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Two modes of coordinations of phospha-alkynes were shown in this paper ie via the lone pair at the phosphorus atom and via the pi-system of the P-C-P-C diphospha-cyclobutadiene ring.
Prof Mohd Jamil Maah
University of Malaya
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This page is a summary of: Use of phospha-alkynes in metal aggregate synthesis. Crystal and molecular structure of the remarkable hexa-rhodium complex [Rh2Cl2{Rh(η5-C5H5)(P2C2But2)..., Journal of the Chemical Society Chemical Communications, January 1987, Royal Society of Chemistry,
DOI: 10.1039/c39870000844.
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