What is it about?

The article investigates the synthesis and optical properties of KSrY1–xErx(BO3)2 phosphors, focusing on their near-infrared emission capabilities. These materials were synthesized using solid-state methods and characterized for their emission of Er3+ electron transition within the 1529–1549 nm range. The study aims to explore the potential of these phosphors in telecommunications, especially for optical signal amplification. A notable finding is the robust emission observed at a 0.4Y/0.6Er ratio, which is suitable for amplifying 1.5 µm laser radiation through end-pumping with a 976 nm diode. The article also reports on polymorphic transitions identified between 580–600°C and highlights that luminescence quenching increases with Er concentration above x = 0.6. The study concludes that the dominant quenching process is due to electronic multipole interactions rather than exchange interactions. This research contributes to the understanding of KSrR(BO3)2-type compounds in optical applications.

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Why is it important?

This study investigates the synthesis and optical properties of KSrY1–xErx(BO3)2 phosphors, which are significant due to their potential application in telecommunications for amplifying optical signals within the critical near-infrared range. The research addresses the challenge of integrating active media with pumping devices in optical systems, emphasizing the role of Er3+ ions in enhancing signal amplification through their distinct emission properties. The study's findings contribute to the understanding of material properties that are essential for the development of more efficient telecommunications technologies. Key Takeaways: 1. The study demonstrates the synthesis of novel KSrY1–xErx(BO3)2 phosphors that emit near-infrared radiation, with a strong emission detected in the 1529–1549 nm range, crucial for telecommunications applications. 2. Findings reveal that the KSrY0.4Er0.6(BO3)2 compound provides optimal luminescence intensity, making it suitable for amplifying 1.5 µm laser radiation via a 976 nm diode, highlighting its potential as an active medium in optical systems. 3. The research identifies polymorphic transitions occurring at 580–600°C in the KSrR(BO3)2-type compounds, providing insights into their structural and thermal stability, which are vital for practical applications in optics.

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This page is a summary of: Growth, crystal structure and IR luminescence of KSrY1–x Er x (BO3)2, Acta Crystallographica Section B Structural Science Crystal Engineering and Materials, March 2024, International Union of Crystallography,
DOI: 10.1107/s205252062400177x.
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