What is it about?
Sterically congested tetraarylpyrenes exhibited emission in both solution and the solid-state. The monocationic species of pyrene 1 could be isolated because of the reasonably protected system.
Featured Image
Photo by Bill Oxford on Unsplash
Why is it important?
The aromaticity relocates from the biphenyl part to the naphthalene unit upon two-electron oxidation.
Perspectives
Read the Original
This page is a summary of: A kinetically protected pyrene: molecular design, bright blue emission in the crystalline state and aromaticity relocation in its dicationic species, Chemical Communications, January 2014, Royal Society of Chemistry,
DOI: 10.1039/c4cc03645j.
You can read the full text:
Resources
Contributors
The following have contributed to this page