What is it about?
Synthesis and investigation (X-ray analysis, electrochemistry, NMR, UV/vis and luminescence spectroscopy) of compounds in which oligothienyl (two and three thienyl, Th) rings are bonded to catenated Si and Ge fragments in terminal or internal manner, are studied in details.
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Why is it important?
The first oligothienyl oligogermanes were obtained, the "structure-property" relationships were found (nature of the metal, number of the atoms and thienyl rings vs. optical properties).
Perspectives
These results are important for construction of optical devices.
Kirill Zaitsev
Moscow State University
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This page is a summary of: Oligothienyl catenated germanes and silanes: synthesis, structure, and properties, Dalton Transactions, January 2018, Royal Society of Chemistry,
DOI: 10.1039/c8dt00256h.
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