What is it about?
The molecular porous zirconium-organic material shows highly selective CO2 adsorption, high thermal stability, reversible hydration, facile ligand exchanges, and exclusive dimerization of phenylacetylene.
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Why is it important?
The reported molecular porous material is thermally stable to over 400 deg C and exhibits differential CO2 gas adsorption properties. The material also shows reversible dehydration/rehydration properties as well as facile ligand exchange reactions. An unconventional dimerization product, 1-phenylnaphthalene, is exclusively obtained from the reaction between the zirconium-organic compound and excess phenylacetylene.
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This page is a summary of: A molecular porous zirconium–organic material exhibiting highly selective CO2 adsorption, high thermal stability, reversible hydration, facile ligand exchange and exclusive dimerization of phenylacetylene, CrystEngComm, January 2014, Royal Society of Chemistry,
DOI: 10.1039/c4ce00253a.
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