What is it about?

By taking advantage of a metals ability to catalyse multiple mechanistically distinct processes, multifaceted catalysis, this work enable to direct synthesis of important compounds in a clean and efficient manner.

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Why is it important?

First multifaceted catalysis approach to the regioselective synthesis of highly substituted pyrroles from oximes and activated alkynes. This mild and flexible method takes advantage of a gold catalysts ability to activate multiple steps of the process, thus utilising the metal more efficiently.

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This page is a summary of: Gold-catalysed rearrangement of O-vinyl oximes for the synthesis of highly substituted pyrroles, Chemical Communications, January 2011, Royal Society of Chemistry,
DOI: 10.1039/c0cc04372a.
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