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Why is it important?
Weak pi-pi interactions can control conformation of flexible molecule.
Perspectives
Attempt has been made to demonstrate utility of butylidine linker, closely related with propylene linker, for studying intramolecular pi-pi interactions for formation of folded conformation (U-motif) in three closely related purine type heterocycles.
kamlakar avasthi
Central Drug Research Institute
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This page is a summary of: Folded conformations due to arene interactions in dissymmetric and symmetric butylidene-linker models based on pyrazolo[3,4-d]pyrimidine, purine and 7-deazapurine, Acta Crystallographica Section C Structural Chemistry, May 2014, International Union of Crystallography,
DOI: 10.1107/s2053229614009449.
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