What is it about?

Fe2(MoO4)3/MoO3 heterostructured microrods had been synthesized by a simple calcination method in which the crystallization event of Fe2(MoO4)3 grew on the backbone of MoO3 single crystalline microrods. The size and the amount of Fe2(MoO4)3 could be tuned by changing the molar ratio of Fe source and Mo source. The Fe2(MoO4)3/MoO3 heterostructured microrods showed efficient photocatalytic activity for the degradation of methylene blue under visible light irradiation. Kinetic studies using radical scavenger technologies suggested that photogenerated holes were the dominant photooxidants. The photocatalytic activity of Fe2(MoO4)3/MoO3 heterostructured microrods decreased with increasing molar ratio of Fe source and Mo source because the surface area of Fe2(MoO4)3 particles decreased with increasing molar ratio of Fe source and Mo source.

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Why is it important?

The investigation concerning the gas sensing of the Fe2(MoO4)3/MoO3 heterostructured catalyst had been reported recently. However, work concerning the photocatalytic activity of the Fe2(MoO4)3/MoO3 heterostructured catalyst has not yet been reported. Therefore, there is a need to investigate the photocatalytic activity of the Fe2(MoO4)3/MoO3 heterostructured photocatalyst.

Perspectives

In this work, the Fe2(MoO4)3/MoO3 heterostructured microrods were controllably synthesized using a facile calcination method. MoO3 microrods formed the backbone material, and the size and the amount of Fe2(MoO4)3 could be tuned bychanging the molar ratio of Fe source andMo source. In addition, the photocatalytic activity and the degradation mechanism of Fe2(MoO4)3/MoO3 heterostructured microrods in the degradation of methylene blue (MB) under visible light irradiation were investigated in detail. The aim of this research was to enrich the available methods for the preparation of novel heterogeneous catalysts with high photocatalytic activity.

Dr Di Li

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This page is a summary of: Synthesis of Fe2(MoO4)3/MoO3 heterostructured microrods and photocatalytic performances, New Journal of Chemistry, January 2016, Royal Society of Chemistry,
DOI: 10.1039/c5nj03227j.
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