What is it about?
The reason to explain why certain catalysts possess a high catalytic activity than other ones has been suggested in terms of a local reactivity descriptor which takes into account the electronic effect exerted by a substituent in the catalyst.
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Perspectives
The catalytic activity might be estimated by combining this local reactivity descriptor along with another one designed to measure the steric hindrance.
Dr Jorge I. Martínez-Araya
UNAB
Read the Original
This page is a summary of: Explaining Some Anomalies in Catalytic Activity Values in Some Zirconocene Methyl Cations: Local Hyper-Softness, The Journal of Physical Chemistry C, November 2013, American Chemical Society (ACS),
DOI: 10.1021/jp402808k.
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