What is it about?
N[1,3]-sigmatropic shift is a crucial process for the formation of semidines in the benzidine rearrangement
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Why is it important?
Formation mechanism on the o- and p-semidines in benzidine rearrangement has been existed for more than one century. Our proposed N[1,3]-sigmatropic shift rationallized the formation mechanism in the benzidine rearrangement experimentally and theoretically.
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This page is a summary of: N[1,3]-sigmatropic shift in the benzidine rearrangement: experimental and theoretical investigation, Organic & Biomolecular Chemistry, January 2014, Royal Society of Chemistry,
DOI: 10.1039/c4ob00080c.
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