What is it about?
A very energetic and a very reactive antiaromatic 1H-Diazirine generated and its unique vibrational signature ("fingerprint") characterized.
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Why is it important?
1H-diazirine is captured for the first time as a key intermediate in the photochemistry of nitrile imine
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This page is a summary of: Generation and Characterization of a 4π-Electron Three-Membered Ring 1H-Diazirine: An Elusive Intermediate in Nitrile Imine–Carbodiimide Isomerization, The Journal of Organic Chemistry, March 2014, American Chemical Society (ACS),
DOI: 10.1021/jo402744f.
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