What is it about?
Gamma-irradiated single crystals of [N(PPh3)2][W(CO)4H{P(OMe)3}] contain an anisotropic EPR signal which exhibits hyperfine coupling to a single 31P nucleus. We used aligned crystals and single crystal EPR to examine back-bonding in such organometallic radicals.
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Why is it important?
Comparison with other 31P hyperfine measurements suggests that EPR provides a good indication of the efficiency of back-bonding in such organometallic radicals.
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This page is a summary of: Electron paramagnetic resonance study of the [W(CO)4{P(OMe)3}]−radical anion trapped in a single crystal of [N(PPh3)2][W(CO)4H{P(OMe)3}], Journal of the Chemical Society Dalton Transactions, January 1990, Royal Society of Chemistry,
DOI: 10.1039/dt9900003655.
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