What is it about?
The relationship among molecular structures, hyperpolarizabilities and crystal structures of cyclobutenediones were discussed to predict optical non-linearity and its stereoscopic conformation in the crystal according to the two level model.
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Why is it important?
The characterization of crystal will be decided by nature of the hydrogen bond energy and stereoscopic confirmation more than molecule dipole-dipole interaction.
Perspectives
molecule with second-order non-linearity tend to make asymmetric. But, hydrogen bond control to arrange the molecule.
Dr Takao Tomono
Keio Gijuku Daigaku
Read the Original
This page is a summary of: Relationship Among Molecular Strctures, Molecular Hyperpolarizabilities and Crystal Structures of Phenylcyclobutenediones, Molecular Crystals and Liquid Crystals Science and Technology Section A Molecular Crystals and Liquid Crystals, March 1997, Taylor & Francis,
DOI: 10.1080/10587259708032295.
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