What is it about?
The catalytic performance of the novel framework {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n was tested in the oxidation of alkenes and benzylic hydrocarbons, using tert-butyl hydroperoxide (TBHP) and molecular oxygen (O2) as oxidants. Excellent conversions were obtained with O2 under solvent-free conditions, in the absence of a co-catalyst, for cyclohexene (95%) and for cumene (91%).
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Why is it important?
The first catalytic frameworks that contain lutetium used as catalyst in oxidation reactions.
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This page is a summary of: {[Cu3Lu2(ODA)6(H2O)6]·10H2O}n: the first heterometallic framework based on copper(ii)/lutetium(iii) for the catalytic oxidation of olefins and aromatic b..., Catalysis Science & Technology, January 2017, Royal Society of Chemistry,
DOI: 10.1039/c7cy01385j.
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