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Surprising diversity of non-classical silicon–hydrogen interactions in half-sandwich complexes of Nb and Ta: M–H ⋯ Si–Cl interligand hypervalent interaction (IHI) versus stretched and unstretched β-Si–H⋯M agostic bonding†
Georgii I. Nikonov, Philip Mountford, Stanislav K. Ignatov, Jennifer C. Green, Michael A. Leech, Lyudmila G. Kuzmina, Alexei G. Razuvaev, Nicholas H. Rees, Alexander J. Blake, Judith A. K. Howard, Dmitry A. Lemenovskii
Journal of the Chemical Society Dalton Transactions, January 2001, Royal Society of Chemistry
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