What is it about?
We show the conditions that are required for borotropic shifting to occur in lanthanide complexes, we show examples of the shift and also our characterisation of the solid state structures we obtained. We also provide NMR data on the systems and rationalise how the borotropic shift can occur.
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Why is it important?
We exemplify the conditions that result in borotropic shifting in scorpionate ligands.
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This page is a summary of: Borotropic shifting of the [hydrotris(2′-furyl)pyrazol-1-yl]borate ligand in high-coordinate lanthanide complexes, Acta Crystallographica Section C Structural Chemistry, April 2024, International Union of Crystallography,
DOI: 10.1107/s2053229624003115.
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