What is it about?
Exo-dig cyclization promoted by base to synthesize 1,4-oxazines and oxazepines.
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Why is it important?
a solvent free reaction to synthesis six member and seven member rings.
Perspectives
It is a communication to represent a novel way to construct complex molecules fro simple starting material with chirality.
Dr Jaya Kishore Vandavasi
Kaohsiung Medical University
Read the Original
This page is a summary of: A New Approach to 1,4-Oxazines and 1,4-Oxazepines via Base-Promoted Exo Mode Cyclization of Alkynyl Alcohols: Mechanism and DFT Studies, Organic Letters, June 2012, American Chemical Society (ACS),
DOI: 10.1021/ol301219c.
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