthesized in high yield and purity. This compound was used as condensation monomer in combination with 4,4'-oxydibenzene-1,2-diamine to yield novel poly(benzimidazole-imide) (PBII). Then it was used as matrix for fabrication of amino salicylic acid (ASA)-functionalized multi-walled carbon nanotube (MWCNT-ASA)/PBII composites with MWCNT-ASA loadings of 1, 2, and 5 wt%.

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Why is it important?

These characteristics indicated that the salicylic acid segments in the polymer backbone have played an important role in the improvement of solubility and thermal resistance of polymer. The thermal stability of the films containing MWCNTs-ASA was improved as the nanotube content increased from 1 to 5 wt% due to the improved interfacial interaction between the PBII matrix and MWCNTs-ASA. Also, the mechanical properties of the composite films were significantly improved with the introduction of small amount of MWCNTs-ASA.

Perspectives

This study demonstrated that good dispersion, morphology, and appropriate adhesion are key parameters to producing high performance reinforced composites. Functionalized nanotubes lead to better dispersion and strong interaction in the polymer matrix and provide great reinforcement to polymer composites. The success of this research could lead to a thin, uniform, and lightweight reinforced film, which has great application in aerospace, microelectronics, and nanotechnology.

Dr Amin Zadehnazari
Petroleum University of Technology, Ahwaz, Iran

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This page is a summary of: Investigation of thermal and tensile properties of poly(benzimidazole-imide) composites incorporating salicylic acid–functionalized multiwalled carbon nanotubes, High Performance Polymers, December 2016, SAGE Publications,
DOI: 10.1177/0954008316684933.
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